Search Documents

By M. Massinaei, M. R. Yarahmadi, S. Zeidabadi, M. Oliazadeh

"Although the majority of new flotation column installations continue to be for cleaning or recleaning, an increasing number of flotation projects are specifying columns for roughing or scavenging duties. NICICO has recently installed flotation columns operating in rougher, cleaner and re-cleaner circuits at three new copper concentrators; Miduk, Sungun and Sarcheshmeh. Miduk is probably one of the unique operations that use flotation columns in a rougher circuit. The Miduk rougher circuit comprises five CISA parallel columns. The rougher concentrate constitutes 88% of final concentrate and reports to concentrate thickener. The rougher tailings are scavenged with ten 50 m3 mechanical cells. The scavenger concentrate is then reground and cleaned in three 3.2 m columns in parallel. The cleaner tailings are scavenged in six 50 m37mechanical cells. The cleaner tailings along with the rougher scavenger constitute final tailings.In Sarcheshmeh, the cleaner concentrate is re-cleaned in a column. The column tailings are sent back to the cleaning circuit and the concentrate is reported to the concentrate thickener.This paper reviews performance details of the flotation columns utilized in rougher circuits at Miduk and compares their metallurgical performances in an industrial scale with columns at cleaning circuits for copper flotation. Practical limitations for applying the flotation columns in rougher circuits will be discussed in details.INTRODUCTIONThe use of flotation columns has grown rapidly since the first successful commercial application at Mines Gaspe, where columns were used in a cleaning circuit to float molybdenite. Early applications of columns were restricted to replacing or adding final cleaning stages in existing circuits. Columns can achieve superior cleaning as compared to conventional cells due to their ability to support a large froth depth and the use of water for washing froth. Wash water travels down through the froth and crosses the pulp/froth interface, replaces the entrained particles reporting to the froth from pulp and improve the concentrate grade."

Jan 1, 2011

By James A. Finch, Stéphanie Somot

"The self-heating facility developed at the Noranda Technology Centre [Rosenblum and coworkers, 2001; 1995] has now been established in the Department of Mining, Metals and Materials Engineering at McGill University. A research program into mechanisms has been initiated (with support now from four industrial partners under Camiro). The first investigation is into the role of pyrrhotite (Po), the most commonly suspected mineral to trigger self-heating. Following a standard experimental protocol, self-heating was assessed on samples of Po mixed with sand as an inert material. With increasing Po content, self heating progressively increased but, interestingly, the samples visually appeared less and less oxidized. A high Po content, it was hypothesized, may give a more reducing environment favouring formation of H2S. The presence of this gas could be significant as it has a high exothermic heat of reaction with oxygen. The system was modified to test the hypothesis by including copper pieces and copper sulphate to react with (and therefore reveal) the gas as copper sulphide. Evidence is presented in support of H2S production, which to our knowledge has not been shown before and introduces a potentially important avenue of investigation into self-heating mechanisms.INTRODUCTIONSelf-heating of sulphide minerals poses potential environmental and safety hazards in mining of ores, and storage and transport of concentrates. While some conditions are known to be critical, the reactions remain poorly understood making self-heating difficult to predict and control.A major advance in measurement was introduced by Rosenblum and co-workers [Rosenblum et al., 2001; Rosenblum and Spira 1995]. A self-heating assessment method was developed and applied to various sulphide-bearing materials The method is based upon automated calorimetric cells with data acquisition, now available to McGill researchers and which have been used for the study reported here."

