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By P Craig, A Crosky, P C. Hagan, E Elias, B Hebblewhite, S Saydam, D Vandermaat

"Premature failure of rock bolts has been recorded at twelve underground coalmines over the past 15 years in Australia. Over the last four years, UNSW Australia has been conducting an Australian Research Council (ARC) and Industry funded linkage research project into premature failure of rock bolts. The extent of the problem was investigated by underground surveys of mines with known prematurely failed bolts using visual mapping, non-destructive load and ultrasound testing. A major component of this project was to define the environmental factors responsible for corrosion of rock bolts. The environment to which a rock bolt is exposed will include groundwater chemistry, the mineralogy of the strata, atmosphere within the drill hole and even microbial activity. This paper focuses on the groundwater survey and analysis findings to date along with in-hole bolt corrosion coupons installed into field sites. Corrosivity classification systems exist for general corrosion but do not apply to the rock bolt stress corrosion cracking (SCC) problem found in Australian underground coal. The method of in situ investigations is leading towards the building of a corrosivity classification model to assist mines in prediction of premature rock bolt failure. An ‘in-hole bolt corrosion coupon’ development by the project may have multiple benefits of: helping quantify any corrosivity classification system providing an in situ ground support corrosion monitoring tool for testing possible corrosion protection solutions.CITATION:Craig, P, Saydam, S, Hagan, P C, Hebblewhite, B, Vandermaat, D, Crosky, A and Elias, E, 2014. An investigation of the corrosive impact of groundwater on rock bolts in underground coalmines, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference, pp 277–286 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 5, 2014

By Anis Farah, Khosrow Aref

Pull-out tests were conducted on cable bolts grouted with concrete, and cement paste. The influence of several parameters on the performance of these cables were studied under loading rates varying from very slow to relatively fast. These parameters include water-cement ratio, cable surface conditions, curing time and embedded length. In addition to being more economical, the results indicate that cables grouted with concrete have higher ductility and ultimate bond strength as compared to those with cement paste only.

Jan 1, 1986

By J. L. Vanderbeek

The SAG milling of ores with markedly variable grinding rates presents definite process control challenges. Decisions must be made regarding the selection of the most appropriate combination of mill volumetric load level, percent solids, and mill speed for the combination of ore types being processed at the moment. An investigation was performed concerning the effects of these parameters. General results are presented.

Jan 1, 1985

By Ashwini Kumar

Flame impingement on the burden is routinely encountered during the initial phase of melting in aluminum reverberatory furnaces. This impingement causes an obstructed pathway for the hot gases, and hence the circulation and residence time of the hot gases are greatly impacted. Moreover, as the load melts, the flames gradually achieve an unobstructed path leading to reduced gas residence times. This flame impingement and constantly changing combustion space volume will lead to vastly different fuel and oxidizer mixing patterns and thus affect the overall furnace performance. Fine tuning the burner operating conditions such as flow rates and injection angles with the changing combustion space could result in significant improvements to the furnace efficiency. However, one has to gain a better understanding of the furnace dynamics to know the suitable parameters to adjust. Physical modeling can be elaborate and expensive to conduct on a regular basis while Computational Fluid Dynamics (CFD) can cost-effectively address this challenge. In this study, the furnace model is created with a particular loading pattern to understand the flame dynamics in the presence of a piled load. This configuration can be thought of as a computational model of the furnace with the burden at a particular stage of the melting process. Thermal efficiency and behavior of the furnace are quantified and the predicted values are compared with the operational data from an experimental reverberatory furnace.

Jan 1, 2008

By Rozycki J

The results of shaft lining monitoring gave rise to an investigation of cracks observed in the structure. An hypothesis was made that the cracks might be due to stresses caused by energy wave propagation, triggered during blasting or by the rock falls. However, it could not be excluded that the cracks had their origin in the rheologic changes taking place in the concrete. To prove the hypothesis, an investigation of the scale of the increase of stress due to the energy triggered was undertaken. At the same time it was decided to attempt to determine the "damage threshold" for such material in the danger zone. In the paper the investigation and its results are presented, as conducted in one of the shafts. In conclusion, certain generaliza- tions are proposed to give a starting point in the consideration of similar problems elsewhere.

