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By Les Johnston

_ BACKGROUND - About EPCOR - Genesee Generating Station - Phase 3 Expansion _ TECHNOLOGY SELECTION - Selection Criteria - Combustion Options - Flue Gas Emission Control Options _ STAKEHOLDER VIEWS _ PROJECT STATUS _ EPCOR is an integrated utility company for water, gas, electricity and technology services. _ EPCOR has about 1.6 million customers in Alberta, Ontario, Manitoba, BC, and the U.S. Pacific Northwest. _ EPCOR Generation Inc. operates three power stations in Alberta which were in operation before deregulation, including the coal-fired Genesee Generating Station. _ EPCOR Power Development Corporation owns generating stations in Alberta, BC and Washington State and will be building the Genesee Phase 3 expansion.

May 1, 2002

By Roy Lindsay, Paul O'Hara, Gary Halverson

"The New Britannia Minesite is located in Snow Lake, Manitoba, 420 miles north of Winnipeg (figure 1). The mine previously operated from 1949 to 1958 extracting some 5.39 million tons of ore at a 0.150 opt gold grade. From 1959 to 1986 the property was held by Nor-Acme and Hudson Bay Exploration and Development and in 1987 High River Resources Ltd. Optioned the property, dewatered the mine and conducted a diamond drill program between the 1 780 and 2400 levels. In 1988 two companies, Nor-Acme Mines Ltd. and High River Gold Mines Ltd., negotiated an option agreement with INCO Gold whereby !NCO assumed management control of all site exploration work. During this period, a bulk sample of 10,000 tons was extracted from the 1780 level with no further exploration recorded after its removal. Both Hudson Bay Exploration and Development and INCO Gold conducted feasibility studies on reactivating the property but at a calculated capital cost of Cdn $70 to $80 million found the rate of return on their investment unacceptable.In 1991 !NCO Gold merged its interest with the assets of TVX Gold Inc. and in February 1994 TVX Gold Inc. and High River Gold Mines Ltd. entered into a joint venture partnership to develop the Snow Lake property, naming TVX Gold Inc. the operator. Upon completion of a feasibility study in April 1994 by Bharti Engineering Associates Inc., a decision was made to reopen the Britannia Mine at an established project cost of US $33 million.Project construction commenced in July 1994 with the hoist house excavation. The first concrete for the hoist house level footings was poured on August 4, 1994 and the project was completed on October 1, 1995 at a cost of US $36 million. The first gold pour took place November 4, 1995.This paper not only presents the metallurgical aspects of the operation but also describes the novel approach used to complete the design and construction of the site facilities."

Jan 1, 1996

By P. N. Saavedra, E. A. Salamanca

"The maintenance strategies in the mining industry are changing from operative and periodic inspection strategies to a condition-based, predictive maintenance strategy centred in vibration analysis plus complementary techniques. Condition monitoring can also help to improve availability by being able to pinpoint and diagnose problems on operating machinery at an early stage. This reduces unscheduled downtime and production losses.However, in mining, for shovels operating in transient modes, with variable load and/or speed, the FFT (Fast Fourier Transform) standard approach is not directly applicable for analysis. This work illustrates how spectral order analysis and new transforms, called time-frequency transforms (TFT), allow us to monitor the shovel when it is working. Some practical examples showing the application of these analysis techniques to occasional vibrations measured on hoist and crowd transmission of a shovel are also presented. It is shown that at present, it is possible to carry out the vibration monitoring in the mining shovel while it is working, therefore avoiding the high cost of a loss of production which can occurr in traditional monitoring, where the measurement is taken while the shovel is out of production."

Jan 1, 2002

By A. R. Miller, G. Desrivières, M. C. Bétournay, D. L. Barnes, P. Laliberté

"Over the last four years, an international initiative, championed by Vehicle Projects LLC, the Fuelcell Propulsion Institute and Natural Resources Canada, has been active in carrying out research projects to prove out the concept of applying fuel cell technology to underground mining vehicles. These have been carried out by a consortium consisting of mining companies, equipment manufacturers, technology developers, national laboratories and consultants, with the participation of Canadian and U.S. mine regulatory agencies.This clean technology, which produces only water and electricity, would allow several advantages to be obtained, in the health area (by eliminating diesel emissions and reducing noise generation), in lowering production costs (such as reducing ventilation required) and lowering greenhouse gas emissions.This paper outlines the results obtained in several key areas, such as, the operation of fuel cells in underground conditions, risk issues related to underground and surface operation of hydrogen vehicles and hydrogen production and delivery systems, and the design and mining performance of the world’s first hydrogen mining vehicle, a mine production locomotive. The work to date on the fuel cell loader, designing the power plant and power transmission systems, operational requirements, and operating cost reductions is also presented."

