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By W. Krieglstein

Due to the natural variability of ores, it is necessary to carefully test flotation behavior of flotation cells before designing flotation circuits. For performing quick and versatile tests in the laboratory, Siemens developed a laboratory-size Hybrid Flotation Cell, which has been down-scaled from the 300 m³/h production cell to a 0.6 m³/h flotation cell. This small cell is being used as a test bed for technical and chemical concepts, the improvement of decisive components and the characterization of customer ores. In this study the evaluation results for Andean porphyry copper ores are shown. Total recovery rates of the order of 45 to 50 % have routinely been achieved in a single flotation cycle over a wide range of feed grades. In addition, the Hybrid Flotation Cell has proven to be particularly well suited for the flotation of fine particles below 20 µm down to below 1 µm, at high recovery rates and concentrate grades.

Sep 1, 2012

By Alok Tripathy

A simulation code called SIMJIG and the user interfaces have been developed using discrete element method (DEM) and the .NET platform respectively for the jigging process. DEM platform is used for tracking of particles in the jigging operation. DEM uses the net force balance on the particles to track the trajectory of the particle. Simulation results are compared with experimental results obtained by jigging of low grade iron ore lumps. Two different iron ore samples one from Chatishgarh and one from Odisha were used for the experimental studies. The Alljig? stratification test rig meant for batch laboratory experimental studies has been used in the present work. The behavior of different sizes of material on jigging has been examined. Later, the particle size behavior during jigging at different layers of the jig bed has been studied. Further stratification profile across the jig bed has also been studied. It was observed that simulation results are matching quite nicely with the experimental results. The SIMJIG simulator developed in the present study could be used for predicting the performance of the jigging operation effectively. Keywords: DEM, gravity concentration, jigging, iron ore, simulation

Sep 1, 2012

By S. F. Ye, L. Xiao, Y. L. Wang, P. W. Han

"Copper anode slime is a precious secondary source for the recovery of silver. However, current recovery process are constrained by either sever pollution or high cost. To cover the drawbacks of current process, this research employed a novel strategy by using the manganese dioxide as the oxidant in acid solution, which avoided the generation of sulfur dioxide while high silver extraction rate was achieved. The effects of manganese dioxide, sulfur acid concentration, stirring speed, temperature and leaching time on silver extraction rate were investigated. The silver recovery reached to 91.68% under the conditions of 1.2 g manganese, 2.0 mol/L H2SO4, 300 rpm, 80 °C and 6 h. INTRODUCTION Copper anode slime is generated from the electrolysis refining of copper and is extremely precious for its containing noble metal such as silver (Chatterjee, 1996; Amer, 2003; Yldrm et al., 2014; Syed, 2016; Wang et al., 2017). Therefore it is of great significance to extract silver from anode slime for the full utilization of resource. Pyrometallurgy is the most mature process for the extraction of silver because of its stability and adaptability (Hait et al., 2009; Zhao et al., 2010; Gao et al., 2017). However, it also suffers the drawbacks of high operating cost, low extraction rate of silver and severe pollution of smoke dust (usually containing lead and arsenic) (Ludvigsson and Larsson, 2003). To cover the drawbacks of pyrometallurgy process, more and more attentions are giving to the semi-hydrometallurgy process which usually includes a pretreatment process of sulphatising roast or low temperature oxidizing roasting (Tishchenko, 1964). After pretreatment, the refractory silver bearing phases (silver selenide, silver sulfide and silver) are converted into readily leached forms which are often extracted by ammonia, sodium sulfite in alkaline solution (Valiuniene et al., 2010; Wojciech, and Kitka, 2017). Despite its relatively high extraction rate and low investment, it still has the disadvantages of releasing harmful gases since the sulfur dioxide are generally generated in the pretreatment process. In addition, the use of ammonia can easily lead to a leaking into the atmosphere once not carefully dealt with (Aylmore and Muir, 2001). As for silver recovery by sulfite leaching, the consumption of sodium sulfite is rather high which often results in a pipe blocked (Yang et al., 2006)."