Jan 1, 1987

By George A. Desborough, Stephen J. Sutley, Reinhard W. Leinz, Paul H. Briggs

The mode of occurrence of metals in mine wastes is investigated using sequential extractions. Metals are extracted from some or all of seven operationally-defined phases: water-soluble, ion-exchangeable, carbonate, amorphous Fe-oxide, crystalline Fe-oxide, sulfide, and silicate. The quantity of metals extracted from each phase varies with particle size. The presence of jarosite (potassium end-member formula, KFe3[SO4]2[OH]6) influences the selection of the procedure for extracting the crystalline Fe-oxide phase. Anglesite (PbSO4) and cerussite (PbCO3) are extracted as several phases. Extraction results can be explained only in part by X-ray diffraction (XRD) mineralogy because of lack of specificity of the extraction procedures, relatively high XRD detection limits, and the presence of 40% XRD-amorphous matter in each waste. The increasing chemical strength of the sequentially applied methods provides a basis for judging metal availability, water-soluble metals being most available and silicate-bound metals being least available.

Jan 1, 2000

By E. G. Kelly, D. E. Walsh

The behavior of gold particles on a spiral was studied using radioactive gold tracers. The method allowed the effects of particle size, particle shape, pulp density, feed rate and splitter settings to be studied. Although the method has been successfully applied to other gravity concentrators, it was found that reliable results were more difficult to obtain on the spiral. However, these preliminary results show that, with suitable precautions, the technique is capable of providing valuable information, unobtainable from conventional studies, that could be used to better optimize spiral performance.

Jan 1, 1993

By D. E. Walsh

The behaviour of gold particles on a spiral was studied using radioactive gold tracers. The method allowed the effect of particle size, particle shape, pulp density, feed rate, and splitter settings to be studied. Although the method has been successfully applied to other gravity concentrators, it was found that reliable results were more difficult to obtain on the spiral. However, these preliminary results show that provided suitable precautions are taken, the technique is capable of providing valuable information that cannot be obtained by conventional studies, and could be used to better optimize spiral performance.

Jan 1, 1992

By Riyad N. Ahmad-Bitar, Shadia J. Lkhmayies

"CdSi-xTex thin films were prepared by first producing CdS:In thin films by the spray pyrolysis (SP) technique and then annealing the films in the presence of Te vapor in nitrogen atmosphere. X-Ray diffraction (XRD) measurements showed that the films are polycrystalline with the wurtzite structure. Transmittance measurements were recorded at room temperature in the wavelength range 400-900 nm and used to deduce the absorbance. The first derivative of the absorbance was calculated and used to find the values of the bandgap energy, where more than one bandgap was obtained for each film. These results show that the films are inhomogeneous or the composition differs with location. The photoluminescence (PL) was recorded at T = 60 K and a deconvolution peak fit was performed for each spectrum. The results of the PL spectra are consistent with those obtained from the first derivative and confirm the inhomogeneity of the films.IntroductionPolycrystalline thin film CdS/CdTe solar cells are promising candidates for low cost and high efficiency photovoltaic applications. The CdS/CdTe interface plays an active role and a detailed knowledge of its properties is crucial for thorough understanding of the device. High efficiency devices have been obtained in spite of the large lattice mismatch (9. 7%) between hexagonal CdS and cubic CdTe. Interdiffusion at the CdS/CdTe interface is considered to affect the performance of the devices [1]. The formation of a mixed crystal or a graded layer at the interface causes a reduction in the lattice mismatch at the CdS/CdTe junction [2] and then a reduction in the number of interfacial states and recombination centers, thus enhancing the solar cell performance [3, 4].The objective of this work is to investigate the transmittance, photoluminescence (PL) and structure of CdSi-xTex thin films prepared by annealing the spray-deposited CdS:In thin films in the presence of tellurium vapor. X-ray diffraction (XRD) was used for exploring the structure. Transmittance is used to deduce the absorbance where its first derivative was used to find the bandgap energy which varies with composition. The evolution of the PL spectra as functions of tellurium concentration was evident and it confirmed the inhomogeneities of the films."

