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By F. Tanaka

Copper losses to discard slag have long impacted on the profitability of copper smelters. Businesses based on the treatment of secondary materials have also revealed that copper losses are indices of precious-metals losses. Many custom smelters are thus required to obtain more reliable controls for reducing copper losses than ever before. Mitsubishi Materials Corp. has cooperated with academic research institutes in conducting research projects on the pyrometallurgical fundamentals of copper smelting systems, including mutual evaluation of magnetite behavior between synthetic and industrial slags. The state-of-the-art pyrometallurgy has subsequently been introduced to Naoshima smelter for controlling the Mitsubishi process. The revised controls function successfully and the operational results demonstrate that avoiding the discharge of solid magnetite from the S-furnace is quite effective to reduce copper losses. Magnetite behavior has been controlled over the Mitsubishi process so as to reduce copper losses while satisfying the needs of recycling businesses growing in Japan. In-situ estimation of magnetite behavior using the absorbed heat from the melts to cooling water will also be discussed.

Jan 1, 2007

By J. Trojacek

A large-scale development in exploration and production of uranium ores in the Czech Republic was done in the 2nd half of the 20th century. Many uranium deposits were discovered in the territory of the Czech Republic. Over a period of 50 years approximately, 110 000 tons of uranium in concentrate were produced. Different mining methods were developed and used. One of the most considerable deposits in the Czech Republic is the site Hamr na Jezere ? Straz pod Ralskem where both mining methods ? the underground mining and the acidic in-situ leaching ? were used. The extensive production of uranium led to widespread environmental impacts and contamination of groundwaters. Over the period of ?chemical? leaching of uranium (ca. 32 years), a total of more than 4 million tons of sulphuric acid and other chemicals have been injected into the ground. Most of the products (approximately 99.5 %) of the acids reactions with the rocks are located in the Cenomanian aquifer. The contamination of Cenomanian aquifer covers an area larger than 27 km2. The influenced volume of groundwater is more than 380 million m3. The total amount of dissolved SO4 2- is about 3.6 million tons. Approximately 0.5 % of the contamination is located in the Turonian aquifer. After 1990, a large-scale environmental program was established and the Czech government decided to liquidate the ISL Mine and start the remediation in 1996. The remediation consists of contaminated groundwater pumping, removing of the contaminants and discharging or reinjection of treated water. The objectives of the remedial activities are the followings : to restore the aquifer to a condition guaranteeing continuing usability of Turonian water of Northern Bohemia Cretaceous, to decommission boreholes and surface installations and to incorporate the surface of leaching fields into the ecosystems taking into account regional systems of ecological stability and urban plans. Nowadays four main remedial technological installations for reaching of these aims are used - the ?Station for Acid Solutions Liquidation No. One?, the ?Mother liquor reprocessing? station, the ?Neutralization and Decontamination Station NDS 6? and the ?Neutralization and Decontamination Station NDS 10?. Total capacity of this complex is sufficient to reach the target values of remedial parameters in 2037. The remediation action consists of: pumping of residual solution to the surface, separating uranium from the solution and reprocessing contaminants into commercially usable or ecologically storable products. It is expected that the amount of withdrawn contaminants will vary from 80 000 to 120 000 tons per year. Total costs of all remediation activities are expected to be in excess of 1.5 billion EUR.

