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By Sugui Tian

By means of the T6 treatment, the measurement of creep curves and microstructure observation, the influence of T6 heat treatment on the microstructure and creep properties of Ti-6Al-4V alloy is investigated. Results show that the microstructure of the forged alloy consists of the banded-like a phase and networks b phase. After sub-temperture T6 treated, the microstructure of alloy consist of the block a phase and ?networks basket? structure. Under the conditions of the applied stress of 575 MPa at 4000C, the forged alloy displays a lower creep lifetimes, after T6 treated the creep lifetimes of the alloy is enhanced to 548 h from 66 h, which is attributed to the formation of the network basket structure in which the needle-like phase are dispersedly distributed. As creep goes on, the denser dislocations in the a phase are concentrated to occur the dynamic recrystallization for refining grain. which is a main reason of the alloy displaying a better creep lifetimes and plasticity. Thereinto, the creep mechanism of the forged alloy is thought to be the slip of the straight <a> and <a+c> dislocation are activated on the prismatic planes and pyramidal planes, while the creep mechanism of T6 treated alloy is that wave-like <a+c> dislocations are activated on the pyramidal planes.

Jan 1, 2009

By Kazuki Morita

A new route to produce solar grade silicon (SOG-Si 6N) from metallurgical grade (MG-Si 98%) has been developed in Japan, which may satisfy the increasing demand for solar cells in the near future. Since some elements such as P and B have very large segregation coefficients, solidification refining is not effective for their removal and costly processes, such as electron beam vacuum melting and oxidation plasma refining, are required. According to our previous results which showed the effectiveness of leaching procedure with Ca addition for Fe and Ti removal, possibility of P and B removal by acid leaching was focused expecting that their affinities for Ca in molten silicon might be considerable. Hence, the effects of Ca addition on the thennodynamic properties of P and B in molten silicon alloys have been investigated for overall control and optimization of the SOG-Si production process in the present study. The interaction parameters between Ca and P, and Ca and B were determined by chemical equilibration techniques at 1723 K. Although the interaction parameter between Ca and B was slightly negative, that between Ca and P showed a large negative value. Also, the results for the leaching test with various amount of Ca addition revealed that the removal fractions of both elements, especially P, drastically increased with increase in the Ca content, which showed very good agreement with the prediction from the interaction parameters derived in the present work. The present results suggest that the preliminary leaching procedure can reduce the processing time and energy for SOG-Si refining. Keywords: Silicon, Solar Cell, Refining, Acid Leaching, Thennodynamics. Interaction, Phosphorus, Boron, Calcium

Jan 1, 2003

By R. Singh, C. Gong, J. Chaudhry

"Metalorganic chemical vapor deposition (MOCVD) is an ideal technique for the deposition of conducting and non-conducting oxide based thin film materials. In this paper we have presented a study of photo assisted MOCVD for the low temperature deposition of a number of oxide based advanced materials. We have used incoherent light sources as the source of optical and thermal energy in our MOCVD system. The vacuum ultraviolet (VUV) and ultraviolet (UV) photons can enhance the surface reaction of the absorbed molecules through the perturbation of the electronic state of binding between the absorbed molecules and the solid surface. Unlike plasma process, no surface damage is expected and high quality materials have been deposited. At a given substrate temperature, the performance of deposited film depends on the lamp configuration.INTRODUCTIONMetalorganic chemical vapor deposition (MOCVD) has become the standard manufacturing technique for the deposition of large area thin films of compound semiconductors. l.(.w-cost, high crystalline quality, atomically clean and sharp interfaces, atomic layer epitaxy, high throughput rates and potential for direct writing are some attractive features of MOCVD. Due to a number of potential advantages mentioned above, MOCVD is considered as an ideal technique for the deposition of various electronic and optical materials for a wide variety of applications. Rapid isothermal processing based on incoherent radiation as the source of optical and thermal energy is emerging as the key low thermal budget (integral of processing time and temperature) processing technique for the fabrication of current and next generation of microelectronic and optoelectronic devices and circuits [1]. In this paper we have demonstrated that the design of the lamp assembly plays an important role in determining the properties of the materials deposited by RIP assisted MOCVD. We have studied the growth rates, structural properties and electrical properties of Y2O3/Si structure. At a given substrate temperature, best results are obtained for the lamp assembly that provides maximum number of VUV and UV photons."