Jan 1, 2018

By J. H. Starkey

SAGDesignTM Testing for grinding mill design was introduced commercially in 2004. Up to January 2008, 18 projects have been completed and 99 samples have been tested using this method. Two papers have been published describing the patented test procedure and one of these shows how the results compare with other grinding test methods. This paper will briefly discuss the theory on which this technology is based, and explain the procedures used to develop the calibration equation. Case studies are also included to demonstrate the effectiveness of the test work being done. These case studies show how the SAGDesign test is being used today: to design new grinding circuits for commercial full scale use; to calculate throughput in existing mills for production planning; and to accurately define grinding mill requirements at the scoping, pre-feasibility or feasibility study stage of project development, in order to economically identify the size and cost of the grinding mills that will be needed for the project. This is important because if the full rec-ommended SAGDesign testing program is done at an early stage in the project, the definitive cost for a guaranteed throughput, grinding mill design (by Outotec if their mills are purchased) is available. New grinding mill design for final engineering will be represented by the test work done on the Climax Molybdenum Project for Phelps Dodge (now FMI) in Colorado, USA. The SAG mill and ball mill for Climax are now in fabrication with project start up in late 2009. Next, the sizing of grinding mills at the scoping, pre-feasibility or feasibility study stage of mine development will be represented by a large metal mining property in Russia. Finally, calculation of the throughput for existing mills will be represented by work done at a base metal mine, in eastern Canada. Test work for designing SAG mills is now done in four laboratories at the time this paper was written. One in the USA at Dawson Metallurgical Laboratories, Inc. in Salt Lake City, two in Russia at the TOMS Research and Design Institute and at the Irgiredmet Research Institute, both in Irkutsk, and a fourth mill has been installed in Australia at AMMTEC Limited?s lab in Perth. A fifth SAGDesign test mill for radioactive ores has been built by Starkey & Associates, specifically for testing uranium ores and can be moved to any licensed lab in the world on a project basis.

Jan 1, 2014

By Jing Zhou

In view of the state of the long time use of sodium cyanide in lead-zinc-sulfur-silver multimetallic ore production, we propose alternative reagents system through experimental research. The experiment first used TJ, sodium sulfide to adjust the flotation pulp, after that, zinc sulfate, sodium sulfite was added to low alkaline pulp to inhibiting zinc sulfur mineral and adapted MB, 25# aerofloat and diethyl dithiocarbamate combination collectors to float lead minerals. The obtained test index is as follows: lead concentrate recovery rate of small scale test was increased by 5 to 10%, the recovery rates of gold and silver in lead concentrate were increased by 7% and 11% respectively; the industrial test is conducted under the condition that the total grade of lead and zinc content in raw ore decreased by 4.81%, the total recovery rate of lead and zinc increased by 7%, recovery rates of gold and silver in lead concentrate were increased by 7.62% and 9.65% respectively. So it successfully realizes the target to replace the sodium cyanide, using low-alkaline non-toxic reagents system in mineral processing practice of three kinds of complex lead-zinc-sulfur ore of this mine. Keywords: refractory lead-zinc-sulfur ore, depressant, non-cyanide flotation

Sep 1, 2012

By L. Semushkina

Next generation flotation agents of KSK series for the concentration of complex copper-lead ores and the new ferromagnetic nanosized depressor of galena are introduced in this work. The feature of the KSK flotation agents is that they exhibit both frother and collector properties. KSK-6 can successfully substitute the widely used in Kazakhstani industry reagent ?-80 at the reduced consumption of butyl xanthate by 30 %. The new ferromagnetic nanosized depressor of galena, besides a low consumption rate of 100 g/t, also makes possible to exclude sodium sulfite (3-4 kg/t) and ferrous sulfate (5-6 kg/t) from the separation process, and receive high metal grade concentrates. Keywords: complex copper-lead ore, flotation agent, concentration method, ferromagnetic nanosized depressor