Aug 1, 2013

By A. E. M. Warner, A. Vahed, P. J. Mackey

"Since early 2015, the price of nickel has dropped from the region of US$6/pound to current levels of around US$4.60/pound (March 2017), reflecting several market factors, but principally due to lower demand from China. Under such conditions, nickel companies have been under pressure to contain operating costs. In addition, labor and energy costs will continue to rise, while nickel ore grades will likely continue to drop. All major companies now accept the need for climate change action and consequently efforts are being made towards lowering carbon-based emissions. Nevertheless, meeting these challenges can also contribute to higher operating costs without parallel innovative developments - which at the same time, under current conditions, major companies are tending to curtail. In this paper, several productivity improvement opportunities to reduce unit operating costs at nickel sulphide and nickel laterite plants are reviewed. Opportunities include: (a) process technology and energy-type selection, production capability, optimization of process intensity and implementation of newer technologies; (b) improved productivity, equipment availability including maintenance best practice; (c) energy savings and recovery opportunities and use of energy surveys and, (d) process modeling and improved scheduling. Such improvements along with an uptick seen in nickel demand going forward should better position the world nickel industry.INTRODUCTION Nickel is an essential metal to modern society, primarily through its use as an important ingredient in stainless steel. Thus, stainless steel finds vital applications in food preparation facilities, as well as important uses in transportation and industrial applications. Canada has always played an important role in nickel production and nickel metallurgy. In the 1940s and 1950s, Canada supplied over 90% of the world’s nickel. However, this proportion has declined considerably to around 10% of the world nickel supply today. Still, Canada remains an important nickel supplier and contributor to nickel extractive technology. Due to the importance of nickel to society, nickel demand is expected to continually rise. On the other hand, nickel companies have been under pressure to contain production costs amid languishing nickel prices. While demand projections show nickel growth, there are uncertainties in actual levels of future market growth. Ore grades are dropping, while labour and energy costs, which are key cost contributors are rising, hence efforts to lower production costs will generally require innovative approaches."

Jan 1, 2017

By R. V. Typliski, G. J. Labarre

"Hudson Bay Mining and Smelting Co., Limited, Flin Flon, Manitoba, Canada, has developed a metallurgical wastewater treatment system employing two-stage lime neutralization, sludge recirculation and conventional mechanical thickening.Laboratory investigations, initiated in 1970, led to the construction of a pilot-scale minewater treatment plant, at Schist Lake Mine, in early 1971. This plant, treating 600 cubic meters/day wastewater containing 30-60 mg/l zinc, demonstrated metal extraction efficiencies of 99% under normal operating conditions.On the basis of this pilot work, a second pilot-scale treatment system was established in 1975 at the Flin Flon metallurgical plant to treat zinc refinery process waste water. Through numerous improvements, including automatic control equipment, the system has evolved to a full-scale operation capable of treating 800 cubic meters/ day wastewater containing 4-11 gm/l zinc. Treated effluent contains 0.2-20 mgll zinc. Hydroxide sludge produced returns to the metallurgical process for recovery of metals while clarified effluent discharges to waste.With the system, Hudson Bay Mining has achieved its original goal: the reduction of environmental contamination, while realizing ii return from metal recovery."

Jan 1, 1980

By F. O. Verret

Several grindability tests were developed over the years to design grinding circuits or optimize existing operations. Each test has its own strengths and weaknesses and it is imperative to select the proper test procedure(s) to meet project deliverables and minimize the risk of a project. Pilot plant testing of large bulk samples historically constituted the traditional approach for AG or SAG design, but was gradually replaced by small-scale tests. Nowadays, conducting grindability tests requiring only a few kilos of material on several samples is a more typical approach to grinding mill design. This paper summarises the requirements and deliverables of various bench-scale test procedures, their strengths and weaknesses, and cases where AG/SAG pilot testing should still be performed.

