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The peak in Sulphur price late 2008 caused again intensified investigation into the decomposition of sulphates and spend acid. One option is the recycling of sulphur from spend acid, which already started more than 40 years ago in the field of spend acid from organic processes in refineries and acrylic glass manufacturing. Since this acid couldn't be neutralized and discarded due to high organic contents, another source of SO2 to produce sulfuric acid is the decomposition of metal sulfates. The decomposition of metal sulfates was investigated at the next peak in Sulphur price in the 80?s. The first major scale pilot tests and studies of gypsum decomposition were carried out for clients in Florida. The decomposition of gypsum was quite often mainly influenced by the strategic decision of some countries to get own and independent acid production. In other cases the industry doesn?t have enough space to dump the gypsum. Therefore the company was also forced to convert the gypsum into ?saleable? products to avoid these residues. Other projects were made for the recycling of iron-sulfates from the pigment industry. The motivations for these projects were not only given by acid price. For the German pigment industry it was no longer permitted in the 80?s to dump the iron sulphate residues into the sea. These regulations forced the industry to develop new technology, which allows converting of the FeSO4-residues into iron oxide and acid. Therefore economical and mainly environmental factors influenced the decision of the companies to develop and to build these plants. Beside the above mention iron- and calcium-sulphates many other process exist, which produce metal sulphates as an intermediate product. These cases are not forced by environmental or strategic factors. In cases like Ni, Co or Mn-decomposition the main product of the plant is treated in the decomposition plant and later on used as ferrous-alloys. These final products are higher in price compared to e.g. CaO, which exclude the high-energy consumption for the endothermic chemical decomposition reaction. The reaction of SO2 generation based on acid or sulfate decomposition takes place in the range of 1000°C. The energy demand of the endothermic reaction is considerable and leads due to the high fuel-combustion off-gas stream to a diluted SO2 gas. Energy prices are usually increasing at the same time like sulphur. Sulphuric Acid based on decomposition is therefore more expensive than as acid based on sulphur combustion. The paper describes fluid bed technology and possible process concepts for decomposition plants. Additionally the thermodynamic background of the decomposition process and the main influence factors are provided to receive a better understanding of this technology.

Jan 1, 2009

The peak in Sulphur price late 2008 caused again intensified investigation into the decomposition of sulphates and spend acid. One option is the recycling of sulphur from spend acid, which already started more than 40 years ago in the field of spend acid from organic processes in refineries and acrylic glass manufacturing. Since this acid couldn't be neutralized and discarded due to high organic contents, another source of SO2 to produce sulfuric acid is the decomposition of metal sulfates. The decomposition of metal sulfates was investigated at the next peak in Sulphur price in the 80?s. The first major scale pilot tests and studies of gypsum decomposition were carried out for clients in Florida. The decomposition of gypsum was quite often mainly influenced by the strategic decision of some countries to get own and independent acid production. In other cases the industry doesn?t have enough space to dump the gypsum. Therefore the company was also forced to convert the gypsum into ?saleable? products to avoid these residues. Other projects were made for the recycling of iron-sulfates from the pigment industry. The motivations for these projects were not only given by acid price. For the German pigment industry it was no longer permitted in the 80?s to dump the iron sulphate residues into the sea. These regulations forced the industry to develop new technology, which allows converting of the FeSO4-residues into iron oxide and acid. Therefore economical and mainly environmental factors influenced the decision of the companies to develop and to build these plants. Beside the above mention iron- and calcium-sulphates many other process exist, which produce metal sulphates as an intermediate product. These cases are not forced by environmental or strategic factors. In cases like Ni, Co or Mn-decomposition the main product of the plant is treated in the decomposition plant and later on used as ferrous-alloys. These final products are higher in price compared to e.g. CaO, which exclude the high-energy consumption for the endothermic chemical decomposition reaction. The reaction of SO2 generation based on acid or sulfate decomposition takes place in the range of 1000°C. The energy demand of the endothermic reaction is considerable and leads due to the high fuel-combustion off-gas stream to a diluted SO2 gas. Energy prices are usually increasing at the same time like sulphur. Sulphuric Acid based on decomposition is therefore more expensive than as acid based on sulphur combustion. The paper describes fluid bed technology and possible process concepts for decomposition plants. Additionally the thermodynamic background of the decomposition process and the main influence factors are provided to receive a better understanding of this technology.

