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By S. Nikolic

"Calcium ferrite slags are currently used in a number of copper-converting processes. Despite the industrial importance of this system the phase equilibria have not been fully investigated. Characterization of this slag system is necessary to improve the control of process parameters, including fluxing and operating temperatures. Recently, a modified experimental method has been developed; this involves rapid quenching of slag samples equilibrated at high temperatures with the resulting phase assemblages analysed using electron probe microanalysis (EPMA). In the present study, experiments were completed under controlled temperatures and oxygen partial pressures using CO/C02 or H2/C02 gas mixtures. The investigated slags were supported during equilibration by a substrate of the primary phase. This technique removes the limitations arising from the use of crucibles and facilitates rapid quenching of the melt. Experiments were carried out at 1200°C and 1250°C (1473 Kand 1523 K) and in the composition range 0-40 wt.% Cu20, 0-25 wt. % CaO and 45-80 wt. % Fe203. Liquidus and solidus data are reported for the primary phase field of spinel between the oxygen partial pressures of 10-4.5 to 1 o- 6-5 atm. The analyzed compositions of liquids and solids are used to construct the phase diagram of ""Cu20"" -CaO-""F ez03"" system in equilibrium with metallic copper at fixed oxygen partial pressures."

Jan 1, 2007

By A. W. Jolliffee

ANY attempt to forecast the mineral resources of a largely unknown region is hazardous and, in the case of the Northwest Territories, such a task is even more hazardous than usual. This is not merely because of the immense territory involved (over a million and a quarter square miles), only a small fraction of which has ever been explored or prospected, but also be-cause both the geology and mineral deposits thus far examined show many unique features, and, finally, because the region is being actively prospected at the present time. However, in view of the present widespread interest in Canada's mineral resources, a brief compilation of what is known regarding mineral occurrences and geology in the explored parts of the far north seems timely. From these assembled data, a few inferences are warranted as to future mineral production from this region. HISTORY The story of mineral discovery in the Canadian northwest is a fascinating one. As well, it abundantly illustrates the importance of mineral occurrences in indicating future mining possibilities. The same sequence of events has repeated itself too often to be merely fortuitous.? In most cases, the dis-covery of a mineral deposit of possible economic value has been foreshadowed by the finding of the valuable mineral or an associated mineral in the same district, generally in small quantity, by an early explorer or traveller. Thus, John Franklin reported oil seepages from the base of Bear Rock, near Nor-man, at almost the very spot where oil was struck nearly one hundred years later. Again, some would-be Klondikers, deterred by the hardships of the route, remained to prospect around Great Slave lake, and were the first to report the Pine Point lead-zinc occurrences there and the gold-bearing veins on Yellowknife bay. Sporadic prospecting followed at the latter locality for over thirty years before the recent rich strikes were made. Similarly, in 1847, Dr. John Rae picked up a boulder of copper ore south of Rankin inlet, on Hudson bay. More than eighty years later, a body of copper-nickel sulphides carrying values in platinum metals was found at this locality. Also, the report of cobalt bloom on the east coast of Great Bear lake brought back by a Geological Survey of Canada party in 1900 was a factor in the events leading to the discovery of silver and radium there in 1930.

Jan 1, 1937

By J. Defreyne

CESL has developed a proprietary hydrometallurgical process for base metal concentrates, notably those of copper and nickel. The process is based on pressure oxidation (PO) of the sulphide minerals, which is done at elevated temperatures in mixed sulphate-chloride liquor at about pH 2 ? 3. The process achieves maximum oxidation of the metals whilst minimizing sulphur oxidation to sulphate. Almost all base metal sulphide minerals are efficiently treated under these conditions. In the case of copper minerals, pressure oxidation does not generally put the copper into solution, because of the relatively high pH prevailing in this process. Therefore, PO is followed by an acidic leaching stage, which specifically aims at maximum copper dissolution with minimal leaching of iron. The overall copper recovery is largely determined by the efficiency of this stage. The process has low capital and operating costs, partly because there is minimal use of acid or neutralizing agents for iron dissolution or precipitation, respectively; this is achieved by minimizing iron leaching during both the oxidation and leaching stages. Iron sulphides in the feed concentrate deport almost entirely to the solid leach residue as hematite, which has superior handling characteristics for filtering and washing. Iron minerals play a key role in the process, with pyrrhotite and pyrite having very different responses to the oxidation process. Acid management for the whole process is affected by the iron mineralogy, and the flowsheet is therefore tuned to the specific concentrate.

