Search Documents

The paper describes the studies conducted to date on the short term adsorption/desorption of gases in coal from the point of view of developing techniques to predict imminent outbursting conditions in coal mines. A number of different parameters such as'dP express, K' and AV 0/60 etc. which have been effectively used overseas were studied on samples of coal from Westcliff and Leichhardt Colliery. Results indicate that these do not seem to be valid indices for predicting an outbursting condition. Based upon desorption isotherms, a new index defined as "L" has been developed which shows promising results. This index is in a position to differentiate the changes in the structures of coal and its proness to outbursts. The "LZ value determinations and its usefulness opens a new field where it would be possible to determine outbursting conditions from existing drill cores obtained during exploration studies or from long holes drilled in advance from underground workings. The index is more or less independent of the time elapsed between the extraction of a sample and the conduct of the test. The test for "L" can be conducted'on site or in the laboratory. The test is simple, easy to carry out and the "L" value for a sample can be calculated in less than 20 minutes. It could be adapted as a routine test for monitoring outburst conditions in mines.

Jan 1, 1980

By S. G. Malghan, D. Santhiya, S. Subramanian, K. A. Natarajan

The adsorption of poly(vinyl alcohol) (PVA) of molecular weight 25,000 onto alumina was studied as a function of pH. The adsorption isotherms were also determined. The adsorption density increases with increasing pH, while the isotherms are rounded and of the low affinity type. Electrokinetic studies indicate that the electrophoretic mobilities are reduced in magnitude in proportion to the PVA concentration, without any shift in isoelectric-point (iep). This resembles the influence of an indifferent electrolyte. The calculated values of the free energy of adsorption between alumina and PVA are suggestive of hydrogen bonding. FTIR spectro-scopic data provide additional evidence in support of hydrogen bonding.

Jan 1, 2000

By E. Szelag

The adsorption and stabilization of mineral dispersed systems by using Pluronic copolymers with different molecular weights and EO content has been studied. The role of sequential adsorption of EO-PO copolymers and cationic surfactant (CTAB) on the carbonate particle properties and in determining the stability of their suspension was studied with particular attention to the conformation of the polymer at the solid-liquid interface. The purpose of this work was to investigate the flocculation phenomena, influence of polymer molecular size on stability of suspensions of magnesite and dolomite and the effect of addition mode of polymer and surfactant. The suspension stability measurements and the determination of sedimentation speed were carried out using an optical analyser (Turbiscan). In most of investigated cases, the biggest floccs and the fastest sedimentation were found for low concentrations of copolymers.

Jan 1, 2014

By Heinz Hoberg, Fred Ulrich Schneider, Rudolf Diegel

The risk of contamination of dumped tailings and ground water by coal flotation reagents has been investigated by using the 14C-radiotracer method for adsorption and desorption measurements. The results indicate, that a high amount of the reagent components adsorbed on the tailings if there was no coal in the pulp. In coal flotation however a competitive adsorption behaviour could be observed, with the effect that only a low quantity of reagents adsorbed on the tailings. Mobilization tests showed, that only small quantities of reagents could be desorbed by rinsing water. Therefore the contamination of ground water should be low.

Jan 1, 1995

By Fazel G. Jahromi, Ahmad Ghahreman

"Several studies were performed on the atmospheric leaching of copper sulfide minerals in the presence of activated carbon and a new catalyst, AF 5. AF 5 is a carbon based catalyst with similar properties to those of activated carbon however much better mechanical properties. The activated carbon surface chemistry has been investigated in various studies; however the connection of the surface chemistry of activated carbon and AF 5 with the sulfide minerals during the atmospheric leaching process is not well-understood yet. Based on the surface analysis, AF 5 showed higher surface area than activated carbon (AC). Adsorption and oxidation of copper, arsenic and iron ions in the presence of different activated carbon were investigated. Adsorption properties of both catalysts were similar and 18-24% of iron, 12-18% of copper and 10% of arsenic adsorbed on the catalysts surface form 5 g/L Fe(III) and Cu(II) and 2 g/L As(III) at 80°C. In oxidation experiments, both catalysts reduced Fe(III) and Cu(II) ions and re-oxidized the reduced species in the presence of oxygen and oxidized As(III) ions. The addition of oxidizing ions can enhance the oxidation process kinetics and increase the catalytic capability of carbon.INTRODUCTION Hydrometallurgical processes of copper sulfide concentrates are under development and various different methods have been proposed to increase the atmospheric leaching rate of copper sulfide minerals. These methods include using different media, reagents, and catalysts. Among different methods, leaching of the copper sulfide minerals in the chloride media has some advantages over sulfate media. Smaller scale of operation, increased leaching rates, and lower sulfate formation are some of the benefits of the chloride leaching media over other similar media. Moreover, using ferric and cupric ions as oxidants and utilizing activated carbon as a catalyst has been proven to enhance the leaching rate of copper sulfide minerals effectively. Activated carbon (AC) and AF 5 (micro porous carbon based catalyst) are two of the most efficient and practical catalysts in copper sulfide leaching processes. AC can enhance the copper recovery of enargite in chloride media from 69% to 92% after 96 hours of leaching under the similar conditions (Jahromi & Ghahreman, 2016). It has been shown that AC at acidic pH can generate hydrogen peroxide in the presence of oxygen which can leach copper minerals (Ahmumada et al., 2002)."

