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By João Queiroz, Cristian Marquez-Sarmiento, Luiz Teixeira

The removal of various metals from process waters and effluents is usually done by precipitation of the corresponding hydroxide. Manganese however is one metal that does not respond efficiently to that approach. It may be seen in its eH X pH diagram that the way of oxidation to Mn IV rather than hydrolytic precipitation of the Mn II ion as its hydroxide, is the way to efficient precipitation of Mn in the pH range 6 to 10. We studied the use of oxidants O2; NaClO; H2O2; Caro´s Acid (H2SO5) and the combinations of O2 or H2O2 with Na2S2O5, and H2O2 with NaClO, for the oxidative precipitation of Mn from synthetic solutions starting with 10 mg/L Mn, at 25 oC. In adequate conditions, which include pH > 8, it is possible to reach final [Mn] less than 0.1 mg/L in 60 minutes of reaction time.

Jan 1, 2014

By Tohru Kamo, Shigeyuki Katano, Hideki Nakagome, Maiko Adachi, Shingo Nakamura, Kaneshi Taniguchi, Zar Zar Hlaing, Takaaki Wajima

Tantalum capacitor is a small-sized and has large capacity, and is indispensable for electric equipment. The demand increases year by year, and a quite large number of used tantalum capacitors is generated. Recovery of tantalum from tantalum condenser is recently important since production of tantalum have not been stable for the price and the quality. However, recovery of tantalum from tantalum-condenser is difficult since tantalum parts strongly cover with the flame retardant resin made of halogenated compound (mold resin). This research investigated recovery of tantalum parts from tantalum condenser using steam gasification with mixed molten carbonate. Mixed molten carbonate (Na2CO3:K2CO3:Li2CO3 = 1:1:1) (3 g) put into the reactor, and heated with electric furnace while flowing nitrogen (160 mL/min) and steam (1 mL/min) warmed by heater. After heating to setting temperature (450 - 650 oC), tantalum condenser (3 g) was put into the reactor, heated for 5-10 min, and then cooled to room temperature to recover the reacted capacitor by filtration after treating with distilled water. At relatively low temperature (550 oC) heating for 10 min, mold resin can be decomposed by using steam gasification with mixed molten carbonate, in comparison with using pyrolysis and steam gasification without carbonate, and decomposition reaction occurred over 500 oC by using steam gasification with mixed carbonate. Recovery of tantalum parts from capacitor is successful using steam gasification with mixed molten carbonate at 530 oC for 5 min, due to the effective decomposition and removal of mold resin from capacitor. Furthermore, most halogen gas generated from decomposition of mold resin can be trapped in molten carbonate not to exhaust halogen gas. These results suggested that recovery process of tantalum parts from used condenser using steam gasification with mixed molten carbonate is expected as a feasible way to recycle the rare metal in electric equipment.

Jan 1, 2014

By Erico Tabosa, Meng. Jun, Kym Runge, Matthew Brennan, Weiguo Xie, Dee Bradshaw

Turbulence and its distribution are of great importance in flotation cell design as they affect suspension of particles, air dispersion and particle-bubble collision rates, which in turn determine flotation performance. However, there is no mature technique to measure turbulence in three phase (liquid-solid-gas) systems such as in flotation cells. In this article, the authors present two new approaches that are suitable for measuring turbulence distribution in three phase systems and validate their applicability. The first technique uses a piezoelectric vibration sensor (PVS) to measure fluid kinetic energy standard deviation and the second technique applies electrical resistance tomography (ERT) to measure conductivity variation at a measurement position in a flotation cell. For the PVS technique, calibration of the sensor was performed to determine the values of parameters that were needed to calculate the force applied to the sensor. Then measurement was conducted in a 60L batch flotation cell and the results were compared with LDA measurement. This demonstrated that the piezoelectric sensor signal provides a good representation of fluid kinetic energy standard deviation at the position of measurement. For the ERT technique, conductivity distribution data was processed to give conductivity variations, which were then used to calculate fluid kinetic energy standard deviation at the measurement position. The spatial distribution of turbulence obtained by performing multiple measurements at different positions in the 60 litre batch flotation cell was found to agree with the PVS measurement results. These two techniques are potentially powerful tools for turbulence measurement in flotation environments, enabling a clearer understanding of turbulence’s influence on flotation performance to be determined.

