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By G. S. Zeng

The mechanism of cobalt removal from zinc sulfate solution with zinc dust is still not understood well. The experiments in this paper were carried out by zinc dust from zinc sulfate solution with high cobalt to study the mechanism of cobalt removal. Residues after the cementation process from zinc sulfate solution were analyzed by SEM and Electron probe micro-analysis (EPMA) to investigate the morphology of products. Different temperature will cause different structure of particles. With the increasement of temperature, cobalt removal can be improved considerably. The mechanism of cobalt removal by zinc dust is thought as follows: firstly, the cobalt ion forms Co-Zn alloy with zinc particles, and the reaction reaches equilibrium quickly; secondly, the Co-Zn alloy continues reacting to Co with Co2+, which is the control procedure of the whole reaction.

Jan 1, 2014

By Denilson Coutinho, Euler Soares, Paulo de Tarso, Jordana Ferreira, John R. Goode, Andreas Sprecher, Alexandre Rocha

The Serra Verde Project is located in the northern part of Goiás state, Brazil, and comprises 49 mineral claims covering an area of 69,814 ha. The Serra Verde deposit is a rare earth element (REE) enriched weathered granite comparable to the weathered granite, or ionic-clay, deposits found in southeastern China. The Mineral Reserves of the Serra Verde Project total 388 Mt (Measured and Indicated) at an average grade of 1,484 ppm of REE oxide (REO). Several hundred agitated leach and column leach tests have confirmed recovery of about 40 to 55% of the REE, except for Ce, using simple desorption techniques. Present plans call for a heap leach operation followed by precipitation of impurities and precipitation of a pure REE carbonate suitable for refining and separation. The project plan includes initial production of 5,000 t/a of REO, with a high content of heavy and critical REO, rising to 10,000 t/a of REO. This production rate will be obtained by mining of the Mineral Reserves over a 22-year mine life at an initial rate of 6 Mt/a for the first four years with the mining rate thereafter increasing as required by grade and production targets.

Jan 1, 2014

By Michael S. Moats, Addin Pranowo, Gerardo R. F. Alvear F., Nigel Aslin

The toxicity of arsenic is well known and documented. However, the presence of arsenic in copper electrorefining anodes and electrolyte is critically necessary to produce high quality cathode. Arsenic as well as antimony and bismuth concentrations vary depending on their relative concentration in the anode copper received from the smelter. This paper will discuss the behaviour and benefits of arsenic in copper electrorefining and the detrimental effects of antimony and bismuth on cathode quality and tankhouse performance. This will include the minimization and mitigation of problems associated with arsenic, antimony and bismuth including cathode contamination, floating slimes, scaling and anode passivation.

Jan 1, 2014

By Paulo Sérgio de Oliveira, Joaquim D. Donda, Andreia C. Rosa

"The search for energy efficient technologies for comminution processes is constant in mineral processing studies, since those processes represent a major percentage of operational costs. In this context the use of stirred mills is increasing, especially for ultrafine grinding. Although many authors claim that these new equipment are more efficient than the conventional ball mills, there were very little chances to prove that in a practical way, since there are few industrial circuits where those technologies perform the same duty. Therefore, the regrinding circuit of Germano second concentrator offers an interesting opportunity: a vertical mill operating in parallel with two ball mills. During almost two years of operation, several sampling campaigns were conducted to evaluate the vertical mill performance and to compare the operational data of the three mills. The industrial data was also compared to jar mill tests results, which are monthly conducted in Samarco labs in order to predict the specific energy consumption required by the ore fed to these circuits. The vertical mill demonstrated the same ability to achieve the product specifications of the ball mills while proved to be able to reduce the medium specific energy consumption in about 40%."

