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By Tianming Sun, Gabriella Tranell, Ragnhild E. Aune, Mark William Kennedy

Rare Earth Elements (REEs) are critical for the production of many advanced materials and products. Mining and primary production of REEs are generally associated with significant environmental impacts. By recovery of REEs from secondary sources, through recycling or as a byproduct, the adverse environmental impacts may be partly avoided. In the present study apatite concentrate originating from iron ore beneficiation done by LKAB in Kiruna, Sweden, is explored as a possible source for REEs. The composition and distribution of the REEs within the concentrates are studied using ICP-MS, XRD and SEM-EDS/EPMA, as well as the melting point and heat of fusion using DTA-TGA-MS. The behavior of the material during melting has also been studied through wetting and slag saturation experiments. The overall aim of the study is to evaluate the implications for future smelting experiments aimed at concentration and recovery of the REEs.

Jan 1, 2015

By C. A. F. Pinto

In the present work compared flotation kinetics of apatite with four different collectors was established. Sodium oleate and rice bra~ oil were used to represent conventional collectors. The new collectors included a sulfosuccinate and a sulfosuccinamate. It was observed that the collection ability of each reagent was very dependent upon the mineral size ranges. The results-were analyzed in terms of size-by-size recovery curves. Flotation rates were also very dependent on size ranges of the mineral particles. One of the new collectors displayed higher flotation rates for coarser particles than the other reagents tested. Synergetic effects were also apparent when a conventional collector was mixed to a new collector.

Jan 1, 1991

By Å Sandström

Loussavaara-KiirunavaaraAB?s (LKAB) iron ore mine, Kiirunavaara, is of magnetite type and associated with apatite, a calcium phosphate mineral. Rare earth elements (REE) have been found in connection with the apatite but also in other minerals. An apatite concentrate was produced by flotation, in order to investigate the possibilities to extract REE from the apatite by hydrometallurgical means. The content of rare earth elements calculated as oxides (REO) was 0.44% in the concentrate. Initially, leaching was done with large excess of sulfuric acid, hydrochloric acid, and nitric acid to study the REE solubility with different acids. In sulfuric acid, the leaching recoveries of the different REE varied between 35% and 69%. The reasons for the relative low recoveries, were that the rare earth elements precipitated together with huge amounts of gypsum, that was formed during leaching. However, both hydrochloric- and nitric acid gave almost complete extraction of the REE into solution. Analysis of the small leaching residue obtained, revealed, that mainly the light REE remained in the residue indicating that a small part of the light REE were present in the concentrate, in some acid, insoluble mineral other than apatite. With the aim to separate the REE from the phosphoric acid, the solutions from hydrochloric- and nitric acid leaching were neutralized to a pH of approximately 2 with ammonia. During neutralization, REE were precipitated as phosphates with good recoveries and a concentrate of 10.5% REO suitable for further upgrading was obtained, while the remaining solution can be used for fertilizer production. In further solvent extraction studies, it was shown, that after re-dissolution the REE could be effectively extracted by Cyanex 923, thus allowing for purification from calcium and phosphate ions. The REE were finally stripped from the organic phase and a REE nitrate solution was produced. Keywords: apatite, rare earth elements, REE, leaching, solvent extraction, cyanex 923

Sep 1, 2012

By O. Martinsson

The Kiruna area is an important mining province in northern Sweden, which is dominated by Fe- and Cu-Au deposits. Economically most important for the region, are the apatite iron ores with an annual production of c. 43 M ton of crude Fe-ore and a total production of more than 2000 M ton of ore the last 100 years. The apatite iron ores in the Kiruna area are dominated by either Magnetite or Haematite and contain varying amounts of apatite giving them a content of Fe and P, which varies between 30-70 % and 0.05-5 %, respectively. A typical geochemical feature of the ores is the strong enrichment of REE that is caused by a high content of REE in apatite and the occurrence of Allanite and Monazite containing 22.4 and 69.8 wt% REO, respectively. At Kiirunavaara, the content of REE in apatite varies between 0.07 to 1.57 wt% REO with a dominance for the light rare earths. The variation in REE-content of apatite depending on textural and paragenetic aspects is not known but apatite grains may display a strong LREE-depletion due to hydrothermal alteration. Monazite occurs as rod-shaped or tabular inclusions in apatite and is suggested, to have formed in response to hydrothermal alteration of apatite after the emplacement of the ore. Inclusions are mainly found in the central part of apatite grains occurring in veins and schliren, while they are rare in apatite occurring disseminated in the ore. Monazite also occurs as larger grains outside apatite and together with Allanite is found in texturally and paragenetically different settings within the ore. These occurrences of REE-minerals may largely be a product of LREE mobilized by alteration of apatite after the emplacement of the ore. However, REE-minerals including Allanite and Monazite might also have formed directly from late magmatic fluids. Keywords: apatite, monazite, allanite, ree, kiirunavaara, iron ore of kiruna type, mineral chemistry