Jan 1, 2009

By A. M. Venter, C. W. Siyasiya, N. K. K. Arthur, M. G. Willemse, D. Marais

Although additive manufacturing is fast gaining traction in the industrial world as a reputable manufacturing technique to complement traditional mechanical machining, it still has problems such as porosity and residual stresses in components that give rise to cracking, distortion, and delamination, which are important issues to resolve in structural load-bearing applications. This research project focused on the characterization of the evolution of residual stresses in Ti-6Al-4V extra-low interstitial (ELI) additive-manufactured test samples. Four square thin-walled tubular samples were deposited on the same baseplate, using the direct energy deposition laser printing process, to different build heights. The residual stresses were analysed in the as-printed condition by the neutron diffraction technique and correlated to qualitative predictions obtained using the ANSYS software suite. Good qualitative agreement between the stress measurements and predictions were observed. Both approaches revealed the existence of large tensile stresses along the laser track direction at the sections that were built last, i.e., centre of the top layers of the samples. This in addition leads to large tensile stresses at the outer edges (corners) which would have the effect of separating the samples from the baseplate should the stresses exceed the yield strength of the material. Such extreme conditions did not occur in this study, but the stresses did lead to significant distortion of the baseplate. In general, the microstructures and spatial elemental mapping revealed a strong correlation between the macro-segregation of elemental V and the distribution of the β-phase in the printed parts.

Feb 6, 2023

A method is proposed for the evaluation of the influence of grout prestressing systems on the support resistance offered by timber packs. It is shown that, in order not to reduce the load-carrying capacity of timber packs, grout prestressing systems need to be at least as stiff as a single timber rise. The method was used to establish strength specifications for the grout prestressing systems to be used under non-seismic and seismic conditions. For non-seismic requirements, the 24-hour grout strength needs to be at least 1,7 MPa, and the 7-day grout strength 4,9 MPa. The investigation showed that the proposed strength specification is realistic in the light of current grout-strength capabilities. For seismic requirements, the grout strength needs to be at least 4 MPa and 8 MPa to prevent extensive damage to the grout during seismic events with a peak velocity of 1m/s 3 m/s respectively.

Jan 1, 1996

The May General Meeting of the Institute was held in Kelvin House, Johannesburg, on 21st May, 1969, at 4.30 p.m. Mr J. K. E. Douglas (Vice-President) was in the Chair. There were also present twenty-two Members, including Messrs F. P. Bath, M. Bareza, A. R. C. Fowler, D. M. Jamieson, C. M. Mavrocordatos, D. G. Maxwell and J. A. Nixon (Council Members), Messrs T. Davidson, G. L. Diering, E. T. Dunstan, D. E. H. French, K. Hodgson, O. A. E. Jackson, A. F. Lee, A. Louw, D. L. Starkey, R. K. Wheeler and M. Youngworth. Four Associate Members including Messrs D. Blair Hook and G. R. Still. One Student Mr N. A. Barcza. Thirteen Visitors, including Messrs S. H. Ash, D. L. G. Bayne, E. Bayne, S. Bell, W. S. Garrett, L. S. Gibbs, R. C. Hamilton, M. Maguire, D. Rose and J. D. van Niekerk. Total Present: Fourty-one. OBITUARY The Vice-President: "It is my sad duty to announce the death of the following member of the Institute: Thomas Spence Haldane, Member, who joined the Institute in 1924 and passed away on 21st December, 1968. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, those present stood and observed silence for a few moments. MINUTES The Vice-President requested that confirmation of the minutes of the previous meeting be held over as they would only be appearing in the Journal of the following month. He also requested that confirmation of the minutes of the 75th Anniversary Meeting be held over. MEMBERSHIP The Vice-President: "I have much pleasure in announcing that the names of the under-mentioned candidates have been published in accordance with By-Law 5.2.2, and Council has elected them to membership of the Institute in the following grades: Members: Gideon Jacob Haumann, Peter John Cumming, Ian Stanley Dudman, Roderick Goldston Murchison. Associate Members: Francois Alwyn Beyers Fouche, Alan Marsh, Johannes Petrus van der Westhuysen, Waldo Edmund Stumpf, Ian Nicholas Ridley. Affiliates: Lutgerus Kolver Jooste, Roger Ainsley Ralph Kebble, Edward John Wainwright, Lewis William Davies. Graduate: Clive Graham Knobbs. MEMBER TRANSFERED TO A HIGHER GRADE From Student to Associate Member: Diethard OUo Eduard Fahrbach. I welcome the newly elected members to the Institute and congratulate the member who has been transferred to a higher grade." (Applause).