Jan 1, 2014

By S. Pauly, U. Kühn, J. Eckert, I. Kaban, G. Wiehl, F. Silze

In the present work, the effect of Ga on the wetting behavior of the Cu-rich braze filler CuGa10 (wt.%) on the steel 304L was investigated. For this, the macroscopic and microscopic effects governing the wetting of pure Ga, pure Cu and CuGa10 alloy (wt.%) on the austenitic steel were analyzed and compared. Contact angle and surface tension measurements were carried out by means of the sessile drop technique and, in addition, the phase formation at the interface was determined. Pure liquid Ga spreads on 304L, which supposedly is related to the formation of intermetallic Fe-Ga phases growing into the liquid Ga. Depending on the annealing time, FeGa3 and Fe14.5Ga12 were identified. In contrast, CuGa10 as well as pure Cu show secondary wetting on the steel surface. Especially, liquid Cu prefers to spread laterally and vertically along the grain boundaries of the steel substrate. In spite of rather similar mechanisms, CuGa10 wets 304L steel at lower rate than pure Cu above the liquidus temperature.

Jan 1, 2014

By Q. Han

Irradiation of high energy ultrasonic vibration in metals and alloys generates oscillating strain and stress fields in solids, and introduces nonlinear effects such as cavitation, acoustic streaming, and radiation pressure in molten materials. These nonlinear effects can be utilized to assist conventional material processing processes. This article describes recent research at Oak Ridge National Labs (ORNL) and Purdue University on using high intensity ultrasonic vibrations for degassing molten aluminum, processing particulate reinforced metal matrix composites, refining metals and alloys during solidification process, welding, and producing bulk nanostructures in solid metals and alloys.

Jan 1, 2014

By Behzad Vaziri Hassas, Firat Karakas, Mehmet Celik, Onur Guven

Since dewatering is a costly process, removal of moisture from relatively fine size lignites is an important industrial problem. As the lignite gets finer, the presence of micropores and relatively low hydrophobic nature of lignite lead to trapping of large quantities of water in the coal matrix. Lignites used in power stations need to be dried to a certain degree of humidity before it is transferred to the combustion chamber. It is generally wise to dewater coal as much as possible by physical means before it is dried. However, dewatering cost in some cases may be prohibitive. Thus, sometimes removal of even little percent moisture may be of great help in such operations. Surfactants have been used to increase the efficiency of coal dewatering. It is crucial to select appropriate type and amount of surfactants in order to get higher efficiency. Since the hydrophobic characteristic of coals increases with increasing the coal rank, dewatering of bituminous and anthracite can be accomplished using low HLB surfactants (Oily), however, these surfactants are not efficient in the case of low rank coals like lignites and brown coals. It is suggested that adsorption of low HLB surfactants on high rank coals is governed by Acid-Base interactions rather than electrostatic and van der Waals forces. Since this characteristic in lignites is not strong enough, low HLB surfactants could not be effectively adsorbed on low rank coals to make surface more hydrophobic. In this paper, a special set-up has been designed to study the effect of high HLB surfactants on dewatering of fine lignite particles. It is shown that high HLB surfactants function more efficiently on low rank coals than low HLB ones.

Jan 1, 2014

By Matthew Novak, J. Brent Hiskey

It is well known that when chalcopyrite is put in direct contact with copper in an acidic medium a galvanic cell is created. Chalcopyrite is reduced to iron and sulfur deficient defect phases such as bornite, chalcocite, and at very low potentials to elemental copper. Galvanic conversion experiments were performed using three chalcopyrite concentrates. The first chalcopyrite contained less than 10% impurity phases. The second concentrate had a high concentration of pyrite, and the third concentrate had a high concentration of pyrrhotite. The effect of temperature, acid concentration, chalcopyrite grain size, copper grain size, and agitation on the rate of chalcopyrite conversion was studied.

Jan 1, 2014

By Ulrich Leiste

If the iron ore loss is 15% in the process of mining, the total iron ore loss in the world will be about 461 million tons, this is equal to the total production of 230 iron ore mines each of which produces 2 million-tons of iron ore per year. Based on a series of blast tests in the Malmberget mine, this paper shows that ore recovery can be markedly increased by improving blasting technology such as choosing a correct primer position and making use of shock wave collision. The paper further suggests that a high ore recovery can not only reduce natural resource loss and mining cost but also prolong the life of a mine. In addition, the paper shows an example of reducing blast-caused rock damage in the roofs and walls of underground drifts (tunnels) by using new blasting methods in the Malmberget mine. Finally, the paper shows how the Malmberget mine has successfully reduced the ground vibrations, without adversely affecting fragmentation and ore recovery in sublevel caving mining.

