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By Michael S. Wieland

Toxic fume concentrations from industrial mining explosives depend somewhat upon the type of rock (or other strata) confinement. Though traditional detonation theory disregards this influence, the work principal from thermodynamics reveals it, when the violent interactions that transpire within the rock blast are taken into proper account. Resolution of the work principle technique requires total thermodynamic equilibrium under constraint, so the nonequilibrium dynamics is rendered in that way, using an old trick from theoretical mechanics that revises the representation of forces. The rock pressure reduces to a four-component sum: the rock compressive strength and natural atmospheric pressure, as reckoned quasi-statically, and the gravitational influence and reversed inertial resistance, as reckoned dynamically. Tabulated specie concentrations and graphical trends reveal the dependency upon rock pressure, rock temperature and the fuel-oil percentage in ammonium nitrate mixtures (ANFO), used to illustrate the model. Rigid-wall test chambers have notable ullage (residual space), where rapid expansion influences the reaction quenching, yielding a fume spectrum unlike that for rock confinement; reported rock tests are therefore used for comparisons. For the thermodynamic regime where quenching occurs, seven concentrations are resolved, including carbon monoxide (CO) and total nitrogen oxides (NOX). Their trends yield inferences regarding the way unwanted charge desensitization from transitory hole-to-hole wave impact in conjunction with reduced rock pressure can yield nasty toxic fumes, the dark rusty cloud phenomenon!

Jan 1, 2005

By Pharis E. Williams

The ability of voids, microballoons, and even solids to sensitize explosives has been known and used for many years. This phenomenon has generally been studied and reported under the terminology of "hot spots" because of the increase in local pressure and temperature when a shock wave encounters such sensitizers. A method for treating this phenomenon in detonation theory or in a detonation model has been studied for almost the same length of time. Perhaps because of the complexity and non-linearity of the void, or microballoon collapse, several of these studies have used the expediency of including additional terms in the burn rate law to account for the influence of hot spots. The detonation model proposed here considers the sensitization due to discontinuities in the shock impedance to be a mechanical phenomenon to be accounted for in the mechanical equations governing the detonation and not in the burn rate law. While this is not a new contention, the method for handling this non-linear phenomenon within the proposed model is new. The model also includes a method which accounts for the manufacturing variables of emulsion matrix cell size, microballoon size and type, as well as energetic additives.

Jan 1, 1992

By Joshua Hoffman, Catherine Johnson, Braden Lusk

Blasting conducted in surface coal mining operations in the Appalachian region consumes a significant amount of blasting agents. Emission of oxides of nitrogen (NOx) from these operations potentially represents an environmental challenge. This paper presents work conducted to quantify NOx output from the detonation of blasting agents common to surface blasting operations in surface coal mines. Annual ANFO and emulsion consumption data was collected from an operational surface coal mine located in West Virginia. It is known that many factors contribute to the types of gaseous byproducts released from the detonation of explosives. These factors include but are not limited to: fuel to oxygenator ratio, degree of confinement, and contamination. While, past research has been conducted to study the relationships these factors play on the release of NOx, these findings do not agree with one another. The annual explosive consumption values from the West Virginian mine were applied to NOx emission conversion factors in published literature. This lead to a range of NOx emissions from 95 to 914 tons in a year. Given the wide range of NOx production the utility of this information is suspect. The EPA recognizes a standard factor of 17 lbs (NOx)/ton (ANFO) however this factor is based on chemical composition and does not address contamination, confinement, or AN to FO ratio. This factor when applied to the West Virginia Mine's explosive consumption produced a value of 215 tons of NOx. There is a lack of information on NOx emission from emulsion type explosives. The work presented in this paper can be used by blasting professionals to quantify NOx emissions and guide future work for producing better predictor factors.