Jan 1, 2012

AT the Annual General Meeting held in Winnipeg last March, the whole of one of the technical sessions was devoted to a special Symposium on Geological Investigations in Canada, introduced by a paper entitled The Geological Survey (lî which had been specially prepared by Dr. G. A. Young, Chief Geologist of the Survey, and had been published in the February BULLETIN, prior to the meeting. Geologists from each of the provinces contributed to the Symposium, including directing officials of the geological divisions of provincial Departments of Mines, representative geologists from the Universities, and company and consulting geologists. Space, unfortunately, does not permit publication of a complete record of the proceedings,_ or even inclusion of all contributions to the discussion. The following summary, however, gives what is believed to be a fair cross-section of the opinions expressed by representatives from each Province. The Symposium resolved itself largely into a discussion as to how the Geological Survey and the several provincial bureaus or divisions of geology could co-operate most effectively in the important task of carrying out geo-logical investigations, with avoidance of duplication of work and waste of effort, and, so far as broad principles are concerned, there was remarkably close agreement among those participating in the Symposium as to how the various types of investigation should be allocated as between the Federal and Provincial organizations. Briefly, the concensus was that the Geological Survey can render the most effective assistance by conducting reconnaissance investigations, with mapping at 4 miles to one inch, leaving to the provincial organizations the more detailed, and hence more local, studies and mapping at larger scales. There was general agreement that the preparation of base maps, essential to systematic geological investigation, is a service devolving upon the Federal Government.

Jan 1, 1940

By T. T. Tigert

INTRODUCTION THE PURPOSE of this article on methane is to present the simple basic facts of the characteristics, detection, occurrence, and control of this natural gas in metal mines, so that operators and .safety men may deal with it with some degree of confidence. Fortunately, although methane has been noted at many metal mines throughout Canada, the occurrences usually are small flows of short duration, and the ignitions experienced have, in most cases, had minor consequences. However, methane does present a hazard that can be of serious proportions, and ?any complacent attitude toward this gas that might exist in the minds .of people engaged in underground mining operations should be dispelled when it is ,pointed out that, in Ontario alone, ignitions of this gas have resulted in at least four fatalities, and eight men seriously injured and burned, during the past three years. lt is well-known that liberation of methane can and does .occur suddenly, often in mines where no gas has been found before, and that many ignitions and explosions have occurred in so called non-gassy mines. In view of this, it is apparent that no mine can, with any degree of certainty, be classified as non-gassy. CHARACTERISTICS OF METHANIZ The characteristics of natural gas encountered in most of the Ontario mines indicate that methane is the chief constituent. Methane (CH4), commonly termed 'marsh gas', and by the coal miner 'firedamp', is a colourless, odourless, and non-poisonous gas considerably lighter than air, and is the explosive gas frequently found in coal mines. Its physiological effects, closely resemble those resulting from nitrogen.

Jan 1, 1951

By T. Holmes, S. Davison

"A surge bin at Agrium’s Vanscoy potash operations has been plagued with flow, wear, and corrosion issues since being built in 1967. The culprits? The bin’s carbon-steel construction, geometry, and the resultant funnel-flow pattern are the root causes. An investigation and cost analysis indicated that hopper redesign and retrofit would increase production and reduce maintenance and capital costs. The retrofitted bin provides safer, more reliable operation and has a much longer predicted working life. Using this example, the authors describe bulk-solids-flow theory and highlight the importance of customizing bulk-material-handling-system design using appropriate flow properties to improve reliability, safety, and cost effectiveness.RÉSUMÉ Depuis sa construction en 1967, un réservoir intermédiaire de l’exploitation de potasse Vanscoy d’Agrium connaît des problèmes de débit, d’usure et de corrosion. Les responsables ? La construction en acier ordinaire du réservoir, sa géométrie et la structure de débit en résultant au niveau de la carotte en sont les causes fondamentales. Une étude et une analyse des coûts indiquaient que la restructuration et la rénovation de la trémie permettraient d’augmenter la production et de réduire les coûts d’entretien et en capital. Un réservoir rénové permet de renforcer la sécurité ainsi que la fiabilité de l’exploitation, et sa durée d’activité prévue en est augmentée. En se fondant sur cet exemple, les auteurs de l’article décrivent la théorie du débit de matières solides en vrac et insistent sur l’importance de personnaliser la conception du système de manutention des matériaux en vrac à l’aide de propriétés rhéologiques adaptées afin d’améliorer la fiabilité, la sûreté et la rentabilité.INTRODUCTIONIn early 2013, Agrium’s Vanscoy Potash Operations (VPO) engaged Jenike & Johanson Ltd. (J&J) to provide testing, consulting, and structural engineering services related to proposed modifications to the 270 t special standard product surge bin, which Agrium planned to undertake during a two-week shutdown in August 2013. The bin, which had been plagued with flow, wear, and corrosion issues for its entire working life, was essential for the continuous operation of two of VPO’s compaction plants and for efficient dispatching to loadout. The bin often experienced product hang-ups, clumping on the walls, and plugging at the hopper outlet. Two recent unscheduled mill shutdowns had been partially attributed to flow issues in the bin due to clumping and product plugging up at the screws. These problems increased maintenance costs, limited production capacity, and degraded product quality. Holes and paper-thin sections in the bin walls discovered during a 2013 inspection revealed the potential for major hot material leaks or even structural failure. Either issue would stop plant operations until the bin could be repaired or bypassed. Clearly, the bin cone had reached the end of its life and required replacement."

