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By Yasuo Kudo, Wu, Hayato Sato, Hiroshi Nakazawa, Shouming

"In order to recover copper from a waste nickel condenser powder, bioleaching experiments were carried out using Thiobacillus ferrooxidans in a shaking flask. The content of nickel and copper in the waste nickel condenser powder in this study were 8.0% and 3.5%. X ray analysis showed the peak of barium titanate. In the preliminary study using metal nickel and copper powders , the dissolutions of nickel and especially copper were accelerated with the addition of ferric iron in the bioleaching of nickel and copper powders while not in the absence of ferric iron. Ferric iron oxidizes both metals, and Thiobacillusferrooxidans oxidizes ferrous iron resulting from the oxidation of metals, whereby the dissolutions of metals proceeds. The dissolution rates of nickel and copper increased with increase in the concentration of ferric iron in the bioleaching of the waste nickel condenser powder.1. IntroductionNickel condensers rejected from manufacturing plants are crushed and landfilled. Waste nickel condensers contain nickel and copper and could be considered as nickel and copper ores. Since the capacity of landfills is diminishing, it is required to recycle metals of waste nickel condensers in order to reduce the amount of wastes landfilled. Conventionally, metals in the waste were recovered by dry metallurgy after the incineration.Nickel has been refined by solvent extraction - electrowinning method (SX-EW method). Recently the amount of copper refined by SX-EW method has increased (Takahashi, et al. 1994). This method is cleaner and consumes less energy than conventional methods. Nickel dissolved well in acid solutions, but copper is not. If copper is leached efficiently from a waste nickel condenser powder, SX-EW method will be applied to recover copper from them"

Jan 1, 2000

Bioleaching of Weathered Saprolite - Heavy Metal Adaptation Mechanisms of Aspergillus foetidus Nickel laterite ores remain important to the future supply of Ni and Co as they contain the bulk of known nickel and cobalt reserves (80 per cent and 90 - 95 per cent respectively). Current commercial extractions of Ni and Co from nickel laterite ores are energy intensive and operational costs are high. Microbial leaching of oxide ores has the potential to offer a much needed step-change in the technology for processing laterite ores. Biological leaching of low-grade nickel laterite is based on a non-traditional leaching of oxide minerals using heterotrophic micro-organisms. The organisms solubilise metals by excreting organic acids; these acids then form complexes with heavy metals. Optimisation of the process in in-situ application, however, has been hampered by the toxicity of the heavy metals that are being leached by the organisms. Our recent study has shown that organisms are able to develop tolerance towards heavy metals by adaptation. This study examined the extracellular metal detoxification mechanisms of A. foetidus in 0.2 per cent (wt/v) to 0.7 per cent (wt/v) of weathered saprolite ore. To support our analysis, FTIR, CHNS and microscopy were used to confirm the participation of specific functional groups in the extracellular detoxification process.

Sep 13, 2010

By F Battaglia-Brunet, D. H. Morin, Foucher S. ’

In the mineral-processing field, bioleaching of metal sulphide concentrates is currently operated in very large mechanically agitated tanks. Such bioreactors have considerable requirements in terms of power consumption for mixing, aeration and heat transfer. The use of slurry bubble column, where the particles are suspended by gas motion as well as by liquid upward flow, could be an alternative to achieve bioleaching in more economical conditions. In order to compare these two techniques, a unit of stirred reactors in cascade and a bubble column were comparatively operated at laboratory scale in the bioleaching of a pyrite concentrate. For both pieces of equipment, experiments were performed not only in batch mode but also in continuous conditions.

Jan 1, 2003

By Morin D. H., Battaglia-Brunet F., D'Hugues P.

"In the mineral-processing field, bioleaching of metal sulphide concentrates is currently operated in very large mechanically agitated tanks. Such bioreactors have considerable requirements in terms of power consumption for mixing, aeration and heat transfer. The use of slurry bubble column, where the particles are suspended by gas motion as well as by liquid upward flow, could be an alternative to achieve bioleaching in more economical conditions. In order to compare these two techniques, a unit of stirred reactors in cascade and a bubble column were comparatively operated at laboratory scale in the bioleaching of a pyrite concentrate. For both pieces of equipment, experiments were performed not only in batch mode but also in continuous conditions.Bubble column performances were significantly affected by unpredictable technical difficulties met to maintain continuous feeding in the bubble column and by a significant settling of the heavy solid particles. Nonetheless, theoretical kinetic data, extrapolated from results in batch conditions, could be compared to those obtained in continuous tests, in bubble column and in mechanically agitated reactors. These kinetic data were used to evaluate the influence of reactor design and configuration choice on bioleaching performances."