Jan 1, 1994

By C. J. Newman

The Kidd Creek Copper Smelter has been expanded from its original design of 59,000 tonnes of copper per year to over 120,000 tonnes per year. Modifications to the process gas handling system and acid plant have been made to accommodate this higher production rate and to generally optimize the operation. The gas handling system associated with the continuous smelting process is discussed in terms of boiler accretions and modifications to minimize their impact on operations; design changes to effect reductions in high pressure drop duct configurations; material changes to overcome corrosion and plant additions to improve gas cleaning capability. The acid plant is reviewed with references to changes? made to accommodate the increased SO2 gas strength resulting from the higher smelting rates.

Jan 1, 1992

By Vinicius Alves Gomes, Jean Igor Margem, Frederico Muylaert Margem, Sergio Neves Monteiro, Marina Rangel Margem

The interface between the matrix and the reinforcing fiber plays an important role in the efficiency by which an applied load is transmitted through the composite structure. The shear stress at the fiber/matrix interface can be associated with this load transference and, consequently, affects the composite strength. In the present work, pullout tests were used to evaluate the interfacial shear stress of malva fiber in epoxy matrix composites. A small critical length was found for the malva fiber embedded in epoxy, which corresponds to a relatively weak fiber/matrix bond and lower interfacial strength.

Jan 1, 2015

By Philip Arthur

The ISASMELT process is making a significant contribution to the global metals industry. ISASMELT furnaces are now operating successfully in eight different countries and treating approximately 3 million tonnes of concentrates and secondary materials per year. The process is currently used in both lead and copper smelting. The most recently commissioned plants were in Germany and China, one for treating scrap copper and the other treating low-grade copper concentrates. The Copper ISASMEL T furnace ("CIF") at Mount Isa Mines Limited ("MIM") has continued to set new operational records, with throughput of more than I million tonnes of concentrate per year and very low operating costs. This paper summarises the latest operational data from the Mount Isa Copper ISASMELT plant and outlines the successful approach to industrial R&D taken by MIM in the development of the ISASMEL T process.

Jan 1, 2003

By A. Perillo

The process, realized in. the Kivcet furnace, can convert continuously lead concentrates, residues and secondary lead bearing materials into a lead bullion free of sulphur and a discardable slag. The lead recovery can be up to 99%. The long experience of about three years at Portovesme demonstrates the capability of the furnace to smelt a very. high range of lead raws without interruption of the operation. The operating costs are very competitive in comparison to the traditional technology. The work place and environment are clean and new tight regulations for the? hygiene control are met. The Kivcet furnace can be considered as consisting of three parts (reaction shaft, waste gas shaft and electro-furnace) connected with a common hearth. The technical basis of the furnace construction is the application of a number of design elements .which have mostly been used before in designs of industrial furnaces, such as open hearth furnace, refining furnace and other furnaces dealing with liquid meta1s. Refractory wear in the reaction shaft with typical pattern from watercooling soon has been stabilized and since maintained. No deformation of the furnace shell and no leakage of metal or s:l:ag through the bottom is? appeared after three years&apos; operations.

Jan 1, 1990

Carbon injection into metallurgical slag is important in electric arc furnace (EAF) steelmaking for foamy slag practices and in nonferrous slag cleaning operations. The current publication presents kinetic data for coal injection into EAF slag to understand the interaction between injected carbon and metallurgical slag. Coal particles were injected into EAF slag and the kinetics were followed by gas and slag analysis. The results were analyzed, in terms of fundamental rate equations for each possible reaction step, as a function of temperature and slag composition.

