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The creation of an accurate and precise enough database requires the collection of many representative samples, subsampling and assaying them without destroying their integrity. The selection and implementation of sampling protocols often lead to severe difficulties, making the unaware practitioner vulnerable to massive exploration, feasibility and operating failures. Therefore, there is no substitute for a good understanding of the Theory of Sampling (TOS). Either because of ignorance, or because of short-term economic reasons, failure to comply with many stringent conditions can be devastating for the validity of a feasibility study, leading to false evaluations, to the abandonment of a viable property, or to the exploitation of one that is not profitable. All these failures have something in common: insufficient duplicate sampling, subsampling and assaying were performed; very important, preliminary heterogeneity tests were never performed; for short-term economic reasons, poor sampling and subsampling protocols were selected, second-class sampling systems and weightometers were installed and poor preventive maintenance and cleaning were implemented;and sampling experts were called only when the project was obviously in trouble. The conclusion is clear: in due time, iterative auditing of sampling practices is an insurance policy against massive financial losses for the company involved. A complete, comprehensive 100 point checklist of sampling Quality Assurance and Quality Control is provided, so critically important details to ensure success are not forgotten.

Mar 1, 2010

By Y H. Zhu, X X. Tang, Y C. Yin, M L. Xing

Based on the stiffness theory, the stiffness difference and energy supply of surrounding rocks are important inducing factors for strain burst. However, due to the lack of multi-level low stiffness testing machine, there are few experimental studies on rock failure mechanisms under the influence of loading stiffness. This paper introduced a self-developed rock testing system with changeable stiffness. The main testing machine of this system is a combined structure of inner and outer frame. The change in the loading stiffness is achieved by using a stiffness servo control system to control the energy accumulation in the inner frame. The tests of the sandstone specimens under three different loading stiffnesses in the testing system showed that the loading stiffness did not significantly affect either the uniaxial compressive strength or the Young’s modulus of the rock. However, the post-peak stress-strain curve of the rock became smoother and steeper when the loading stiffness was decreased, and the stress drop rate increased. It is shown that the stress drop rate had a power function correlation with the loading stiffness. After the peak load, the inner frame of the testing system rebounded several times at high speeds. The magnitude of the instantaneous rebound speed and the rebound duration increased with the decrease of loading stiffness. Both the mean rebound velocity and the total rebound deformation had power function correlations with the loading stiffness. The loading stiffness has limited effect on the energy storage and energy dissipation characteristics of the specimen, while the released energy of the testing machine increases as the loading stiffness decreases, which is the key factor affecting the failure mode of the specimen. According to the test results, a rock burst mechanical model considering the stiffness is established, and the energy supply mechanism of rock burst is quantitatively explained.

Nov 29, 2022

By X Z. Sun, N Jiang, J H. Zhao, C X. Wang, L Y. Bai

In backfill grouting for underground coalmines, the filling materials strengthen the caving rock and support the overlying strata to reduce surface subsidence. The broken roof strata fail and collapse during mining operations without appropriate supporting measures being taken. It is difficult to perform continuous backfill mining on the working face of such roofs using the existing mining technology. Therefore, in order to solve the above problems, fly ash and mine water are considered as filling materials, and flow characteristics of fly-ash slurry are investigated through laboratory experiments and theoretical analyses. Laws governing the diffusion of fly-ash slurry in the void of caving rock masses and in the void between a caving rock mass and a basic roof are obtained and verified. Based on the results obtained from the above analyses and field conditions at the Zhaoguan coalmine, Shandong Province, China, a cave backfill grouting system of the hauling pipeline is developed and successfully tested at the 1703 working face. The results demonstrate that a filling rate of 43.46 per cent is achieved, and the surface subsidence coefficient of the grouting process is found to be 0.475. Compared to the total caving method, the proposed system is found to achieve a reduction rate of 40.63 per cent. This effectively helps in lowering the value of the surface subsidence coefficient. Fly ash and mine water, considered as primary materials in this study, also play a significant role in improving the air quality and water environment.