Jan 1, 2014

By Brent Blanchard

The use of explosives to safely fell structures can be traced back over 300 years. Since then, dozens of chemists, inventors, blasters and demolition experts worldwide have played prominent roles in the evolution of what has become the modern-day explosive demolition industry. In America, one of the earliest applications of explosive demolition occurred in response to the great fires of San Francisco, where homes and businesses were blasted with gunpowder in a desperate attempt to create firewalls. Later in the 19th century, inventions such as nitroglycerine, dynamite and blasting caps made structural blasting a safe, efficient alternative to conventional demolition methods. The 20th century brought the first experiments in shaped charge technology, and this, combined with developments in portable seismology and non-electric delay systems, allowed an ever-expanding variety of structures to be explosively felled by demolition experts throughout the country. The 1950s and .60s brought a new wave of commercial structural-blasting entrepreneurs (several of whom are still active today), and their efforts towards improving adjacent-structure protection and public relations beget the felling of large commercial buildings in dense urban environments. By the late 1980s, publicity-driven motives were gaining greater influence in the decision to .implode. various structures, and the transformation of blasting operations into promotional spectator events played a role in several injuries and fatalities. Since that time, however, a renewed sense of responsibility practiced by most blasting firms and project officials has resulted in the safe, successful completion of hundreds of recent endeavors. In sum, what appears today as an efficient, economical - and visually spectacular - way to demolish structures has its roots in developments of the past several centuries

Jan 1, 2002

By D T. Froedge

A new system for acquiring blast vibration data and a method for presenting that data in such a way that there can be an extraordinarily enhanced insight into the understanding of vibrations produced by blasting is described in this paper.

Jan 1, 1989

By J S. Kuszmaul

The economic development of modified in situ oil shale retorting will benefit from the ability to design a blasting scheme that creates a rubble bed of uniform permeability. Preparing such a design depends upon successfully predicting how a given explosive will break rock. Numerical models are used to make predictions of the extent of damage caused by an explosion.

Jan 1, 1985

By M Oldenburg, P J. Digby, L Nilsson

A constitutive model for the simulation of fracture and fragmentation processes in rapidly loaded rocks is studied. The model was included in a wave propagation finite element code. The results obtained from two different configurations of explosive charge and reflecting surfaces in a plane strain problem were studied. The evolution of the time-dependent fracture pattern is presented.

Jan 1, 1985

By R C. Berglund

Since the Republic Mine began production in the mid 1950's, drilling and blasting practices have continually changed. In recent years, progress has been achieved through the development of more precise blast engineering methods, in greatly increasing the use of non-water resistant ammonium nitrate explosives, and in changing to a non-electric in-hole delay initiation system. Also, recent experience indicates that ammonium nitrate fueled with nitropropane and methanol is a viable substitute for aluminized AN-FO.

Jan 1, 1980

By LaRay Collyer

San Juan Mine began pre-splitting the highwall prior to cast blasting in August 1986. The first pre-split shot used six inch PVC (polyvinylcloride) pipe inside a 10 5/8 inch hole, drilled at a 74 degree angle. The powder factor was about .90 pounds per cubic yard.

Jan 1, 1990

By Thomas C. Rube, T S. Bajpayee

The Bureau of Mines conducted research to determine the safe operating conditions for using recycled (used) lubricating oil from mining equipment as a partial replacement for diesel fuel to make ANFO-type blasting agents. The use of recycled oil (RO) saves energy, reduces oil imports, and reduces mining costs.

Jan 1, 1996

By B Mohanty

The current basis for rating of commercial explosives is examined, with particular emphasis on calculated bulk and weight strengths, detonation velocity and underwater energy measurement. The calculated strengths still form the basis for selecting explosives for most blasting applications, with the measured detonation parameters serving only as a measure of the quality of the explosive. The major drawbacks with this approach are discussed, in view of the non-ideal nature of commercial explosives and the field conditions prevalent during the blasting operation. A unified approach to rating explosives on the basis of blasting performance rather than calculated energy alone is presented for various types of explosives. This incorporates the relevant field parameters as well as the effect of non-ideal reactions, both of which affect explosive energy release and its transfer to target rock.