By A. V. Z. Brink

This paper describes the development of a monitoring architecture that allows for continuous monitoring of the process of mining, the underground environment, the state of the rockmass and its response to mining. The system is based on an open standard and is non-propriety. It allows for dense sensor arrays in the workplace, wire less communication to the closest power line, and TCP/IP communication to a central server. Continuous monitoring and quantification of the appropriate parameters allows a mine to optimise its mine process; to dynamically access the safety and health risk to people and equipment; and to quantify exposure to potential heath hazards such as dust, gas or noise. Current application examples of continuous monitoring include an application to optimise drilling and blasting thought fragmentation monitoring; an application of wireless sensor network-based monitoring in to provide early detection of potential rockfalls; and a trail to continuously assess the gold grade at the shaft through correlation with radioactivity. It is unlikely that a single monitored parameter will provide adequate knowledge of the assessed risk or even an optimisation approach. Multiple parameters are being combined using cognitive science tools such as Bayesian theory and other statistical methods to improve the accuracy and relevance of, for example, risk quantification. The decision maker is not confronted with massive amounts of raw data but rather with a single knowledge statement such a probability of failure, a human physiological strain index or an optimisation index.

Jan 1, 2008

The May General Meeting of the Institute was held in Kelvin House, Johannesburg, on 21st May, 1969, at 4.30 p.m. Mr J. K. E. Douglas (Vice-President) was in the Chair. There were also present twenty-two Members, including Messrs F. P. Bath, M. Bareza, A. R. C. Fowler, D. M. Jamieson, C. M. Mavrocordatos, D. G. Maxwell and J. A. Nixon (Council Members), Messrs T. Davidson, G. L. Diering, E. T. Dunstan, D. E. H. French, K. Hodgson, O. A. E. Jackson, A. F. Lee, A. Louw, D. L. Starkey, R. K. Wheeler and M. Youngworth. Four Associate Members including Messrs D. Blair Hook and G. R. Still. One Student Mr N. A. Barcza. Thirteen Visitors, including Messrs S. H. Ash, D. L. G. Bayne, E. Bayne, S. Bell, W. S. Garrett, L. S. Gibbs, R. C. Hamilton, M. Maguire, D. Rose and J. D. van Niekerk. Total Present: Fourty-one. OBITUARY The Vice-President: "It is my sad duty to announce the death of the following member of the Institute: Thomas Spence Haldane, Member, who joined the Institute in 1924 and passed away on 21st December, 1968. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, those present stood and observed silence for a few moments. MINUTES The Vice-President requested that confirmation of the minutes of the previous meeting be held over as they would only be appearing in the Journal of the following month. He also requested that confirmation of the minutes of the 75th Anniversary Meeting be held over. MEMBERSHIP The Vice-President: "I have much pleasure in announcing that the names of the under-mentioned candidates have been published in accordance with By-Law 5.2.2, and Council has elected them to membership of the Institute in the following grades: Members: Gideon Jacob Haumann, Peter John Cumming, Ian Stanley Dudman, Roderick Goldston Murchison. Associate Members: Francois Alwyn Beyers Fouche, Alan Marsh, Johannes Petrus van der Westhuysen, Waldo Edmund Stumpf, Ian Nicholas Ridley. Affiliates: Lutgerus Kolver Jooste, Roger Ainsley Ralph Kebble, Edward John Wainwright, Lewis William Davies. Graduate: Clive Graham Knobbs. MEMBER TRANSFERED TO A HIGHER GRADE From Student to Associate Member: Diethard Otto Eduard Fahrbach. I welcome the newly elected members to the Institute and congratulate the member who has been transferred to a higher grade." (Applause).