Jan 1, 2003

By Kevork Chouzadjian, Gary Davis, Nicholas Katsikaros, Bruce Kelley, Mellie Mavatoi

A process has been developed to recover gold and copper from two waste materials at the Bougainville Copper Limited mine in Papua New Guinea. It involves the bioleaching, in reactors, of a pyrite concentrate to liberate refractory gold and generate sulphuric acid, ferric sulphate and biomass for bacterial leaching of a chalcopyritic waste rock dump. Gold is to be recovered by cyanide leaching and copper by solvent extraction/electrowinning. The reactor bioleaching was developed in continuously operated reactors of 1 m3 capacity by CRA Advanced Technical Development at Cockle Creek, while the dump leaching was developed in 750 kg columns on site at Bougainville Copper Limited. The process was to be piloted on site.

Jan 1, 1990

By D. Kidd, T. Tucker, L. M. Indergard, S. Davis

"INTRODUCTION The Lisbon Valley Mining Co LLC (LVMC) operates the Lisbon Valley Mine located in SE Utah. The mine includes 3 open pits, 150-acre heap leach pad, and solvent extraction electro winning plant (SX/EW). Approximately 25MM tons of ore has been mined since 2005. The ore is stacked on the leach pad to an average height of 55 feet and occurs as a blend of crushed material (minus 2”) and run-of-mine (minus 24”). The host rocks include Dakota and Burro Canyon Sandstones. Copper occurs finely disseminated in this material at an average grade of 0.46%. Minerology is 63% sulfide, 27% oxide, and 10% insoluble. Total inventory mined through 2016 is approximately 230 MM lbs. METALLURGICAL CONSTRAINTS Copper production is constrained by areas of low permeability ore and geochemical issues, including acid consumption. The intrinsic permeability the ore ranges from 10-2 to 1 Darcy. This permeability does not permit sufficient aeration by natural convection, therefore oxygen transport is largely limited to the mass of oxygen that can remain dissolved in leachates. As a result, greater than 50MM lbs of copper remains in inventory and occurs secondary sulfides, including chalcocite, covellite, and bornite. BIOLEACHING FUNDAMENTALS Due to the higher activation energies of secondary sulfides, notably covellite and bornite, a strong oxidant is needed to remove an electron from the metal-sulfide lattice and release the copper cation into the sulfate solution. This process occurs most efficiently using the strong oxidant ferric iron (Fe3+). Ferrous iron can be oxidized to ferric iron by oxygen via chemical oxidation or biologically; which was measured to occur 500,000 times faster when using microbes versus oxygen.1 The microbes that oxidize ferrous iron (Fe2+) to ferric iron are naturally abundant and will develop biomass when appropriate conditions and nutrients present themselves. Most nutrients are provided by the ore/irrigation (P,N,Mg, Ca & Fe2+) while the others (O2 and CO2) are provided by air. In most cases, oxygen transfer is the rate limiting step during copper sulfide leaching. 1 Lacey & Lawson 1970 FORCED AERATION SYSTEM DESIGN This paper describes LVMC’s efforts to bioleach the remaining inventory by forced aeration. Two basic aeration systems were installed and tested including vertical wells and horizontal piping. Vertical System The vertical system was installed using the mine’s blast hole drilling rig. Wells were constructed using 4” high-density polyethylene (HDPE) connected to 4” polyvinyl chloride (PVC) screens similar to conventional bioventing wells. Ore samples were collected at each well location to characterize the spatial distribution of the remaining inventory along with fines (minus 200 sieve), pH (acid consumption), and iron. A block model of each analyte was developed and mapped in 3D."

Jan 1, 2017

By M. Oliazadeh

The bioleaching of fine low grade copper sulfide ore is described. A sample of ground (> 1 mm) copper ore from Sarcheshmeh, Iran, was subjected to a series of agglomeration procedures and subsequently leached. The best agglomerate was obtained by using lime and sulfuric acid as binders. A column bioleaching test of agglomerated ore was then run for 105 days along with a non-inoculated control column having thymol as bactericide. The results show that about 77.5% of copper was extracted in the bioleaching, whereas the control column achieved only 57% copper leaching.