Jan 1, 2014

By Áureo Del Vecchio, Lídia Dely Alves de Sousa, José Pereira

The potassium demand for agriculture purposes has increased in Brazil, which has great deficit of internal demands. Potassium-rich rocks have been used as fertilizers as technological alternatives for agriculture aimed to reduce the amount of chemicals and the sector dependence for such products. Vermiculite tailings from União Brasileira de Mineração - UBM, at Santa Luzia - PB, was studied aiming their application in agriculture by potassium release. The sample was analyzed by XRF and XRD; studies on release kinetic with particles smaller than 2 mm added of organic acids (citric and oxalic) at 10-2 mol/L concentration; samples were analyzed by XRD after kinetic assays. The work was conducted using a shaker incubator at 300-rpm agitation and time variation to better understand the potassium availability in the ground. Results show the presence of K2O at 3.46% concentration. Citric and oxalic acids increased the release speed to almost the same level with speed coefficients (k) of 2.61x10-2 h-1/2 and 2.55x10-2 h-1/2 respectively. In statistical terms for both acids, the linear equation represents more than 99.0% of the experimental assays. Stonemeal was applied to banana seedlings in experiment conducted in a greenhouse. The use of vermiculite tailings in banana seedlings promoted potassium absorption, which influenced its growth. The amount of potassium liberated from vermiculite tailings could be used as a long-term alternative to fertilizers in agriculture cultures.

Jan 1, 2014

By R. Bugueño, W. Calderón, G. Montes-Atenas

From the point of view of industrial performance of metal extraction, the efficiency of a column leaching operation depends strongly on the leaching agent and the ore properties such as mineral composition, mineral liberation and particle size distribution. One aspect that has become particularly important is how the leaching solution flows through the porous structure which contains the valuable minerals. It is known that the output flow rate of leaching solution depends mainly on factors of the input flow, environmental condition and porous bed properties. The latter factor is often evaluated and reported under saturated conditions but in practical leaching systems unsaturated conditions are dominant. This investigation has the purpose of determining the residence time of the leaching solution in columns with different diameters under unsaturated conditions by using experimental data and numerical simulations. Laboratory leach test were performed using isothermal jacketed columns with top cap to reduce the evaporation. The simulations were performed using the software SVFlux® which incorporates material properties such as Soil Water Characteristic Curve (SWCC) and Unsaturated Hydraulic Conductivity. Preliminary results indicate a non-linear asymptotic behavior of the saturation rate with respect to the operation time. Results from numerical simulations show the same non-linear behavior and a considerable delay between input and output flows. Further analysis concerning with the effect of transpiration and evaporation mechanisms is discussed.

Jan 1, 2014

By Marlize Barkhuizen, Chris Aldrich

"Owing to environmental constraints, safety considerations and competitive pressures, the development of model-based process control and other automated systems have experienced considerable growth in the last few decades. Reliable process models are usually critical to the successful implementation of these systems. In complex processes, these models are often constructed from process data, as modelling from first principles may not be feasible or cost-effective.Even so, modelling or identification of nonlinear systems from historic plant data can be a daunting task and in the process industries the problem is complicated by the presence of noise from various sources, nonstationarity of the data, intermittence, such as observed in particulate flows, etc. Traditional methods, such as frequency analysis and linear modelling do not handle these systems well. Similar problems arise with the application of nonlinear theory developed over the last few decades, where much of the analysis depends on embedding of the data in a phase or pseudophase space, since these methods were not originally designed to deal with noisy systems.With singular spectrum analysis, the data are embedded in a high-dimensional reconstruction, followed by the introduction of a new coordinate system, where the origin is moved to the centroid of the reconstructed system states and the axes are represented by the dominant principal components of the states (points)."