Jan 1, 2017

By Qingzhu Li

The brewing industry byproduct, spent grain (SG), was evaluated for its ability to adsorb Ag(I) from aqueous solutions. Ag(I) adsorption was dependent on solution pH, contact time, adsorbent dose, initial Ag(I) concentration and temperature. The kinetic data were well described by pseudo-second-order kinetic model, indicating that chemical adsorption was the rate-controlling step. The equilibrium data followed Freundlich isotherm rather than Langmuir isotherm, suggesting heterogenity of the adsorption sites on spent grain. Ag(I) desorbed from Ag(I)-loaded spent grain was also evaluated in this study. HCl, NaOH, Na2S2O3 and ultrapure water were chosen as eluants and desorbed Ag(I)-loaded spent grain for 30min, Ag(I)-loaded spent grain desorbed in 0.1M Na2S2O3 exhibited higher elution efficiency as compared with other eluants. The results indicated that application of spent grain for adsorption and recovery of silver from aqueous solutions was feasible.

Jan 1, 2009

By K. N. Han, Q. Xu

The adsorption behavior of gold in ammoniacal solutions on activated carbon was studied. The gold adsorption capacity of the activated carbon and the recovery efficiency were examined. The parameters affecting the adsorption of gold on the activated carbon included temperature, agitation speed, the concentration of cation and anion and the concentration of ammonia. It was found that the maximum gold adsorption was about 10 kg/t of carbon. The recovery of gold by the adsorption, from ammoniacal solutions was found to be dependent upon the initial gold concentration. Under experimental conditions, a gold recovery of 98% was obtained after 120 hrs of adsorption. It was also found that the initial adsorption rate was relatively fast, when compared to the entire adsorption period. The apparent activation energy for the adsorption was determined to be 15.8 kJ/mol. It was believed that the kinetics of gold adsorption on the activated carbon was controlled by pore diffusion.

Jan 1, 1997

By A. W. Wensel

The adsorption behavior of sodium oleate on brucite, Mg (OH)2, has been studied by Fourier transform infrared spectroscopy. Both internal reflection and diffuse reflection (DRIFT) methods were used to characterize the adsorbed oleate on brucite. DRIFT measurements were shown to be quantitative, and an equilibrium adsorption isotherm was obtained. The conformational behavior of the adsorbed oleate was investigated as a function of adsorption density. It was found that at sub-monolayer coverage the alkyl chains of the adsorbed oleate had more ?gauche? character than at multi-layer coverages. Also, DRIFT spectra revealed that the adsorbed species were magnesium dioleate. For internal reflection measurements single crystals of MgO were hydrolyzed to form a thin Mg (OH)2 layer.

Jan 1, 1994

By D. Kang, K. N. Han

The adsorption behavior of silver in ammoniacal solutions on activated carbon was studied. In addition to the concentration of ammonia, the parameters that affect adsorption include temperature, degree of agitation and anion and cation concentrations. In the study, it was found that the adsorption of silver from ammoniacal solutions is dependent on the initial silver concentration in the solution. It was also found that the recovery of silver from ammoniacal solutions is not as effective us gold. The adsorption rate was relatively slow overall, despite a rapid initial adsorption. The apparent activation energy ,for the adsorption was measured at 30.2 kJ/mol. It was believed that the kinetics of the silver adsorption on activated carbon was limited by a mixed control mechanism.

Jan 1, 1999

By K. N. Han, J. J. Kellar, Y. Guan

The adsorption of zinc species onto silica in ammoniacal solutions was studied. The adsorption isotherms indicated that the adsorption of zinc increased with increasing pH. The adsorption density increased as the zinc equilibrium concentration increased up to =3.5x10-4 M. Above this concentration, the adsorption density was independent of the equilibrium concentration, and a maxima adsorption density was reached. Temperature had no significant effect on the adsorption density.