Jan 1, 2006

By Olli Haavisto, Lauri Koresaar, Navid Khajehzadeh

In recent times sustainable minerals processing is an important topic in research. Sustainable mining is linked with efficient use of energy and human resource in all process stages including beneficiation of the ore. Controlling and optimizing the recovery while preserving the grade of the concentrate is extremely important in flotation plants. This development requires new technological solutions and has given rise to the multitude of application areas for lasers. X-ray Fluorescence (XRF) and Laser-Induced Breakdown Spectroscopy (LIBS) are currently two of the predominant non-contact and direct analysing methods in industry. LIBS and XRF measurement techniques both have high capabilities for measuring elements. LIBS has a very simple and easy-to-implement spectroscopic setup, wider range of elements can be detected with online LIBS and measuring light elements is simpler by LIBS compared with XRF. It is of great interest to extract mineralogical information from the elemental results with no modification on the measurement setup. In order to achieve this, more advanced interpretation of the elemental peaks of LIBS spectra is required. Therefore, the major focus of this research is about measuring mineral concentrations from the elemental lines of LIBS spectra using advanced statistical methods. This accomplishment provides knowledge about mineral concentrations from the real-time assay data of the slurry LIBS analyzer. Consequently, this paper first discusses an analytical method called partial least squares regression leading to rapid mineral identification from the elemental contents of the LIBS technique. Then the technique is employed to analyze the mineral contents quantitatively through the information acquired from an on-stream LIBS slurry analyser. This can lead to many benefits such as rapid control of concentrate quality, enhanced recovery, saving time, energy and manpower.

Jan 1, 2016

By M. L. Jeremic

Altered and unaltered coal from the Star-Key Mine near Edmonton, Alberta has been tested under compression and under tension. The test results showed that altered coal samples have an appreciably lower strength than unaltered coal. Altered coal samples do not give a linear load-displacement curve, peak strengths are poorly defined and yielding is observed over a range of loads, so the material can be regarded as relatively plastic. However, unaltered coal samples produce a linear loading curve with a high tangential modulus and an easily distinguished peak strength at which there is a sudden brittle failure. These findings lead to important differences in the theoretical design of ribs and pillars in underground mines in the two coal types. The substantial differences in the strength properties and behaviour of the two types of coal are governed by a higher intensity of cracks in the weathered coal. Two causes of the additional cracking can be suggested-subaerial weathering and subterranean weathering of the coal.

Jan 1, 1979

By B. Jin

Removal of fluoride and chloride by alkaline washing from direct lead smelting dust which originated from an Ausmelt furnace is reported. The results show that the fluoride removal efficiency increases with an increase of alkaline concentration, alkaline washing temperature and time. The L/S ratio has little effect on fluoride and chloride removal efficiency. A new flow sheet for removal of fluoride and chloride from the dust was successfully proposed according to the results. Fluoride and chloride removal efficiencies are more than 53.68% and 63.18% respectively using the flow sheet under the optimum parameters of temperature 338 K, L/S ratio 3:1 and alkaline washing time of 1.5 h. The contents of fluoride and chloride in the alkaline washing residues can meet the standard of zinc purity as hydrometallurgical materials for zinc processing.

Jan 1, 2014

By R. H. Knudsen

"In view of the chronic overcapacity problem in the world potash industry and Saskatchewan's recent emergence as a major producer, the long-term outlook for potash productive capacity and consumption is of importance and interest to both the Saskatchewan Government and the potash industry. This paper is based on a report recently published by the Saskatchewan Department of Mineral Resources on projected world potash productive capacity and consumption for the ten-year period 1970 to 1980. Potash productive capacity and consumption are estimated on a country and regional basis and projected annually to 1980. Tables and graphs are included which summarize projected capacity and consumption for the period and illustrate the impact of Saskatchewan's capacity upon the North American and world potash industries."