Jan 1, 2003

By Heribert F. Broicher, Arne Volland

The application of remote sensing techniques combined with fluorescence spectroscopy is realised in analytical devices called LIF Analysers. The analysis of laser-induced fluorescence facilitates non-destructive, non-contact, on-line and real-time rock identification and quality control of bulk solids in transport. LKAB of Sweden was the first company to test LIF Analysers in the Kiruna Mine for bulk sorting of run-of-mine ores depending on the phosphorus content. Other applications tested in Germany so far are quality control of limestone (iron and/or dolomite content) and rock identification in lignite mining. Of special interest also is rock identification in diamond mines for dilution control. The paper summarises the present state of the application of LIF Analysers.

Jan 1, 2003

By Carlos Pereira, Fábio de São José, Francielle Nogueira

Votorantim Metals Corporation is one of the leader companies in the extraction of zinc in Brazil. One of its mines, located in the city of Vazante - MG, was composed by zinc silicate ores, but recent studies have indicated a change in mineralization type with arise of zinc sulphide’s ore bodies with disseminations of galena (PbS) and silver. The liberation size between sphalerite and galena in this ore occurs in very fine granulometry (approximately 18µm), fact that has negatively influenced into the flotation process. Aiming to reduce this problem, studies about the use of dispersing in the flotation process have started. Thus, this study investigated the action of different reagents dispersing on the stability of the suspensions. The tests were carried out with samples of mineral galena and sphalerite using four types of dispersing within two different dosages and two pH. The reagents tested were sodium hexametaphosphate, sodium silicate, carboxymethiylcellulose, and sodium polyacrylate. The results of the dispersion tests were analysed in relation to dispersion index. The tests with hexametaphosphate showed high dispersion for both galena and sphalerite. The sodium polyacrylate and arboxymethiylcellulose showed a high dispersion index for galena and a low index for sphalerite implying that reagent can be used in the concentration process of galena.

Jan 1, 2014

By F. Xie

Low gold and silver leaching kinetics has been commonly observed in traditional gold-silver cyanidation process, especially in those heap-leaching operations. The reactivity and availability of oxidant was believed to be the critical limitation for gold and silver dissolution. The occurrence of silver sulfide such as acanthite (Ag2S) in the ore may also result in low overall silver extraction. Leaching of gold and silver sulfide in the ferricyanide-cyanide solution has been investigated through rotating disc tests and the assistant effect of ferricyanide on increasing the dissolution rate of gold and silver was noticed. The potential use of ferricyanide as an auxiliary oxidant in gold/silver cyanidation process was proposed based on the results of leaching of gold-silver ores.

Jan 1, 2014

By Gregory Harbort, Sarah K. DeBono, Alan J. Monaghan, Emmanual V. Manlapig

"The Jameson Cell is a type of flotation machine in which air and pulp are brought together in a vertical tube called a downcomer. Within the downcomer the air and pulp are dispersed into a dense foam of fine bubbles, which creates a favourable environment for bubble-particle collision and subsequent collection of hydrophobic particles. The intense collection zone within the downcomer can be considered similar to the zone between the rotor and stator in mechanical flotation cells.Research into the bubble-particle collision and fluid dynamics of mechanical cells rotor-stator zone has been limited by the difficulty of achieving accurate measurements in production sized machines. With the Jameson Cell the downcomer is largely external and separated from the flotation tank, allowing ready access to the primary contacting zone for measurement and analysis.An investigation has been undertaken into the operating characteristics of the downcomer relating to bubble-particle collision. An effective mapping of the downcomer has been made through measurements of void fraction and bubble size taken across cross sections of the downcomer. Analysis of these measurements has provided an interpretation of the variations in the air and fluid dynamics, bubble size and distribution throughout the downcomer chamber.Existing models of bubble-particle collision efficiency are reviewed in respect to the collected information and refinements conducted. The area of maximum bubble-particle collision efficiency is defined. Findings are related to operation within the rotor-stator zone of mechanical flotation cells."