Jan 1, 2018

By B. Meddings, O. J. I. Evans

"This paper is mainly concerned with the present and probable future role of hydrometallurgy in the production of base metals.The economic and technological bases of the hydro-metallurgical plants built and operative in the mid-fifties are compared to those in production in the mid-sixties. The trends observed are extrapolated and some estimates made concerning the probable size and type of hydrometallurgical plants which will be operative in the mid-seventies.The impact of emerging socio-economic factors such as pollution control and the market demand for specialized metal products which favour hydrometallurgical recovery processes are also discussed."

Jan 1, 1971

By Pierre Gauthier

Is the hydrogen economy of the future just another fish story? Absolutely not! There have been many changes affecting the energy equation over the last 10 years and conditions have changed. In this presentation, we will examine the reasons why, in the very near future, hydrogen production and distribution will be increasingly visible on many industries? radar screens.

May 1, 2007

By Adam Moore, Ryan Gillespie, Jarrett Quinn, Audrey Walters, Peter Radziszewski

"Vale Long Harbour Processing Plant (LHPP) was designed to process Voisey’s Bay nickel concentrate into finished nickel and associated copper and cobalt products. The plant includes a secondary grinding circuit comprising two Stirred Media Detritors (SMDs) operating in parallel. The ultrafine grinding circuit was designed to process concentrate at a rate of 33 t/h and produce a ground product (P80) of 20 µm to feed the leach circuits. Start-up of the grinding circuit at LHPP was undertaken in December 2014.The objective of this paper will be to describe the design, commissioning, start-up and performance of the secondary grinding circuit with a focus on the two Metso SMD-355-C mills. Following a brief overview of Vale’s LHPP and the SMD technology, the paper will review the design of the SMD secondary grinding circuit from lab tests through to scale-up performance prediction. This will be followed by the results of circuit commissioning outlining some of the issues raised and addressed after which SMD performance will be outlined. Specifically, the SMD circuit grinding performance will be examined since start-up which will include the effect of media size and wear on grinding. Furthermore, impeller wear will be examined by determining initial “shear volume” and worn “shear volume” as well as its effect on mill power and the means to maintain it. The paper closes with a discussion on grinding performance."

Jan 1, 2016

By André van Wageningen

Since the beginning of this century Boliden Mineral and Atlas Copco have worked together in stages on improving the accuracy and quality of drilling. Navigation of the drill rigs with IREDES has been in use in the Boliden mines for several years. Recently the capability of the system has extended with map navigation to more accurately follow the ore in cut&fill mines. The system allows for changes on the individual round level to follow the ore without changing the whole design for the heading. Those changes are done in a CAD-system and remove the need for face markings and will allow for even better accuracy in both height and wall position. All the information between the CAD-system and the drill rigs is exchanged using the IREDES standard. This paper describes the workflow and the use of the IREDES standard.