Jan 1, 1973

By M. Wu, G. Plascencia, A. E. M. Warner, A. Vahed, T. A. Utigard

Nickel oxide granules formed by pyrohydrolysis of a chloride solution, were reduced in hydrogen. Below 400 °C, an incubation period was observed, followed by very slow reduction. In the temperature range from 400 to 600 °C, the rate of reduction increased with increasing temperature and increasing hydrogen pressure. Microscopic analysis showed that in this temperature range the reaction followed the shrinking core model. Above 600 °C, the reduction rate decreased noticeably before suddenly becoming very fast at and above 950 °C. Microscopy showed inner bands of metallization inside the outer metallic rim, indicating partial blockage of the interface between the reacted and un-reacted NiO core. At these temperatures, particle agglomeration and sintering were also found to take place. Surface segregation of sulphur may account for the slow down in reduction rate above 600 °C. From an industrial point of view, reduction should be carried out from 550 to 600 °C with as high a concentration of hydrogen as possible. If sintering and agglomeration are not of any concerns, reduction can be carried extremely fast at about 1000 °C.

Jan 1, 2005

By Charles T. Harper

The uranium deposits discovered by Amok (Canada) Ltd. in the Cluff Lake area of north western Saskatchewan occur at or near the southern edge of the uplifted basement core of the Carswell circular structure. Two types of mineralization, distinguishable, by their geological and structural setting and mineral paragenesis, have been recognized. The N-Claude type is characterized by a relatively simple mineral assemblage, consisting of uraninite or pitchblende with coffinite, and is accompanied by variable amounts of graphite and organic matter, and Fe, Cu, Pb and Mo sulphides. Both N and Claude orebodies occur within quartzofeldspathic gneisses of the basement core. On the other hand, the D-type ore has a complex mineral assemblage consisting of: uraninite, pitchblende, thucholite and coffinite, along with native gold and selenium; gold tellurides, and selenides of Pb, Bi, Ni and Co; sulphides of Fe, Cu and Pb; and organic matter. The D orebody occurs within carbonaceous shales at the base of the Athabasca Formation as well as in fault zones in regolithic quartzo feldspathic gneisses above the inverted unconformity. An age of 1050 m.y., which is consistent with a period (circa 1200-1000 m.y.) of widespread hydrothermal activity and uranium mineralization or reworking within and adjacent to the Athabasca Basin, has been obtained from uranium mineralization from the D orebody. Later reworking (circa470 m.y.) of the mineralization occurred at the intersection of older mineralized shear zones with radial faults produced during meteorite impact.

Jan 1, 1978

By Jolanta Olkowska-Oetzel

Reactions of gold?phosphino complexes [(AuX)(PR3)] (X= Cl, Br, I; R = organic rest) with Se(SiMe3)2 lead to the formation of gold complexes with chalcogenide bridges. The reaction of the complex Ph3PAuCl and tBuSe(SiMe3) gives the cluster [Au5Se2(PPh3)4]Cl 1. The in situ preparation of the complex [(AuCl)2dpph] (dpph = Ph2P(CH2)6PPh2) by reaction of dpph with Me2SAuCl, and subsequent reaction with Se(SiMe3)2 leads to the formation of [(Au3Se)2(dpph)3]Cl2 2. Reactions of the gold(I) complex [(AuCl)2dpppe], (dpppe = Ph2P(CH2)5PPh2) with Se(SiMe3)2 and InCl3 in different molar ratios lead to the formation of [Au10Se4(dpppe)4]InCl5 3 and [Au4(SeInCl3)2(dpppe)2] 4. The reaction of [(AuCl)2dpph] with Te(SiMe3)2 and GaCl3 produces the isostructural cluster compound [Au4(TeGaCl3)2(dpph)2] 5. From the reaction of Se(SiMe3)2 with [(AuCl)2dppe] (dppe = Ph2P(CH2)2PPh2) and InCl3 [Au8Se4In(dppe)4](InCl4)3 6 can be isolated. The structures of 1 - 6 were determined by X?ray diffraction.