Jan 1, 2003

By L. X. Zhang

It is very important to improve the A/S of the bauxite to keep sustaining development of Chinese alumina industry. This article summarized the issues of several desilication technologies, which are named as normal flotation, reverse flotation and bi-flotation. Normal flotation has been got industrialization because of technologic advantages. The campaign experiment of reverse flotation which has principle advantage was carried out in 2004, and bi-flotation which is combined the advantages of both the normal flotation & reverse flotation has the most attractive future. The development of bauxite flotation will be focused on multi-utilization of bauxite by mineral process technology and corresponding equipment which satisfied with the flotation technology and reagent.

Jan 1, 2014

By M. Ranjbar, M. Khosravi Rad, A. Tohry

"The filling degree is defined as the volume ratio of the load inside the mill, which determines the power drawn from the motor, as long as the filling degree is not more than the optimum level. As the filling degree increases beyond the optimum level, the impact energy inside the mill will decrease and as a consequent, the mill power output will also decrease. Therefore, the mill filling degree is a key parameter in evaluating the grinding circuit performance, as it determines the mill reaction to the input feed. Since this parameter has an impact on the mill capacity, measuring the mill load is vital for control and optimization of grinding process. As in Choghart Processing Plant no instrument is available to measure the AG mill filling degree, an empirical model based on the bearing-oil pressure is proposed. The AG mill filling degree was related to the differences between the average pressure of input and output bearings, the circulating load and power drawn. It was shown that a quadratic model could relate the mill filling to the above mentioned measurements. This model showed that when the power drawn and circulating load decreases the bearing-oil pressure needs to be checked. If the bearing-oil pressure increases the feed rate needs to be decreased and steel ball be charged to the mill to increase the grinding and prevent mill overloading. INTRODUCTION The feed quality (size and hardness) affects the grinding process in AG mills. Reducing the top feed size and increasing the ore hardness reduce the mill efficiency and increase the particles with critical dimensions inside the mill. These will result in increasing the mill filling degree and reducing the mill throughput and efficiency (Wills and Finch, 2015). The volume ratio of the load inside the mill is called filling degree, which determines the mill power drawn. It is believed that if more energy is mainly spent on grinding (Wills and Finch, 2015). Therefore the mill power draw is used as a mean to control the mill efficiency."

Jan 1, 2018

By Bern Klein, Givemore Sakuhuni, Libin Tong

The use of continuous discharge centrifugal concentrators introduced in the early 1990’s for recovery of gold associated with sulphides has introduced a novel application niche for gravity concentration which could not be realized with the low mass yield batch and semi-continuous concentrators. A typical application is scavenging gold associated with sulphides from flotation tails which has potential to increase productivity by reducing gold loss to tailings and lower grinding cost by using a coarser grind. However, the full potential of this technology has not been fully exploited partly due to the lack of reliable small sample procedures to demonstrate applicability. This paper introduces a bench-scale procedure developed to characterize the Knelson Continuous Variable Discharge concentrator (CVD) for scavenging gold from flotation tails. The procedure code named gravity release analysis was derived from standard flotation release analysis. It is a modification of the gravity recoverable gold and gravity amenability test in order to best simulate continuous centrifugal concentration. Based on this iterative procedure, a gravity release index similar to the flotation rate constant, for measuring individual mineral gravity susceptibility for an ore is introduced which can be a useful quantitative measure to both predict application of centrifugal concentration and for plant design. The gravity release analysis procedure was tested on a polymetallic flotation plant tailing at Myra Falls, BC, Canada and results show that it can predict CVD performance. The gravity release index for gold was observed to decrease with each successive cleaner stage showing that the initial stages recover liberated gold whilst successive runs recover gold associated with sulphides and or gangue. The difference in magnitude of the gravity release index for different mineral species shows the species separable by centrifugal concentration.