Nov 29, 2022

By Y D. Jeon, K S. Kim, C-H Eom, C M. Yoon

The carbon neutrality continues to require reduction of carbon usage in ironmaking and steelmaking processes. Specially, it is expected that the hot metal ratio (HMR) in the steelmaking process should be reduced essentially. Unfortunately, the reduction of the HMR in converter can bring about poor environment for nitrogen removal from molten Fe. From this situation, nitrogen prediction model has been developed to understand the fundamental of behaviour of nitrogen and quantitatively interpret its content changes in the converter process. Thermodynamic and kinetic approaches were improved based on existing mathematical model and attempted to predict nitrogen content in realtime by combining process data. In present study, heat supply from the oxidation (mainly carbon and silicon) and CO evolution in the converter are considered, and scrap melting due to the heat transfer from the molten Fe to the solid scrap charged in the converter also be considered.

Aug 21, 2024

By M Bettison, R Marton, R Wright, M Lowry

Depending on the geological setting, waste rock from mining can present risks to achieving acceptable closure outcomes. In the Pilbara iron ore mines, the majority of waste rock is geochemically inert. However, small percentages of pyritic material with the potential to generate acid and metalliferous drainage (AMD) require considered management within mine waste stockpiles designed to minimise AMD release to the environment. A larger percentage of waste rock has physical characteristics (e.g. erodibility) that may impact upon long-term landform stability. CITATION:Marton, R, Wright, R, Lowry, M and Bettison, M, 2018. The golden thread of waste characterisation from exploration drilling to waste rock placement, in Proceedings Life-of-Mine 2018, pp 90–92 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 25, 2018

By J Santana, V Ferraz, G Pinto, G Cruzado

Morro Agudo is an underground zinc and lead mine owned by Nexa Resources. The mine uses room and pillar as the main mining method. The recovery of pillars as well as the opening of new excavations using sublevel stoping as mining method has been studied. On some occasions, the need to recover pillars and open a stope by using the sublevel method happens in a region that is already excavated or in deeper areas than those mined so far. These changes represent a major geotechnical challenge due to the complex openings of the mine and interaction between two different mining methods. Historically, geotechnical mapping, kinematic analysis and a 2D numerical model were used to evaluate the new mine openings, and in 2021, 3D numerical model was introduced, which enabled global and local assessment of new excavations impact and the stability of openings after recoveries. The 3D model, made with MAP3D, is used to evaluate each pillar to be recovered, considering the spans of the resulting openings, the ideal sequencing of removal to maintain stability, in addition to the impact and geometry of the pillars left in the chambers. Pillar recoveries done in 2021 and the impact of it on the pillars left were the sources of the back analysis to calibrate parameters inputted on numerical model to assess recovery on new chambers and Phyllite has been considered into the model and it has been a source of instability due to its parallel position to roof of room and pillars and stope hanging walls.

Nov 29, 2022

IN preparing a sample of refined lead for analysis, it is necessary to exercise great care to avoid contaminatien, as the amounts of the various impurities present in market lead are very small. The lead is cut into convenient-sized pieces, which are flattened out with a hammer, so that, on putting tbe lead through the rolls, strips of about one inch in width and Ij32iu. in thickness are obtained. The hammer, anvil, and rolls should be carefully cleaned before use. The strips oflead are cut up into pieces of about one inch square. If the lead is roIled out very thin and cut up into small pieces there is considerable risk of the acid acting too violently and causing loss through frothing over. A blank assay on all the reagents used should becarried right through, along with the actual analysis of the lead. This is of the greatest importance, particularly with regard to the determination of such impurities as iron, sulphur, arsenic, and antimony.METHOD OF ANALYSISThe method of analysis is as follows: Take two lots of 600 gIm. each, place in a large beaker, add 2000 cc. distilled water and 750 cc. concentrated HNOs. Cover with a clock glass and warm on a hot asbestos plate until all action ceases. (If any white precipitate forms, filter off and examine for Sn and Sb.) Add 420 cc. H2S04 (1-1), and stir well while adding the acid: Allow PbS04 to settle, pour off the clear liquid into a 12-in. porcelain evaporating dish, and start evaporating down, the dish being placed directly on an 8-in. ring gas burner. Wash the precipitate three times by decantation using approximately 1200 cc. hot water for each washing, and stir well...

