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By H. C. Ko

Heats of solution of calcium carbon-ate (calcite) and calcium oxide in hydrochloric acid were determined by solution calorimetry. Combination of these two heats yields a value of 42.643±0.024 kcal/mole for the enthalpy of calcination of calcite at 298.15 K. Literature data on ?H°298.15 of calcination of calcite were reviewed and compared. Thermodynamic properties for the calcination process were calculated from 298.15 to 1,500 K using Gibbs energy functions. This research was undertaken by the Bureau of Mines as an effort to provide thermodynamic data for the advancement of minerals technology, energy conservation, and environmental preservation.

Jan 1, 1982

By Thomas H. Dubaniewicz

Thirteen miners died as a result of 2 explosions in the Jim Walter Resources No. 5 mine near Brookwood AL in September 2001. Both explosions were ignited in intake air entries, and both were probably ignited by electrical equipment. With few exceptions, permissible equipment is not required in intake air entries of US underground coal mines Researchers with the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory. studied the electrical equipment ignition sources for the Brookwood and other w disasters to develop recommendations for preventing similar disasters Adherence to National Electrical code® requirements for flexible cords installed in hazardous (classified) locations may have prevented the second massive Brookwood explosion. The 30 CFR Part 7 requirements for battery assemblies should be reevaluated, taking into consideration United Mine Workers of America recommendations and the Zone 1"increased safety" standard requirements for battery assemblies, Class 1 Division 2 or Zone 2 explosion protection techniques are recommended for intake air equipment so that they do not present a methane air ignition source under normal operation before mine power is shut down during emergencies Battery powered circuits intake air that are likely to remain energized during emergencies should be protected by more stringent protection techniques, to protect rescue/recovery personnel. Index Terms -Class 1 hazardous location, mine explosion, flexible cord, battery assembly, permissible equipment

By Robert P. Vinson, John C. LaScola, Fred N. Kissell, Edward D. Thimon

The face ventilation measurement method developed by the Bureau of Mines involves releasing a small volume of tracer gas (SF6) on the off-curtain side of the working face at the start of the mining cycle. At the same time, gas bottle samples are taken in the immediate return airway. The gas samples are analyzed, and a curve is drawn of SF6 concentration versus time. From this curve, the percentage of gas removed per time is calculated. A curve showing a high percentage of the tracer gas removed in a short period would represent a well-ventilated face. The face ventilation measurement method was tested in a full-scale mine entry model. Subsequently it was used underground to evaluate the spray-fan ventilation system and in an MSHA test facility to test machine-mounted scrubbers. The method was shown to be a simple and effective way of evaluating face ventilation systems.

Jan 1, 1980

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

2, Survey of Representative Group of Metal and Non-mental Mines Before proceeding to develop and analyze Emergency Escape System Guidelines, it was necessary to obtain a broad range of information, including both fact and opinion. Although there were many areas to consider, the surveys had three primary goals 1. To determine the current state of underground escapeway planning and execution in American, metal and non-metal mines. 2. To determine, for a wide range of mining conditions, what difficulties can be encountered in complying with present and proposed escapeway regulatory standards. 3. To determine what improvements could be made and what equipment and technology was available to aid in implementing these improvements. To accomplish these goals, three major surveys were undertaken¬ 1. Survey of MESA and State Mining officials, discussed in Section 2. 1. 2. Survey of representative U S metal and non-metal mines, discussed in Section 2. 2. 3. Survey of manufacturers supplying equipment, primarily hoisting, suitable for use in escape systems, the product information which was obtained is discussed in Section 7.

Jan 1, 1976

By Fred N. Kissell

Methane-flow and pressure data taken from a mine in the Pocahontas No. 3 coalbed are compared with flow rates from lump coal obtained in laboratory experiments. From this, it is concluded that the main source of gas is the intact coalbed rather than a "crushed zone" near the working face. The permeability and sorption capacity of the intact coalbed are calculated and gas emission rates are theoretically accounted for.