Sep 1, 2012

By R. Sakthivel

Blue dust is a high grade soft haematite material containing 96.14% Fe2O3 transformed into magnetite (Fe3O4), when it is subjected to planetary ball milling in the presence of iron powder as reducing reagent. X-ray diffraction (XRD), Field emission scanning electron microscope (FESEM) and Laser particle size analyser have been employed to characterize various samples collected at various milling times to know the phase evolution, particle size distribution and morphology of particles. X-ray diffraction studies reveal the formation of magnetite phase at the optimum milling time of 40 hours. Vibrating sample magnetometry (VSM) study demonstrates, that sample obtained at 40 hours of milling time exhibits saturation magnetisation of 14.757 emu/g whereas the starting material used in this study shows only 1.0425 emu/g. Keywords: Blue dust, reaction milling, magnetite, saturation magnetization

Sep 1, 2012

By Z. Hu

A complex polymetallic sulfide ore in Yunnan, China, has various valuable minerals, which are Chalcopyrite, Galena, Pyrite, Gold, Silver, and Magnetite. A reasonable new flowsheet with a bulk flotation and a flotation separation of sulfide minerals that are Chalcopyrite, Galena, and Pyrite was carried out at first stage. After that tailings were treated by low intensity magnetic separation to achieve magnetite concentrate. A high Pb concentrate assaying 60.00 percent Pb at total recovery of 75.71 percent with 40.50 g/t Au and 1390.00 g/t Ag, a final high Cu concentrate assaying 24.45 percent Cu at high recovery of 92.03 percent and a magnetite concentrate assaying 60.78 percent Fe at recovery of 33.61 percent with 18.45g/t Au and 234.99 g/t Ag, are obtained. The total recovery of Gold and Silver in Pb concentrate and Cu concentrate reached 71.63 percent and 67.32 percent, respectively. It is shown, that this new flowsheet could realize efficient recovery for all of the valuable minerals in the ore and is easy to be industrialized. Keywords: bulk flotation, magnetic separation, polymetallic sulfide ore, depressant

Sep 1, 2012

Domestic production of pyrite cinder reached 15.95 million tons in 2006. The pyrite cinder used in cement industry accounts for about 30% production. The remaining 70%, 11.17 million tons, was thrown away as waste, which brought serious environmental and resource problems. A new technology of composite pellet reduction-roasting and magnetic-separation (CPRM) has been developed to utilize pyrite cinder. Pyrite cinder sample, containing 45.56% Fe, 0.19% Cu and 1.45% S, was pelletized with addition of 5% composite agent in balling disc. Green balls after drying were reduced at 700~800 ? for 20min with 300kg/t pulverized coal injection in rotary kiln. After two stages of ball-grinding and four stages of magnetic separation, high grade magnetite concentrate with 66.23% Fe was produced, meanwhile impurities Cu and S was decreased to 0.048% and 0.053%, respectively. And iron recovery of 73.32%, desulphurization of 96.34% and decoppering degree of 74.73% were achieved. Key technique is that composite agent can accelerate reduction of Fe2O3 and transfer copper and sulphur into water-soluble inorganic salts, which can be removed during wet magnetic concentration. This new technology can be used to fully utilize pyrite cinder and produce high quality magnetite concentrates as feed for steel industry, which will help tackle the pollution problem of pyrite cinder and extend iron-bearing raw material sourcing for Chinese steel industry.

Jan 1, 2014

By F. Y. Kang

Graphite with layers structure is easily to form graphite intercalation compounds (GICs) by means of intercalation reactions due to the weak cohesion force among carbon layers, van der Waal?s interactions. By controlling the oxidation-intercalation, high quality exfoliated graphite with low residual sulfur content and MClx-GICs (M=Fe, Co, Ni, Cu, Zn) powder for electromagnetic wave absorbing and shielding materials have been invented. The expansion volume of expandable graphite can be larger than 160 mL/g while the residual sulfur content is less than 800 ppm. The MClx-GICs powder can shield infrared ray and laser completely up to 15 min. We have also in-vented exfoliated graphite for heavy oil adsorption and mild-expansion exfoliated graphite for anode materials in lithium ion battery by controlling the intercalation/de-intercalation. The exfoliated graphite can adsorb heavy oil up to 80 g/g, it also exhibits better performance than commercial active carbon in sewage treatment. The mild-expansion exfoliated graphite as anode material shows high capacity of 370 mAh/g and good cycle performance.