Jan 1, 1995

By Y. Guan

The adsorption of zinc species onto silica in ammonical solutions has been studied. Adsorption isotherms reveal that increasing adsorption occurs as the solution pH is made more alkaline. Fr-IR spectroscopy revealed that the adsorbed species is a zinc ammine complex.

Jan 1, 1993

By S. Sheng, Y. G. Huang, W. Chai

"Polyacrylamide (PAM) is a typically synthetic depressant and may be used as a depressor of pyrite. The modification of polyacrylamide may improve its physicochemical properties and performances. Sulfonated polyacrylamides (SPAM) with different sulfonation degree (SD) were prepared using sodium sulfite as the sulfonating agent, and the interactions of SPAM and pyrite were investigated by the adsorption experiment in this work. The adsorption tests of SPAM on pyrite were conducted as a function of sulfonation degree, pH value and contact time. Pyrite and SPAM were constructed and optimized through MS software. The interaction mechanisms of sulfonated polyacrylamide and pyrite were simulated by molecular dynamics simulations. The results show that the adsorption capacities of SPAM at neutral and weak alkaline conditions are higher than that at acidic and strong basic conditions. The high sulfonation degree favors the adsorption of SPAM on pyrite surface. The adsorption process can be described best by the pseudo-second order kinetic model. Molecular dynamics simulations show that the adsorption of sulfonated polyacrylamide on pyrite is better than that of polyacrylamide. Sulfonated polyacrylamide can be used as a potential depressant of pyrite with the main interacting mechanism of hydrogenbond force.INTRODUCTIONPyrite is the most abundant sulfide mineral and often associated with valuable minerals such as galena, chalcopyrite, sphalerite, molybdenite, gold, diaspore as well as coal (Forrest et al., 2001; Jaiswal et al., 2015; Maier and Dobiáš, 1997; Qiu et al., 2017; Xin and Liye, 2010). Froth flotation is the most popular method to remove pyrite from valuable minerals. Pyrite could be floated as the flotation concentrate either by its hydrophobicity or activation by metal ions (Chandra and Gerson, 2009). What is more, pyrite could be seperated as flotation tailing by adding highly selective depressants including inorganic and organic modifiers. Polysaccharides polymers and lignosulfonate-based biopolymers are common natural organic depressants (Deng et al., 2017; Mu et al., 2016). While the synthetic organic products have proved to be particularly versatile in terms of molecule tailing capability and controlled structures (Boulton et al., 2001a; Raffa et al., 2015)."

Jan 1, 2018

Adsorption Behaviours of Humic Substances onto Iron Ore Particle Surface Humic substances extracted from lignite mainly consist of fulvic acids (FA) and humic acids (HA), which have been successfully used as good composite binders for iron ore pellets in laboratory tests and industrial production. However, there exists a general lack of understanding of the interaction between humic substances and iron ore particles surfaces. In this research, by means of zeta potential measurements, Fourier Transform Infrared (FTIR) spectrum, colorimetric method and Environmental Scanning Electron Micrograph (ESEM) imaging, the adsorption behaviours of FA and HA onto the surfaces of iron ore particles are investigated. The zeta potential results indicate that adsorption of FA on the iron ore particles can be characterised by specific and electrostatic interactions, while adsorption of HA is by electrostatic and chemical adsorption interactions. FTIR spectrum results show that adsorption force of FA on the iron ore particle surfaces is stronger than that of HA. From results of colorimetric method, compared with HA, adsorption amount and adsorption rate of FA is more and faster, respectively. FA molecule presents on the surface of magnetite in the shape of an araneose network structure according to the ESEM images, while HA molecule appears on the surface of magnetite in the form of small flocs or microclusters. Humic substances are effective to iron ore pelletisation. Comparsion of agglomeration results show that the different mechanisms of adsorption result in varied agglomeration behaviours. Theses findings above would be beneficial to the implications of composite binder for agglomeration.  