Jan 1, 1922

The experiments described in this paper were carried out as a preliminary to a comprehensive study of the factors which affect the behaviour of lead during and subsequent to deformation by rolling and pressing. These observations are therefore to be considered as introductory to a further paper dealing more specifically with the above-mentioned variables.EXPERIMENTALThe rolling was carried out in a small mill with six-inch diameter surface ground rolls, both of which were electrically driven at 15 r.p.m. The average draft per pass approximated 0·03 in. The pressing was performed between platens in the compression unit of a 30-ton Amsler machine. The flat faces used had a ground finish comparable with the surface of the rolls. All hardness measurements were made with a Herbert "dead load" Brinell machine. The following te'sting conditions were maintained: ball diameter-5 mm.; load-10 kgms.; duration of loading-30 seconds; temperature of testing-16 to 18°C. The hardness values which are given are the mean of two or more impressions made at corresponding positions on the test specimens.PREVIOUS WORKSince the researches of Tresca (1):j: into the nature of the plastic flow of metals during various forging and extrusion...

Jan 1, 1939

By M Yadav, K Clode, S Daykin

The mining industry faces numerous challenges related to sustainability and circular economy principles, necessitating strategic approaches to innovation and resource management. As demands for mineral resources continue to rise, mining companies are under increasing pressure to address environmental impacts, minimise waste generation, and optimise resource utilisation. These challenges underscore the importance of Research and Development (R&D) roadmaps as strategic tools for guiding innovation and sustainability efforts within the sector (Jochen Berbner, 2022). A design-led methodology offers a structured approach to R&D roadmap development, emphasising stakeholder engagement, collaboration, and alignment with industry objectives. By leveraging design principles, mining companies can ensure that their R&D initiatives are responsive to evolving challenges and opportunities, fostering a culture of innovation and continuous improvement. Against this backdrop, the project aims to address the pressing challenges associated with sustainability and circular economy in the mining industry. Through the development of R&D roadmaps and the application of a design-led methodology, the project seeks to identify innovative solutions for enhancing resource efficiency, minimising environmental impacts, and promoting sustainable practices within mining operations. This paper highlights the collaborative efforts among Isle, the mining industry, and water utilities, which have yielded tangible benefits. The study demonstrates how the outcomes from the roadmaps outlined below effectively align research with strategic objectives, fostering innovation to address pressing challenges.

Sep 1, 2024

By Amer S, Novais A. Q, Limpo Gil J

A proprietary hydrometallurgical ammonium chloride process for the recovery of not only zinc, but also copper, lead and silver from sulphidic zinc-rich concentrates has been developed at bench scale by CENIM and INETI (ex-LNET) as part of a research project supported by the Commission of the European Community (DGXII). This paper deals with the innovative chemical aspects applied to this chloride process and also with the more relevant data relating to mass balance, heat balance and process economics. Under mild temperature and oxygen pressure leaching conditions it is possible to extract practically all the zinc together with the other metals of interest and to precipitate simultaneously the solubilised iron fraction as goethite. The pH is kept close to neutrality in spite of the ammonia released in the leaching of the non-ferrous sulphides. A buffer effect is observed mostly due to the formation of zinc ammines which are very soluble in this medium. The zinc is further extracted by D2EHPA, the acidity being neutralised by the ammonia. Most of the ammonium chloride is naturally regenerated in this step. The zinc is recovered as zinc cathodes in a conventional sulphate electrowinning circuit. All the main raw material consumptions excluding the concentrate, such as oxygen, lime and ammonium chloride are linked to the sulphate formation in the leaching step which must be kept as low as possible by decreasing the reaction time under neutral conditions. The process analysis is complemented by the economic evaluation of a reference case. Difficulties encountered in finding a more convenient method of assessing the economics of the process in the absence of a reference price for a complex sulphide concentrate are examined and discussed. The reason why this analysis was performed with a much more optimistic metal prices scenario is also highlighted. The process economics are primarily dependent on the zinc market quotations and of course on the concentrate cost. Around 70 per cent of the total revenue is due to zinc sales. Assuming an internal rate of return of 17 per cent, the price of the concentrate can be as high as 255 $US/t for a plant capacity of 320 000 t/y (90 000 t/y of zinc).