Jan 1, 2014

By Jurgens J. Louw, Vincent C. Smith, Gareth C. Smith, Agit Singh, Dave G. Hulbert

"The flexibility of the PlantStar control platform has enabled Mintek to investigate and easily develop new control strategies for both milling and flotation. This includes a Solids Feed Controller, a Safety Limit Controller, Mill Power Optimiser and Flotation Optimiser, amongst others.The solids feed controller was developed for minerals processing plants using a specialised time delay compensator. Using conventional time delay compensators that are purely model based, results in robustness problems due to model uncertainties. The Mintek Solid Feeds Controller makes use of a plant model, but compensates for model inaccuracies, giving more controller stability and a more robust delay compensation algorithm.The safety limit controller has been developed to switch smoothly between normal and safety control loops without bumping the process. The safety loop output is chosen in accordance with a predefined list of priorities and whether the respective constraint boundaries are exceeded.The Mill Power Optimiser helps to find the power peak on the mill power curve. This insures maximum grind with maximum throughput. It also prevents power dips due to mill overloads, making the milling circuit easier to operate.The flotation optimiser algorithm analyses trends of all accessible variables in the process. The algorithm uses this information to calculate operating conditions that will control the residence times, mass pulls and circulating loads within a flotation circuit to a specified setpoint. Research is being done to now optimise these setpoints in order to achieve better recovery."

Jan 1, 2003

By G. Y. He

The large-scale 8.53m×3.96m (28?×13? F/F) SAG mills was first applied in Donggua Hill Copper Mine which processes 13,000 tons ore per day. The crushing and grinding circuit went into operation in the Donggua Hill plant in October 2004. However, at the beginning, the productivity of grinding only reached 58% of the capacity expected and some indexes of the crushing and milling circuit didn?t meet the requirements. Especially, the total load of the 8.53m×3.96m (28?×13? F/F) SAG mills was up to 34%~41% (25%~30% designed)and some hard rocks with the size of 25~70mm, which can?t be treated as a medium or even would be crushed and make larger ores or steal balls necessary, were seriously accumulated in the SAG mills. Consequently, they occupied the effective mill volume which in turn reduced the efficiency of the SAG mills and increase the energy consumption. In order to solve the problem of accumulation in the SAG mill and increase its productivity, some measures were taken, such as passing more hard pebble through the grate at mill dis-charging end, changing the type of steal balls and so on. And the results showed that these measures functioned well and had good effects, which is that the filling percentage of the SAG mills has been reduced to 26%~29% from 34%~41% with the composition of particle sizes improved a lot and the productivity increased by 77.4% reaching up to 13,380 tons per day.

Jan 1, 2014

By Peter Riccio

Oxiana Sepon?s mineral processing facility in south central Laos produces copper cathode using leach-autoclave-SX/EW flotation technology. Pyrite recovery in the flotation circuit is critical to the operation, as it is used to generate acid for the leach circuit. However, low pyrite recovery has been an ongoing challenge in the flotation circuit. Tailings characterization work done by Ian Wark Research Institute showed that the pyrite losses to the tail are made up of a combination of coarse liberated particles and finer particles that have been coated by clay fines. In December of 2005, a joint Cytec-Oxiana technical program was initiated to address the pyrite recovery issue. A series of diagnostic tests were performed in the Cytec Stamford Research Facility using synthetic plant water showing that the collector was precipitating as a metal salt, and was un-available for mineral attachment. The tests also identified several collector chemistries that would likely be robust in the Sepon low pH, high dissolved metal ion environment, and will not complex with ferric, ferrous, or copper in solution. With the support of the Sepon on-site engineers, an extensive, successful laboratory program was completed, which then was followed by on plant testing that showed a step wise improvement in pyrite recovery.