Jan 1, 2003

By T. Yeomans

NVI Mining’s Myra Falls operation is a forty-year-old underground mining operation feeding a 4,000 metric tonnes per day concentrator. The current mill, built in 1985, was designed to process a massive sulphide ore-body. This orebody, known as the HW, contains about 50% pyrite. Minerals of value are chalcopyrite and sphalerite, with precious metals occurring in all mineral types. By 1997, mining of a new ore-body, known as Battle-Gap, commenced. Mineralogically complex, the new orebody contains about 15% pyrite copper minerals, including primary chalcopyrite and secondary bornite, chalcocite and tennantite, combined with increased galena and sphalerite. Flotation performance generally decreased with increasing amounts of Battle-Gap ore types, with both copper concentrate quality (increased lead and zinc content) and copper recoveries being affected. Following significant metallurgical test-work, a new, fully sequential copper-lead-zinc flotation flow sheet and reagent scheme was developed. This sequential flow sheet was progressively installed and commissioned during 2006. Copper concentrate lead and zinc smelter penalty contents have been reduced by some 40%, while increasing copper recovery by 10%.

Jan 1, 2009

By Peter Wells, Laxman M. Amaratuga, Todd M. Kanhai

"Certain mining methods (eg. Cut-and-fill) result in the contamination of run-of-mine ore with shotcrete. This shotcrete remains mixed with the ore throughout processing. Experimentation performed by Falconbridge Limited revealed that underground contamination of ore by shotcrete (eg. as little as 1% by weight) has led to ill-effects on the nickel recoveries from the flotation process in the mill. The nickel recoveries of contaminated samples were lower than tests without the shotcrete Contamination.To optimize flotation circuits it is important to know why the contamination has created these effects and also to find a method to abate or remove them. Laboratory testing showed that the age of the shotcrete was a factor in it’s effect on nickel recoveries. Younger aged shotcrete gave nickel recoveries lower than baseline nickel recoveries with no contamination. Older shotcrete gave nickel recoveries similar to the baseline.Literature on other cementitious material contaminations on ore revealed that a possible means of remediating this problem is the use of acid in the flotation. The initial pH in the flotation pulp was designed to be pH 9.2, but with the young shotcrete contamination the pH was in the neighbourhood of 10.5. Acid addition may act as a means of lowering the pH to the optimal operational value. Laboratory test work showed that acid addition brought nickel recoveries closer to the baseline."

Jan 1, 2000

By Don Peel

Mineral aggregate, the most widely used mineral resource globally, has attracted little academic or public interest. Of all mining developments, the aggregate resource is seldom factored into resource management decisions. This lack of recognition to the strategic aggregate resource has significant economic, environmental, and social implications. Impact to the economics, the environment, and the community coincide with the key elements of the United Nations concept of ?sustainable development?. To build on the concept, the mining sector contracted the International Institute for Environment and Development to assess how mining activity contributes to sustainability. As a result, a useful assessment process was developed by the Mining, Minerals and Sustainable Development (MMSD) Task Group entitled ?Seven Questions to Sustainability: How to Assess the Contribution of Mining and Mineral Activities.? In Alberta, recent opposition to mineral resource development by community residents offers an opportunity to employ the MMSD?s assessment procedure. The public opposition to the mining activity was addressed through a stakeholder planning process initiated by the municipal council of Sturgeon County, Alberta. As a result the Calahoo/Villeneuve Area Structure Plan (CASP) was formulated and adopted. To measure the effectiveness of the CASP planning process in terms of sustainability, this paper applies the MMSD?s Seven Question assessment to the Calahoo/Villeneuve Area Structure Plan.