EMMES Sampling Conference BACKGROUND & INTRODUCTION ?Impala acquires toll material to supplement production from ROM ?Toll material consists of filter cake, slurry and catalysts ?Samples are collected to determine the commercial values of the lots ?Slurry deliveries projected to remain relatively constant at 120tons dry solids per month, whereas filter cake deliveries set to increase five-fold to 800 tons dry solids per month ?Due to projected increase in toll material, new sampling and offloading facility presently under construction at Impala ?Presentation will cover two projects aimed at reducing the uncertainty associated with sampling of toll deliveries ?i.e. slurries and filter cake.

Jan 1, 2005

By R. C. Urquhart, W. P. Channon, D. D. Howat

Discussion: The mode of current transfer between electrode and slag in the submBerged-arc furnace by w. P. CHANNON, R. C. URQUHART, and D. D. HOWAT J. MEINTJES I have read the paper with much interest, and I should like to make a few observations. (I) The experimental work deals with resistance heating by an electrode immersed in a slag... AUTHORS' REPLY We thank Mr Meintjes for his critical analysis and helpful comments arising out of his study of our paper. Possibly we should emphasize at the outset that our experiments all related to the conditions in which the lower portion of the electrode was immersed in molten slag. We believe, however,

Jan 12, 1974

By V. G. Pienaar, B. M. Mbiya, P. T. Slatter

[a constant b constant cc onstant c' constant D pipe diameter (m) Dshear shear diameter (m) E error function fth theoretical friction factor F function F' function K fluid consistency index (Pa sn) kv valve loss coefficient L pipe length (m) n flow behaviour index N number of data points ?P valve pressure drop (Pa) Q flow rate (m3/s) Re Reynolds number Re3 Reynolds number (Slatter) V average velocity (m/s) Vann annulus velocity (m/s) x variable X number of independent variables y variable Y number of fundamental dimensions z variable µeff effective viscosity (Pa s) ? valve degree of opening d partial derivative ? fluid density (kg/m3) [ ] function]

Jan 1, 2007

By J. P. G. Pretorius, T. C. Partridge

The analysis of angular atypicality of lineaments as an aid to mineral exploration by J. P. G. PRETORI USc, M.Sc. (Pret.) (Visitor) and T. C. PARTRIDGE, Ph.D. (Natal) (Visitor) In an exploration project, data pertaining to 84000 lineaments in an area of 25 000 km2 were recorded. The total length of lineaments in intervals of one degree was determined. Angular intervals with Iow length densities were regarded as atypical. The proportion (by length) of lineaments with such atypical orientation was calculated for 5 km X 5 km grid squares. This index of angular atypicality was contoured and, used in conjunction with conventional photogeological techniques, contributed in a large measure to the success of the investigation.