Jan 1, 2014

By F. Sheykh-Jaberi, S. L. Cockcroft, A. B. Phillion

A coupled fluid/structure model has been developed to simulate semi-solid deformation in an industrial aluminum casting alloy, A356. Although this alloy has a significant eutectic fraction, nearly 50%, it still shows susceptibility to hot tearing. The model geometry consists of solid grains, created from a Voronoi tessellation of the domain, surrounded by liquid. The simulation is performed using the commercial codes, Abaqus Standard and Abaqus CFD. The solid model calculates the velocity, stresses and distortions in response to an applied uniaxial strain, and transmits them to the fluid-flow model, which computes the velocity and pressure fields in the liquid. It was shown that grain size and configuration, fraction solid and fluid properties all affect the semi-solid deformation behaviour.

Jan 1, 2014

By Rudolph P. Frizzi

"Abstract Pile design for building structures in the United States is typically performed by: 1) investigating and assigning engineering parameters to the respective ground bearing materials, 2) calculating ultimate pile to ground (geotechnical) capacity which is then reduced by a Safety Factor deemed appropriate by a registered Design Professional thereby arriving at an allowable pile geotechnical pile capacity, and 3) determining the required pile structural section using allowable pile section material properties. It is advantageous to use a Working Stress Design Method (WSDM) approach as one system of loads (service loads) are used in both the geotechnical and structural evaluation. There are a variety of methods used to determine the ultimate and allowable geotechnical capacity, and Building Codes often require a registered Design Professional to determine the appropriate method(s) and capacities. The International Building Code is the Code typically referenced in building design and construction in the United States. Structural design usually follows Building Code requirements and Allowable Stress Design (ASD) procedures. As design of the overlying structure typically follows a Strength Design Method (SDM) approach using factored loads, in some cases piling is first designed for pile-to-soil interaction using service loads, followed by evaluating the pile geometry for factored loads. Construction is the finalization and implementation of the designed piling. As such, project-specific technical specifications are typically developed by a registered Design Professional such that a project Owner can bid, buy, and instruct a Contractor as to the desired piling work and acceptance criteria. There are several Industry groups, including DFI, PDCA, ADSC, and ACI that provide guidance documents which the registered Design Professional can refer to in developing the piling technical specifications. It is the author’s opinion that the registered Design Professional is best suited to observe and verify the piling installation; many Building Departments require verification and documentation by a registered Professional as a condition of final acceptance.INTRODUCTIONPile design for building structures consists of: investigation, design, specification, and verification. In major metropolitan areas within the United States, Building Codes typically identify minimum requirements for each of the above steps. The International Building Code (ICC, 2012) is the Code typically referenced in building design and construction in the United States. Recognizing the ground conditions as well as piling construction means and methods can vary on a site-by-site basis, latitude is given to the registered Design Professional and Contractor to optimize the piling system for the respective project conditions. Field testing and quality control / assurance measures are typically implemented to verify the design intent is attained for the production pile elements."

Jan 1, 2014

By J. H. Cloete, S. M. Bradshaw, D. K. Chibwe

"The primary function of a tundish in the steelmaking industry is to serve as a buffer tank, accepting molten steel from the batch ladle process and allowing it to be cast continuously. However, modern steelmaking has more stringent demands for the quality of the steel product, requiring increased control over the properties of the molten steel before casting. For this reason tundishes have been developed as metallurgical reactors to serve as the final step in refining of the molten steel by removing non-metallic inclusions, preventing the formation of new inclusions, and promoting chemical and thermal homogeneity. In this study the flow behaviour in a four-strand tundish was investigated by means of a half-scale water model as well as numerical modelling. Both the numerical study and physical model were used to characterize residence time distribution (RTD) in the vessel and calculate properties pertaining to the tundish flow regime. Three different tundish configurations were investigated: a bare tundish with no flow control devices, a tundish with a turbulence inhibitor and a tundish with both a turbulence inhibitor and a dam.The physical and numerical models showed that a tundish without flow control devices was prone to significant short-circuiting. A tundish with a turbulence inhibitor was shown to be successful in preventing short-circuiting and provided surface-directed flow, which aids inclusion removal in the slag. Despite the benefits of the use of turbulence inhibitors, it was observed that the upward-directed flow increased the maximum turbulence kinetic energy near to the surface by approximately 120% compared with the bare tundish. Therefore the potential for slag entrainment should be considered during the design and operation of tundishes utilizing turbulence inhibitors."