Jan 1, 2006

By J. Zollinger, J. R. Kennedy, J. H. Park, D. Daloz

"In order to improve the properties of cast Ti-Al alloys to replace Ni-based superalloys past the low pressure stages of aircraft engines investigations into inoculation for grain refinement were carried out. Previous work showed isomorphic self-inoculation using Ti-Al-Nb particles was effective for grain refinement, however the relatively fast diffusion of Nb in Ti-Al make it difficult to observe the mechanism of nucleation. An alternative alloy was developed in the Ti-Ta system for isomorphic self-inoculation, maximizing the Ta content to improve the particles survivability in the melt. The powder processing produced comparatively small inoculant particles which dissolved, however larger particles were seen to survive solidification. The density difference between the inoculant particles and melt resulted in an inhomogeneous mixing of the particles and the melt with larger particles found near the outer edges of the ingots. Variations on particle size and interaction time between the inoculants and the melt resulted in the Ti-Ta inoculant reducing the as-cast equiaxed grain size by a factor of two compared to non-inoculated samples as well as increasing the equiaxed fraction in the ingot.INTRODUCTION Lightweight metals are of particular interest in aerospace applications. The hot sections of turbines are dominated by blades made of nickel based superalloys. Recently the GEnx turbine introduced TiAl blades in the last low pressure stage of the turbine to reduce weight and improve fuel efficiency (Kim & Dimiduk, 1991). In order to carry these benefits deeper into the turbine the high temperature (>800oC) properties of the alloys must be improved. Current grain refinement methods to improve properties rely on boron additions which may not be applicable for all blades as brittle precipitates may be formed during processing (McCullough, Levi, Mehrabian, & Hyman, 1991). A novel grain refinement process was previously introduced called “isomorphic self-inoculation” using Ti-Al-Nb particles to successfully grain refine TiAl (Kennedy, Zollinger, Bouzy, & Daloz, 2016). In order to better understand the mechanism of this process an investigation was carried out using the same process but with a Ti-Ta alloy which is more stable in the TiAl melt than the Ti-Al-Nb."

Jan 1, 2017

By C. Larsen, E. Gratch, B. Flintoff, R. Bradburn

"In 1973 Brenda Mines Limited first investigated the potential use of a process computer to aid in the development of a control system for the concentrator grinding circuit. This initial study and its results are reviewed (1) in a previous paper.Since that time the computer system and its applications have been expanded. After the initial success of grinding circuit control, a second process computer was purchased to function as a back-up device. The two processors are currently operated in a foreground-background mode which allows extensive use of the computing facility for engineering and development work as well as operator training.Because of the relative ease of expansion, the computer has been incorporated into a flotation control system as well as an electrical peak power savings program.It is the purpose of this paper to review the successful application:; of the process computer and to indicate applications which are envisaged for the future."

Jan 1, 1978

By Michel Brissette

"To recover more valuable ore and considering the complexity of minerals, the needs to grind finer is increasing. To reach the desired fine grinding targets, using the existing grinding media size, the energy consumption is increasing exponentially. As already proved at this conference, small grinding media represents the best potential to improve grinding efficiency. How do the small grinding media perform in industrial grinding mills?The use of small grinding media in regrind mills proved that finer grinding can be achieved at lower energy consumption. In ball mills, smaller grinding media versus 25 mm media generate a power saving from 10% to 44%. In vertical stirred mills, the power saving increases from 20% to 60%. More potential savings have been identified.For the same operating conditions, how a vertical stirred mill is performing compared to ball milling? In regrind application, a vertical stirred mill with small media (5-12 mm Millpebs) will require at least 62% less energy than a ball mill charged with 25 mm grinding media.INTRODUCTIONIn some mining applications, fine grinding is needed to liberate further the valuable ore. The purpose of regrind mills is to achieve the last stage of grinding before final flotation stage: the cleaners. In part because of high prices of small grinding media as well as availability, the most widely used size of grinding media is 25 mm.When calculating the recommended ball top size from Bond’s formula (Bond, 1961), the size for regrind applications is much lower than 25 mm. Today, the barrier for small grinding media is broken. They are best suited in regrind application. The size of grinding media is one of the most important variables affecting the mill efficiency (McIvor, R., 1997; Nesset, J.E., Radziszewski, P., Hardie, C. & Leroux, D.P., 2006).Conventional ball milling was discarded for fine grinding because of its very poor energy efficiency (Zheng, J., Harris, C.C. & Somasundaran, P., 1994; Yan, D.S., Freeman, M. & Dunne, R., 1995). Therefore, new technologies as stirred mills were developed to grind finer more effectively. Three fundamental questions should be asked. What is the best fine grinding technology? What should be the best media size to use? Is it possible to grind finer by using less energy with the existing regrind equipment?"

