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By John Kosek

The electrochemistry of carbon monoxide, nitric oxide and nitrogen dioxide was investigated at a variety of electrode materials in different supporting electrolytes. A portable detector for carbon monoxide was developed using a porous gold anode in perchloric acid supporting electrolyte. This detector has two full scale ranges, 0-100 ppm and 0-500 ppm. A portable detector for mixtures of nitric oxide and nitrogen dioxide was developed using a porous silver cathode in sulfuric acid supporting electrolyte. Nitrogen dioxide was determined in the gas stream by electroreduction. The nitric oxide in the gas stream was oxidized to nitrogen dioxide by passing it over Cr(VI) on firebrick. Electroreduction gave the sum of NO + N02. Analog circuitry was used to display the amounts of NO and N02 separately. Two ranges were available for each gas. They were 0-10 and 0-50 ppm for NO and 0-2 and 0-10 ppm for N02.

Jan 1, 1979

By John W. Nebgen

This report contains findings from a U.S. Bureau of Mines study concerning the inhibition of acid mine drainage formation from underground coal mines. A series of experiments was performed in which three different pyritic materials (wastes from coal production plants) were evaluated using several candidate inhibiting agents. Data obtained from the inhibitor-treated pyrites were compared with data from control experiments in which untreated pyritic wastes were used. The experiments were conducted by placing treated and untreated pyrite in columns, passing moist air through the columns to promote oxidation of pyrite, and washing the columns weekly to collect oxidation products for analysis. Experimental results indicate that quantities of acid mine drainage can be substantially reduced if soluble iron III (ferric) ion is controlled. The best inhibitors are neutral or alkaline siliceous materials such as fly ash, blast furnace slag, portland cement, and cement kiln dust. These materials appear to insolubilize iron III species to make them unavailable for reaction with pyrite. The data strongly suggest that the soluble ferric ion aqueous is a key oxidant for pyrite to produce acid mine drainage. The role of aqueous ferric ion as an oxidizing agent is substantiated further by data obtained using metallic iron (nails) as an inhibitor. The iron nails tended to keep the soluble iron in the iron 11 (ferrous) state. Experimental results indicate that sulfate and acidity levels are reduced when pyrite is in contact with the metallic iron.

Jan 1, 1979

By Francis Church Lincoln

"INTRODUCTION During the period from September 18 to November 27, 1944, the Bureau of Mines conducted an investigation and exploratory churn-drilling program in an area immediately north of the Crow Branch Diggings, a district lying approximately 2 1/2 miles southwest of the town of Livingston in Grant County, Wisconsin.The work was undertaken as part of a general Bureau of Mines investigation of the zinc-producing area of southwestern Wisconsin at a time when all effort was being made to increase the production of metals important to the Nation's war prrgram.Although no mining has been done in the district in recent years the Crow Branch Diggings were an important source of galena and may be found today in the dumps remaining from old surface-mining operations.The Bureau of Mines undertook an exploratory churn-drilling program on the northwestern projection of the general strike of the digging in a zone where subsurface,lead and zinc mineralization had been reported from drilling done in the early 1900's."