Jan 1, 2014

By K. Adham

"Fluidized beds are utilized in a wide range of high-temperature applications throughout the metals and materials industry. Their main advantage is the fast and uniform heat and mass transfer between the hot combustion gases and the particulate solid feed. A further benefit can be the lowering of the processing plant's energy consumption, through heat recovery from the fluid bed processes used for solids heating. Here, the enhanced energy efficiency of fluidized systems is investigated and the modeling results are discussed for three configurations: the flash tube, the single bubbling bed and the multi-stage fluid bed. Key thermal design aspects of each system are identified based on results from process simulations, in order to benchmark their main operating features and overall energy efficiency. Suitability and applicability of each configuration is also discussed based on a number of process and material property considerations.IntroductionCombustion based heating of particulate solids is commonly done using three different types of fluidized beds. The flash tube (FT) is similar to a hot pneumatic transport system. The single-stage fluidized bed (FB) typically uses in-bed combustion. The multi-stage fluidized bed (MSFB) can have two or more stages stacked into a tower.Flash tube (FT) suspends the incoming solid charge in a high-velocity stream of hot combustion gases. To maintain the solids suspension in the FT, two parameters are required: high velocity for elutriation of the particles and adequate solid-to-gas ratio for avoiding high pressure drops and solids drop-out [l].The fluid bed (FB) works at much lower velocities than the flash tube. Therefore, most of the solids are not conveyed in the gas stream, but are only suspended in a liquid-like manner. At minimum fluidization velocity (Umr), the gas flow exerts just enough force on the solids to keep them suspended in place [2].Multi-stage fluid bed (MSFB) heats up the solids as they are transferred from an upper bed level to a lower one, counter-current to the rising flow of hot gases generated at the lowest stage. As the temperature and volumetric flow of the gases decrease from bottom to the top stage, smaller bed diameters can be used in the energy recovery stages [3]."

Jan 1, 2014

By B. Q. Xiao

The nitrate content is an important factor for environmental water samples and flour. In a 0.35 mol/L H2SO4-2NO solution, has a strong catalyzing function on the decolourization of Gallocya-nine (GC) oxidated by NaBrO3. Based on this, a novel method was developed to measure the NO and -3NO concentrations in water and flour. The flow injection technology was introduced into the analysis system. A single-valve dual- cingulums to inject which the Copperized-Cadmium slice and the reduction zone are isolated. The optimum solution for this method contains 1.48×10-4 mol/L GC, 0.06 mol /L NaBrO3 and 0.2 mol /L of NH4-2NOCl. Two empirical equations were proposed to calculate the and -3NO concentrations based on the measured signals. It can be used to measure -2NO of from 0.001 mg / L to 2.0 mg/L and -3NO of from 0.002 mg / L to 2.5 mg/L. The measurement frequency can be up to 20 samples / h. The relative standard deviation for eleven samples is less than 5%.

Jan 1, 2014

By R. X. Li

The overall flow-sheet of producing chromium (III) sulfate is described in this paper. The suitable conditions of each process such as sintering, leaching, aluminum removal, reduction, and de-composition conditions were experimentally studied. The results show it is reasonable to produce chromium (III) sulfate with the flow-sheet pointed out in this research work. The final product is Cr2(SO4)3 solution contained 150~250g/L Cr.