Jan 1, 1972

By L. A. Johnson

The Bureau of Mines analyzed three cores from the south Seep Ridge area of the P. R. Spring tar sand deposit of northeastern Utah. Four tar sand zones are indicated in the area. The zones range in average thickness from 13 to 24 ft. The total net thickness of the tar sand in the three coreholes ranges from 71 to 112 ft. The tar sand occurs between the depths of 27 and 254 ft. It has good porosity, 25.6 pct of bulk volume; high permeability before and after oil extraction, 819 and 2,218 md, respectively; but a relatively low oil saturation, 36.5 pct of pore volume. Gravity of the oil ranges from 8.20 to 16.5° API.

Jan 1, 1975

By B. J. Scheiner

Carbonaceous gold-bearing ores of the type that occur in north-central and northeastern Nevada were investigated by the Bureau of Mines as part of its Heavy Metals Program. Specific objectives were to identify the carbon and organic compounds that prevent adequate gold recovery from the ore by cyanidation and to develop an economical process that would overcome the detrimental effect of the carbonaceous constituents. Activated carbon and long-chain organic compounds containing sulfur and nitrogen were found in the ore. Part of the material consisted of stable gold organic complexes. A mild oxidation technique that allowed gold extraction as high as 96 percent by subsequent cyanidation was developed. A variety of oxidants was shown to be effective in improving gold recovery, including chlorine and sodium hypochlorite (NaOC1). An electrolytic oxidation process was developed that was particularly advantageous from an economic and effectiveness standpoint.

Jan 1, 1971

By G. B. Atkinson

To develop technology to help assure an ample domestic supply of zinc, the Bureau of Mines is investigating an aqueous chlorine-oxygen leaching process for treating complex sulfide concentrates. This report discusses the purification of aqueous C12-02 leaching solutions by utilizing zinc cementation to remove Cd, Co, Cu, Ni, and Pb. Additional processing of the purified solution is necessary to produce ZnC12 crystals suitable for molten-salt zinc electrowinning cells. The effects of solution temperature, reaction time, zinc dust concentration, ZnCl2 concentration, and degree of agitation on the removal of impurities were investigated for both simulated and actual leaching solutions. Zinc dust addition to a leaching solution at 30° C decreased the Cd, Cu, Ni, and Pb concentrations to acceptable levels of less than 3 mg/1 each. By increasing the solution temperature to 75° C, the cobalt content was decreased to less than 5 mg/l, an acceptable level for producing electrolytic cell-grade ZnC12. Impurity removal rates from ZnCl2 solutions are Pb>Cu=Cd>Ni>>Co. An increase in the solution temperature increases the rate of removal for these metal impurities.

Jan 1, 1982

By Roberta L. Hudak, Ellsworth R. Spencer, Eric R. Bauer, Adam K. Smith

The National Institute for Occupational Safety and Health (NIOSH) is conducting research with the objective of preventing hearing loss in the mining industry. Longwall mining is one sector that has received considerable attention. Studies involving the monitoring of worker noise exposures, characterizing equipment sound levels and dominant noise sources, evaluating engineering noise controls, analyzing hearing protection device (HPD) effectiveness, and testing of improved sound level monitoring techniques specifically for longwall mining systems, are being conducted. The research efforts revealed that stageloader operators are the most exposed longwall workers, with the discharge end being the noisiest location along the stageloader. In addition, the studies have shown that using stationary dosimeters, coupled with observational data of the cutting cycle and worker habits, has the potential for improved monitoring of the effectiveness of engineering noise controls. To address the ineffective use of soft foam earplugs, a simplified 3-step method was developed for inserting soft foam earplugs. Results indicate a 9 dB greater attenuation after training subjects on the 3-step method. Finally, muff type HPDs are being evaluated for effects of speech intelligibility in noise. The combined results of these studies illustrates that much can and has been done to prevent noise-induced hearing loss (NIHL) in the mining industry, especially with respect to longwall mining workers. This paper presents an overview of ongoing studies, a progress report of results, and the implications for reducing worker noise exposures and preventing NIHL in longwall mining workers.