Feb 1, 1947

By Steven R. Munts

The U.S. Bureau of Mines investigated mines, prospects, and mineralized areas in the South Providence Wilderness Study Area (WSA) in 1982. No mines are currently operating in the WSA, however, the Golden Gift Mine in the southeastern part of the WSA produced $6,800 1/ worth of gold and silver and five mines adjacent to the east boundary of the WSA had a total production of about $3,500,000 1/ in gold, silver, lead, and copper. There is no recorded placer gold production. Over 350 lode and placer mining claims are in and immediately adjacent to the WSA. Of these, 74 were actively held (1982) and at least one area, which is partly within the northeast portion of the WSA, was being actively explored by private industry in 1982. Adjacent to the southeastern border of the WSA the Big Horn Mine contains an estimated 200,000 tons of indicated and inferred marginal reserves averaging 0.25 oz/ton gold; and the Hidden Hill Mine has 550 tons of subeconomic resources averaging 0.60 oz/ton gold. An additional 11,000 tons of marginally economic gold-bearing dump reserves average 0.17 oz/ton gold at the Bighorn, Hidden Hill, and the Buena Vista Mines and the Midas Touch Prospect. Sample analyses indicate eight mines and prospects in, and five adjacent to the WSA may have additional gold-silver-lead-copper vein-type resources. Five of these prospect areas may have a disseminated gold resource and one may have gold resources in a skarn. One prospect may have a porphyry-type copper-molybdenum resource. Although gold placer claims were filed sporadically throughout the WSA, none appears to have placer gold resources. Likelihood for mining is greatest at the Big Horn Mine; if a mill is built there, it could process Big Horn Mine ore, ore from the Hidden Hill Mine, and gold-bearing dumps at the Big Horn, Hidden Hill, and Buena Vista Mines and the Midas Touch Prospect. All of these resources are adjacent to the WSA; however, their development would increase likelihood for development of resources in the WSA. Two major fault zones (the Hidden Hill, and the Big Horn) appear to have controlled the mineralization at many of the prospects and mines. All of the prospects or mines with vein-type occurrences and resources are on or adjacent to one of these fault zones. Veins throughout the eastern half of the WSA contain various amounts of gold, silver, and copper; only veins near the Big Horn Mine and in the northeastern corner of the WSA contain lead. Some veins are as thick as 6 ft, are traceable intermittently for over 2 mi along strike, are sporadically mineralized, are encased in prophylitic, argillic, and phyllic altered host rock, contain pyrite, chalcopyrite, galena, specularite, barite, or fluorite, and display multiple stages of quartz veining and (or) brecciation. Sample analyses at five prospects (map nos. 3, 18, 23, 24, and 31) indicate they may have disseminated gold resources. To date no oil or gas has been discovered within the WSA. However, some oil and gas leases are currently (August 1982) held within this study area.

Jan 1, 1984

By W. G. Phillips

This report presents results from a study whose objective was to evaluate noise control options for existing equipment used in metal and non-metal processing plants. This equipment performs 3 basic functions, crushing, grinding to a point where the product can be liberated from the waste, and agglomeration A the product. Specifically, the study was directed towards taconite processing since the extreme hardness of taconite results in high noise levels and in considerable maintenance of the processing equipment. Both of these factors make this process a very challenging noise control task. Plants processing other ores use similar equipment, consequently the results of these studies should he applicable to a wide variety of plants. The report presents the source diagnosis and potential retrofit noise control treatments for fine screens, mills, crusher sizing screens, and vacuum disc filters. Estimates are make of the noise reduction from each treatment. The report concludes with recommendations for future research on each piece of equipment.

Jan 1, 1978

By Donald B. Lindsay

A new concept was proposed for a personal warning device for use by miners who may be exposed to health hazards from inhalation of alpha-emitting radionuclides, especially radon-222 and its short-lived daughters. Two successive prototype models of the proposed instrument were designed, fabricated and tested. The Personal Alpha Alarm, in its final form, weighs less than 90 g (3 ounces), and can easily he mounted on a miner's safety cap. It is powered r, by electricity drawn from the cap-lamp battery, and consumes less than 100 n A at 4VDC. It is entirely passive and has no moving parts. Alpha-radiation originating in the air around it is detected by a 5 cm2-area semiconductor-type sensor that was developed especially for this purpose. The presence of alpharadiation in the air is communicated to the wearer by means of a small flashing light-a light-emitting diode-clipped to the brim of the safety cap. When the intensity of alpha-radiation exceeds a predetermined threshold, the flashing mode changes to a continuous illumination, thus providing an alarm signal to the wearer. Because the detector senses all alpha-emitters in the air, including 222Rn, it is not able to measure Working Levels accurately. For its intended purpose, however, which is to give a timely warning of excessive levels (several times the normal control level) of radon and/or radon daughters in an individual's air environment, the Personal Alpha Alarm is expected to be a useful instrument.