May 1, 2004

By André van Wageningen

Long term mine scheduling is one of the most difficult optimization problems. The problem is said to be NP-complete in that the best possible solution cannot be found any quicker than checking all possible permutations and combinations. In current mining operations, it is important to report changes in long term plans as soon and as accurately as possible. Where geological data can change rapidly, such as in narrow vein deposits, the need to quickly identify and optimize different long term alternatives becomes a difficult task and can lead to many permutations of the long term mine plan. The question arises, is the new plan optimal or not? Can the company objectives be met while adhering to operational constraints? Although a number of optimization techniques have been used in the past, many include significant simplifications or fail to produce acceptable results within the required timeframe. Genetic Algorithms (GAs) are among the most promising optimization techniques within operations research. They are based on natural selection and evolution of solutions to complex problems. They have been known to quickly converge within a few percent of the optimal solution by examining only a fraction of the possible permutations. The GA itself contains very little problem specific information and, as such, in this study, has been linked to a discrete-event simulation (DES). The DES is able to evaluate each sequence proposed by the GA and determine the effectiveness and value of each schedule. The DES feeds information regarding the feasibility and quality of the solutions back to the GA during the optimization process. In this paper, GAs and DES are described and the coupling of the two methods is outlined. The GADES module is then used to ?optimize? a narrow vein theoretical case study and the results discussed in a broader mining context.

Oct 1, 2004

In order to maintain a production rate of 6,000 tonnes per day from underground at the Williams Operating Corporation, two independent mining areas were required which created a long narrow sill pillar between them. During initial mining of the sill pillar there were a number of significant ground falls [LeBlanc and Murdoch, 2000] and in March 1999, with no active mining ongoing in the sill pillar area, a rockburst of magnitude 3.0 Nuttli occurred. Extensive ground support was designed and installed to withstand events of similar magnitude [Bawden and Jones, 2002]. A mine wide microseismic system was installed to monitor mine induced seismic behaviour over the entire mine. The area most directly affected by the 1999 rockburst was rehabilitated using a highly ductile support design. Along with microseismic instrumentation, the areas were instrumented using conventional SMART Cables and SMART MPBX?s. Subsequent to this, the area was impacted by a large number of high magnitude seismic events [magnitudes between 1.7 and 3.5 Nuttli]. The ground support performed very well during these events, providing confidence in the mine?s ability to control the ground under severe rockburst conditions. Analyses of microseismic and conventional instrumentation, combined with numerical analyses of sequence alternatives, were used to develop an optimal mining strategy for the sill pillar area. The selected strategy involved utilization of instrumentation data and calibrated model results to analyze yield zones in the sill. The analyzed ?yielded? zones were assessed to be low seismic risk. Initial mining in the sill was then concentrated in these low risk areas, with the objective of further concentrating stress into the remaining seismically active area, in order to induce ultimate failure of the sill. Continuing large magnitude seismicity and resulting damage in the remaining ?high seismic risk? area, led to abandoning a second portion of the footwall access and the strategic decision to extract a stope near the centre of this zone in order to force final failure of the sill pillar. During execution of this plan two large magnitude seismic events occurred resulting in destressing and final failure of the remaining sill pillar. The paper provides a detailed description of this ?strategic mine sequence driven self-destressing process? and the implications to final extraction planning in this area of the mine.