Sep 1, 2012

By Bertil I. Pålsson

The most common REE containing mineral that is worked today is bastnäsite. It means that mineral processes are adapted to it and that the metallurgical separation techniques for winning of individual REE are adapted to bastnäsite concentrates. For all other deposit types, suitable mineral processing methods and separation technologies need to be adapted and/or developed. Preliminary mineralogical analyses indicate that slightly less than half of the REE in the tailings dumps at LKAB/Kiruna are associated to apatite. The rest is in the minerals monazite (maybe associated to apatite) and allanite. At least allanite is probably not floatable with reagents commonly used for apatite. Mass and element distributions for the tailings sand reveal that very little apatite is present above 300 µm, and that approx. 30 % is below 20 µm. REE does not follow P2O5 completely and are also present in coarser fractions. Flotation results show that the best condition for both apatite and REE winning is pH 9, high collector addition and low dosage of water glass. Under these conditions, the lab-scale flotation gives an apatite concentrate with at least 30 % P2O5 at 70 % recovery. REE follows apatite in the cleaner steps but only partly. Its recovery is approx. half compared with apatite. The reason for the low REE recovery is likely to be that REE to a large extent is trapped in non-winnable minerals, especially allanite. The REE grades in the concentrate are expected to be in the range 3000 ? 4500 g/ton. Keywords: flotation, REE, apatite, monazite, allanite

Sep 1, 2012

By M M. M LT Tassinari, A B. Braz, L M. SantÆAgostino, C Ulsen

Several mineral resources have been recognised to alkaline igneous rocks. In general, these mineralisations present low P grades, so a complex concentration process is required to achieve commercial grade concentrates. This process is guided not only by the ore characteristics, such as apatite grain size and liberation degree, gangue minerals and slimes content, but also by different apatite varieties, iron oxi-hydroxide surface coating and roughness. The main techniques applied to apatite and phosphate ore characterisation, such as optical microscopy, cathodoluminescence (CL) microscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), surface techniques and magnetic separation are discussed, aiming to evaluate distinct apatite varieties and their technological behaviour.

Jan 1, 2008

By T. Banerjee, Y. Dumais, R. Lemire

"Agnico Eagle LaRonde produces over 300,000 ounces of gold annually, along with silver, zinc and copper by-products. The LaRonde plant consists of a conventional SAG and Ball mill circuit, followed by flotation. Load management is imperative for maintaining stability in grind size and ensuring consistency of the flotation feed. In flotation, the mass pull profiles of the cells and reagent dosage rates need to be managed to maximize recovery, while maintaining product quality. This is achieved by controlling the air, level and reagent addition set-points across the circuit. However, disturbances such as feed size distribution, ore hardness and mineralogy make it challenging to maintain efficient control using traditional control techniques. LaRonde therefore worked to develop a progressive control strategy, targeting stability and optimization. This started with a year-long instrumentation upgrade campaign, focusing on optimizing the performance and reliability of plant-wide instrumentation. The process was then optimized, leveraging AwaRE advanced controllers running in closed loop with PARC modules embedded within the PLC. The installation of 8 PFC cameras in flotation changed the flotation operation from a level and air control based strategy, to one that controls mass pull. This new control philosophy has allowed the plant to effectively manage mill load, improving grind size and providing increased throughput with better flotation performance.INTRODUCTION Background Since 2015, Agnico Eagle LaRonde has been conducting an optimization campaign to maximise the performance of plant assets leveraging instrumentation and control. The grinding and copper flotation circuits were identified as the areas having the greatest opportunities and value proposition for advanced control. A disciplined approach was followed to design and implement a progressive control solution to achieve operational excellence."