Oct 1, 2009

By A. Takala, H. Cline, D. Girard

"This article describes the project development and successful implementation of a particle sorter at the Kensington mine. The Kensington underground gold mine and associated milling facilities are located within the Berners Bay Mining District on the east side of Lynn Canal about 45 miles north-northwest of Juneau, Alaska. The paper describes the project from concept, through the development phase, including test work confirming feasibility, to a discussion of operational data and includes shared experiences from operation and maintenance. The project has proven successful in recovering gold that was previously lost to the waste dump and has already resulted in a positive return on investment. The payback was achieved in less than one year.INTRODUCTION The first paragraphs of this paper describe Coeur Mining and the Kensington Mine, its history, geology, mining operation and mill. The second part of this paper gives a quick introduction to sensor-based sorting in general and X-ray transmission sorting (XRT) in particular. This article does not cover costs or economic impacts apart from the pay-back period for the investment at Kensington. Interested readers find more in information on this in the literature (Kleine & Wotruba, 2010; Robben, 2013). Since the publication about XRT sorting at TGME in Pilgrim’s Rest (Kleine, Riedel, Ketelhodt, & Murray, 2010), this is the first time that a comprehensive data set on gold ore sorting using XRT is published. Following chapters highlight the aim of the project for Coeur Kensington, project development through testing and operation before concluding. ABOUT COEUR MINING’S KENSINGTON OPERATION Coeur Mining is the largest U.S.-based silver producer and a significant gold producer with five precious metals mines in the Americas employing approximately 2,100 people. Coeur produces from its wholly owned operations: the Palmarejo silver-gold mine in Mexico, the San Bartolomé silver mine in Bolivia, the Rochester silver-gold mine in Nevada, the Kensington gold mine in Alaska, and the Wharf gold mine in South Dakota. The Company also has a non-operating interest in the Endeavor mine in Australia in addition to royalties on the Cerro Bayo mine in Chile, the El Gallo complex in Mexico, the Zaruma mine in Ecuador, and the Correnso mine in New Zealand. In addition, the Company has two silver-gold feasibility stage projects—the La Preciosa project in Mexico and the Joaquin project in Argentina. The Company also conducts ongoing exploration activities in Alaska, Argentina, Bolivia, Mexico, and Nevada. The Company owns strategic investment positions in several silver and gold development companies with projects in North and South America."

Jan 1, 2017

By T. G. Joseph, G. W. Hansen

"This paper considers the duty cycle of an electric cable shovel and correlations with measured passive seismic responses of the underfoot oil sands material in-pit. It has been observed that the cyclic activity during operation of any shovel in the oil sands environment causes the material to deteriorate and provide a less than ideal footing for this large item of equipment, whose dead weight approaches 1500 tons with a footprint of merely 75 sq. yd. Consequences are manifested in the form of carbody and side frame cracks, and associated downtime, maintenance activity, cost, and subsequent loss of availability.The objective of these considerations, as part of the Oil sands-Equipment Interaction Program (OsEIP), currently a joint venture between Syncrude Canada Ltd., James Progithin International (JPi) Ltd., Caterpillar Inc., P&H MinePro and the University of Alberta, is to identify and provide feedback to the manufacturer and end user of adverse shovel-ground conditions. This would enable the manufacturer to incorporate greater knowledge into the design process and the end user to direct operations in an enhanced proactive maintenance stance."

Jan 1, 2002

By Côme Carbonneau

The ten -year case history of La Société Québécoise d'Exploration Minière (SOQUEM) is reviewed under the headings of the company's raison d'être, objectives, policies, structure and final goal. A brief analysis of its past operations is presented: aborted efforts, findings and developments. A projection is made of the future earnings, in terms of estimated present value, of its three main discoveries - Louvem , Niobec and Selim.