By D. O. Kennedy

THIS CHAPTER on minor nonmetals covers greensand, meerschaum, mineral wool, and wollastonite. Mineral wool was by far the most valuable material among these minor nonmetals reported in the United States in 1956. GREENSAND Output of greensand (glauconite) declined in 1956. The Kaylorite Corp., Dunkirk, Md., and the Inversand Co., Sewell, N. J., were the only firms that reported production of this commodity. Output came from open pits in Calvert County, Md., and Gloucester County, N.J.

Jan 1, 1958

By W. F. Hughes

The thermodynamics of an electromagnetic field-fluid interaction system is discussed. A review of the thermodynamics of linear media (the permittivity and permeability taken as functions of density and temperature) is presented; then an extension is made to nonlinear media (the permittivity and permeability taken as functions of the fields). Expressions for thermodynamic properties and reversible work are derived and the first law of thermodynamics for magnetohydrodynamic flow is discussed.

Jan 1, 1968

By A. D. Mah

Thermodynamic data on compounds of arsenic and sulfur were critically evaluated by the Bureau of Mines. Changes of standard enthalpy and Gibbs energy, and logarithms of the equilibrium constants were tabulated as a function of temperature for reactions involving these compounds.

Jan 1, 1982

By Lon D. Santis

The Code of Federal Regulations Title 30, Parts 56, 57, 75, and 77 require that detonators and explosives be separated by four inches of hardwood or equivalents when transported together in mines. This standard was developed to protect the explosives from initiation by the more sensitive detonators. The research reported here is an attempt to quantify the fire protection offered by four inches of red oak and other materials. Boxes with a volume of 6.75 cubic feet were made from four-inch thick rough green oak (RGO), two-inch thick RGO plied, two-inch thick #1 common (dried) red oak plied, and a metal/plywood composite. These and boxes meeting the Institute of Makers of Explosives' (IME) Safety Library Publication No. 22 were tested in bonfires. The boxes were instrumented with thermocouples, filled with detonators, and placed over a kerosene fire imparting about 16 kilowatts per square meter heat flux for up to 3 hours. Tests showed that the wood boxes protected the detonators for over an hour with variations between the different trials. In the IME 22 container tests, detonators began exploding in as little as 17 minutes in one test and not for 2-/12 hours in another test. Detonators in the metal/plywood boxes began to explode in about 15 minutes but with minor alterations, were able to contain the detonators. The test results show that the exterior of an IME 22 container significantly affects its thermal properties. Defects in the form of cracks and the manner in which the container is closed have a significant effect on the performance of a detonator container in a fire.

By G. B. Fritts, A. C. Moschetti

"INTRODUCTION The act of Congress establishing the Bureau of Mines in 1910 delegated to the Bureau, as one of its principal duties and functions, the study of health and safety in the mineral industries with a view to devising and putting into operation means of conserving the health and safety of persons employed in the industries. One of the first health and safety activities of the Bureau of Mines was therefore organization of a trained force to promote instruction in first aid in the mineral industries. First-aid training has been an important activity of the Bureau of Mines since its establishment. The standard first-aid course requires a minimum of 15 hours of instruction and practice work. A person completing the initial training course is issued an engraved certificate and pocket card certificate; thereafter, only a pocket card certificate is issued for additional training.From 1910 to 1926 first aid was taught by trained Bureau of Mines employees; consequently, only a comparatively few persons were trained. In 1926, however, cooperative first-aid training was initiated, which provided the means to train the entire personnel of mines or plants within a short time in a single campaign. Many mines and plants have taken advantage of the cooperative plan, whereby keymen in a mine or plant, in addition to the initial training received, are given intensive training in first aid by a Bureau of Mines instructor. Those men who show an aptitude for teaching are selected as tentative provisional first-aid instructors. In order to qualify as a provisional instructor, a tentative instructor must, under the supervision of a Bureau of Mines instructor, train a class of at least six persons employed in the minerals industries in the standard Bureau of Mines course in first aid. After it has been determined that the class has been trained properly, a provisional first-aid instructor's pocket card certificate is issued to the class instructor. The first-aid instructor can renew his pocket card certificate each year by training or retraining at least six persons connected with the mineral industries to satisfactorily pass an examination given by a Bureau of Mines representative. After five yearly renewals of a provisional instructor's pocket card certificate, an engraved, permanent instructor's certificate and a permanent instructor's pocket card certificate are issued to the instructor."