Jan 1, 1978

By Louis R. Iverson

Analysis of seed numbers present in topsoils (a grazed area, an ungrazed area, and two stockpiles) indicated that seeds of the most prevalent colonizers (e.g., Kochia scoparla, Setaria virdis, and Salsolo collins) were not present in the topsoil upon respreading but rather appeared by immigration from the surrounding areas. The grazed site had a seed density of over 7,700 seeds m-2 (of which 43% were from weedy species) and the ungrazed site had 3,900 seeds m-2 (of which 7% were weeds); the stockpiled topsoils had very low seed densities (255 and 520 seeds m-2). Seed densities and diversity decreased with depth on both the grazed and ungrazed sites; this was especially true on the grazed site where 94% of the seeds were found in the surface 7.5 cm. Several species were present in the seed bank (e.g., Hedeoma hispida, Artemesia ludoviciana, A. frigida, and A, abslnthlum) which were also found on the three and four year old mined sites in the aboveground vegetation survey. Seeds from these species may germinate after several years of dormancy, thereby starting populations on mined sites and enhancing plant diversity. Seed bank analysis was also undertaken on mined sites ranging in age of 2 to 6 years (plus an unmined site). Mined site seed densities ranged from 1630 to 3980 seeds m-2, with the four year old site having the greatest density (largely because of high Melilotus spp. populations); unmined site and stockpiled topsoil sample had lower seed densities. A significant positive correlation between total viable seed content and soil-water saturation percentage indicated that soil texture may influence seed viability/ dormancy (the. finer the material, the higher the seed population). As with the previous part of this study (and other studies), there was a poor correlation between the aboveground flora and the belowground seed composition.

Jan 1, 1982

By Scott A. Stebbins

This Bureau of Mines publication presents a method for estimating capital and operating costs associated with the exploration, mining, and processing of placer deposits. To ensure representative cost estimates, operational parameters for placering equipment and basic principles of placer mining techniques are detailed.

Jan 1, 1987

By James L. Hendrix

The applicability of a rotating drum with an attached trommel as a flocculation dewatering device of Florida phosphatic claywastes was studied. Several experiments were conducted in order to determine the important fabrication and operating parameters. Results from the experiments indicated flint the dosage of polyethylene oxide required to form a satisfactory product cake could be reduced by using the rotary drum, which introduces less shear stress into the fluid than a constant stirred tank mixer. It was found that the length of the mixer was the most important parameter. Increased length increased the retention time the flocs stayed in the mixer without dewatering. Such increased time decreased the stability of the flocs. Through analysis of residence time distribution data it was found that the longer mixers approached plug flow characteristics. Other important parameters were trommel length and rotational speed. Mixers from 10 cm diameter to 35.6 cm diameter were tested with good results.

Jan 1, 1982

Many of the difficulties faced by the U.S. mineral industry in 1982 and 1983 emanated from the worldwide recession, from the high value of the U.S. exchange rate, and, in part, from actions taken by foreign governments to protect selected industries. While some problems will be minimized with continued worldwide economic recovery, others remain and may require special attention by U.S. policymakers. These problems include declining U.S. production capacity in selected mining and mineral processing industries, the impact of the high value of the U.S. exchange rate, and protectionist trade practices by competitor nations. Illustrative of the last is the International Trade Commission (ITC) determination in June 1984 that both the domestic steel and copper industries have been substantially injured by foreign imports. In its July 1984 recommendations to the President, the ITC suggested higher tariffs and quotas for 5 years on 70 percent of steel imports but conditioned the aid on cost-cutting and modernization steps by the domestic industry. In the copper decision, two commissioners recommended increased duties, two recommended that quotas be imposed, and one recommended that no relief be provided. The President decided in September to seek voluntary restraint agreements with nations that export steel to the United States and rejected both quotas and higher tariffs on copper imports. General Economic Setting This decade opened with the U.S. mineral industries struggling to deal with double-digit inflation, record high peacetime interest rates, and almost 7 years of oil-cartel-induced energy price increases that seriously affected the profitability of energy-intensive industries such as mineral production and processing.