Jan 1, 2009

By Patrick F. R. Murphy

The mechanization of platinum group metal (PGM) underground reef mining in South Africa has posed a challenge to mining engineers for several decades. This is primarily due to the shallow dip angles and narrow thickness (<1.1m) of the tabular orebodies mined, and the issues faced in developing reliable drilling, bolting and loading machines suitable for such hard-rock mining applications. Presently, mining is typically conducted using hand drills and scraper shovels. These methods, however, are intensive in terms of manual labor, and limited in terms of productivity, and improved methods are desired. This paper will review the technical features of a 4 tonne, low-profile, LHD for narrow-reef PGM mining, developed by EJC Loaders Division.

May 1, 2003

By Pierre Boileau

Outline ? Who are We? ? Canada?s GHG Emissions 1990 - 2000 ? Emissions from the Petroleum Sector ? Emissions from Petroleum Exports ? Emissions from Manufacturing Industries ? Emissions from Mining and Metallurgy ? Conclusions Greenhouse Gas Division Key Functions: ? National GHG Inventory Report, Emission & Removal Trends Analysis, and Indicator Fact Sheets ? Scientific and Engineering Guidance, Technical Advice, Data Quality Assurance & Quality Control and Methodological/Data Development ? International Negotiations (FCCC) & scientific/technical guidelines (IPCC & ISO) ? Expert Review Teams (ERTs) ? Outreach ? GHG Verification Centre ? Clearinghouse ? Protocol Development

Nov 1, 2002

By L. Li

The rock quality designation (RQD) was initially introduced by Deere (1963) for civil engineering. But, its application has been largely extended to rock mechanics and has become a fundamental parameter in geotechnical engineering (e.g., Hoek & Brown 1980; Milne et al. 1998). The success of this definition is due, in great part, to its simplicity. However, this index includes a number of limitations. Among these limitations, a critical one is associated with the arbitrarily selected threshold value (e.g., Priest & Hudson 1976). Consequently, the RQD value would vary with different threshold length for the same core. Also, using the customarily and universally adopted but very arbitrarily selected threshold value of 10 cm (for NX cores) in the assessment of RQD, the RQD values usually tend to be either high or low in most rock engineering. Some intermediate values (50%) are less frequently encountered (Harrison 1999). The original definition of RQD does not well represent the actual quality of rock masses. In this paper, an improved definition of rock quality designation (RQDc) is given.

May 1, 2009

By F. Dai

Due to difficulties associated with gripping in direct tension, indirect methods are commonly used to measure rock tensile strength. In this work, we adopt an innovative indirect tensile test method: Semi-Circular Bend (SCB) to measure the tensile/flexural strength of Laurentian granite (LG). The static tests are carried out with a servo-controlled material testing machine and the dynamic tests are conduced with a Split Hopkinson Pressure Bar (SHPB) system. Pulse shaping technique is adopted to achieve dynamic force equilibrium in SHPB to facilitate data regression. Finite element method is used to relate the failure load to the tensile strength. Strong rate dependence of the tensile strength is observed. The flexural strength is higher than the tensile strength measured using Brazilian Disc (BD). This difference is rationalized using the non-local theory. To further validate the method, a coupled Finite element/Discrete element method (Fem/Dem) in conjunction with the smeared crack model is utilized to simulate the fracture process during dynamic SCB tests. The resulting fracture patterns are qualitatively consistent with those from recovered samples. Both the experimental and numerical methods have validated the results and this new method is readily to be used for other rocks and other brittle materials.