Jan 1, 2011

By M. G. Corson

UNTIL recently, the characteristics of cast copper have seldom been studied and such study as has been made has been inadequate. The prevailing idea seems to be that since pure copper is infrequently used in the cast state, there is no reason for trying to establish precise data regarding the properties of the metal in that condition. On the other hand, wrought copper either in the shape of sheets or wire rarely fails in service, except as a result of the action of reducing gases at the annealing temperatures, so there is little incentive to study the properties of the cast shapes -cakes, bars, ingots and billets-for the sake of tracing the causes of failures of the wrought metal to the cast stock. However, about a decade ago, wirebars of American origin often cracked badly while being hot-rolled in mills in Germany. This led to four investigations: by E. Seidl and E. Schiebold,1 by P. Siebe,2 by 0. Bauer and G. Sachs,3 and by G. Welter.4 These authors came to the conclusion that failures in hot-rolling were due essentially to the presence of a' wide zone of columnar crystals between the thin layer of fine crystals near the surfaces of the bars and the large but more nearly: equiaxed grains of the central core. This macrostructural defect was explained in turn by the probable upward deviation in the temperature of the metal while it was being poured into the molds of the casting machine. More recently, cast shapes of copper were investigated by N. P. Allen5 and by C. Blazey.6 Allen examined vertically cast wirebars and horizontally cast wedge cakes of electrolytic tough-pitch copper, but only for the distribution of densities; i.e., porosity. Blazey was interested mainly in the mechanism of the variations in electrical conductivity due to cold-work and anneal, but gave introductively an account of the composition and average densities of the tough-pitch horizontally cast wirebars used. As far as the present writer can tell, no investigation was undertaken for the sake of presenting a picture of the distribution of mechanical characteristics in the wirebars of copper, tough-pitch or otherwise.

Jan 1, 1938

By M. G. Corson

UNTIL recently, the characteristics of cast copper have seldom been studied and such study as has been made has been inadequate. The prevailing idea seems to be that since pure copper is infrequently used in the cast state, there is no reason for trying to establish precise data regard-ing the properties of the metal in that condition. On the other hand, wrought copper either in the shape of sheets or wire rarely fails in service, except as a result of the action of reducing gases at the annealing tempera-tures, so there is little incentive to study the properties of the cast shapes -cakes, bars, ingots and billets-for-the sake of tracing the causes of failures of the wrought metal to the cast stock. However, about a decade ago, wirebars of American origin often cracked badly while being hot-rolled in mills in Germany. This led to four investigations: by E. Seidl and E. Schiebold,1 by P. Siebe,2 by O. Bauer and G. Sachs,3 and by G. Welter.4 These authors came to the conclusion that failures in hot-rolling were due essentially to the presence .of a wide zone of columnar crystals between the thin layer of fine crystals near the surfaces of the bars and the large but more nearly equiaxed grains of the central core. This macrostructural defect was explained in turn by the probable upward deviation in the temperature of the metal while it was being poured into the molds of the casting machine. More recently, cast shapes of copper were investigated by N. P. Allen5 and by C. Blazey.6 Allen examined vertically cast wirebars and hori-zontally cast wedge cakes of electrolytic tough-pitch copper, but only for the distribution of densities; i.e., porosity. Blazey was interested mainly in the mechanism of the variations in electrical conductivity clue to cold-work and anneal, but gave introductively an account of the composi-tion and average densities of the tough-pitch horizontally cast wirebars used. As far as the present writer can tell, no investigation was under-taken for the sake of presenting a picture of the distribution of mechanical characteristics in the wirebars of copper, tough-pitch or otherwise.

Jan 1, 1938

By F. T. Cawood

The new mineral royalty regime for South Africa was signed into law in November 2008, with its main objective being to compensate the State for the depletion of public minerals through a royalty charge payable from 1 March 2010. The aims of this paper are to establish the potential impact of mining royalties on State revenues, industry affordability, and explore whether the dual formula system is likely to encourage miners to become refiners. It also measures the royalty dispensation against economists? tax standards in an attempt to make a judgement on the ?equity? of the new system. This paper argues that most stakeholders should be comfortable with most of the requirements of the Act for most of the time. However, the new regime is unlikely to motivate miners to become refiners, as the benefit of the reduced rate on refined minerals appears to be insufficient to justify the additional costs to refine the mineral resource to the prescribed states of beneficiation.