Jan 1, 1978

By M. Pfeifer, M. N. Brodie, D. J. Barratt

"This paper reviews design trends related to the various SAG mill configuration and drive options available today. The impact of these options on capital and operating costs is assessed, and key technical issues reviewed. The discussion is based on the conventional North American ’pancake’ mill configuration. IntroductionDuring the past decade mill technology has evolved significantly in the following key areas:• improvements in variable speed motors continue with on-going advances in electronics;• ring motors, or gearless drives, are becoming more common in mill sizes 32 ft and larger, with ratings of 10 000 HP and greater;• geared drives have become available up to ratings of 9500 HP per pinion, compared to the earlier 6000 HP guideline;• improvements in speed reducer technology due to the use of carburized and ground precision gearing, make the high speed motor-speed reducer drive more competitive with the direct coupled low speed motor drive;• a unique speed reducer drive is being introduced to this industry which combines ring gear drive pinions with speed reduction. mprovement in gear alignment is claimed, and the overall drive arrangement is more compact than is possible with a conventional speed reducer drive;• the first 38 ft and 40 ft diameter mills have been designed and manufactured; and • application of large multi-shoe bearings have made shell supported mill configurations available for all, including the largest sizes. These designs have flat instead of conical mill shell ends, and have the potential for technical and cost advantages compared to conventional trunnion supported designs.This proliferation of mill design features provides several options to those involved in planning and design of milling plants, and requires more extensive evaluation to optimize mill design features to best suit specific project requirements."

Jan 1, 1999

By Catherine N. Mulligan

Thickening of mine tailings is a relatively new concept for their sustainable management. Removal of water from the tailings to form a paste instead of slurry disposal decreases environmental and geotechnical concerns. As the use of these pastes is relatively new, their behaviour requires investigations such as liquefaction and seismic stability, freeze-thaw behaviour, consolidation and leachate characterization. Slurry density, ore type, particle size distribution, specific gravity and environmental conditions can all influence paste characteristics. In this paper, the effect of the above-mentioned parameters is examined. New developments in water removal, and additives (such as flocculating agents, cements, organics, fertilizers, etc) leading to low moisture content tailings are reviewed, and the potential for thickening to enable sustainable management of mine tailings is discussed with respect to storage volume requirement, use of virgin land, consolidation of the tailings, land use after decommissioning.

May 1, 2007

By M. B. B. Research Council of Alberta Crockford

Introduction Kootenay strata of Lower Cretaceous age contain much of the highest rank coal produced in Alberta. These strata outcrop in the foothills and mountains of southwestern Alberta and southeastern British Columbia, and the economic value of the coal seams contained in them was evident to the earliest explorers, who refer co them in their journals. Lacer, investigation of the .coal measures was undertaken by prospectors and by a succession of geologists, most of whom were in the employ of the Federal government, but some acted for private interests. Surveys by these men proved chat foothills and mountain regions hold immense quantities of high-grade coal within easy reach of transportation facilities, and their conclusions have accelerated the development of the coal-mining industry m Alberta. Among geologists who have contributed much to our knowledge of the region are J. M. Dawson, G. M. Dawson, R. C. McConnell, D. B. Dowling, J. D. Mackenzie, B. Rose, J. R. Marshall, B. Rose, J. R. Marshall, B. R. McKay, J. A. Allan, and J. L. Carr. The present paper is to a great extent a compilation of the work of the above men and of several others who have investigated the area lying between Bow river and Crowsnest pass. Space does not permit a list of all the sources of information so chat only chose of prime importance are given in the text. Data for the map and ?cross-sections of Figure 1 were taken from the following published maps of the Geological Survey of Canada: Cascade Coal Basin, Pub. 933; Canmore, Maps 322 and 323; Upper Elk River and Upper Highwood Rivers, Pub. l980; Blairmore, Pub. 1584; Southfork Coal Area Map l03A; and of the Research Council of Alberta: Highwood-Elbow Area, Map 20; and Ribbon Creek Area, Map 21. In some cases, the cross-sections have been simplified or otherwise altered, and for these revisions the writer cakes full responsibility. The stratigraphic sections of Figure 2 have been taken from published reports of the above mentioned organizations. The area covered in this paper is shown in Figure l. It is wholly within Alberta, and reaches from township 5 to township 27 and from range 1 co range 11, west of the fifth meridian. Its location is about fifty miles west of both Calgary and Lethbridge. Topography of the area ranges from foothill on the east to mountainous on the west. In this paper' the foothill region is considered to be chat which lies immediately east of the most easterly mountain ranges, such as Livingstone and Highwood. There are two principal coal mining districts in the area, one served by the main line of the Canadian ?Pacific railway and centring about Canmore, the other by a branch line of che same railway and centring about Bellevue, Blairmore, and Coleman.