May 1, 2009

By A. Uribe-Salas, J. A. Finch, B. J. Huls

Froth depth or interface level is an important control variable in column flotation which can influence both grade and recovery. A common method of locating the level is based on sensing the hydrostatic pressure at one or more points along the column. The level position is then calculated from these pressure readings using an equation which includes the bulk density in the froth and bubbling zones. The precision with which the level is detected depends on how well these density values represent both zones. The calculation of these bulk densities from theoretical considerations is not possible and, therefore, the practice is to estimate them by calibration. Unfortunately, the calibration parameters often do not report the level with an acceptable accuracy. A portable conductivity probe has been developed to detect the position of the interface from conductance measurements across the interface. The location of the interface corresponds to the position where a large change in conductance is observed, which is primarily a consequence of the difference in gas holdup between the bubbling and froth zones. This probe can be used to detect the position of the interface to an accuracy of± 5 cm. The probe can be used while the column is in operation, which allows the on-line calibration of the level detection system. Results obtained in its application in a pilot-scale column (0.91 min diameter) are described.

Jan 1, 1989

By D. M. Doyle

"In this paper I will summarized the Falconbridge Nickel Mines1) energy costs and consumption data by fuel, process, cost centre and estimate our future costs and consumption patterns 2) detail the distribution of electrical energy 3) distribution of other forms of energy 4) describe present and planned energy conservation schemes; and 5) discuss economic justification and responsibility.There is sufficient material in this presentation to warrant several technical papers, however we felt that an overview of all our data and endeavors on the subject, would be most beneficial to those companies formulating energy conservation plans. The data briefly referred to in this slide presentation can be found in the technical paper.Over a five year period, total energy costs will vary between $63 and $94 MM depending on the future rate of energy cost escalation. An unrealistic 32% reduction in energy consumption is required to hold our own in the years ahead whereas an attainable 10°;, reduction in energy consumption would save $9 MM over this five year period.Total energy consumption, tonnage of ore delivered to plants and their ration BTU’s per ton of ore, are graphed for the years 1973 through 1976 and forecasted for the 1980’s. In 1974 we along with other member companies of the Mining Association, determined our purchased energy per ton consumption rate and set, as our goal, a 20% reduction by 1980. The dotted lines calculated from the energy audit, based on 1976 data shows there is a potential for a 10% increase in energy per ton. This could result from a lower than forecasted mining rate and operation of the new roasting, electric furnace and acid recovery facilities installed for environmental considerations at designed capacity."

Jan 1, 1978

By Filipe Beretta

This study investigates geophysical logging capacity to predict coal quality. It was analyzed for possible correlation, some parameters determined via laboratory analysis of coal against results for the same parameter derived from wireline logs recorded by a geophysical probe. These probes detect variations in some rock physical properties, such as their natural gamma ray emissions and electrical resistivity. Results showed a strong correlation between natural gamma and ash content, establishing a linear model to estimate ash content from geophysical logging data with a low estimation error (less than 5%). Besides, results showed that there is no correlation between sulphur content or volatile matter and resistivity, neither with natural gamma of the rocks. Ash content derived from gamma ray values can be used as secondary information to evaluate coal quality during resources estimation, using methods such as soft indicator kriging. The methodology is illustrated using a case study at a coal deposit in south of Brazil.