Jan 1, 2011

By Steven Wright

The reduction of a slag produced 6om the recycling of lead batteries was studied in a kilogram scale laboratory investigation by reacting with graphite at temperatures of 1180 and 1200°C. Simultaneous reduction of PbO, Fe203, Sb203 and As203 occurred with the Sb and As reporting to the metal while the lead content in the slag was above 2 wt%. The Sb and As distributions between metal and slag were strongly affected by temperature and slag oxidation state. The rates of reduction of PbO and Sb203 increased with increasing slag basicity and temperature and decreased as the PbO content in the slag decreased. The reduction rate of PbO from these slags was similar to other industrial lead slags at the same CaO/SiO2 ratio and temperature. The implications of the behavioural similarities of the antimonous slags during reduction with carbonaceous reductants and other lead slags are briefly discussed.

Jan 1, 1994

By D. J. McAdam, R. W. Mebs

THE technical cohesive strength of a metal means, not the interatomic forces, but the technically estimated resistance to fracture. An example of such resistance to fracture is the so-called "true" breaking stress of a tension-test specimen, the breaking load divided by the sectional area at fracture, According to the prevalent view,8 the technical cohesive strength of a metal, in any particular state as regards prior mechanical treatment and heat-treatment, is determined by a limiting value of the algebraically greatest principal stress.? In two previous papers by one of the authors,14,15 evidence was presented to indicate that the technical cohesive strength of a metal cannot be represented by a single stress value, but that it comprises an infinite number of values corresponding to the infinite number of possible combinations of the principal stresses. The technical cohesive strength thus comprises an infinite number of technical cohesion limits, each representing a specific stress combination at fracture. In the same papers, evidence was presented that plastic extension causes a continuous increase in the technical cohesive strength. Such a variation is not in accordance with the prevalent view that plastic extension first increases, then decreases, the technical cohesive strength.8 In this paper, as in the previous papers,14,15 the algebraically greatest principal stress will be designated S1, the least principal stress will be designated S3, and the intermediate principal stress will be designated S2. The technical cohesion limit under polarsymmetric tension (S1 = S2 = S3) will be termed the "disruptive stress," and the cohesion limit under unidirectional tension (S2 and S3 = o) will be termed the "severing stress." 14,15 The yield strength of a metal, according to the generally accepted theory, may be represented by a constant value of the shearing-strain energy, and hence by a constant value of the sum of the squares of the three principal stress differences. In the second of the previous papers,"' however, evidence was presented that the limiting yield stress decreases with increase in the volume stress, the algebraic average of the three principal stresses.* This influence of the volume stress becomes prominent only in the field of triaxial tension. In the two previous papers, 14,15 diagrams were presented to show the variation of the technical cohesion limit, yield stress, and ultimate stress with the combination of principal stresses and with plastic extension. Those diagrams and the resultant conclusions are derived from experimental data obtained by other investigators. They are based chiefly on results of tension tests

Jan 1, 1943

By G. S. Hansford, G. E. Searby

The rate of bioleaching of pyrite at 70ºC by a thermophilic archaeal culture was measured as a function of the solution redox potential by the staged addition of pyrite to a batch system. The results were compared to the rate of ferrous iron oxidation over the same potential range to determine the applicability of the multi-sub-process leaching mechanism developed for mesophilic bioleach systems.

Jan 1, 2003

By G. Davis

Mineral properties and mineral firms often trade at a market value that is significantly greater than the value indicated by discounted cash flow (DCF) techniques. A possible explanation is that DCF analysis does not consider the value derived from managerial flexibility. Presumably, then, at least some of the difference between DCF value and market value is due to managerial flexibility. This paper surveys the recent attempts to empirically quantify the value of managerial flexibility using option pricing theory. The results indicate that managerial flexibility, at least as measured by the option pricing methodology, falls well short of explaining the gap between DCF value and market value.