Apr 1, 2005

By Elmer Stewart, Richard May

"The Central Mukur deposit was discovered by the Semipalatinsk Geological Exploration Expedition (GEE) during detailed searches from 1977 to 1980. Andas Altyn Ltd., a Kazakhstanian gold mining company acquired the property and commenced mining in 1995. In 1998, Andas-Altyn Ltd. became a wholly owned subsidiary of Eurasia Gold Corporation.The Central Mukur gold project covers a linear series of parallel, discontinuous zones of near surface oxide gold mineralization that covers a distance of 7 kilometers and extends past the property boundaries. The oxide gold mineralization is a result of the regional oxidization of a primary sulfide gold mineralization emplaced in a series of shallow dipping thrust faults. Resources as calculated by the GEE are 3.45 mt at an average grade of 1.84 gmt Au in the C1 +C2 category and 7.52 mt at an average grade of 1.80 gmt Au in the P1 category. The Central Mukur Gold Heap Leach Mine consists of an open pit, heap leach pads, and an ion exchange resin gold recovery plant. Limited gold production (<2,500 ounces/year) has been achieved over the past three years leaching run of mine oxide gold mineralization. Gold recovery utiling cyanide to dissolve the Au and ionic resin technology to recover the Au for the leachate is approximately 60%. Loaded resin is shipped to a treatment plant at Almaty where the gold is stripped from the resin, refined and sold.This paper will describe the geology, mining, and processing of the Central Mukur ore. In addition, it will describe what it is like doing business in Kazakhstan and the transition from a Soviet style operation to a more western style operation.INTRODUCTIONThe Central Mukur Mine is owned and operated by Andas-Altyn Ltd. a Kazakhstanian gold mining company located in northeast Kazakhstan. Andas-Altyn is a wholly owned subsidiary of Eurasia Gold Corp., a Canadian public company listed on the Alberta Stock Exchange. The Central Mukur mine consists of a small open pit, and a heap leach operation that utilizes ion exchange resin to recover gold from pregnant solutions. In addition to the Central Mukur mine, Eurasia also owns the Myaly heap leach gold project which is also operated by Andas- Altyn Ltd."

Jan 1, 1999

By Steve Massman, Edward Wipf, Gary Beerkircher

"As mine size and tonnage continues to increase, material handling/processing equipment has also increased in size with 400 MT haul trucks, 2000 KW crushers, 12 M SAG/AG mills, 8.5 M ball mills, 3000 M3 flotation cells and 12.5 MW HPGR’s all with planned designs to increase in size further. Related equipment including vibrating screens have also increased in size with screens seeing feed rates of 3000 MTPH. Open circuit SAG Pre-Crush and closed circuit HPGR flowsheets are becoming more common with large screening requirements. Large multi-slope (banana) or horizontal screens are commonly used for these applications, however as the size of these screens has increased, the number and size of the brute force/overhead exciters has increased but with limitations. An example is a SAG discharge screen that will see surges of material from the SAG mill which overload the screen, reducing the screen stroke or throw causing a large reduction in screen efficiency with excessive fines & moisture in the screen oversize feed to the pebble crushing circuit. This paper will present some actual examples of the use of Two-Mass screens as a solution to these overloading problems and the advantages of Two-Mass screens in other high tonnage applications.Brute Force Drive Compared to Two Mass Drive Vibrating ScreensThe standard single mass screen as depicted by figure 1 is generally recognized in the mining industry. It is characterized by the screen body – labeled as the single mass (Mt) that is supported by isolation springs (Kiso). The stroke needed to process material is obtained by incorporating large eccentric wheels and/or drive boxes (Fb) directly mounted to the screen body via a drive tube."

Jan 1, 2017

By Francis Chachula, Niel Erasmus

"In 2002, Titanium Corporation Inc. focused its attention on the development of a process for the recovery of valuable heavy minerals, including zircon and titanium bearing minerals from oil sands froth treatment tailings. The development of a process flowsheet to recover the titanium and zircon minerals from the Athabasca oil sand tailings has evolved through many laboratory, bench and pilot scale iterations.Initial development work focused on so-called ‘beach sand’ material, which is tailings material deposited over a period of time close to the tailings pipe discharge. The derived process flowsheet primarily consisted of gravity concentration stages, which is typical of all mineral sands operations. Titanium Corporation’s business plan calls for the utilization of tailings directly from the tailings pipeline – the process developed around the beach material is therefore risky as it differs from the live tailings in a number of aspects, with the effects on the process unknown. Titanium Corporation successfully obtained an intermediate product through a ‘bulk sampling plant’ coupled directly to an Oil Sands operator’s froth treatment tailings pipeline, during the summer of 2005. Subsequent further processing of this material resulted in poor separation or concentration of the heavy minerals due to a number of reasons. A more effective process flowsheet had to be developed.The newly derived process is basically a marriage between mineral sands technology and oil sands technology that can economically concentrate and recover the heavy minerals and entails the incorporation of a flotation process that takes advantage of the entrained bitumen in the feed to separate the heavy mineral fraction from the quartz gangue This paper will describe the newly derived process as well as the successful results of a subsequent on-site concentrator pilot campaign completed during the 3rd Quarter of 2006."