Jan 1, 2014

By Sanjay Agarwal

Polymetallic sea nodule is a good source of manganese having 22.3% Mn, 5.4% Fe, 6.14% Si, 1.1% Cu, 1.15% Ni, 0.076% Co & others. These nodules are available in plenty on the sea beds, generated over thousands of years. Nodules mainly consist of manganese dioxide and iron oxide phases and other metals are entrapped in the complex cage of these Mn-Fe oxides phases.World-wide research is going on sea nodules as an alternative future source of many metals, which has led to intensified efforts to develop practical and economical processes for recovery of these metals. Very little attempt has been made world over on manganese extraction from sea nodules. We at CSIR-NML, India have developed a direct reduction smelting process of nodules to recover manganese as Fe-Si-Mn alloy. This alloy is extensively used in the steel industry as deoxidizer and as an alloying element to make different grades of steel. Lab scale experiments were conducted to study the manganese distribution between Fe-Si-Mn alloy and FeO-SiO2-MnO-CaO-Al2O3-MgO slag at different temperatures by varying the basicity of the slag. The direct reduction smelting of nodules is carried out on 1 kg scale in 50 kVA electric arc furnaces to have Cu, Ni and Co alloy and Mn rich slag. This manganese rich slag is further treated in 50 kVA arc furnace to produce Fe-Si-Mn alloy. The composition of Fe-Si-Mn alloy obtained is in the range of Mn: 60-65%, Si: 14-17%, C: 1- 2%, S: 0.03% and the balance iron which is acceptable grade for industrial use. The equilibrium amount of MnO in the final slag is controlled by the temperature of the final melt and the silica, lime, alumina content of the final slag. Increasing the basicity of the slag plays a major role in minimizing the loss of MnO to slag, increasing the amount of SiO2 of the slag, increases the manganese loss in the slag. Increasing the CaO/ Al2O3 ratio of the slag decreases the manganese loss in the slag. Increasing the MgO/CaO ratio of the slag increases the manganese loss in the slag. Thus by adjusting

Sep 1, 2012

By E. V. Konoplev

Russia is one of the largest manufacturers of potash fertilizers in the world. Processing of potash ores basically is carried out by a flotation way. Potash ores of the Verhnekamsky potash deposit contain sylvite (KCl), halite (NaCl) and water insoluble impurity (up to 8 %), presented silicate- carbonate minerals, easily slimed by ore crushing in rod mills. Ore of some deposit sites, developed by ?Uralkali? Co, contains a significant amount of a carnal-lite (KCl.MgCl2.6H2O). Work practice of flotation potash plants has shown, that increase of car-nallite content in ore leads to increase magnesium ion content in a circulated plant brine (saturated salt solution of potassium and sodium chlorides-sylvite brine) and to deterioration of indicators of ore processing. In the Paper we present results of researches of floatability of various size sylvite and influences silicate-carbonate slimes on sylvite flotation in brines with the various magnesium chloride content. It is established, that with increase magnesium chloride content in the brine mainly decreases the flotation of coarse sylvite and amplifies adverse effect of silicate-carbonate slimes on sylvite flotation. In this connection deterioration of potash ore flotation is caused not only decrease sylvite floatability but also strengthening adverse action of water insoluble impurity on potash flotation. It is shown that the application of frothing agents, which render the stronger dispersive action on the colloidal-micellar structures of amine in the salt solution increases the absorption of collector on the sylvite and improves the flotation of sylvite into magnesium the containing salt solutions. The application of an organic depressor to the greatest degree of decreasing the absorption amine on the slimes and to the smallest degree possessing anionic properties proves to be most effective with the flotation carnallite of the containing potassium ores. It is offered the application the frother on a basis of glycol ethers and organic depressor on a basis of urea-formaldehyde resin. Results of industrial tests developed reagent modes for flotation treatment of ores with the raised carnallite content (to 6 %) on ?Uralkali? Co plant have shown that their application has allowed to receive equivalent indicators potash flotations at change of magnesium chloride content in the brine from 0.7 % up to 2.4 % .