Jan 1, 2003

By Frame Ritzert, Dennis Keller, Vijay Vasudevan, David Arenas

"An investigation was conducted to describe topologically close packed (TCP) phase instability as' a function of composition in the advanced ·Ni-base superalloy Rene N6. TCP phases are detrimental to overfill high-temperature performance of Ni-base superalloys because of their brittle nature and because they deplete the Ni-rich matrix of potent solid solution strengthening elements. Thirty-four variations of polycrystalline .Rene N6 determined from a design-of-experiments approach were cast and homogenized at 13 l5°C for 80 hours followed by exposure at 1093°C for 400 hours to promote TCP formation. The alloys had the following composition ranges in atomic percent: cobalt 10.61 to 16.73, Mo 0.32 to 1.34%, W 1.85 to 2.52%, Re 1.80 to 2.11%, Ta 2.36 to 3.02%, Al 11.90 to 14.75%, and Cr 3.57 to 6.23%. Physical and chemical characteristics of all microstructures obtained were described using various analytical techniques. From these observations, a mathematical description of TCP occurrence (s and P phase) was generated for polycrystalline Rene N6.IntroductionNi-base superalloy single crystals represent the state-of-the-art for turbine engine airfoil application as they offer the best balance of properties to allow for the high operating temperatures required: for efficient engine operation.1 Current trends in alloy design take advantage of improved creep rupture strength with the addition .of higher levels of refractory elements. 2 In .particular, the addition of significantly higher levels of Re in third generation superalloys is key for both microstructural stability and creep rupture strength. 3 While the presence of the refractories is thought to provide strength benefits from solid solution hardening, a tendency for alloy instability in the form of topologically-close-packed (TCP) phases or secondary reaction· zone (SRZ) ·phenomena accompanies the high refractory content. 3 The formation of these phases in sufficient amount is detrimental to the overall high temperature performance of Ni-base superalloys because of their brittle nature and because they deplete the Ni-rich matrix of potent solid solution strengthening elements.4 The tendency for a particular composition to form TCP may not be immediately known since the precipitation of TCP phases in Ni-base superalloys is nucleation controlled, thereby requiring long times at elevated temperatures to precipitate. 5 They preferentially nucleate along the octahedral planes of the Ni-base superalloys, usually in areas of refractory metal enrichment at grain boundaries or inside dendrites.5-6 In Rene N6, two closely related TCP phases, a and P, have been observed.2"

Jan 1, 1998

By Alicia Esther Ares

This study was conducted to investigate the directional solidification of Zn-20%A1 and Zn20% A1-1O%Si-3o/oCu alloys under different conditions of heat transfer at the metal/mould interface. The type of structure obtained in both cases was analyzed and related to the solidification thermal parameters such as cooling rate, growth rate, thermal gradient and recalescence which were determined from the temperature versus time curves. These parameters were correlated with the structure-like length of columnar grains and size of equiaxed grains. The metallographic analyses were done performing quantitative metallography and composition analysis of the different alloying elements along the cast samples by SEM (Scanning Electron Microscopy) and EDXA (Energy Dispersive X-Ray Analysis). Correlations between properties, structures and thermal parameters were found.

Jan 1, 2008

By S. Agatzini-Leonardou

The objective of this work was to prove repeated loading capacities and investigate the selectivity of physically stabilized algal biomass from Spirulina platensis and Chlorella sp. for the removal and recovery of cobalt, nickel and chromium from laterite heap leach liquors. The testwork was carried out on a bench scale in small glass columns and proved that it was possible to immobilize the biomass on the highly porous surface of pumice stone (kissiris). Nickel and cobalt could be removed from pure aqueous solutions of each metal by the immobilized cyanobacterial biomass. Nickel and also cobalt biosorption was sensitive to the initial solution pH. Cobalt recoveries up to 80% were achieved after 5 loading cycles, from low concentration solutions, at pH 6.0. Nickel removal was complete under the same conditions, whereas chromium sorption was ineffective. Desorption of the metal loaded columns was effected by dilute sulfuric acid. The algal species giving the best adsorption capacities for the metals under consideration was selected for further experimental work with real laterite heap leach solution produced by column leaching. A statistical analysis of all obtained results was conducted using the fraction of metal removed as response. The ratio "mass of metal removed to mass of protein contained in the immobilized cells" was determined as well. The described method might be applicable for recovery of cobalt and nickel from diluted laterite heap leach solutions, such as heap wash waters, or for their removal from waste streams of a hydrometallurgical extraction process.