Jan 1, 2007

By Elmer Pabel Huayna Peraltilla

El proceso de lixiviación es un método para el tratamiento de minerales sulfuros y sulfuros mixtos que consiste en la utilización de un consorcio microbiano acidófilo y una solución rica en cloruro de sodio. En ese sentido, el presente texto destaca el método de la biolixiviación como la alternativa adecuada -en tanto solución ácida (cobre) que contiene el metal en su forma soluble. Dicho proceso se desarrolla en dos etapas: En la primera se usa una solución de cloruro de sodio, el compuesto protector, más un inóculo del consorcio microbiano. La mezcla permite obtener una recuperación de cobre de hasta un 80% basados en pruebas preeliminares. En la segunda etapa, se le agrega un agente oxidante, que no daña a las bacterias, con el fin de disminuir la pasivación del mineral y un inóculo fresco del consorcio y así prolongar la recuperación.

Sep 1, 2013

By M. Kalin

"Ecological Engineering and Biological Polishing technology is a decommissioning approach for inactive coal, uranium and base metal operations. To improve acid mine drainage water some fundamental aspects of wetland ecology and sediment microbiology are combined, to provide conditions to allow for biomineralization of the contaminants.This paper summarizes the first records of microbial alkalinity generation in acid mine drainage through the utilisation of the ARUM process. The process requires that the seepage is at pH 4.5 where sulphate reducers utilize sulphate to produce hydrogen sulphide, which in turn precipitates with metals. The pH increase is brought about by alkalinity generating microbes.The ARUM process has been successful in increasing the pH from 2.5 to 7.0. Flow through reactors operated in the laboratory continuously for more than 60 days have removed Ni from 13 mg/L to < 0.01 mg/L. Design parameters are being developed for low flow rates of 5 L/min in a test system receiving seepage from a tailings.1.0 INTRODUCTIONAcid mine drainage associated with mining wastes poses a significant environmental problem. Conventional means to treat acid mine drainage (AMD) use chemical treatment system. Ecological Engineering technology uses natural biological means to curtail and ameliorate AMD during mine operations and at the time of decommissioning. The premise underlying Ecological Engineering technology is that AMD is the result of a natural process enhanced by mining activities. Therefore, in nature, a process providing a natural balance to AMD has to exist, which, when assisted through appropriate means, can counteract the detrimental effects of AMD on the environment. This process is microbial alkalinity generation which is known to occur in wetlands, lake and ocean sediments (Baas Becling et al, 1960)."

Jan 1, 1991

By B. E. Dindsale, P. B. Altringer, R. H. Lien

The Bureau cf Mines, U.S. Department of the Intericr, is investigating biolcgical and chemical deccntaminaticn of cyanide- containing leachates and residues. Biolcgical cyanide cxidaticn, using bacteria isolated from a precious metals tailings pond, destroyed >85 pct of the cyanide in several prccessing solutions containing up tc 280 ppm CN. Reaction time varied from about 4.5 hr in a trickling reactor using quartz as a bacterial substrate to 2 mo in unagitated, covered flasks. Chemical techniques were used to destroy the remaining complexed cyanide down to 1 ppm. Exploratory tests were also conducted using spent ore from heap leach operations as the bacterial substrate to determine if biological cyanide oxidation could be used to destroy the residual cyanide in spent heaps.

Jan 1, 1991

By K. R. Gardner, P. B. Altringer, R. H. Lien

The Bureau of Mines, U. S. Department of the Interior, is investigating biological and chemical reduction of selenate and selenite from waste waters. A mixed bacterial culture, isolated from agricultural waters, removed selenium from four oxidized cyanide solutions from precious metals operations containing 0.6 to 30 ppm Se and 13 ppm CN. Up to 85% selenium removal was attained using bacteria under controlled batch conditions in a 3-L stirred tank reactor and in small-scale continuous tests conducted in a rotating biological contactor (RBC). Fe(OH), reduction of the selenium reduced the effluent concentration to 0.02 ppm Se; however, the reagent costs were prohibitive. A final processing scheme may involve a combination of biological and chemical treatments.