Jan 1, 2014

By Pawel Strzalkowski, Marta Baszczynska, Urszula Kazmierczak

The paper presents issues related to interference of mining activities with the environment. Exploitation of mineral resources causes primarily a modification of the landscape. All of the negative impacts on environment are short-lived and last as much as it takes to exploit the raw material. After the mine closure reclamation is necessary during which all aspects that reduce harmful effects of the mining activities on the environment must be taken into account. Current ways of reclamation allow recreating natural environment, which is different from the original and enriched in diverse new values. This requires propositions of new forms of converted land development through a detailed analysis of technical, natural, planning, economic and social sphere requirements. Before making final decisions regarding selection of direction of reclamation, a thorough analysis of the key factors has to be carried out. All steps related to the implementation of the reclamation project are shown in the paper using Limestone Mine "Górazdze" located in the south-western part of Poland as an example. This paper also presents an analysis of current ways of post-mining reclamation towards agricultural and forestry landscape, along with our own suggestion for their extension in order to preserve biodiversity. For choosing optimal solutions the most relevant criteria were considered: existing natural values and possibility of their protection. Taking into account the economic and social aspects, supported by natural potentials, implementation of tourism and recreation in this area were proposed. It was shown that this proposition would not interfere with the current trends of the natural landscaping. Finally, after completion of reclamation and land development in the considered mine area, creation of a geo-park was proposed along with appearance of geotourism in the area. To illustrate the proposed forms of post-mining land development in the form of maps, an ArcGIS(ESRI) software was used.

Jan 1, 2014

In this study, the effect of different regrinding conditions on the depression of fine pyrite at the cleaner stage was investigated. The regrinding condition was manipulated by different grinding media (stainless steel and mild steel). It was found that, after regrinding with mild steel grinding media, the flotation recovery of pyrite is much lower than with stainless steel grinding media, and it is more difficult to restore by adding more collector. This means, regrinding with mild steel grinding media may depress the pyrite flotation more strongly. The copper activation of pyrite during regrinding was also studied. It was found, that the mild steel grinding media is more beneficial to copper activation than stainless steel media. Additionally, the analysis of pyrite recovery based on the particle size indicated, that the fine particles are more susceptible to different grinding environments than intermediate and coarse particles and therefore are more easily depressed with a much lower flotation recovery.

Sep 1, 2012

By A. Collings, A. Farmer

Power ultrasound may be used in the processing of mineral suspensions to clean the particle surfaces of oxidation products and fine coatings, mainly through the large, but very localised forces, produced by cavitation. This effect may be utilised in lowering the level of iron contamination in silica sand used for glass making, in improving the sharpness of electrostatic separation of heavy mineral concentrates, in shortening the time of leaching of minerals and in improving the selectivity and recovery of flotation processes. Parameters affecting the efficiency of these processes, such as input power and levels of reagent addition, are discussed. In particular, we present data showing the relationship between power input and the particle size of surface coatings removed, which can be explained by the Derjaguin approximation for the energy of interaction between a sphere and a flat surface. Pilot scale studies, using commercially available components, are currently being used to assess process viability and will be compared with laboratory scale results.

Jan 1, 2003

By T. N. Aleksandrova, A. V. Afanasova

"The research is aimed at solving the problem of enrichment of sulphide ores, counting for more than 40% of the reserves in Russia. The aim of the research is to develop and scientifically substantiate the scheme for processing this type of ores in order to extract fine-dispersed noble metal particles (FNMP). In this work samples of sulfide carbonaceous ore and flotation concentrates were analyzed using complex precision methods of analysis: electron microscopy, spectral analysis with induction plasma, complex thermogravimetric analyzes, etc. Data on the composition of the organic constituent of the samples were obtained with the usage of complex thermogravimetric analysis. The presence of various types of kerogen and bitumen has been established. Experimental studies on the coarsening of FNMP from the initial ore and flotation concentrates using electromagnetic radiation have shown the effectiveness of this coalescence method. The data on the elemental composition of the samples and the amount of FNMP were obtained. Thus, studies on the extraction of FNMP from carbon sulphide ore have shown the possibility of effective usage of combination of electromagnetic action and classical enrichment methods to extract fine particles of noble metals. INTRODUCTION Due to the depletion of free-milling raw materials the involvement of new types of deposits is the strategy of developing mining industry of Russia. The black shale raw materials show interest as a non-traditional source of precious metals since its genetic and positional gold-carbon connection. Muruntau, Sukhoi Log, Bakyrchik, Natalkinsky, Nezhdaninskoye, Olimpiadinsky, Homsen and others are the examples of well-known deposits of the black shale formation [1]. In fact the main gold-dispersed regions of Russia are composed of black-shale strata. Review of literature [2-5] shows that in recent years in almost all deposits of the black shale formation metals of the platinum group (PGM) were detected that significantly increases their practical importance."