Jan 1, 1985

By Stephen C. Tadolini

The U.S. Bureau of Mines has developed ultrasonic measurement instrumentation capable of measuring strains and elongations on tensioned and untensioned mine roof bolting systems. This report evaluates the pulsed-phase-lock-loop and pulse-echo systems. The pulse-echo systems measure time of flight of a signal through the bolt. The ultrasonic instrument converts the measurement into elongations or stress. The most recent Bureau instrument development converts travel-time measurements directly into elongation, load, stress, and torque by simple data manipulation from the keyboard. Bolt preparation and instrument calibration are described in detail.

Jan 1, 1990

By J. J. Forbes

This publication is a revision of the first of a series of four Miners' Circulars originally prepared and issued in 19'29 for use in a course of training designed to prepare mine officials to organize men for rescue and recovery operations. These circulars were revised in 1937 and 1938 and again in 1948. This circular (Miners' Circular 33) discusses mine gases and methods for detecting them. The second of this series (Miners' Circular 34) gives instruction in Bureau of Mines methods of sampling and analysis of mine gases; the third (Miners' Circular 35) describes methods and equipment used for protection against mine gases; and the fourth (Miners' Circular 36) explains procedures used in sealing and unsealing mine fires and in recovery operations after mine fires or mine explosions.

Jan 1, 1954

By A. A. Berk

Other Federal agencies have been coming to the Bureau of Mines for help with the purchase and utilization of fuel, largely coal, almost since the day the Bureau was created in 1910. The requests covered a wide range of fuel- economy problems and included boiler-water treatment after it became apparent that water-formed deposits on heating surfaces acted as insulators, decreasing heat transfer and impairing fuel efficiency. Dr. Ralph E. Hall, a Bureau of Mines physical chemist determined the 3 reactions that cause adhering scale to form in boilers (7)2 and went on to introduce scientific principles into water treatment for scale prevention (8). Widespread publicity of these achievements increased the requests for help from Federal steam-generating plants. Since no other Federal agency (even those which were more directly concerned with testing water) wanted to provide boiler-feedwater service, the Bureau decided to continue to give requested help to Federal agencies, Later, the Congress endorsed such agency cooperation as an economy measure,

Jan 1, 1963

By J. F. McIlwain

The Bureau of Mines has investigated fumes generated by selected welding electrodes used in mines in order to help determine their relative health hazard potential. Fumes were generated and collected in an enclosed chamber for subsequent generation rate and chemical constituent determination. Shielded metal arc electrodes from the following groups were tested: AWS types E308-16 and E310-16 stainless steel, ECoCr-A Co-Cr hardfacing alloy, ENiCr Ni, an Mn-Cr buildup alloy, E7018 carbon steel, and EII018-M low-alloy steel. Flux-cored wire electrodes of this last group also were tested. Fume generation rates and the chemical composition of the fumes were measured. From these data, exposure in-dices were determined, which give a relative measure of the health hazard potential of using the electrodes. The effect of welding onto build-up alloy layers on the fume composition also was examined for five of the higher alloy groups.

Jan 1, 1987

By R. J. Leary

Iron and steel scrap has accounted for 45 to 50 percent of the metallics used by the steel industry. In an electric furnace which utilizes a 100-percent cold charge consisting of about 99 percent scrap and 1 percent pig iron, sensible heat from molten pig iron is not present as it is when hot metal is charged to open hearths and converters. A study of means for more efficient utilization of iron and steel scrap in steelmaking indicated that the time and fuel requirements to melt scrap were important cost factors, particularly in arc-furnace steelmaking. A process to preheat scrap economically prior to charging into the arc furnace has been developed, utilizing efficiently the heat from combustion of fossil fuels as a substitute for electric-arc heating in the initial stage of arc-furnace steelmaking. Scrap is loaded into a portable vertical cylindrical furnace body that is open at the top and has a perforated dropout door at the bottom. In the heating operation, the furnace body containing scrap is placed upon a hollow base connected to a flue, and then the burner and combustion-chamber unit is lowered on top of the furnace body. The stream of hot-combustion products flows down through the bed of scrap imparting heat to it, and the cooled gases exhaust through the flue. After the heating operation the furnace body containing hot scrap is transported to the arc furnace for charging. Thus, the furnace body serves as a charging bucket for top-charged arc furnaces, enabling this preheating process to be integrated into existing material-handling patterns in many arc-furnace plants.