Jan 1, 2008

By Frederic M. Langevin

?? Introduction ?? LaRonde ?? History of Seismicity and Rockbursting ?? November 27th 2002 Rockburst ?? April 1st 2006 Rockburst ?? December 11th 2006 & January 11th 2007 Rockbursts ?? Seismic Risk Management Plan ?? Conclusions ?? Located in Northwestern Quebec (Can.) ?? In operation since 1988 ?? Reserves at Shafts #1 and #2 depleted ?? Production now comes entirely from Penna Shaft ?? Deepest single-lift shaft in the western hemisphere (2240 metres) ?? 7300+ tonnes per day ?? 2007 Reserves (proven & probable): ?? By-products: Ag, Cu, Zn ?? Sinking #4 Shaft (LaRonde II winze)

Feb 1, 2008

By J. D. T. Steyl, C. A. Biley

"The chemistry of electrolyte systems containing iron remains generally poorly understood despite their prevalence in many natural and industrial processes, particularly in hydrometallurgy. These systems are typically challenging to study and model due to their affinity for complex formation and precipitation even at low pH. Recent developments in the hydrometallurgical processing of nickel laterites at Anglo American have called for a deeper understanding of the fundamental chemistry of the Fe2(SO4)3–FeSO4–H2SO4–H2O system. This paper details the development of an internally consistent, Pitzer ion-interaction model of this system, with explicit recognition of important contact ion pairs (CIPs). The primary application of this model is a thermodynamic framework for the interpretation of kinetic processes occurring during iron(III) reduction with SO2. Adopting a rigorous thermodynamic basis for the system chemistry facilitates the formulation of simple rate expressions that are capable of inherently capturing complex effects. While the iron(III) reduction case study remains the focus of this work, the developments have more universal applications and the thermodynamic speciation model can be extended into other systems containing acidic ferric sulfate.INTRODUCTIONIron is present in nearly all hydrometallurgical refining circuits typically as both a necessary and unwanted impurity and needs to be removed and disposed in a safe and efficient manner. This is generally performed by precipitation to form a range of solids such as hematite, goethite or jarosite. Numerous studies in the open literature have focussed on the removal of iron from refractory gold sulfide ore (Berezowsky & Weir, 1989; Berezowsky et al., 1991) and zinc pressure leaching (Buban, 1999; Ismael, 2003), and PGM matte sulfide circuits (Dutrizac & Monhemius, 1986). Moreover, since ferric iron is a strong oxidizing agent, it has been used extensively as a leaching agent for sulfide minerals (Dreisinger, 2006). Given the outlook of challenging economic conditions, declining ore grades and increasing levels of impurities, effective iron management is going to become increasingly critical to all hydrometallurgical processes.Against this background, and considering the widespread importance of acidic iron sulfate systems throughout natural and industrial processes, it is unexpected that the knowledge of the fundamental solution chemistry of these systems contains such significant gaps, particularly at the conditions typically found in hydrometallurgical applications. Existing literature describing the measurement and modelling of solution speciation in these systems have highlighted their significant chemical complexity (Magini & Caminiti, 1977; Magini, 1979; Lee & Tavlarides, 1985; Stipp, 1990; Papangelakis et al., 1994; Gil et al., 1995; Majzlan & Myneni, 2005; Kormanyos et al., 2008; Yue et al., 2014). Partially responsible for the lack of quantitative speciation measurements is the strong tendency of ferric to hydrolyse at even low pH (Flynn, 1984), complicating the laboratory study of such systems. Moreover, the large number of aqueous species that may co-exist simultaneously makes the study of individual species and the modelling of the numerous interactions between these species extremely difficult (Dry & Bryson, 1988; Stipp, 1990; Majzlan & Myeni, 2005; Kobylin et al., 2007)."