Jan 1, 1993

Coal losses and dilution are among a coal mine operators everyday problems. These losses and unwelcome additions are generated primar- ily by the stripping operation and secondly by the coal mining opera- tion. Losses in yield due to preparation plant efficiency are a separate issue although they may be related to the coal mining operation. The losses and dilution can be traced to the following operations: (A) Overburden or Interburden Removal (1) Removal of coal edge by blasting operations. (2) Removal of top of seam by drilling/blasting. (3) Removal of top of seam by stripping equipment. (4) Removal of coal edges by stripping equipment. (5) Dilution due to stripping equipment. (B) Coal Mining (for the case where seams are ripped rather than shot) (1) Coal rib losses. (2) Coal rib dilution. (3) Coal left in floor. (4) Coal left in fault areas. (5) Floor material picked up whilst loading. (6) Spoil material picked up. (7) Spoil material from poor surface clean up. (8) Top of coal losses from final clean up. (9) Dilution from ripping too deep, i.e. into floor below seam. (10) Dilution from interseam parting. The losses apply to both the single seam and multi seam oper- ations although they are more pronounced in the multi seam mines than in a single seam mine due to the position of the coal which is lost. For example in the multi seam case the top seam coal edge loss is final. There is little chance of recovery with the subsequent pass even if the extra rehandle is done. However conversely the lower seam is relatively easy to locate as it has nowhere to go being contained by the lowwall bench.

Jan 1, 1988

By T J. Howard

At BHP Billiton Iron Ore operations, run of mine ore from the several Newman Joint Venture (NJV) mines is railed in 12 kt rakes to Port Hedland. Rakes are processed sequentially, with the lump and fines components from each rake sampled after crushing and screening. The grade of ore from the individual mines varies around consistently different means. Although a discrete sample is attributed to each rake, the sample contains some material from the following and/or the preceding rakes due to dilution by ore from the neighbouring rakes during the dumping, screening and crushing processes. Individual rake grades at the port are therefore biased according to the mine sources of adjacently processed rakes. Dilution does not affect the grade of the overall NJV product or the accuracy of port stockpile grades; however, it does limit the ability to use port rake grades to review the quality performance of individual mines and provide meaningful lump-fines algorithms and port to mine biases for individual mines, information that is useful when scheduling ore for mining. A non-linear regression model has been used to estimate the average dilution from the preceding and following rakes. It has been shown that the lump and fines samples for 12 kt rakes are each diluted within the Port process with about 8.3 per cent of the sample coming from the preceding rake and about 3.6 per cent from the following rake. This can bias the reported rake grade by up to one per cent iron. The results of this analysis have been incorporated into the daily grade scheduling system to provide more accurate individual mine grade data and consequently better decision making.