Sep 13, 2010

By A. M. L. Cushing, S. Kelebek

Presently, adsorption is one of the effective methods of removing toxic contaminants from waste waters. The contaminants from metal mining industrial operations include an effluent water containing various types of heavy metal species at concentrations beyond the maximum allowable limits, which are 0.5 ppm and 0.3 ppm for nickel and copper species, respectively. Adsorption behavior of copper ions pre-chelated with diethylenetriamine (DETA) and triethylenetetramine (TETA) onto natural bentonite and peat has been investigated. Both natural bentonite and peat was found to be capable of removing these copper-polyamine complexes from aqueous solutions relevant to process water effluents. However, the adsorption capacity of bentonite was significantly higher than that of peat. Two models were used to study the adsorption kinetics: a pseudo-first-order rate expression and a pseudo-second-order rate expression. For both adsorbents, the data conformed best to the pseudo-second-order rate expression. Representation of the experimental data through adsorption models was also investigated. Out of the four cases considered, namely, Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms, it was found that for both bentonite and peat, the copper polyamine adsorption data conformed best to the Dubinin-Radushkevich adsorption model. The Langmuir model also represents the bentonite-copper polyamine adsorption system reasonably well as the second best case, suggesting that the amount adsorbed on bentonite might be a monolayer with strong affinity.

Jan 1, 2015

By Cheng Wei

Fly-ash was used as adsorbent to remove butyl xanthate from aqueous solution in this study. Adsorption kinetics investigation reveals that the adsorption process abides by the Lagergren-second-order Kinetic Model, and fine fly-ash prepared by grinding has a higher second-order adsorption rate as 1.25 g/mg?min and a higher saturated adsorption amount as 10.92mg/g. Four influencing factors as adsorption temperature, solution pH, consumption of fly-ash and adsorption time were investigated. Testing results indicate that butyl xanthate removal rates declines slightly with the temperature increase within the range of 15-50?, increases slightly when pH rises from 7.27 to 8.01 and then declines from 99.65% to 98.25% when pH rises from 8.01 to 11.10. An enhancement of removal rates can be observed by increasing the consumption of the adsorbing agent or prolonging the adsorption time. Thermal desorption was adopted to regenerate the used fly-ash, and test results show that fly-ash possess good regeneration performance and could be used as adsorbent repeatedly with little influence on the adsorption capacity.

Sep 1, 2012

Adsorption Effect on Multi-Heavy Metal Ions in Wastewater by Water-Washing Waste Saccharomyces cerevisiae

Sep 13, 2010

Adsorption Isotherm Measurement of Sodium Oleate on Haematite Using Differential Thermal Analysis

Sep 13, 2010

By L. R. Plitt, M. K. Kim

The collecting properties of the fatty acid type collectors for barite were studied using zeta potential measurements, infrared spectroscopy, and Hallimond tube flotation tests. Based upon the experimental results, an adsorption model has been formulated which emphasizes the predominant role of the hydrocarbon chain in collector adsorption.

Jan 1, 1975

By Sandenbergh RF

The debate on the mechanism of adsorption of gold and silver di-cyanide onto activated carbon could be divided into two schools of thought. On the one hand, it has been proposed that the combined effects of electrostatic and chemical interaction between the activated carbon surface and adsorbing gold di-cyanide anion results in the adsorption of the latter. On the other hand the `ion-pair' adsorption reaction mechanism has been vigorously advocated as the dominant mechanism responsible for the adsorption of gold di-cyanide onto activated carbon. It is maintained that gold is adsorbed onto the carbon surface as the neutral ion-pair [M"+][Au(CN)z ]". Adsorption is viewed as the result of mainly the chemical interaction while electrostatic interactions are neglected. The validity of the `ion-pair' adsorption mechanism may be challenged on a number of counts. However, the alternative mechanism (based on aqueous surface chemistry principles) has not gained general acceptance yet, because it has not been applied widely enough to explain the different adsorption phenomena associated with gold di-cyanide on activated carbon. In the present study the case in favour of an adsorption mechanism based on general aqueous surface chemistry principles is presented. A model framework is developed for the adsorption reaction mechanism of gold di-cyanide onto activated carbon which incorporates the effects of chemical and electrostatic interactions between the dissolved species, the aqueous solution and the carbon surface. This model is then employed to explain a wide variety of reported adsorption phenomena for gold di-cyanide on activated carbon, such as the effects of pH, the adsorption of different metal cyano complexes, ionic strength, and type and concentration of cations in solution. In addition the effects of cyanide and dissolved oxygen concentration were investigated. No ready explanation, in terms of aqueous surface chemistry principles, is yet available for the switch in adsorption behaviour that agrees with ion exchange to ion-pair adsorption with increasing ionic strength.

Jan 1, 1997

By E. Sabah

A series of adsorption tests are carried out to understand the ability of cationic surfactants and metal ions to adsorb onto sepiolite. Adsorption tests conducted as a function of heat treatment reveal that sepiolite is rather conducive to the uptake of both organic and inorganic ions. An ion exchange mechanism between surfactant or metal cation and magnesium ion followed by chain-chain association is proposed to explain the incorporation of cationic surfactants into the structure of sepiolite.

Jan 1, 1998