Jan 5, 1974

By F. P. A. Robinson, C. R. Thomas

Stress-corrosion studies on materials used for surgical implants * by C. R. THOMAS and F. P. A. ROBINSON Samples of Vitallium (a cobalt-chromium alloy), 316L stainless steel, and titanium T318 were subjected to the boiling magnesium chloride test so thattheir susceptibility to stress-corrosion cracking could be determined, and their behaviour under service conditions was then assessed. Stress-corrosion cracking was confined to the stainless-steel samples, while gross pitting was detected in the samples of forged Vitallium. It was concluded that the use of stainless steel should be avoided for long-term surgical implants. Surface imperfections on the stainless steel are generally the cause of pitting, from which stress-corrosion cracks are sometimes propagated.

Jan 11, 1976

By F. L. D. Cloete, A. K. Haines, T. D. Sampson, T. H. Tunley, W. A. M. te Riele

The recovery of zinc from pickle liquors by ion exchange A. K. HAINES. Ph.D. (Visitor) T. H. TUNLEY. B.Sc;.(Chem.Eng.)(Visitor), W. A. M. TE RIELE. pr, Eng.. Ph. D. (Visitor), F. L. D. CLOETE. M.Sc. (Chem..Eng.)(Visitor), and T. P. SAMPSON. Pr. Eng.. BSc, (Chem.Eng,). B. Econ. (Visitor) Picklers and galvanizers in and around Johannesburg are encountering an ever-increasing problem in disposing of spent liquors from their hydrochloric acid pickling baths. Particularly troublesome is the zinc-contaminated liquor that is produced as a result of the clean-up of rejects from the galvanizing operation. Because of the volatility of zinc chloride. this liquor presents difficulties when processed in a conventional pyrohydrolysis acid-recovery unit. The paper describes the Metsep Process. developed by the National Institute for Metallurgy and Woodall-Duckham S.A. (Pty) Ltd. which involves the use of continuous ion exchange for the separation of the zinc from the pickle liquor. and the use of liquid-liquid extraction for the conversion of zinc chloride eluate to salable zinc sulphate. A description of laboratory and pilot-plant tests is given. and the approach used in the design of a full-scale continuous- ionexchange plant is outlined.

Jan 11, 1973

By H. Ruthert

An understanding of wear in systems conveying solids is extremely important from the standpoints of design and economics. The lifetime of any bulk solids-handling system depends on the type of solids present and the operating parameters of the transportation system. The relationship between wear in backfill pipelines on South African gold mines and the transportation system's operating parameters is well understood. However, the effect of the transported solids on the pipe wear is less well understood, because of an inability to characterize particle sharpness. The sharpness of the particles, together with their size and hardness, is responsible for the aggressivity of particles, or their ability to cause damage and wear. This paper presents a novel method for the characterization of particle sharpness. The results presented rank particles according to the sharpness of their surfaces.

Jan 1, 1993

10th COMMONWEALTH MINING AND METALLURGICAL CONGRESS-CANADA, 1974 The Commonwealth Council of Mining and Metallurgical Institutions has received and accepted an invitation from The Canadian Institute of Mining and Metallurgy for the 10th Commonwealth Mining and Metallurgical Congress to be convened in Canada in April, 1974, immediately following the Annual General Meeting of The Canadian Institute of Mining and Metallurgy. It is proposed that the Congress centre will be Montreal and that, after technical sessions, tours of operations will be arranged. Further information will be issued in due course by The Canadian Institute of Mining and Metallurgy and enquiries should be addressed to the Executive Director of the Institute, 906-1117 Ste. Catherine Street West, Montreal 110, P. Quebec. NOTICE TO ALL STUDENT MEMBERS OF THE SOUTH AFRICAN INSTITUTE OF MINING AND METALLURGY The Institute offers each year for competition among Student Members of the Institute a prize, or prizes, should entries so warrant it, of up to the value of R100 to be awarded to the Student Member or Members who submit the best paper or dissertation on a topic appropriate to the interests of the Institute. In the case of Student Members who are in full time study at a university the dissertation or thesis which they may have to write in part fulfilment of their university curriculum may be accepted provided it is presented in a manner and on a topic suitable for publication in the Journal. The closing date for the receipt of papers shall be 31st December each year.