Jan 1, 2018

By J. Vilcáez

The copper extraction yield from thermophilic bioleaching of chalcopyrite depends on temperature, pH, and the oxidation-reduction potential (ORP), as well as the activity of the microbe used. We studied copper extraction yields obtained from chalcopyrite with three thermophiles, Acidianus brierleyi, Sulfolobus metallicus, and Metallosphaera sedula, under various pH and temperature conditions and with different initial amounts of ferric iron. The results indicated that the capacity of each thermophile strain to leach iron as Fe3+ differed, which affected the influence of pH, temperature, ORP, and microbial activity level on the yield of copper. Microbial activity can cause ORP to be close to the critical value (450 mV) at which copper extraction at 65 °C can be higher than that at 80°C. An initial pH of 1.5 retards the precipitation of jarosite, allowing temperatures as high as 80°C to result in copper extraction yields close to 100%. However, if a thermophile with a poor capacity to form Fe3+ is employed, 100% copper extractions can also be obtained at pH 2.5, because ORP is low as result of low amounts of Fe3+ in solution. Optimum temperatures for the growth of thermophiles did not always mean high copper extraction yields. Conversely, high biomass concentrations depending on the capacity of the thermophile strain to leach iron as Fe3+, can result in excess Fe3+ in solution, leading to the precipitation of large amounts of Fe3+ as jarosite. The bioleaching capacity of A. brierleyi was reduced or suppressed when insufficient initial Fe3+ was pro-vided to trigger the leaching reaction, whereas S. metallicus and M. sedula were less sensitive to the initial availability of Fe3+. This result confirmed that a direct enzymatic attack on the mineral surface could initiate the leaching reaction, but later ORP governed the leaching rate of chalcopyrite.

Jan 1, 2014

By Reza M. Rahman, Seher Ata, Graeme J. Jameson

"This paper presents the results of a through investigation into the froth recovery measurements in a controlled plant environment using a device that allows direct collection of dropback particles from the froth phase. Test work was performed at the Northparkes concentrator (NSW, Australia), using a feed taken from the head of the cleaner scavenger bank. The feed slurry had a relatively higher copper grade varying from 5.2% to 6.8%. Experiments were performed to investigate the effect of important flotation parameters such as air flowrate on the froth recovery. The size of the particles in the relevant streams was also analysed to acquire in-depth knowledge about the froth dropback mechanism. The results suggested that the froth recovery could be as low as 70%, although it was relatively easy to achieve the values in the range 75% to 85% by the correct choice of operating variables. It was found that the air flowrate has a positive impact on both collection (pulp) and froth zone recoveries. However, the effect was more prominent in the froth zone. It appeared that the froth recovery is a strong function of particle size."

Jan 1, 2014

Gold thiosulfate complex is difference with gold cyanide complex, which is easily adsorbed on activated carbon while gold thiosulfate complex cannot be satisfactorily recovered by activated car-bon. However, Gold thiosulfate could be recovered by activated carbon if cyanide is added into the thiosulfate solution. To avoid the cyanide solution, this paper will review several possible processes to recover the gold from thiosuldate solution: such as the cementation with metals, ion exchange resin and solvent extraction. The gold cementation with the powders of zinc, copper, iron and aluminium will be discussed. The advantage and disadvantage of each are compared. The consumption of thiosulfate and copper and feasibility of solution recycling will be discussed. The gold recovery by some ion exchange resins will be suggested. The processing conditions, its applications and the resin elution methods will be presented. The gold recovery by using solvent ex-traction will be reviewed. The processing conditions of solvent extraction process are discussed and compared.

Jan 1, 2014