Jan 1, 2014

By M. A. C. Goes

Over the last twenty years CETEM has been involved in the preparation and certification of reference material from ores, concentrates and related materials for use in analytical laboratories associated with mining, metallurgy and earth sciences. CETEM provides reference materials from mineral samples, not available from the existing sources, to meet the needs of the mining and mineral industry. CBPA-1 and CBPA-2 respectively are samples of copper sulphide ore and flotation concentrate, both originated from Sossego Mine, located in Pará State, Brazil. The batch characterization was carried out by a collaborative measurement program with participation of 20 industrial, commercial and government laboratories from South America, North America, Europe, Asia and Africa. The certificates and report were issued in December 2007 (http://www.cetem.gov.br/ mrc/ing). The objective of this paper was to describe the procedures for material preparation and the collaborative approach involving a collaborative interlaboratory measurement program to certify CBPA-1 and CBPA-2.

Jan 1, 2014

By Chuanyao Sun, Longli Liu, Fayu He, Guiye Wu

Utilizing thioglycolic acid (TGA) as a template and using structure-guided design, a molecular modelling approach has been used to design and screen appropriate dispersant for chalcopyrite. A series of organic dispersants based on a TGA substitution with hydroxyl and amino and sulfonic functional groups have been examined on chalcopyrite surface. 20 organic depressors of chalcopyrite have been investigated to study the quantitative structure-activity relationship (QSAR) of chalcopyrite depressors. For the chalcopyrite surface, depressor containing carboxyl and sulfonic group is generally stronger than the depressor containing hydroxyl group. Increasing the number of hydrophilic group can effectively enhance the inhibition. Increasing the number of Solidophilic group does not necessarily lead to enhanced inhibition ability; steric factor is one of the important factors to affect the interaction. Extension alkyl carbon chain length cannot enhance the interaction of depressors. Isomers principle as well as applies to the chalcopyrite depressor molecular design. Flotation verification tests further confirmes the accuracy of the molecular simulation. Through the Computer Aided Molecular Design (CAMD) technology, we can save enormous time and resources to design novel surfactants. This research and application will play a great significance role in sulfide flotation.

Jan 1, 2014

By Mario Terceros H., Bengt H. Fellenius

"ABSTRACTFour strain-gage instrumented bored piles were constructed in a sedimentary, dense to very dense, fine to medium sand in Santa Cruz, Bolivia. Two of the test piles were the normally used bored pile constructed with bentonite slurry and two piles were Bauer Full Displacement Pile (FDP). One of each pair was equipped with the Expander Body, an inflatable steel cylinder that on pressure-grouting provides an enlarged pile toe. Head-down static loading test were performed on three of the piles and a bidirectional test was performed on the fourth pile, a standard pile with Expander Body and a bidirectional cell placed immediately above the EB. The latter pile was tested in 3 phases. First by activating the cell, second, by a head-down test, and, third, by a repeat bidirectional cell test. The static loading tests proved the shaft resistance of the FDP pile to be about twice that of the standard bored pile and that the Expander Body more than doubled the toe stiffness. The strain-gage records showed that the standard bored piles had multiple bulges and neckings, which affected the evaluation of the axial stiffness and load distribution of the piles. The testing programme was used for a prediction event with 60 persons, ahead of the tests, submitting predictions of the load-movement curves for the test piles and also a capacity appraised from the curves.1. INTRODUCTIONOn April 23 - 26, 2013, the First International Conference and Seminar on Deep Foundations was held in Santa Cruz, Bolivia under the auspices of INCOTEC SRL, the UAGRM University, and the Bolivian Association of Civil Engineers and Chamber of Construction. To coincide with the conference, a research study on construction and static and dynamic testing of four instrumented bored piles was undertaken. To ""add spice"" to the conference, a prediction event was organized on the test programme. This paper presents the soil conditions at the site, the type and construction of the test piles, the outcome of the prediction event, and the results of the static tests.2. SOIL CONDITIONSGeotechnical studies comprising SPT and CPT tests with routine laboratory analysis were performed on recovered soil samples. Three SPT boreholes were put down at three of the locations of Pile TP1, TP2, and TP3, at 5.0 m distance from each other. The SPT procedure consisted of manual hoisting of the weight by three crew members pulling on ropes over a pulley supported by a tripod and letting the weight fall by gravity. The groundwater table lies at 3.5 m depth.Figure 1 shows diagrams of the SPT N-indices and the distribution of water content in the three boreholes. The SPT-indices show the soil density to be compact. The average water content is about 15 %, plus-minus a few percent."