Jan 1, 1961

By J. R. Nettle

The development of a process for upgrading offgrade titanium metal by electrorefining in molten salt led to an investigation of the electrotransfer characteristics of selected metals when alloyed with the titanium to be refined. Previous tests on seven binary titanium alloys showed that the degree of transfer of the alloying constituent depends on the constituent and on the operating procedurese.5 This report describes tests on electrorefining ternary mixtures of titanium with selected metallic elements. Ten alloys were prepared from high purity titanium and 2-1/2 percent of each of the metal pairs selected from the same elements used in the binary study; manganese, vanadium, chromium, zirconium, tin, molybdenum, aluminum. Operating variables were similar to those investigated in the binary alloy study that gave minimum alloy metal transfer. The data presented indicate the transfer characteristics of the various metals and combinations tested relative to each other.

Jan 1, 1962

By Robert A. Cummings

A rock mass classification system has been developed for recommending drift support requirements in block caving mines. This development follows a two-year program incorporating field observations of support practice and performance in rocks of different classes, at several U. S. block caving mines. Popular rock mass classification systems presently in use for tunneling were applied at the various field sites; and were evaluated for conformance with caving mine support requirements and for general utility to caving mine operations. The developed system (MBR System) accepts readily-obtainable engineering and geologic data to yield a rational estimate of support requirements. The background and development of the MBR system is described in this report (Volume I). The use of the system is given in the Manual, a separate volume (Volume II).

Jan 1, 1984

By Louis Schaffer

This report characterizes several coal Dine mobile equipment operator populations with respect to age, mine experience, machine operator experience, and training. The information is used to demonstrate a method of normalizing the injury data collected by the Mining Enforcement and Safety Administration-Health and Safety Analysis Center.

Jan 1, 1977

By A. A. Berk

Other Federal agencies have been coming to the Bureau of Mines for help with the purchase and utilization of fuel, largely coal, almost since the day the Bureau was created in 1910. The requests covered a wide range of fuel-economy problems and included boiler-water treatment after it became apparent that water-formed deposits on heating surfaces acted as insulators, decreasing heat transfer and impairing fuel efficiency. Dr. Ralph E. Hall, a Bureau of Mines physical chemist determined the reactions that cause adhering scale to form in boilers (7)2 and went on to introduce scientific principles into water treatment for scale prevention (8). Widespread publicity of these achievements increased the requests for help from Federal steam-generating plants. Since no other Federal agency (even those which were more directly concerned with testing water) wanted to provide boiler-feedwater service, the Bureau decided to continue to give requested help to Federal agencies, Later, the Congress endorsed such agency cooperation as an economy measure,

Jan 1, 1963

By Ross W. Smith

Microflotation and surface chemical studies were conducted on a chromite from the Stillwater Complex in Montana and on some of the minerals usually found to be associated with such chromites. Considering the chromite it was found that aging the ground mineral in air or heating it markedly affected its flotation behavior. Much of the observed effects could be attributed to oxidation reactions involving surface chromium and iron species. Strongly acid pretreating the mineral appeared to reverse such effects. Thus, it can be concluded that the manner in which the mineral (or the ore) is pretreated is of utmost importance in its flotation. Work carried out on associated gangue minerals determined how they are likely to behave in a flotation environment and how certain foreign ions derived from a chromite ore itself can affect their surface characteristics and, thus, presumably also their behavior in a flotation circuit.

Jan 1, 1981