Oct 1, 2009

By J. Sammut, T. G. Joseph, R. Andreev, M. Curley

"Decisions regarding mining method and subsequent choice of excavator must take into account the quantitative factors of productivity, availability, and capital, operating, and maintenance costs. Dig performance was compared between a hydraulic excavator (HE) and electric rope shovel (RS) of similar size class (i.e., use the same amount of energy to excavate a unit quantity of the same material from a mining face), focusing on the quantitative factors above. Machine performance, normalized to bucket capacity, was assessed as a function of hours of service (60,000 hours per machine). Results showed higher production rates for the HE of similar capacity and age. In general, the RS exhibited lower service cost per volume capacity, though it had higher capital cost. The RS became more cost effective than the HE of similar capacity within approximately 30,000 hours of service. ¦ KEYWORDS Cost, Electric rope shovel (RS), Excavation, Hydraulic excavator (HE), Surface mining RÉSUMÉ Les décisions concernant la méthode minière à adopter et le choix ultérieur d’un engin d’ex¬cavation doivent tenir compte des facteurs quantitatifs de la productivité, de la disponibilité ainsi que des coûts d’investissement, d’exploitation et d’entretien. Cette étude compare les performances en termes d’excavation d’une excavatrice hydraulique et d’une pelle électrique à câbles de même taille (qui utili¬sent par exemple la même quantité d’énergie pour creuser une quantité unitaire du même matériau dans un front de taille), en se concentrant sur les facteurs quantitatifs susmentionnés. La performance de la machine, normalisée à la contenance du godet de volume unitaire, est évaluée en fonction des heures de service (60 000 heures d’activité par machine). Les résultats montrent des taux de production plus élevés pour l’excavatrice hydraulique d’une capacité et d’une ancienneté similaires. De manière générale, la pelle électrique à câbles affiche un coût d’entretien par capacité volumique inférieur, mais son coût d’in¬vestissement est plus élevé. La pelle électrique à câbles devient plus rentable que l’excavatrice hydrau¬lique d’une même capacité au bout d’environ 30 000 heures de fonctionnement. ¦ MOTS CLÉS coût, excavation, excavatrice hydraulique, exploitation à ciel ouvert, pelle électrique à cablesINTRODUCTION The most common excavating tools in surface mining operations are the hydraulic excavator (HE) and electric rope shovel (RS). In general, electric RSs are more reliable and cheaper to maintain (P&H Mining Equipment, 2007), but where complicated geological conditions exist, HEs are preferred because they are generally considered to be more mobile."

Jan 1, 2019

By Gordon F. Scott

This paper considers a recently completed hoist project for IAMGOLD. Called the Westwood project, this mine utilises some of the largest drum hoists supplied to the North American Market in recent times. This project is an example of where many of the design features discussed the associated paper, (Robotham, 2011) were incorporated. Director of sales and marketing, Gordon Scott has worked at DavyMarkham for over 30 years in a variety of roles starting as a mechanical design engineer, moving to project management before joining the sales department. Gordon has an honours degree in mechanical engineering from Leeds University.

May 1, 2011

By John G. Peacey, Leoncio Sevilla G., Ford. Kevan J. R., Erling Villalobos C.

"Kinross Gold Corporation’s Mantos de Oro (MDO) gold/silver mine in northern Chile currently processes 15,000 tpd of oxide ores through a mill, whole ore cyanide leach plant followed by a Merrill-Crowe refinery. With the expected depletion of these oxide ores in a few years a new sulphide mineral deposit, Ladera-Farellón has been identified to potentially replace existing ore reserves. The deposit contains approximately 0.5g/t Au, 6g/t Ag and 0.5% Cu. The principal sulphide mineral in the deposit is enargite (Cu3AsS4) which hosts the majority of gold and silver and the copper. Direct cyanidation testwork has shown the sulphide mineral is refractory with a low gold recovery of 36% and silver recovery of 45%. Oxidation of the sulphides is required to liberate gold and silver and allow recovery of copper as an important pay-metal. Therefore, at MDO a new metallurgical process route with oxidation as a pretreatment step is required for viable treatment of such new sulphide mineralized material with acceptable recoveries of pay-metals.Analysis of flowsheet options was completed based on bench-scale and pilot scale metallurgical testwork as well as with reference to existing studies and operations. The process options investigated assume concentration of sulphides by flotation, followed by either pressure oxidation, bacteriological oxidation or roasting. Preliminary evaluation of flowsheet options focused on process risk, operability, technology availability and the economics of the project with emphasis on use of the existing metallurgical plant to reduce capital cost. Operating costs for each process option were also included in the relative analysis.The challenges of treatment of MDO sulphides, principally enargite and pyrite for recovery of gold, silver and copper center on fixation of arsenic and sulphur capture with environmentally acceptable disposal of residue tailings. This environmental focus was included in the process option selection and comparative analysis.This paper presents a review of the process options considered and highlights comparative advantages/disadvantages of each process with associated environmental issues. Preliminary conclusions are drawn on roasting as a potentially favorable process option for the treatment of MDO sulphides."