Oct 1, 2003

By E. L. C. Martins, M. J. Nicol, D. Majuste, A. D. Souza

The effects of organic compounds on the current efficiency (CE), morphology, crystal structure and mechanical properties of the metal deposited during the electrowinning of zinc are described. A flotation collector and lubricating oil were selected based on observations made during the industrial production of zinc from silicate ores, in Brazil. The analysis by Fourier transform infrared spectroscopy of these compounds, which may be present in minor amounts in the electrolyte solution, indicated the presence of a polar amine group in the collector, while the lubricating oil is a non-polar compound. The average CE value obtained from organic-free industrial solution was 91.15 ± 0.26 %. The CE dropped to 54.35 ± 0.73 % in the presence of 100 mg·L-1 of collector in the solution, and a negative effect was also observed in the presence of similar amounts of oil (88.84 ± 0.61 %). The characterization of the deposits by scanning electron microscopy and X-ray diffraction revealed the formation of pores in deposits obtained from solutions containing the oil, while a different growth pattern (perpendicular zinc platelets) was identified when the flotation collector was added to the industrial solution. In the presence of these contaminants in the solution, guided-bend tests revealed that the deposits have a higher resistance to deformation, but lower ductility, properties that may affect the performance of the stripping stage. As a result of this work, simple control and optimization actions were applied in the industrial plant, which resulted in important improvements in the electrowinning process.

Jan 1, 2014

"Developed by CRIRSCO, IRT is a document that draws on the best of the CRIRSCO-style reporting standards. These reporting standards are recognised and adopted world-wide for market-related reporting and financial investment.The IRT is not an international reporting code and does not supersede existing national reporting standards. Rather it is a guideline that encapsulates the content of these standards for the benefit of the international mining industry and its various stakeholders.The template is a 'living document' that is continuously updated and improved as new national laws, rules, codes and guidelines are created or amended.The International Template is advisory only and where national codes already exist, these will take precedence. The International Template is intended to assist those countries that either do not have a reporting code or whose code is outdated, to produce a new code consistent with international best practice. It also provides a consolidated version of national codes that reflects their compatible international components and may thus be used in comparisons with other international reporting systems. The word 'Template' is used advisedly to indicate that this document is a model for code development and does not in itself constitute a 'code' which implies that it has legal or other regulatory force.From this point forward, the Template includes words that imply a mandatory action, such as ""requires"", ""applies"", ""must"" etc. This is to enable the Template to be easily adopted by countries and organisations wishing to do so, and does not imply that the Template itself is a mandatory reporting standard.INTRODUCTION2 In this edition of the International Reporting Template (""The Template""), important terms and their definitions are highlighted in bold text. The guidelines are placed after the respective Template clauses using indented italics. They are intended to provide assistance and guidance to readers for interpreting the application of the clauses in the Template.Indented italics are also used for Appendix 1 — 'Generic Terms and Equivalents"", and Table 1 —'Check List of Assessment and Reporting Criteria' to make it clear that they are also part of the guidelines for the application of the Template.Appendix 1 contains a table of generic terms and their equivalents, designed to avoid unnecessary duplication or ambiguity in the textAppendix 2 provides Rules of Conduct for Mineral Resource and Mineral Reserve estimators that may be considered in addition to the Codes of Ethics or Practice normally applying to members of professional institutions."

Jan 1, 2003

By Michael Harley, E. Guy Charleworth

"Bedding-parallel thrust-hosted gold veins are developed in the Sabie-Pilgrim's Rest goldfield, eastern Transvaal, South Africa. The reefs display a complex history characterized by temporally and spatially overlapping events of similar mineralization and deformation. Recognition of the episodic reactivation of these low angle (5° to 10°) thrust faults implicates high fluid pressures (equalling or exceeding lithostatic pressures). Geochemical constraints limit the amount of fluid-rock interaction and the occurrence of transgressive mineralization within the Archaean granitoid basement suggests that the high pressure fluids originated at depth beneath the Transvaal Basin.Similarities exist between gold deposits of Sabie-Pilgrim's Rest and Telfer, Western Australia as well as Passagem de Mariana, Minas Gerais, Brazil. All deposits are sub-parallel to the enclosing bedding which is shallowly inclined. Furthermore, they are also hosted by contractional deformational structures and are clearly epigenetic in origin."