Jan 1, 2016

By A. E. Taylor, A. S. Judge, P. T. Lafleche

"Resource development in northern Canada has special requirements which derive from the unique environmental and eco-logical nature of the northern environment. In this paper several case histories in which the Permafrost Research Section of the Geological Survey of Canada (GSC) has participated are used to illustrate how geophysical methods may be used to address some of these considerations. Although some of these examples were developed while examining problems directly related to oil and gas development and transport in frontier regions, such or similar methods also have application to mining problems.IntroductionA critical parameter is the distribution and thickness of permafrost, which in northern Canada varies from being a few metres and discontinuous at the southern limit to thicknesses in excess of 700 m in the Arctic Islands&apos;!&apos;. Figure I is a schematic diagram of typical ground thermal conditions in a permafrost zone. The upper zone is defined by an active layer which undergoes a seasonal freeze/thaw cycle. In the simplest case, the ground remains permanently frozen below the active layer to the depth of the O°C isotherm, which is defined as the base of the permafrost. Water chemistry, pore structure and pore or grain size may cause the base of the frozen ground to be above the permafrost by up to 100 m(2). Ice can be found within the permafrost in the pores of solid rock or sediments, as massive ice within unconsolidated sediments or as ice lenses within fissures in a solid rock mass. The mining technique used in these conditions, whether open pit or underground, can differ considerably from that used in southern Canada. In the high Arctic, for instance, the dry drift method is feasible underground in the permanently frozen host rock. The frozen nature of the wall rocks can obviate water-related problems."

Jan 1, 1987

By D. Gendzwill, N. Martin

"In early 1987, the Patience Lake potash mine near Saskatoon, Saskatchewan, was closed due to uncontrollable floodingWater inflows were first encountered during routine mining in 1975 at the south boundary of the mine lease. Underground grouting and construction of bulkheads limited the flo but did not completely stop it. Subsequent seismic surveys showed that the mine had approached the edge of a large collapse structure in which the salt and potash had been partly dissolved and removed by groundwater.In 1986, the small flow into the mine started to grow. Despite renewed grouting, the flood increased and outstripped pump capacity. The grouting program temporarily slowed the inflow but was unable to stop it. Eventually, from seismic and drilling evidence, it became clear that the water source was an extensive system of vertical fractures which would be impossible to seal by drilling and grouting from underground. A new plan to install 14 bulkheads underground would have sealed the water source from the rest of the mine but the construction program could not be completed before rapidly increasing inflow threatened to fill the mine. The underground mine was closed and a new solution mine started in 1988."

Jan 1, 1996

By W. H. Gross

To pollute means to make impure or unclean. We tend to forget that man defecates, urinates, sweats, expectorates and exhales and in himself is a beastly little pollutor-but then so is Mother Nature! The object of this paper is to try to put what man and nature do into perspective. The facts indicate that although man may sweat a little, Ms. Nature is by for the greatest pollutor of all.

Jan 1, 1979

By Michel Fontaine, Bruno St-Cyr

"The mission of the CENTRE DE RECHERCHE INDUSTRIELLE DU QUEBEC (CRIQ) is to stimulate economic development by guiding businesses in their pursuit of innovation.With a comprehensive approach to their needs, CRIQ provides businesses with expertise based on the most recent developments and insights in the fields of:Research and Development ServicesAutomation and production processesDevelopment of industrial equipmentEnvironmental biotechnologiesTesting and Product Qualification Services Industrial and Technological Information ServicesConsultancy and competitive intelligence servicesIndustrial information bankStandardization ServicesElaboration of standards and product certificationSystems registrationEXPERTISE COMPETENCE, INNOVATIONSince its founding in 1969, CRIQ has been involved in over 100,000 projects. The results of its research and development services have enabled it to build over one hundred pieces of equipment, almost all still in operation today. CRIQ has been and remains the driving force of innovation and expertise on the industrial scene, offering highly competitive solutions to a clientele from numerous industrial sectors.CRIQ became a crown corporation operating on a commercial basis on June 30, 1997. This change in its corporate structure has enabled it to put a marked emphasis on trade and implement an array of new operational practices.The formation of marketing companies with private partners, the opening up to corporate business and international markets, the new directions for internal research and the strengthening of its marketing component are among the activities CRIQ has initiated over the last fiscal year to finally reach its cruising speed."

Jan 1, 2000

By Y. Özçelik

Rocks show a variety of engineering and physical properties that affect typical quarry operation such as diamond wire cutting in the marble quarry. The physical and mechanical properties of rocks depend on their mineralogical and petrographical characteristics. The purpose of this study is to investigate the effects of mineralogical and petrographical properties of a rock, such as grain size and mineral content, and how these affect the wearing of diamond bead and cutting rate in a diamond wire cutting operation in a marble quarry. Statistical analysis is used to carry out the study. Three different rock types were examined, namely, hard rock (andesite) and softer rocks like limestone and marble. The study revealed that the mineralogical and petrographical properties of the rocks, such as percentage of quartz, biotite, plagioclase, matrix minerals, and opaque minerals, are important. In addition, the grain size of quartz and plagioclase in andesitic rocks and calcite grain size for carbonate rocks significantly influenced the wear rate and cutting rate in diamond wire cutting operations.