Jan 1, 2009

By D. Kidby, A. Briggs

"Vitrokele ™ is a synthetic adsorbent, using chelating groups on large polystyrene beads, developed in Canada over 7 years ago, and first commercialised in 1985 to recover noxious metals from plating wastes.Pilot plant trials have been performed in Australia and Canada to demonstrate the recovery of cyanide and removal of metal cyanide complexes from gold plant effluent using Vitrokele1 M 912. The pilot plants comprise a simple adsorption train (similar to a CIP circuit) followed by complete elution facilities, so that loaded Vitrokele™ can be stripped and returned to the adsorption circuit.An account of these campaigns is provided, showing the reduction of total CN levels from over 200 ppm to less than 0.5 ppm and Cu levels from approximately 100 ppm to less than 0.3 ppm in treated tailings.Comparisons between pilot plant results and laboratory test data are given and probable future work on the process and its application to the gold mining industry is discussed.INTRODUCTIONThrough millions of years of evolution, life forms have developed specialised molecules with exceptionally high affinity and selectivity for various metals such as iron, cobalt, zinc and copper.In the early 80's professors at the Faculty of Medicine of McGill University engaged in research on the extremely efficient ways that living cells captured trace metals essential for life.As research progressed, it became evident that the special molecules used by biological systems to capture metals could be synthesized to capture selected metals with similar efficiency from water or other solutions.The technology was first commercialised in 1985 to recover noxious metals from plating wastes with compositions applying the special molecules (chelating groups) on vitreous particles (hence Vitrokele™). To date approximately three commercial Vitrokele™ plants have been installed for treating plating waters in Ontario and Quebec."

Jan 1, 1992

By R. H. O. Wagner

"This paper describes the bench testing, pilot plant studies of alternative flowsheets, to determine the feasibility of gold recovery, by carbon in pulp extraction, in the Schumacher Mill gold flotation tailings. The economics were calculated based on pilot plant recoveries and actual industry operating costs.The economics of the carbon in pulp treatment of the gold flotation tailings were not justifiable. The economics of desliming the gold flotation tailings followed by carbon in pulp treatment were marginal, but favourable. INTRODUCTIONPamour Porcupine Mines, Limited is a gold, silver and copper producer located in Timmins, Ontario. In 1983 the head grade of Pamour's gold ores averaged nine one hundredths of a troy ounce of gold per short ton.Pamour operates two area mills to concentrate the gold ores. Free milling gold ores are processed at the Pamour One Mine mill, whereas the refractory carbonaceous gold ores, and complex gold, silver, and copper sulphide ores, are processed through the Schumacher Mine mill.The complex Schumacher mill feed ores do not all react favourably to flotation methods, consequently this study was commissioned to investigate the feasibility of the carbon in pulp cyanidation of the Schumacher mill gold flotation tailings. These tailings contain ten to fifteen percent of the gold in the mill feed. During the study period, the average grade of the Schumacher mill flotation tailings was nine one thousandths of a troy ounce of gold per ton, or one quarter of a gram of gold per metric tonne."