Jan 1, 2007

By C M. Rebagliati, J G. Payne, K Roberts

The Pebble deposit, located in south-west Alaska, is one of the largest Copper- Gold-Molybdenum (Cu-Au-Mo) porphyry systems in the world, with a current resource of >8 billion tonnes which contain 73.7 billion pounds of copper, 87.1 million ounces of gold and 4.16 billion pounds of molybdenum. The Pebble deposit formed at ~90 Ma, during emplacement of subduction-related hornblende granodiorite porphyry intrusions emplaced into Jurassic-Cretaceous sedimentary, volcanic and subvolcanic intrusive rocks of the Kahiltna Terrane. The Pebble West and Pebble East Zones represent two thermal and fluid centres in a single large magmatic-hydrothermal system. The West Zone extends from surface to about 500 m depth, has thin zones of oxide and supergene mineralisation overlying hypogene chalcopyrite mineralisation, and is amenable to open pit extraction. The East Zone extends to at least 1700 m depth, is higher grade, occurs beneath an eastward-thickening cover of younger sedimentary and volcanic rocks, lacks oxide and supergene mineralisation, and is being evaluated for underground block-cave mining. Most Cu-Au-Mo was introduced with early K-silicate alteration and related quartz-sulfide veins. In the East Zone, a structurally-controlled overprint by advanced argillic alteration significantly increased Au and, to a lesser extent, Cu grades. Exploration potential at Pebble and its surrounding district remains high. Several other porphyry, skarn and epithermal deposits have been discovered in the district, but only limited exploration has been conducted. The eastern, higher grade part of the Pebble deposit remains open in several directions, with significant potential for resource expansion by ongoing, aggressive drill exploration. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By H R. Watling, W van Bronswijk

Of the various copper sulfides in the EarthÆs crust, chalcopyrite is by far the most common. This mineral is also the most difficult to leach, with hydrometallurgical extraction processes characterised by prohibitively slow kinetics. While a number of processes, including leaching at atmospheric pressure and temperature, pressure leaching at higher temperature, and bioleaching of concentrates in stirred tanks and whole ores in heaps have been demonstrated to some extent, there is currently no full-scale unit process for the hydrometallurgical extraction of copper from chalcopyrite ores. Titan Resources NL operated a test bacterial heap leach at Radio Hill, Western Australia in 2001, to extract nickel and copper from a mixed sulfide ore that contained significant amounts of chalcopyrite, pentlandite and pyrrhotite. A proprietary mixed bacterial culture was used to inoculate the heap, and the nickel and copper were precipitated from the resultant solution as mixed hydroxides. Although 65 per cent of the copper from the Radio Hill heap was eventually recovered, the rate of extraction followed an unexpected trend, as the initial rates of copper recovery were much slower than column tests had suggested. It was postulated that this was due to dissolved copper precipitating as covellite or chalcocite in the most poorly aerated zones within the heap, ie furthest from the aeration pipes at the base. It was further hypothesised that the lack of oxidants (oxygen, ferric iron) and the likely inactivity of bacteria in these areas limited the re-dissolution of such secondary copper precipitates. In this study the above hypothesis was tested in column experiments using the same mixed sulfide ore and a synthetic leach solution. One set of columns was aerated and another set was operated without aeration. Results showed that precipitation of copper occurred regardless of whether the column was aerated or not. The results suggested that pH of the leach solution played a significant part in the precipitation of the copper. Further column tests revealed this to be the case. These results are described here in detail.

Jan 1, 2004

By M J. Ireland, D P. Horne, S J. Simpson

The Sinclair Nickel Project, wholly owned by Xstrata Nickel Australasia (XNA), includes an underground mine, a concentrator, a village, an all-weather airstrip and associated mine infrastructure. The operation is located 70 km north of Leonora in the prospective and historically productive eastern Goldfields region of Western Australia. Xstrata Nickel has successfully developed the Sinclair deposit into a 350 kt/a operation since its discovery in November 2005, with contained nickel metal production to date in excess of 10 600 t, of which 5500 t is from the underground operation.The narrow, continuous, medium-grade Sinclair nickel sulfide deposit accessed by the Phoenix Decline has a shallow 15¦ - 20¦ plunge that is approximately 1000 m long down dip and open at depth to the north. The flat plunge and low-grade nature of the orebody presents challenges regarding the amount of horizontal waste development that can be economically excavated, which in turn affects ventilation, egress, mine services and diamond drilling.The mineralisation is hosted between an ultra mafic hanging wall and a basalt footwall and is being mined using a bottom up, sublevel open stoping method. The stopes are retreated to a central access, filling voids in the process with waste mullock where possible and using cemented mullock fill where end exposure is required. Tight filling the flat dipping hanging wall has proved to be challenging given the angle of repose for the waste mullock fill is steeper than the angle of the hanging wall.Reconciliations of mine performance against the original feasibility study show positive changes and operational optimisations enabling Sinclair to achieve its mining targets in a safe, sustainable and economic manner. This paper discusses the mining operations associated with the first two years of the Sinclair Underground Nickel Project, providing an overview of the various issues encountered and the lessons learnt in the process.CITATION:Ireland, M J, Horne, D P and Simpson, S J, 2012. Overcoming mine design and production challenges at the Sinclair underground nickel project, in Proceedings Narrow Vein Mining 2012 , pp 37-48 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By S Yang, J Wang, J G. Ning