Jan 1, 1995

By J. L. Rodda, R. L. Wilcox, E. C. Truesdale

IN recent years various problems in connection with research work on the preparation and properties of zinc-base alloys have required reliable information concerning the constitution of the zinc-rich portion of the iron-zinc equilibrium diagram. On numerous occasions rather positive indications were obtained that, for example, the solubility of iron in zinc was incorrectly represented on .the current equilibrium diagrams.. A careful study of all the available literature relating to the iron-zinc system led to the conclusion that much of the early work was unsatisfactory as measured by present standards of experimental accuracy, and as a result it was decided to redetermine the location of the liquidus curve and of adjacent portions of the diagram. Part I. of this paper comprises a description of the experimental methods and a summary of the results by means of which the zinc-rich end of the iron-zinc diagram has been revised in the following ways: 1. Measurements of the solubility of iron in liquid zinc by several different sampling methods, leading to a relocation of the liquidus curve. 2. Microscopic, conductivity, and X-ray studies of the solid solubility of iron in zinc, which, together with thermal analyses, have resulted in new values for the solid solubility and the eutectic temperature and composition. 3. Heating and cooling curves, obtained by a refined differential method, leading to new locations for the two peritectic horizontals. In Part II of the paper the attempt is made to review all of the published work having a bearing on the constitution of the iron-zinc system, and to correlate the present results, and some recently published data

Jan 1, 1935

By E. C. Truesdale

IN recent years various problems in connection with research work on the preparation and properties of zinc-base alloys have required reliable information concerning the constitution of the zinc-rich portion of the iron-zinc equilibrium diagram. On numerous occasions rather positive indications were obtained that, for example, the solubility of iron in zinc was incorrectly represented on the current equilibrium diagrams. A careful study of all the available literature relating to the iron-zinc system led to the conclusion that much of the early work was unsatisfactory as measured by present standards of experimental accuracy, and as a result it was decided to redetermine the location of the liquidus curve and of adjacent portions of the diagram. Part I of this paper comprises a description of the experimental methods and a summary of the results by means of which the zinc-rich end of the iron-zinc diagram has been revised in the following ways: 1. Measurements of the solubility of iron in liquid zinc by several different sampling methods, leading to a relocation of the liquidus curve. 2. Microscopic, conductivity, and X-ray studies of the solid solubility of iron in zinc, which, together with thermal analyses, have resulted in new values for the solid solubility and the eutectic temperature and composition. 3. Heating and cooling curves, obtained by a refined differential method, leading to new locations for the two peritectic horizontals. In Part II of the paper the attempt is made to review all of the pub-lished work having a bearing on the constitution of the iron-zinc system, and to correlate the present results, and some recently published data

Jan 1, 1935

By Filiz Sahin

This paper presents a synthesis of TiB2 via carbothermal reduction method using a mixture of TiO2, B4C and C prepared in molar ratio of 2:1:3. Reduction experiments were carried out in a high temperature graphite furnace in a graphite crucible under argon atmosphere at different time (0, 15, 30 and 60 min.) and temperatures (1400, 1500 and 1600 °C). The products obtained were investigated using XRD technique.

Jan 1, 2008

By Fermino R

Reduction of waste oxides from steel plant operations was investigated in a laboratory tube furnace at different temperatures and furnace atmospheres. The results have shown that the waste oxide pellets are reduced rapidly to very high degrees of metallization irrespective of the furnace atmosphere and that the reduction is simultaneously accompanied by significant low- ering of the original impurities. It is shown, for example, that treatment at 1000¦C for 30 min. can reduce the Zn content from 0.98% to 0.0065% and K and Na contents from 0.19% and 0.76% respectively, to less than 0.01%. However, pellet strength at 1000¦C was low but this, as shown in the paper, can be very significantly improved by treatment at 1250¦C. The results indicate that the reduction of the waste oxide pellets of this investigation proceeds almost certainly by a chain reaction mechanism and that this principle could be advantageously extended to the reduction of iron ores and other oxides in general.

Jan 1, 1984