Jan 1, 1988

By John L. Floyd

One of the key factors that controls the overall profitability of surface operations is the required volume of excavated material. If the overall angle of final walls can be maximized the amount of material excavated will be reduced. However, as the slope angle becomes steeper the wall's factor of safety decreases. As a result, the development and implementation of efficient wall control blast designs becomes critical to achieving stable walls. Many site specific conditions should be taken into account when defining the methods that will be used to lessen blast induced wall damage. This paper will discuss the steps needed to properly evaluate the site and develop efficient designs. Four variations of wall control blast designs will be evaluated in terms of cost and performance. In addition, the paper will include the quality controls needed to successfully implement and refine the blast design.

Jan 1, 1998

By Stephen A. Rholl

Computer software has been developed which uses fast Fourier Transform (FFT) techniques to analyze the frequency spectrum associated with peaks in ground vibration time histories. The procedure consists of filtering the FFT of a time history into individual frequency components.

Jan 1, 1996

By N H. Maerz

The digital image analysis program WipFrag has been developed under contract to INCO for use in quality control of underground blasting operations. This paper outlines the relevance of fragmentation to underground mining, the hardware and photography requirements, and key features and operating principles of the software.

Jan 1, 1995

By Les W. Armstrong, Stephen B. Richardson, Neville T. Moxon

A study was carried out to determine how different degrees of stemming confinement, that is the retention of the explosives gases, effects fragmentation and movement during blasting.

Jan 1, 1993

By Roger L. Keller

This paper examines the aspects of differing types of blasting cuts in underground headings with consideration to the reduction of number of holes and costs. At least one comparison study is related where costs per advance meter were significantly improved. The technical aspect of the paper covers a study of the effects of various blasthole delay intervals on resulting crater volume, ground vibration, and fragmentation for six hole V-cuts.

Jan 1, 1989

By R Keller, R Law

In the rush to beat the clock before the handover of Hong Kong back to China in June of 1997, an unprecedented amount of infrastructure work is being undertaken at a breakneck pace. In the middle of this construction explosion, on this island of barren granite , stands some of the most concerning and restrictive slope stability measures. So conservative, these measures impact blasting and vibration control to an extent unmatched anywhere in the world.

Jan 1, 1996

By Calvin J. Konya

The Woodville Lime and Chemical Company Limestone Quarry is located in Sandusky County, Ohio. Fifty years ago, when quarrying began, it was situated approximately two miles from the town of Woodville. Today new houses border the quarry property within 1,500 feet of one of the working faces. During the past two years, the operation has systematically changed the blasting program to achieve better fragmentation, lower costs, and to maintain good relations with the local property owners. This paper will discuss systematic changes made in the blasting program to increase productivity and reduce costs.

Jan 1, 1977

The most common method for identifying the potential for blast damage is the peak particle velocity. But this can depend on many factors such as the type of blast, explosive, confinement, timing and the rock mass. The value must then be used to estimate damage. But the amount of damage will depend on the rock mass quality and the excavation size and shape. The amount of damage that can be accepted will depend on the purpose of the excavation. This paper presents a logical, but very approximate, procedure that the mining engineer can follow in order to assess the potential for damage in the control of that blasting.

Jan 1, 1987

By Yang Ruilin

Bulk gassing technology is a growing trend in the commercial explosive industry. The gassed bulk products produced differ from microballooned bulk products or cartridged products. It is easy to know the loaded or in-hole density for microballooned bulk products or cartridged products, whereas it is not as straight forward to know the m-hole density for gassed bulk emulsions. The loaded density is one of the key parameters affecting explosive performance and therefore it is important to have a field technique to monitor the in-hole properties of gassed bulk products in order to accurately predict the blast performance and to ensure efficient use of the products.

Jan 1, 1999