Jan 1, 1984

By K. L. C. Gonçalves, V. K. Alves

"CVRD’s Department of Development and Technology – GETEK has been developing and perfecting a general methodology for scaling up flotation and grinding circuits over several years. This methodology has been applied in several prospective CVRD mining projects. It encompasses a procedure for variability analysis based on bench scale tests, pilot scale grinding and flotation tests and modeling and simulation for scaling up the industrial flowsheet.The bench scale tests include the determination of the Work Index, simplified DWT tests, rougher flotation and locked-cycle tests with samples that are representative of the ore body variability. After completion of these studies, continuous, pilot-scale flotation tests are carried out at a Mini Pilot Plant with drill core samples representative of different stages of the mine life. Finally, studies are carried out with large volume samples using a conventional grinding and flotation pilot plant. This sample is also used for liberation characterization, grinding kinetics, flotation kinetics and industrial circuit scale up. This methodology has been successfully employed in the development of CVRD’s new mining projectINTRODUCTIONCVRD has been developing and perfecting a general methodology for scaling up flotation and grinding circuits over several years. The definition of the processing route and the sizing and scale up of the processing system are some of the products generated during the pre-feasibility of a greenfield project. This paper is focused on the scale up of grinding and flotation circuits, operations known to be of the most importance in a mineral processing plant.The methodology for the definition of the flotation and grinding circuits is divided in the following stages: bench scale ore variability studies, pilot plant operation and modeling followed by simulation. The product of this work is a calibrated simulator that can be utilized for plant operation as well as mine planning, looking to achieve optimal operational conditions.The current models used for scale up of the grinding circuits are aimed at the generating information about the size distribution of the circuit product. However, it is well known that the liberation state of these products may be of critical importance for the performance of the concentration processes downstream. Nevertheless, CVRD has been developing a methodology for liberation kinetics during grinding, aimed at optimizing grinding circuit throughput together with downstream flotation recovery."

Jan 1, 2006

By Jessica Barber

Problem ? Mining operations consistently need equipment that is available, and able to perform to its maximum potential ? The most difficult part of a Maintenance Manager?s job is often a lack of knowledge on how long their equipment has to last ? The short term view can lead to interim fixes that accumulate into larger problems ? It is always difficult to justify major overhauls and upgrades when there is pressure to meet mine plan production targets

May 1, 2008

By J. Dong

"Xanthate is a sulfide collector that has been widely used in flotation for almost a century. It is inexpensive, easy to synthesize and apply, and produces good metallurgy in the right applications. However, a major drawback of xanthate is that it decomposes easily and generates CS2 gas in transportation, storage and operation, which can be harmful to human health. Also, excessive xanthate in tailings pond leads to toxicity of the process water and potential damages to aqua-life systems. New regulations in Ontario require that the TWA (time-weighted-average) value of CS2 in the work place is below 1 ppm, which is 1/10 of the previous limit. The stringent regulation may eventually sweep other regions of Canada with the increased awareness of healthy working conditions and environment protection. Therefore, it becomes very important to find xanthate replacements which will be “green”, i.e., environmentally friendly.In this research work, a systematic procedure is used for collector evaluation using the Sudbury nickel sulfide ores from Vale’s Ontario operations, starting with the collector properties (MSDS) evaluation, followed by batch flotation tests, miniplant tests, plant trials and economic evaluation. It is found that the most promising xanthate replacement is dithiocarbamate.INTRODUCTIONSulfide mineral flotation has been practiced since the early 20th century. Its industrial importance is well recognized as mineral concentrates from flotation can be economically smelted and refined to provide primary metals. Collectors play a vital role in froth flotation. There are reagents possessing both a polar group that binds them to the mineral surface and a nonpolar group that is oriented away from the surface to attach air bubbles. The introduction of xanthate as a sulfide collector in 1925 was a remarkable development in froth flotation (Keller, 1925). It is low cost, easy to synthesize, water soluble, simple to control in application. Most importantly, it has strong capability and usually good selectivity for sulfide mineral flotation, which have been keeping its application prominent for almost a century."

Jan 1, 2011