Jan 1, 2014

By Ibrahim Alp, Ersin Yazici, Oktay Celep, Haci Deveci

Low extractions (<80%) in cyanide leaching impose the application of physical and chemical pre-treatment methods (e.g., ultra-fine grinding, roasting, alkaline leaching) prior to cyanide leaching to achieve acceptable recoveries. The effectiveness of the selected pre-treatment method is linked intimately with inherent mineralogical properties of ore. In this study, a refractory silver ore assaying 145 g/t Ag was subjected to various pretreatment tests in an attempt to eliminate its refractoriness. Direct cyanidation of the ground ore (d80: 65 µm) produced a low silver extraction of only 29.5% over 24 h indicating its high refractoriness. Previous studies have shown that silver occurs mainly as Sb/As containing sulfide minerals such as pyrargyrite (Ag3SbS3), tetrahedrite (Cu12Sb4S13) and proustite (Ag3AsS3), which do not respond well to cyanide leaching. Also, silver-containing minerals are closely associated with and/or encapsulated in other mineral phases that can restrict the contact of cyanide with silver. Therefore, alkaline leaching (using 3 M of Na2S, NaOH or KOH solution) and ultra-fine grinding as pre-treatment methods were tested to improve the extraction of silver. All the alkaline leaching tests were carried out for 3 h at800C. Neither NaOH nor KOH leaching produced the desired effect on the extraction of silver (i.e., ~30%). Even, a sharp decrease in the extraction of silver (i.e., 10%) was observed in Na2S leaching. On the other hand, ultra-fine grinding (UFG) (d80: 3 µm) substantially improved the extraction of silver in cyanide leaching (95% Ag at 24 h after UFG). It can be inferred from these findings that the refractoriness of the ore is essentially physical in character (i.e. the encapsulation of silver presumably in non-sulphide minerals such as barite and quartz).

Jan 1, 2014

The traditional technological flow sheets for processing of ferrous quartzite (magnetite ores) al-low production of the iron concentrates with Fe content of 65%~68 % and recovery level about 55 %. The losses of iron with the tails of wet magnetic separation are related to hematite and quartz-magnetite particles, which are not extracted under low magnetic field employed. This work presents the results of the application of reverse cationic flotation for production of hematite concentrates with weak silica content from the tailings of wet magnetic separation of mag-netite. Fine particle size, complex mineralogy and presence of locked particles determine the impos-sibility of direct production of hematite concentrate by flotation or magnetic separation. The gravity concentration allows obtaining of iron concentrate from the well-prepared feed (size fraction -53+20 µm) but with very low recovery. Thus, hematite concentrates with weak silica content and satisfactory iron recovery were obtained by reverse cationic flotation, when it was fed with iron pre-concentrate produced by high gradient magnetic separation. The best flotation results were obtained by the use of formulations based on amines of different molecular structure that modulate the structure of adsorption layer, and favour a shifting of hydro-philic-hydrophobic balance on the surface of silicates with adsorbed starch and their preferential transfer into the froth product.

Jan 1, 2014

By Zhu Yangge, Hu Xiaoxing, Feng Qiming, Zhang Guofan, Zhang Xingrong

"During the flotation process of ilmenite and titanaugite with fatty acid as collector, unavoidable ions such as Ca2+, Mg2+, Al3+, Fe3+ and Fe2+ demonstrate considerable influence on the floatability of the minerals. In this study, flotation test, zeta potential test, and solution chemistry calculation were adopted to investigate the mechanism of how these metal ions affect the floatability of ilmenite and titanaugite in different pH conditions. The results show that in weak acidic solution, Ca2+ and Mg2+ mainly freely exist in the solution with little adsorption on mineral surface, and their reaction ability with oleate ions is weaker than active site on ilmenite surface (Fe), thus they show negligible effect on the flotation of ilmenite; Al3+ shows similar reaction ability with oleate ion compared to Fe3+, which lead to competitive reaction with collector, so the flotation of ilmenite is depressed. While Fe3+ can adsorb on surface of titanaugite in the form of Fe(OH)3, and it shows stronger reaction ability with oleate ion compared with active site on titanaugite surface (Ca and Mg), which proves an activation effect on titanaugite flotation. In alkaline solution, all these five kinds of ions can adsorb on titanaugite surface, and the floatability of titanaugite will be activation. Based on the above analysis, it can be deduced that in the flotation system using fatty acid as collector, the adsorption of metal ions on mineral surfaces and the stronger reaction ability with collector than active site on mineral surfaces, are the two prerequisites for metal ions show activation effect on mineral flotation.INTRODUCTIONIn flotation pulp, the existence of metal ions is often inevitable. There are two sources for these metal ions: the first part is generated in grinding and flotation process due to the oxidation, reduction, corrosion or dissolution of minerals or grinding medium; the second part is from the flotation water or the addition because of the technology need. The metal ions in the pulp have a considerable influence on mineral flotation. Earlier researches are focus on the activation effect of mineral floatation by metal ions to obtain a higher flotation efficiency, many effective activators were found, such as Cu2+ activated sphalerite, Pb2+ activation wolframite, and Ca2+ activation quartz flotation, these metal ions have become the commonly used activators in industrial production. And many studies attempted to explain the mechanism of how metal ions affect the floatability of minerals. James (James et al, 1972) suggests that metal hydroxide precipitation is the main component leads to activation effect, while the study of Fuerstenau (Fuerstenau, 1976) showed that the metal ion hydroxyl complexes played significant role. In recent years, the reuse of mineral processing wastewater has attracted more attention (Rao et al, 1989; Liu et al, 2013; Wang et al, 2014), as a main component in flotation wastewater, the influence of “unavoidable ions” on flotation process still need in-depth study."