Jan 1, 1994

By E. Peters

Roasting processes are divided into several elementary mechanisms, any of which could be significant or pre-dominant in a particular roast. The elementary processes considered in-elude beat transfer, gas-solid inter-actions with accompanying mass transfer between the bed and furnace atmosphere, vapor phase transport processes in solid-solid interactions, and solid phase diffusion processes. Examples are chosen of processes in which one of these mechanisms pre-dominates and some recently obtained data is presented to support the existence and significance of these mechanisms. Proposals are also made for future research in these areas, and for utilizing the information in the improvement of roaster capacities’ OASTING of ores as a preparative treatment for smelting or leaching has been practiced for so long that its origin has been lost in antiquity, but little has been under-stood of its basic nature until fair-ly recent times. The nominal chemistry of roasting processes is now understood; that is, the initial chemical com-pounds present in the ores or con-

Jan 1, 1961

By D. S. Speakman

The copper-zinc orebody at Sherritt Gordon's Ruttan Mine occurs in a structurally complex area of the Rusty Lake greenstone belt in northern Manitoba. Problems in interpreting drill results indicated a large deviation, and the structural complexity an erratic deviation, of drill holes. This was confirmed when a surface hole was intersected 420 feet to the left of line on the 800 level. This problem acted as a catalyst in promoting a search for a suitable down-hole survey method. The instruments investigated included magnetic multishot and gyroscopic units as well as the ABEM Reflex-Fotobor. Only the Fotobor came close to meeting the company's needs of simplicity, reliability, accuracy and ownership. In this paper, the methods of operating this instrument, as well as the data extraction and reduction techniques, are described. Data on the accuracy and repeatability of the instrument are presented, and a tabular presentation of the results of surveying on 86 holes totalling 64,000 feet of drilling is made. Preliminary statements of the results of ongoing research on causes of hole deviation are presented and recommendations for minimizing deviation are given. The use of the survey device is recommended in areas of structural complexity, for very steep or backsight holes and where expected ore intersections are missing.

Jan 1, 1978

By W J. Dyck

Past attempts to establish an integrated steel industry on the West Coast of Canada have been unsuccessful for at least three reasons: (a) insufficient reserves of a suit-able iron ore supply; (b) a relatively small local market for iron and steel; and (c) the non-availability of an economical process to produce primary iron on a small scale. Today, the reserves of economically mineable ore deposits are ample to support a steel production of 100,000 to 200,-000 tons per annum. The local market has increased so as to be able to absorb most of this capacity. With-in the next few years, a small integrated steel plant, including the "H-Iron" direct iron ore reduction process for electric furnace charge stock production, will be able to show a profitable operation. Introduction

Jan 1, 1963

By H. H. Bleakney

The merit of reduction-in-area as a criterion of quality in metals is shown to lie in its influence on breaking stress, but the virtue of elongation is not easy to find. In order to assess the value of elongation, either as a measure of quality or as a guide to design, it will be necessary to separate the overall de-formation occurring in tension tests from the localized deformation associated with localized reduction in area. The obstacles to a successful solution of this problem have been shown to be more formidable than is generally appreciated, and a new solution to the problem has been suggested. This solution involves a de-vice by which an electric circuit is broken when the particular value of strain is reached that is to be taken as the point of separation between general and localized deformation. The report presents results from a number of tests on both low-carbon and alloy steels. These results indicate that the selected criterion of separation is accurately identified by the proposed method; that it

Jan 1, 1962

By Tyson Birketi, Françoi Robert, Steve Green, Dan Richardson

Detailed sampling using a portable diamond drill, and inter laboratory comparison of selected samples have been combined with statistical studies of truncated populations to establish the gold content of several outcrops in the Val d'Or area. The outcrops chosen are non-mineralized. The background gold concentration in the rocks of the region is 5 ppb or less. Gold is distributed relatively homogeneously within the outcrops studied except for slightly increased concentrations within quartz-tourmaline veinlets. Three samples, of which 20 grams of powder are analyzed for each, can adequately determine the gold concentration of a structurally simple outcrop in the Val d'Or area.