Jan 1, 1991

By L. H. Ketchum, T. L. Theis, W. H. Engelmann

The use of a suspended growth system of Thiobacillus ferrooxidans attached in a film to individual particles of bentonite and operated as a sequencing batch reactor is shown to be a practical way of oxidizing ferrous iron in acid mine drainage. This component, followed by limestone neutralization, is both a technically and economically feasible approach to treating these waste waters, compared to existing and other proposed methods. The advantages, in addition to less expense, are greater safety, acceptable treatment at a lower pH, lower solids buildup, less danger of overtreatment, and greater flexibility in operational characteristics. In this paper, data on the continuous bench scale operation of the system under a variety of conditions shows sustained levels of oxidation in excess of 98%. Capital and operating costs are projected to be $80/1000 m3 ($80 per 35, 000 cu ft) of waste water.

Jan 1, 1985

A biological column leach testwork program was undertaken on a chalcocite ore. Three tests were conducted in all, using 65 in x 100 mm columns in three sections. The tests were started with varying acid strengths and inoculated with bacterial solutions from previous column testwork. The leaching of Cu was found to occur in three stages. These stages consisted of direct acid leaching, bacterial oxidation and ferric iron leaching. These leaching stages can most easily he described through the examination of not only Cu dissolution but also Fe dissolution and its subsequent oxidation and precipitation. The p11 of the system was found to he critical in establishing and maintaining the bacterial leaching system. The oxidation potential was seen to he influenced by the leaching system as the oxidation states altered. Test variables such as, 02, COz, and temperature were all found to influence the system. Final copper recoveries were in excess of 90 per cent in each column test over a leach time ranging from 211 to 328 days. Given similar leach conditions are applied, the application of this technology to site is expected to give comparable results.

Jan 1, 1994

By D. L. Lampshire

Biological leaching using native heterotrophic bacteria was studied by the U.S. Bureau of Mines as a means of extracting manganese from a domestic low-grade wad ore. Column heap leaching simulation techniques were employed using molasses as the nutrient source for the bacteria. These column studies were designed to investigate the effects of molasses medium flow rate, concentration, and replacement interval on the extent and rate of manganese extraction. .Results showed that flow rates between 0.41 and 8.1 L/min/m2 had little impact on manganese extraction. The total amount of molasses used did have a direct effect on the extent and rate of manganese extraction. Manganese extractions over 90-pct were obtained in 12 weeks of bioleaching with 2-week medium replacement cycles.

Jan 1, 1993

By D. J. Adams

Cyanide heap leaching is the predominant technology used in processing low-grade gold ores. During closure ora heap leach operation, residual cyanide must be removed from the process and waste solutions, as well as the heap. Biological cyanide oxidation is a proven, economical technology for destroying cyanide in process and waste waters and spent heaps; The use of biological cyanide degradation eliminates the need for toxic or corrosive chemical oxidizers and has- been implemented at full scale at treatment costs usually <$0.50/1,000 gal. The Applied Biosciences biological cyanide destruction (BCND?) process has been demonstrated to effectively treat cyanide, concentrations up to 350 mg/L. Treated process solutions and wastewaters also contained other contaminants such as arsenic, copper, iron, silver. selenium, mercury, nitrate and zinc, much of which was removed in the cyanide degradation process. Under optimal conditions, microorganisms can rapidly oxidize free cyanide in some process solutions from over 250 mg/L down to 0.1 mg/L in 4 to 5 hr. Cyanide is degraded to ammonia and carbon dioxide, with 50%ofthe cyanide carbon liberated as C02. In general, carbon tank based bioreactors degrade cyanide at significantly higher rates than process or wastewater pond configured treatments, which usually degrade cyanide-more rapidly than in heap treatments. Investigation of cell-free enzyme preparations as an alternative to live microbial cyanide degradation shows promise. Advantages of enzymes over live microbes for cyanide degradation include: (I) the ability to tolerate and degrade higher cyanide concentrations (> I ;000 mg/L), (2) nutrients to support live microbial cells are not required, (3) the effects of other toxic contaminants, such as metals, found in mining waters-are eliminated and (4) the potential for greatly increased kinetics.

Jan 1, 1998

By Nelson Collao I.

Loss of the organic phase from solvent extraction circuits is a major cost factor for SXEW operations. Recognized sources of loss include evaporation, entrainment, and biological degradation. The mechanisms for both entrainment and evaporative losses are well recognized. Biological degradation of the organic has not been as extensively evaluated as the other mechanisms but is a major source of loss. This paper discusses the impact of biological degradation on an operating plant, potential mechanisms for degradation, conditions under which biodegradation of plant organic can occur and plant conditions that may assist in promoting biodegradation.