Jan 1, 1949

By J. Budac, J. Dennett, D. Mayne, P. Nawrocki

"The Nickel/Cobalt operation in Fort Saskatchewan, Alberta has successfully used an oxidative ammonia leach process to refine a variety of feeds into high quality nickel and cobalt products for over 60 years. Fundamental changes to the refining process were made when the major feed was converted from nickel concentrate to cobalt rich mixed sulphides in the early 1990s. Since the early 1990s, the production capacity of the refinery has expanded to match increases in both mixed sulphides and other feeds. In addition to increasing the production capacity of the refinery, other changes have been required in order to improve the operability and reliability of the refinery as well as to deal with increasingly stringent safety and environmental requirements. This paper describes recent changes at the refinery including changes to the flow sheet, improvements in unit operations, incorporation of new feeds, management of byproducts, and control of impurities.INTRODUCTION The Cobalt Refinery Company (Corefco) plant in Fort Saskatchewan processes nickel-cobalt mixed sulphide intermediate produced at the lateritic nickel mine and high-pressure acid leach (HPAL) facility in Moa Bay, Cuba. Both operations are jointly owned and operated by Sherritt International and General Niquel of Cuba. The mixed sulphide, along with other feed materials, is processed at the Fort Saskatchewan refinery using a pressure ammonia leach-hydrogen reduction process to produce nickel and cobalt metal. This refinery was originally constructed in 1954 to treat nickel concentrate from Sherritt’s Lynn Lake mine in Manitoba. (Benson and Colvin, 1964; Boldt and Queneau, 1967; Forward, 1953; Forward and Mackiw, 1955; Kerfoot, 1989) From the mid-1970s until the early-1990s, the facility operated as an independent refinery, treating nickel-bearing feeds from around the world. The flowsheet was changed in 1992 to address the increased cobalt content of the feed. (Cordingley and Krentz, 2005; Kerfoot and Cordingley, 1997) The flowsheet was adapted further in 2009 to improve cobalt speciation in the leach process, which allows better cobalt-nickel separation. The 2009 iteration is shown in Figure 1. Three ammonia leach stages were used to ensure high recoveries of nickel and cobalt. Underflow solids from the final leach stage contained mainly iron oxides. One of the features of the leach process is the innovative recycling of ammonia. Ammonia vented from the leach process in tail gas and from atmospheric tanks is recovered and recycled into the refinery using water based scrubbers and a high pressure distillation process. Indeed, roughly 250 t NH3/d is recovered as distillate and recycled back into the process. Also, air enriched with ammonia which is vented from the later first stage autoclaves is recycled to the lead first stage autoclaves to maximize oxygen and ammonia utilization."

Jan 1, 2017

By B. Fang

Electrochemical behavior of an X-80 pipeline steel, including frequency-sweep electrochemical-impedance spectroscopy (EIS), time-sweep EIS at a constant frequency and open-circuit potential (OCP) monitor, was investigated using four-point bending specimens subjected to a stress-corrosion cracking (SCC) test in a near-neutral pH environment, The capacitive loop became smaller with test duration, revealing an increase in the corrosion rate, The resistance obtained in the constant-frequency EIS test showed two regions, of which the region with a remarkable decrease in resistance transformed into a region of slow decrease, whereas the capacitance increased with test time indicating that iron dissolution was fast at first, and then a corrosion product or film formed and covered the surface, leading to the pitting formation.

Jan 1, 2005