Jan 1, 1992

By Long Han, A. V. Kalinin, Xiujian Luo, Xiaobo Wang, Xiaoou Xia

"Inertia vibration crusher is a kind of vibration equipment which crushes ore by vibration. When the inertia vibration crusher works, ore between the two moving jaws is subjected to the high frequency contact force, which is produced by the two moving jaws with high frequency synchronous reciprocating motion. The synchronous motion of the two moving jaws depends on the self-synchronous feature of the inertia vibration crusher. To study the self-synchronous feature of the equipment, the dynamic model was established, in which relative parameters were taken into consideration. The kinematic coupling relations of the assemblies are discussed, and appropriate calculation method is chosen to solve the vibrating differential equation. Whether the two vibration exciter can realize synchronous operation depends on the ability of the vibration system's capture moment. Results show that though the two rotors’ motors and damping coefficients are different, and two jaws’ damping and stiffness coefficients are also different, as angular velocities of the two unbalanced rotors reach a certain value, the vibrating system can be stable. Their angular velocities tend to be equal, and the swings of the two moving jaws can be the same. The horizontal vibration and swing of the frame are large in a few seconds after starting the machine. When the system runs stably, the horizontal vibration and swing vanish, and the vertical vibration is stable. The study and its results can provide reference for the optimization design and parameter setting of inertia vibration crusher and related vibratory equipments.INTRODUCTIONMaterials can be easily broken by using the inertia force of the vibration exciter, which can effectively realize the selective crushing, reducing excessive combinations and the energy consumption, as introduced by Zhang in 2005. The initial micro crack between crystals in the material increases and new cracks can be manufactured because of the high frequency impact and the extrusion of the vibration crusher, so vibration crushing equipment can make it possible for any high strength brittle material to be broken theoretically. Inertia cone crusher and inertia vibration crusher have been successfully used in the treatment of metallurgical slag and construction waste, and it verifies the efficiency of vibration crushing."

Jan 1, 2016

By Pizhi Zhao, Jingwei Zhao, Zhenshan Liu, Yiheng Cao

"A new Al-Mg-Si-Zn alloy designed for automotive outer panel was trial-produced with industrial procedure. The final product shows a strong planar anisotropy. X ray diffraction analysis shows such strong anisotropy is caused by the dominating cube texture component in the final product. The reason for such high cube texture component was investigated by tracing texture evolution starting from the hot roll slab. It is found that certain cube texture components already exists in the hot rolled slab. The density of cube texture component shows as a wavy change through the following1st cold rolling, inter-annealing, 2ndcold rolling and solution treatment. This study shows that the cold rolling in the laboratory can well represent the texture evolution during the industrial production. The results obtained by lab rolling hints that change of second cold rolling reduction has weak effect on the planar anisotropy, when the gauge of hot rolled slab and final sheet are fixed.INTRODUCTIONWith the rapid progress of light-weighting in the automotive industry, aluminum sheets get more and more application as closure panel and structure parts. Recently the dominating alloy for outer panel is 6xxx series, containing the main alloy elements Mg and Si. The popular gradesareAA6016,AA6111, AA6022, and AA6014. These alloys still cannot satisfy the various requirements from automotive manufacturers. Most suppliers of automotive aluminum sheets are developing their own specific grades according to the customer’s demand. To increase the baking response, anew Al-Mg-Si-Zn alloy was designed, concerning the high combination energy between Zn solutes and vacancies formed during the quenching stage of automotive sheet manufacture. This combination is helpful to the precipitation of ß”phase during the paint baking (Wang, 2015,2016; Yan, 2014).The plastic strain ratio (r value)is a key index of the formability of automotive body sheet. A high r value means a good formability. The r values in different directions can be used to evaluate the planar anisotropy of the metal sheets. The trial produced Al-Mg-Si-Zn sheet shows a strong planar anisotropy with respect to r values. Since the r value is tightly related with texture, the texture evolution from hot roll slab (HRS) to final T4P temper was analyzed with X ray diffraction (XRD) to find the reason for the high anisotropy. Besides, the cold rolling reduction (CRR) was varied in the laboratory to modify the texture distribution, i.e., the planar anisotropy."

Jan 1, 2018