Jan 1, 2018

By Kerry Spickelmier

Editor's note: information for this feature was taken from the published APCOM proceedings. Computer trends, with special focus on the reasons for computer use, grabbed the lion's share of attention at the 23rd worldwide meeting on the Application of Computers and Operations Research in the Mineral Industry (APCOM 23). However, technical topics did not provide the meeting's sole focus. The last-minute inability of certain former communist countries to fund the travels of a few scheduled speakers was a reminder that science does not operate in a void. As with all technical progress, the APCOM presentations raised interesting questions regarding interrelated organizational dynamics and political and socioeconomic issues. Consider US Bureau of Mines (USBM) research to design an expert control systems to "duplicate" an experienced, "good" operator during automated underground roof bolting. In his presentation of the project, Takach, Jr. stressed the importance of preserving the ability to switch from automatic to manual drilling control. From a technical standpoint, this allows the expert system to "learn" from a good operator. As important, he said, is that this flexibility decreases the human operator's sense of being replaced by the machine. The question arises: Which will loom larger in union minds, increased operator safety through remote opera¬tion or the potential for total operator replacement? Like any new product, computer technology relies on marketing to aid its acceptance and use. Consider, too, a decision support system, by Schena and Gochin, for mineral resource management in a developing country. The authors said "the analysis permits the assessment of the overall socioeconomic consequences of mineral prospects and allows incorpo-

Jan 1, 1992

By Alfred Weiss

At the end of the first decade of digital computing in the minerals industry, geostatistics in North America was still in its infancy. This was in contrast with the rest of the world where the technique of kriging was already widely practiced. By the end of the 1970s, there was increasing awareness among practitioners of its potential. But it was not until the late 1980s that geostatistics was universally applied and accepted. This was due, in large measure, to contributors at Applications of Computers and Operations Research in the Minerals Industry (APCOM) symposia. Such an evolution in new computer methods could again be observed at APCOM 26.

Jan 1, 1996

The 26th international APCOM symposium, hosted by The Pennsylvania State University, was held Sept. 16 to 20, 1996 in University Park, PA. Conducted about every 18 months throughout the world, APCOM symposia focus on the Application of Computers and Operations Research in the Mineral Industry. The APCOM International Council is the governing body of the symposia and determines the symposium’s locations and sponsorships. This group is composed of the nine permanent (voting) members. They include the University of Arizona, Colorado School of Mines, Pennsylvania State University, Society for Mining, Metallurgy and Exploration, Inc., Canadian Institute of Mining, Metallurgy and Petroleum, South African Institute of Mining and Metallurgy, Technical University of Berlin, Institution of Mining and Metallurgy and Australasian Institute of Mining and Metallurgy. The three nonvoting members are Moscow Mining Institute, China Institute of Mining and Rudarski Mining Institute of Slovenia.

Jan 1, 1996

By Jorge Madias

Durante la laminación de barras y alambrones para construcción civil; perfiles y ángulos estructurales y barras redondas y hexagonales de aceros de corte libre puede presentarse la apertura de la punta o la cola y el estallido central, con la consiguiente parada y caída de la productividad, y pérdida de rendimiento metálico. En este trabajo se analizan las diversas causas que confluyen para que este problema ocurra. Se analiza la influencia de posibles defectos en las palanquillas, las características del corte de las mismas y otros problemas de calidad. Se revisa el rol del precalentamiento previo a la laminación, la refrigeración de los cilindros, el diseño de pasadas y la respuesta del material en función de su ductilidad. Se presentan diversos casos industriales para ilustrar las diferentes razones detrás del problema de la apertura de punta.

Jul 30, 2018

By José Arce

El presente texto señala la importancia de los métodos geofísicos en la exploración de yacimientos minerales del Perú. De acuerdo a las diferentes situaciones geológicas se elige el método más adecuado. Para el caso de vetas de gran buzamiento con sulfuros metálicos se utiliza el método electromagnético autopotencial, cuyo accesorio es la resistividad; para el caso de Mantos de bajo ángulo o bolsonadas con sulfuros metálicos, se cuenta con el método electromagnético y para la estructura de sulfuros diseminados Placeres Hierro, pirrotita, cobalto, níquel, se emplea la polarización inducida y el electromagnético, cuyo accesorio es la resistividad y gravimétrica.

Jan 1, 1972

By José María Lezcano, Diego Urquiaga, Pedro Delvasto, Marcos Garayar

La extracción de minerales ricos en sulfuros metálicos tiene el inconveniente de generar drenajes ácidos (AMD), los cuales causan severos impactos en los ecosistemas acuáticos, el suelo y el recurso hídrico. Como posibilidad de remediación (alcalinización) de estos pasivos, en el presente trabajo se propone el uso de coproductos férricos oxidados (CFO). Luego de presentar las características de un tipo de CFO específico, se muestran los resultados —a escala de laboratorio—sobre la respuesta alcalina del mismo, y se discuten las implicancias de estos hallazgos para el tratamiento de los AMD.