By R. A. H. Lycett, P. R. Jochens, D. D. Howat

The crystallization of rutile from titaniferous slags by R. A. H. LYCETT, M.Se. (Eng.),"A.M.I.M.M. (Visitor), P. R. JOCHENS, Pr. Eng., M.Se. (Eng.) (Rand), Ph.D. (Member), and D. D. HOWAT, B.Se., Ph.D., F.R.I.C., F.I.M. (Fellow) Factors affecting the precipitation of rutile from smelter slags were investigated, with particular reference to the effect of additions of phosphorus pentoxide to the slag. The phases were identified and the phase boundaries determined for slags having phosphorus pentoxide additions of 0 to 50 per cent. The liquidus temperatures of these slags were determined, and a pseudo-binary phase diagram was constructed. Rutile crystallized as the primary phase from melts having a phosphorus pentoxide content of more than IS,S per cent. Prismatic rutile crystals whose TiO. content was more than 97 per cent were grown from melts that had a phosphorus pentoxide addition of 30 per cent. However, the morphology of the precipitated rutile was such as to make subsequent separation impracticable.

Jan 9, 1975

By Christopher J. Oates

Overview ? Mining Codes ? Best Practice ? Mining Standards Guidelines ? Get it right from the start ? External Auditors ? The 5% rule ? MMCRM's - The Key Components ? The MMCRM Report / Certificate ? MMCRM's & Round Robins ? Summary

Jan 1, 2005

By D. Pienaar, D. Stanton

This paper provides an overview of possible approaches for structuring the ventilation systems for mines that will become operational within the next decade. Features addressed in the paper include: aspects of airway design and layout in the absence of centralized vertical return shafts, the impact of using diesel-powered trackless equipment in conjunction with conveyor belts in the development and production phases of the project, and the need to balance increasing electrical power costs against the requirement for reduced capital expenditure. The paper provides brief descriptions of the strategies employed in real-life situations and presents an overview of various operational parameters affecting the design of ventilation systems that will be used as ?platforms? for much deeper mines in the future.

Jan 1, 2006

By L. W. Helle

In this investigation, which was conducted at the Metallurgical Research Plant, Lulea, Sweden, a series of experiments were carried out using a water-model to simulate the gas rinsing of a ladle containing liquid metal. The factors examined include the effect of gas flowrate, the position of a porous plug or lance, the immersion depth of the lance, and the geometry of the bath at the time of complete mixing. Mixing times were recorded by conductivity measurements. The results showed that there is a threshold level for mixing above which no advantage is to be gained from an increase in the gas flowrate. It is suggested that the results can be applied to rinsing ladles in working situations, the levels being approximately 270 dm3/min for 40 t ladles and 780 dm3/min for 150 t heats. The optimum siting of the lance or porous plug is a position that is three-quarters of the internal radius from the centre of the ladle with the lance penetrating as deeply as possible into the ladle. The best design of liquid bath is that having a diameter-to-height ratio of I. An equation was developed for the calculation, by dimensional analysis, of the time required for mixing during gas rinsing, and a comparison of the calculated mixing times with the results from production trials shows a satisfactory agreement (with a correlation factor of 0,91). Thus, an equation is available for the calculation of the stirring time needed to completely mix the bath in production situations.

Jan 1, 1981

By Ernst-Ulrich Reuther, Alexander Donmen

Mine ventilation in the German coal mining industry is concerned mainly with problems of thermal environment arising from greater depths and with increasing emission of methane gas. The development of computer techniques over the past ten years for solving these and ancillary problems is reviewed. The emphasis from a planning and control point of view falls mainly on ventilation network calculations, temperature predictions and advance estimates of methane emission.

Jan 1, 2014