A series of conventional dynamic uniaxial compression (CDUC) tests and coupled static-dynamic loading (CSDL) tests were conducted using a split Hopkinson pressure bar (SHPB) system to explore the dynamic mechanical behaviour and fracture characteristics of medium sandstone on a microscale in the laboratory. In the CDUC tests, the dynamic uniaxial compressive strength of the medium sandstone was rate-dependent, while the dynamic elastic modulus was not dependent on the strain rate. Then, we proposed a generalised model to characterise the rate-dependent strength from 17.5 s-1 to 96.8 s-1. In the CSDL tests, with increasing initial pre-static stress, the dynamic elastic modulus and dynamic strength increased nonlinearly at first and then decreased. The results show that two classical mechanical types (ie Class I and Class II) are observed from the dynamic stress-strain responses of the CDUC and CSDL tests. By means of scanning electron microscopy (SEM), the micro difference of post-loading microfracture characteristics in Class I and Class II behaviour was identified. In Class I behaviour, intergranular fracture (IF) usually initiates at or near the grains, most cracks deflected along the grain boundaries, resulting in a sharp angular edge, then coalesces to the main fracture surface that splits the specimen along the direction of stress wave propagation. In contrast, Class II behaviour results from the combined IF and transgranular fracture (TF).

Nov 29, 2022

By Crapp C. E

The Collinsville Coal Measures consist mainly of arenaceous sediments but indude eleven named coal seams. The Formation outcrops around the northern end of tbe Bowen Basin where it attains a thickness of 700 ft. in the Collinsville-Scottville area and overlies Lower Bowen Volcanies with angular unconformity. Most of the members in the Formation thicken basinwards. The regional dip is about 8 degrees. The Formation thins southwards and does not occur south of the Bowen River on the eastern flank. On the western flank it is represented by 60 ft. of barren sandstone at the limit of our mapping, 12 miles south of the Bowen River. Two seams are mined, the Bowen and the Blake; coal from the former produces high grade metallurgical coke, and the latter seam is mined for steaming coal. Where mined, the seams are about 20 ft. thick. The coals are of medium volatile bituminous rank and the lower coals are of higher rank than those above them.Reverse faults striking across the Coal Measures have been delineated and the existence of areas of intrusive rocks has been established. Intrusions rose up fault planes and, as felspar porphyry sills, selectively intruded coal seams, decimating reserves of coalavailable for mining. One sill, in the Blake Seam, attains a known thickness of 115 ft. Because the distribution and thickness of the sills is rarely predictable, density of drilling has been greater than in most coalfields.INTRODUCTIONThe assemblage of sediments occupying the northern portion of the Bowen Basin (Fig. 1) may be divided into four formations of Permian age:The Upper Coal Measures (U. Bowen)The Middle Bowen Marine Beds (M. Bowen)The Collinsville Coal Measures (M. Bowen)The Lower Bowen Volcanics (L. Bowen).Of these, the Upper Coal Measures and the Collinsville Coal Measures are known to contain coal seams of workable thickness.