Jan 1, 2003

By Robert H. Poppe

The Regional Copper-Nickel Study examined the potential impacts of copper-nickel sulfide mining, concentrating and smelting operations in northeastern Minnesota and gathered extensive monitoring data on the ecological characteristics of the region&apos;s aquatic and terrestrial biota. Because of the many development options possible, the diversity of the region&apos;s ecology, and the uncertainty of future environmental regulatory requirements, the Study did not attempt to measure the magnitude of environmental impacts on specific biological communities from a specific development proposal. The Study provides a broad base of environmental resource and impact information that hopefully will assist mining developers and environmental regulators when assessing specific proposals in the future. The following discussion is not a description of what will happen if copper-nickel development occurs in northeastern Minnesota but an exploration of why certain potential aspects of such development should be carefully considered and adequately understood before unnecessary or irreversible decisions are made.

Jan 1, 1980

By Leslie C. Thompson

The heap leach process used for recovering gold from oxide and sulfide ores is operated as a closed circuit system in which the cyanide process solutions are continuously recy­cled. In a well-designed operation there is little or no dis­charge of cyanide to the environment. Spent leached ore residues are water washed to remove most of the trace cyan­ides and precious metals remaining after completion of cyan­ide leaching. After the washing step, small amounts of cyanide, metal-cyanide complexes and nitrates remain in the residue. Most of the cyanide and nitrate residue constituents exist in the pore water of the spent ore rather than in the solid mineral fraction. More than 90% of the complexed cyanides in a freshly washed ore residue are present as free cyanide or weakly complexed metal-cyanides. Natural volatilization and decom­position rapidly remove most of these easily dissociable cyanides from the spent ore. Only the stable, strongly com­plexed metal-cyanides, such as gold, cobalt or the ferrocyan­ides and other constituents such as nitrates have a long term persistence in the spent ore residue (Towill et al). Despite washing and natural removal mechanisms, spent ore has the potential to act as a point source of com­plexed cyanides and nitrates for soil and groundwater con­tamination if inadequately contained (Huiatt et al). The groundwater contamination is caused by the leaching of the soluble cyanide compounds and nitrates from the pore water of the residue.

Jan 1, 1990

The production of 100,000 tonnes per year of synthetic rutile from the processing of ilmenite, coal and copperas (iron sulphate) produces 200 cubic metres per hour of effluent water. A 2.0 hectare biological filter, comprising natural and man- made wetlands, has been built into the last stage of the effluent water treatment system. It is an area of shallow water (

Jan 1, 1988

By J. Huisman

With the introduction of ever-stricter environmental operating guidelines, capital expenditure restrictions and operational budget cutbacks, the biological method of SO2 removal becomes more and more attractive. Biological treatment of dilute flue gases is a more cost effective technology in comparison to conventional sodium hydroxide scrubbing. Although the investment costs for sodium hydroxide scrubbing is lower, the operational costs are significantly higher. In addition, the end product of the biological installation is sulfur instead of sodium sulfate; and no further wastewater treatment of the bleed from the biological installation is required since heavy metals are removed simultaneously. Another option for the treatment of SO2 containing gas at a sulfuric acid plant is the production of extra sulfuric acid of the discharged SO2 by applying an additional converter. Comparing biological treatment with this option shows much lower investment costs for the biological installation. Sulfur is produced which can be converted to sulfuric acid, so the bio-route will be more cost-effective than an additional converter. In principle, the biotechnological gas cleaning system is an integration of an absorber with a wastewater treatment facility. In the absorber, the SO2 containing gas is brought into contact with the washing water. The effluent absorber liquid contains a mixture of sulfite and sulfate that is converted into elemental sulfur. This conversion takes place in an integrated system; first, the sulfite/sulfate mixture is converted anaerobically into sulfide; secondly, the sulfide is converted aerobically into elemental sulfur. Subsequently the sulfur is separated and the water is returned to the absorber. Due to the buffer capacity of the washing water, removal efficiencies over 98% are possible. In addition to SO2 removal, it is possible to convert for example other bleeds streams such as scrubber acid or weak acid to sulfur in the same SO2 installation. Recent evaluations concluded that biological desulphurization of flue gases is not only economically attractive in comparison to convention sodium hydroxide scrubbing but also in comparison to gypsum producing systems and even seawater scrubbers. This paper describes the technological and economical viability of biological flue gas desulphurization.

Jan 1, 2005