Jan 1, 2014

By T. Wajima

We tried to convert paper sludge ash (PSA) into zeolitic product with high cation exchange capacity (CEC) through acid leaching. Typically, PSA from incineration of paper sludge contains a high percentage of calcium in the form of anorthite (CaAl2Si2O8) and gehlenite (Ca2Al2SiO7). It is difficult to convert the ash with a high Ca content into zeolites, or at least into more desirable zeolite phases. Acid leaching with HCl was applied to reduce the Ca content to synthesize zeolitic product with high CEC. The raw ash was treated with 1 M, 3 M, and 5 M HCl solution for 0.5~24 hours (the ratio of the ash to volume of HCl solution was 1/4), and then zeolitic product was synthesized from leached ash through the reaction with 2.5 M NaOH solution at 80 oC for 24 hours. During acid leaching, gehlenite is readily dissolved in a lower HCl concentration solution than anorthite. With increasing HCl concentration, the amounts of Ca, Mg, Si, Al, Fe and Ti extracted from the ash increased. Ca and Mg contents were easily extracted from ash than other elements. The contents of Ca and Mg extracted rapidly at initial stage, and then levelled off. The saturation times of Mg and Ca are almost 0.5 h using all concentrations of HCl solutions. After the synthesis from leached ashes, zeolite-A and -P were synthesized from ash leached in 1 M HCl solution, and 3 M and 5 M HCl solutions, respectively, regardless of leaching time. With in-creasing HCl concentration, the Ca content eluted from the product decreased, due to the removal of Ca via acid leaching before the synthesis, while the Na content eluted from the product increased to 3 M HCl and then decreased, which was almost similar to the CEC of the product, due to the ion exchange of Na-type zeolitic phase in the product. The change of zeolite phases in the product and the CEC of the product depend on the concentrations of Si and Al in the solution during the synthesis. The highest CEC of the product is about 220 cmol/ kg, which was synthesized from the ash leached in 3 M HCl solution.

Jan 1, 2014

By Arkady Senchenko, Andrey Vasiliev, Alexander Aksenov, Metodi Zlatev

"This paper considers the issue of treating argillaceous oxidized ores with low gold grade (around 1.0 g/t). These ores according to their gold recovery level can be treated by heap leaching and agitation cyanide leaching, but low gold grade makes this treatment uneconomic. Heap leaching of argillaceous ores requires high consumption of binding agent for pelletizing to create suitable hydro-physical properties of material, which leads to increasing process cost and makes the material treatment unprofitable. Agitation cyanide leaching of this ore requires grinding processes; these expenses would not be paid back by the amount of gold recovered. Considering the above, poor argillaceous oxidized ores are recommended to be treated according to a combined technology including fractionation of ore, heap leaching of coarse fraction and agitation leaching of argillaceous fraction. Complex approach application allows one to avoid expenses incurred for material grinding and high consumption of binding agent for pelletizing. The success of this technology implementation will firstly depend on the quality of material fractionation, therefore the section of disintegration and division of ore into different components will be the most important part of flowsheet development for gold production. When disintegrating minerals at positive temperatures both standard (mechanical disintegration - scrubbers) and innovative (hydraulic method of disintegration - HydroClean units) equipment is applicable. HydroClean units are characterized by lower energy and water consumption. In a number of cases it is required to treat frozen ores. When treating frozen material standard approaches to disintegration are not reasonable due to their low efficiency. In order to treat frozen material a two stage disintegration flowsheet with screening after each stage is recommended. The first stage is recommended to be performed in a scrubber, the second - in a HydroClean unit. This technological flowsheet will provide high and steady values for ore separation into fractions at low energy consumption for disintegration."

Jan 1, 2014