Jan 1, 1997

By E. J. Peuraniemi

Primary copper production using suspension smelting techniques like Outokumpu Flash Smelting always causes some dust formation. Flue dust particles are formed when sulphide feed material reacts violently with oxygen inducing particle disintegration and total desulphurisation of fragments. In the process, flue dust follows the off-gases to the heat recovery boiler (HRB) where its sulphation takes place because of prevailing conditions. Sulphation releases heat and causes also a drop in particle melting temperature and, further, particle sticking to the walls and heat exchange tube banks. Sulphation of synthetic CU20 particles were examined using a laboratory scale fluid-bed reactor. This study aims to a better understanding of flue dust behaviour in a HRB and, thus, to a better operational practise and design of a HRB. The effect of PSO/PO2 -ratio and temperature on the sulphation kinetics were tested. Standard chemical analysis, light optical and scanning electron microscopy with energy dispersive spectroscopy were used to examine the samples.

Jan 1, 2001

By P. A. Metz

The Fairbanks mining district has produced in excess of 7.5 million troy ounces of placer gold and 250,000 troy ounces of lode gold since gold was discovered in the area in 1902. The Fairbanks mining district is in the northwestern part of the Yukon-Tanana Upland Schist Terrane, an area of approximately 240,000 square km that has produced in excess of 21 million troy ounces of placer gold. All lode gold production from the terrane has been from the Fairbanks mining district, and all of this production has come from high-grade gold-quartz polymetallic sulfide veins. Gold grains in the vein systems range in size from several microns to several millimeters. The veins are localized in a complex metamorphic rock assemblage which includes greenstones and felsic metavolcanic and volcaniclastic rocks, meta-exhalatives and metasediments. Gold occurs in the metamorphic host rocks in association with arsenopyrite and arsenic-antimony sulfides which occur in lenses and disseminations within the host rock. Gold grains occurring in the metamorphic host rocks range. in size from sub-micron to a few microns in diameter.

Jan 1, 1987

By J. A. Bakken

Thermal plasmas are interesting for a wide range of metallurgical and chemical processing applications. The 300 kW experimental reactor PRESS, which has been in use since 1987, is operated in the transferred arc mode with three or one plasma torches . Tests include remelting of silicon fines and production of ultrafine silica. Work on a novel three stage process for production of silicon metal is under way. A 1:1 model of the plasma reactor is used to measure the wall heat flux distribution calorimetrically. The cold walls of this model are divided into several water-cooled sections. The same plasma torches as in the real hot-wall reactor are used. In parallel to the experiments and calorimetric measurements theoretical work is done on numerical modelling of one and three transferred arcs. A modified version of the flow simulation program FLUENT from Creare Ltd. is used.

Jan 1, 1991

By Yimin Ruan

"An inverse design method is developed to obtain the optimal cooling conditions for the continuous quenching of precipitation hardenable sheet alloys to achieve the required yield strength. The yield strength of a precipitation hardenable alloy is obtained by allowing solute to enter into solid solution at a proper temperature and rapidly cooling the alloy to retain the solute in the solid solution. An aging process may be needed for the alloy to develop the final mechanical properties.The objective of the design is to optimize the quenching process so that the required yield strength can be achieved. With the inverse design method, the required yield strength is specified and the sheet thermal profile at the exit of the quenching chamber can also be specified. The conjugate gradient method is used to optimize the cooling boundary condition during quenching. The adjoint system is developed to compute the gradient of the objective functional. An aluminum sheet quenching problem is presented to demonstrate feasibility of the inverse design method.IntroductionQuenching is a critical step in metal production to achieve desired material properties, such as yield strength, hardness, etc., for precipitation hardenable alloys. In most cases, rapid quenching from the solution heat treatment temperature is necessary to obtain the required material properties, but rapid quenching may cause other problems such as excessive distortions of the quenched materials.In a solution heat treatment, the alloy is heated to a suitable temperature, held at that temperature to allow the soluble alloying elements to enter into the solid solution, and cooled rapidly (quenching) to retain the alloy elements in the solid solution. An aging process, which controls precipitation of fine particles at room (natural aging) or elevated temperatures (artificial aging), is generally followed after the quenching process to develop the final mechanical properties of the heat treated alloys."