Nov 30, 2020

By Raymond E. Riethmann

El clasificador de espiral fue diseñado originalmente para circuitos cerrados de molienda. Desde entonces se ha aplicado con éxito a otros trabajos de clasificaci6n donde se necesita realizar un corte de dos productos. Inherentemente a las cualidades especiales de este cla- sificador está especialmente preparado para: clasificar, lavar, o agotar materiales tales como minerales, roca fosfática, arenas, carbbn, conchas de ostra y sales fosfáticas. Presentamos ahora las características de operation, flexibilidad de diseiio y líneas maestras para una apropiada aplicación.

Jan 1, 1982

By Zenón Quispe

El presente trabajo describe la importancia de la aplicación de técnicas de análisis de cuencas sedimentarias en la exploración de minerales del área de Cajamarca. Para ello, se determinaron los espesores originales de las Formaciones Chimú, Santa- Carhuaz, Farrat e Inca y los porcentajes de disminución de espesor y con los resultados obtenidos, se diseño y analizó el gráfico de curvas corregidas por descompactación y sin corrección por descompactación. Asímismo, se explica la posible formación de fallas no tectónicas debido a la compactación diferencial y las unidades estratígráficas que comprende el estudio.

Sep 9, 2007

By Jorge Castillo

El presente texto señala el uso del polímero denominado quitosan para el proceso de floculaciòn de pulpas minerales. Dicho biopolímero es un derivado de la quitina proveniente del caparazón de langostinos, el cual es desechado por la industria langostinera peruana. El estudio, se realizó con pulpas de mineral del tipo sulfurado que van desde los 20 hasta los 36 % de sólidos, donde los mejores resultados de floculación se obtuvieron en medio cercanos al neutro y con una concentración de 0,2 % de quitosan y 0,2 % de ácido clorhídrico. En consecuencia, el biopolímero con un floculante industrial produce velocidades similares de sedimentación y menor altura de lodos en la zona de compactación.

Sep 12, 2011

By Hernán Zapata

"El presente trabajo describe el proceso de recuperación del oro y plata en diferentes medios, utilizando un biopolímero o derivado de la quitina proveniente del caparazón de langostinos. La quitina calcárea, después de la celulosa, es el segundo polímero más abundante en el planeta, cuya ventaja estriba en el poder de sorción en la plata y su bajo costo en comparación con el quitosan. El estudio se realizó con soluciones estandarizadasde oro y plata en medio ácido y medio básico, éste último conteniendo además cianuro en solución."

Sep 14, 2009

By Luis Haro Chávez

La bioingeniería es una aplicación combinada de las prácticas de ingenierías y principios ecológicos que diseña y construye sistemas vivos (plantas) y materiales inertes que controlan y protege el suelo de la erosión. Asimismo, la vegetación es un mecanismo de defensa que produce la naturaleza para cuidar el río, generando estabilidad del sub-suelo contra la erosión. Por ello, el presente trabajo describe el uso de dicha disciplina por la Compañía Minera Poderosa en el control y ejecución de planes referidos a la inestabilidad de taludes, defensas ribereñas en depósitos de relaves, desmonte, control de erosión en laderas, rehabilitación de carreteras y otros que ha significado mejoras en la estabilidad, costo y seguridad de estas estructuras con un mínimo impacto en el ambiente.

Sep 12, 2005

By J. M. Minguet

El cálculo de investigación de la mina tiene por objetivo investigar los procedimientos necesarios para que por determinadas galerías (generalmente talleres) circule un caudal de aire suficiente para hacer posible el trabajo en dichos puntos. Sin embargo, los cálculos de redes de ventilación se limitan a los análisis de redes previamente establecidas por métodos matemáticos que no pueden ser utilizados en pequeños ordenadores. En ese sentido, el presente texto señala las aplicaciónes del nuevo algoritmo matemático aplicable al cálculo de redes por ventilación de minas.

Sep 1, 1975

By . Jaime G Tapia Aguirre

La Unidad Minera Rosaura del Grupo Glencore fue considerada la mina subterránea más segura del país durante los años 2005, 2006 y 2007. Sin embargo, cuando el Grupo Glencore adquirió la concesión de Rosaura, el panorama minero era de una mina marginal, de bajas leyes. Por esta razón, el único metodo a ejecutar para hacer de Rosaura una mina rentable era el de utilizar un método masivo. Em ese semtido, el presente texto señala la operación de mina cone el análisis y conocimiento de causa raíz en la prevención de caída de roca.

Sep 12, 2011