Jan 1, 1960

By C X. Zhang, W K. Ru, S C. Hu

To study the creep properties and the energy evolution characteristics of the weakly cemented rock (WCR) in western China, the creep deformation damage law of weakly cemented mudstone (WCM) under graded loading and the energy evolution characteristics of each creep stage were analysed based on the triaxial graded loading creep test of WCR. The results showed that as the confining pressure increased, the creep failure strength of the WCM increased from 9.5 to 24.8 MPa, and the relative displacement of the mineral particles in the mudstone increased gradually, resulting in a reduction in the fracture angle from 79.7° to 58.3°. At the same stress level, the strain energy Ue, the total energy U, and the dissipation energy Ud all increased as the confining pressure increased, but the growth rates of U and Ud decreased gradually, while the growth rate of Ue remained high. At the end of the stable creep stage, Ue increased slowly with the confining pressure, while U and Ud increased rapidly with the confining pressure, and their growth rates were basically the same. At the end of the accelerated creep stage, the growth trends of these three energies were all positively correlated with the confining pressure, Ue was significantly lower than that at the end of the stable creep stage, and Ud and U were further increased. These results revealed the unique creep properties and energy evolution characteristics of the WCR, providing a theoretical basis for long-term stability control of roadways that are built with WCR.

Nov 29, 2022

THE slag from the blast furnaces having been granulated, a representative sample is taken to the sample mill. It is then dried, crushed through a 100-mesh screen, intimately mixed, and packeted for assay purposes.METHOD OF ANALYSISINSOLUBLEWeigh 1 grm. of the finely-pulverized slag into a 3t-in. casserole, moisten with a little water to prevent sticking, cover with a clock glass, and add 20 cc. of hot acid (1 HNOs, 3 HCI, 4 H2 0). Evaporate slowly to dryness on a hot plate and bake (without overheating) until all the gelatinous silica is dehydrated. Cool, add 20 cc. HCI (1-1), and boil gently for several minutes; filter into a 300-cc. beaker, cleaning out the casserole thoroughly with a rubber-tipped glass rod. Wash residue with hot distilled water and transfer it to a No. 1 porcelain crucible. Dry, ignite, cool in a desiccator and weigh as total insoluble matter. Dilute filtrate to 200 cc. and neutralize some of the excess HCI with NHa.OH. Warm, and pass H2S for 15 min. Filter and wash withhot water. Boil off H2 S, oxidize with 5 cc. HNOll , reduce bulk of the solution by evaporation. to about 100 cc., and transfer to a 250 cc. flask.SILICAFuse insoluble residue over a blast lamp in a platinum crucible with three or four times its weight of anhydrous carbonate of soda, for 10 to 15 minutes, or until decomposition is complete. Cool, and extract fusion in an 8-in. evaporating dish with HCI (1-1); rinse crucible and cover with distilled water, and evaporate to dryness over a water bath. Take up dry mass with 10 cc. strong HCI, and then.

Jan 1, 1922

By W Y. Guo, L X. Chen, D X. Zhang

To obtain the rock type-I crack propagation process accurately, a novel fixture is used to make the prefabricated crack of rock propagation along the predetermined direction. In this study, the crack propagation process of rock is monitored with the digital image correlation method (DICM), and a mechanical model of crack directional propagation was established. The results show that the simple crack directional propagation device can effectively realise the stable propagation of type-I crack along the predetermined direction, the crack initiation angle is less than 10°, and the deviation between the peak strength of crack propagation calculated by a simplified mechanical model and the tensile strength of Brazilian splitting is 22.76 per cent and 7.53 per cent, respectively. According to the deformation field evolution law, crack propagation can be divided into three stages: microcrack development, main crack propagation, and main crack propagation. As for the rock type-I crack initiation and propagation mechanism, before reaching the peak strength, the prefabricated crack tip is subjected to maximum tensile stress; the elastic energy increases rapidly, and the dissipation energy increases slowly; after the peak strength, elastic energy exceeds its energy storage limit and released rapidly, and most of the input energy is converted into dissipation energy, which makes the crack propagation rapidly. The crack directional propagation device will be further optimised and improved, and it is expected to provide a new method for the study of crack propagation mechanism, rock failure precursor information and crack arrest principle, etc. It will also provide theoretical references for the optimisation of coal strata directional blasting, fracturing, fracture arrest, and other related technologies in geotechnical engineering.

Nov 29, 2022