Jan 1, 1998

By J. Méndez-Nonell

The thermodynamic and chemical properties of SrSO4 and SrS in a gaseous flow of CO and CO2 at high temperature are discussed. The thermodynamic analysis of the system was made using data from the literature. The results obtained from the thermodynamic analysis were experimentally verified using the thermogravimetric technique. The experimental results suggest the formation of a complex compound between SrO and SrSO4. It was also found a change in the chemical mechanism of the process between SrSO4 and CO-CO2 and in the chemical mechanism of the process between SrS and pure CO2.

Jan 1, 1995

By T. J. White

Each year, thousands of tons of toxic concentrates are produced as the unwanted byproducts of industrial operations and smelting activities. The fate of these materials remains open, as in general their consumption is limited and potential markets contracting. Xtaltite (pronounced crystal-tight) is a Synthetic Mineral Immobilization Technology (SMITE) optimized for the concentration, detoxification and consolidation of toxic metal wastes. In this approach, we seek to mimic nature to produce durable synthetic minerals that survive for aeons in well characterized geological settings. This approach has high public acceptability because the concept is easily understood by the layperson and the long term stability of the waste form may be predicted with confidence. In addition, where Xtaltite is used for mine backfill, a system of ecologically sustainable mining development is established. This paper details the design and fabrication of Xtaltite under oxidizing and reducing conditions. To illustrate and contrast these stabilization regimes, specific reference will be made to the treatment of thallium, chrom~um and arsenic wastes. Waste form performance under TCLP, dynamic boiling water tests and in other leaching media will be compared and discussed with respect to their relevance to different disposal options.

Jan 1, 1995

By Vaughan R. Voller

"Solidification systems from conduction controlled freezing of a pure material through to alloy phase change that include flow and segregation processes are described. The components in a general solidification model-variables, governing transport equations, and local scale relationship-are outlined. A central focus is the presentation of an explicit procedure for coupling between macroscopic and local scale variables.IntroductionSince the seminal work of Byres et al.[!] in the 1940's there has been a steady progress in modeling solidification systems with increasing levels of complexity. The object of this paper is to track the evolution of these solidification models and present a general modeling approach that applicable to a wide range of the solidification systems of current interest.Solidification SystemsIn a broad sense the underlying physics in a solidification process occur at two distinct length scales:1. The macroscopic scale of the process over which the governing transport equations of heat, mass and momentum hold.2. The local scale at the solid-liquid interface where the solidification phenomena are operative."

Jan 1, 1999

By Guo Xueyi

The dissolution behaviors of valuable metals, lead and zinc, from secondary fly ash generated in municipal incineration plants were investigated using some lixiviants: sulfuric and hydrochloric acids, acetic acid and some chelating reagents including L-asparaginic-N,N-diacetic acid (ASDA), a biodegradable, and therefore, environmentally benign novel chelating reagent. It was found that zinc exists mainly as ZnO, whereas Pb probably as PbOHCI and PbO, and the easily soluble components in SFA are KCI and NaCl. Suitable amount of HCI can dissolve all of lead and zinc from SFA. Sulfuric acid can selectively extract zinc leaving lead in the residue. Ethylenediaminetetraacetic acid (EDTA) is an effective chelating reagent to extract both zinc and lead. Although ASDA and diethylene¬triaminepentaacetic acid (DTPA) can selectively extract more than half of lead from SFA, it would by no means be regarded as highly effective reagents for the extraction of these metal values. Keywords: Lead, Zinc, Secondary fly ash, Leaching, Dissolution

Jan 1, 2002

By Joseph Hamuyuni, Pekka Taskinen

We present experimental results for the liquidus in the system Cu2O - CaO -Al2O3 at 1250 oC. In this study, we quantified the liquidus by the equilibration/quench/analysis technique, with Cu2O, Al2O3, and CaO as primary materials exclusively. Experiments were conducted in air at an at oxygen pressure (p) = 21.3 kPa). Equilibrated specimens were quenched in brine solution of 10 wt% NaCl. We then quantified the liquid chemical compositions by means of Energy-Dispersive X-Ray Spectroscopy (EDS) and Electron probe micro-analyzer (EPMA). This study reveals inconsistences in liquidus surface of the present ternary diagram of the system here in mentioned. Differences of up to 10 wt % compositions of the species have been observed.

Jan 1, 2015