Jan 1, 2005

By Weng Fu, James Vaughan, Stefan Lakemond

Uranium bearing copper sulphide flotation concentrates produced from iron oxide copper gold uranium (IOCG–U) ore contains radionuclides such as 238U, 230Th, 210Pb, 226Ra, 210Po, which have the potential to reduce their marketability, thus posing a challenge to the industry. Thus, a two–stage leach process has been proposed in this study. In first stage, a sulphuric acid leach process effectively dissolve most of the 238U and 230Th into solution, but other radionulclides (mainly 210Pb, 226Ra and 210Po) remain associated with copper sulphide minerals owing to their low solubilities in sulphuric acid solution. In the second leaching stage, the use of methanesulfonic acid (MSA, CH3SO3H) is investigated to selectively dissolve the 210Pb, 226Ra and 210Po from the residue of the first stage. The results indicate that 96% of 238U, 87% of 230Th, 90% of 210Pb, 86% of 226Ra and 17% of 210Po are dissolved using 3 mol/L MSA solution at 90°C for 3 hours, which represents a dramatic decrease in the radioactivity of the copper concentrate. INTRODUCTION Australia is host to one of the largest iron oxide copper–gold–uranium (IOCG–U) deposits in the world. Most of the value in these deposits is associated with copper. In mineral processing, the gangue minerals are separated from copper sulphide minerals that report to a copper flotation concentrate. However, due to the strong association of uranium with copper minerals and hematite, even clean copper concentrates can contain significant amounts of uranium (238U) and its radioactive decay elements, of which thorium (230Th), radium (226Ra), lead (210Pb), and polonium (210Po) are the long life radionuclides. These hazardous radionuclides negatively affect the marketability of the copper concentrates. Customer copper smelters in China, Japan and Europe may consider the radionuclides penalty elements or may not be able to process the feed. Therefore, there is a strong motivation to remove radionuclides from copper concentrates at the mine site before shipping to custom smelters in global market. Hydrometallurgical leaching has been widely employed to remove radionuclides from different kinds of minerals such as copper concentrates (Ragozzini & Sparrow, 1987), zircon concentrates (Aral, Sparrow, McDonald, & Norgate, 2007), and coal ash (Lei, Qi, Sun, Xu, & Wang, 2014). Leaching using sulphuric acid (H2SO4) solutions is the most widely used process for the extraction of uranium from uranium ores due to the relatively low cost and wide availability of the acid (Bhargava et al., 2015; Gilligan & Nikoloski, 2015). The leach process involves treating ground ore slurry with sulphuric acid at elevated temperatures (typically 60–90 °C) under oxidising conditions in order to convert the uranium in the minerals 2+ from the relatively insoluble tetravalent form (UO2) into water–soluble hexavalent state (UO2), which then complexes with SO42- and forms UO2(SO4)22- in solution. The uranium oxidation is generally carried out in the presence of ferric ion (Fe3+), regardless of the reagent and oxidant used. The most commonly used oxidants for uranium include sodium chlorate, pyrolusite and oxygen (Ring, 1980). These oxidants act indirectly by converting ferrous sulphate, formed by the oxidation reaction of UO2 in slurries, into ferric sulphate. The presence of Fe–containing gangue minerals such as hematite in the ore usually provides sufficient Fe required for the oxidation of UO2. After sulphuric acid leaching, the locked thorium (230Th), radium (226Ra), lead (210Pb), and polonium (210Po) elements are chemically liberated from hematite and uranium mineral grains (Ciobanu, Wade, Cook, Schmidt Mumm, & Giles, 2013). However, the extraction rate of radium (226Ra), lead (210Pb), and polonium (210Po) in sulphate solution is very low due to the limited solubilities of (Ra, Pb, Po)SO4 (Bagnall & Freeman, 1956; Liu & Papangelakis, 2006; Nikitin & Tolmachev, 1933).

Jan 1, 2019