Jan 1, 2018

By Benoit Clermont, Jan Lux

"Magotteaux and Anglo Platinum started a co-operation program with the main aim of establishing the optimum milling configuration measured in terms of throughput, fineness and energy consumption.For this purpose, a fully instrumented pilot milling plant, supplied by Magotteaux (Pty) Ltd, and equipped with a 0.9 x 1.0 m ball mill, was erected at Frank concentrator (Merensky Pt ore). The primary ball mills at Frank concentrator were surveyed in order to set the conditions for the base case. This data was then replicated in the pilot mill under the same configuration. Thereafter, a series of different parameters were varied in order to attempt to optimize the milling system.Some of the grinding parameters that have been studied are:•,Gate versus overflow discharge•,Open versus closed circuit•,Different filling degrees•,Different shell liner profilesOnly grate versus overflow discharge and open versus closed circuit will be discussed in this paper.It should be noted that this paper does not attempt to give a universal solution as to what milling configuration is optimum in all cases. The conclusions apply for this particular case and probably most others, but it would be advisable to consider each case on its own."

Jan 1, 2003

By T. Chmielewski

Unique mineralogical and petrological properties of black shale in the copper ore deposit of the Foresudetic Monocline (SW Poland) resulting from three lithological layers have been described in terms of its unfavorable behavior in the ore processing circuits. A concept of processing of a part of the black shale fraction from the flotation circuit of the concentrating plant by separating a by-product enriched in the shale matter was presented. This by-product represents the tailings of the first cleaning flotation and, as a hard-to-treat circulating middlings, overload the cleaning operation in the flotation circuit. It was found that the investigated by-product cannot be effectively up-graded using standard xanthate flotation. This is due to a fine dissemination of sulfide minerals in the dolomitic and clay shale particles significantly enriched in organic carbon. The content of the organic carbon is similar to that in the petrographically "pure" black shales. After a comprehensive examination of the shale by-product it was recognized that the investigated middlings can be regarded as a specific shale concentrate for individual processing. The effect of non-oxidative leaching of middlings with sulfuric acid on their further flotation was presented. It was shown that non-oxidative leaching is a selective process, in which calcium and magnesium carbonates decomposition leads to effective liberation of sulfide minerals which were finely disseminated in the hydrophilic carbonate gangue. Leaching of the flotation feed with sulfuric acid selectively decomposes carbonate minerals and consequently enhances flotation results. Saturation of leaching slurry with gaseous carbon dioxide favorably creates non-oxidative conditions and leads to a great decrease of the electrochemical potential of sulfide particles as well as hinders their solubilization. Partial carbonates leaching from middlings resulted in evident liberation of valuable minerals. Consequently, it resulted in an increase of both recovery and grade of concentrates obtained by flotation of shale by-product after non-oxidative leaching.

Jan 1, 2014