Feb 1, 1955

By Karl R. Becker

Detonators representing a sampling of various domestic commercial delay detonators were fired at various direct-current (dc) firing levels. Results of firings using well-below-recommended firing levels showed marked increases in delay times above the nominal values. There was also a marked increase in variation, to the extent that out-of-sequence firings would be essentially assured in any typical blasting round at these low firing levels. Within the range of recommended levels the effects of current increases were not considered to be of great importance relative to other overriding effects, such as the significant difference noted in average values of detonators from different lots having the same nominal delay. This effect, when combined with the normal variation noted among members from the same lot, would cause out-of-sequence firings with detonators from a neighboring delay period. Where comparisons with results from another study were possible, it was found that both studies observed quite similar variations in delay times about the average values, and a lower probability of out-of-sequence firings for the shorter delay period groups. The criterion of the previous study for assessing the likelihood of observing out-of-sequence firings, when applied to the Bureau of Mines data, properly identified two neighboring delay period groups where out-of-sequence firings would occur.

Jan 1, 1981

"The dust/lung research of the Center has several long-range objectives:* better methods for the early diagnosis of coal workers' pneumoconiosis (CWP);* methods to modify the disease process;* tests to identify toxic products; and* tests to identify individuals with heightened susceptibility to pneumoconiosis.A major immediate objective is to define the mechanism of dust-induced lung disease. This means determining:* dust characteristics that are important in causing lung diseases;* important interactions between dust and lungs; and* earliest detectable stages of the disease.Several of the Center's projects involve exposing lung cells in culture (in vitro) or animal lungs (in vivo) to samples of the suite of characterized mineral dusts described earlier. The responses of the lung cells or tissues to the dusts are being studied in order to better understand how inhaled dusts cause lung disease.One project is studying the effect of dust exposure on the production of mucus by rat tracheal explants in vitro. Mucus is a major factor in clearing inorganic dusts from the lung. Results thus far have shown that exposure of tracheal cultures to coal dust caused a decrease in micin production in comparison to parallel cultures without dust. To examine the effect of in vivo coal dust exposure, rats were maintained in an inhalation chamber for two weeks, and control rats were in an identical, but dust-free chamber. Tracheal explants results indicate that the effect of in vivo dust exposure is similar to that noted in the in vitro experiments.Pulmonary alveolar macrophages (PAMs) are a key component of the lung's response to inhaled particulates, and they play several important roles in pulmonary inflammatory and repair processes. PAMs are the cells that actually ingest dust particles. Other studies have shown that they play a critical role in the development of silicosis and asbestosis. The Center is studying the effect of dust exposure on the release of oxygen free radicals (superoxide) by PAMs. Intercellular production of superoxide occurs when PAMs phagocytize particles, such as inhaled bacteria, and is an essential mechanism by which PAMs kill ingested, bacteria. A number of complex physiological events occur during this process which are not clearly understood. It is thought that PAMs containing indigestible materials, such as mineral dusts, overproduce superoxide, or inappropriately release it into the surrounding tissues. If true, this would cause toxicity to surrounding lung cells by peroxidation of the lipids in the cell membranes. In vitro exposure of PAMs to low or high doses of kaolin is inert. Preliminary studies indicate that coating the quartz particles with a surfactant reduces toxicity."

Nov 1, 1988

"Correlatina Lung Crackle Usina Holographic lnterf erometryAli Afshari, MS, West Virginia University, 1989The Effect or Surfactants on Suppression of Non-Wettable ParticlesAli Alaboyun, MS, Mineral Engineering, The Pennsylvania State University, 1989Geochemical Characterization of Kerogem, ShaJes, and Coal .Refme ~ted with Allegheny Fonnationof Cases of Northern West VirginiaDick Andre, MS, West Virginia University, 1987Particle Concentrations in a Hazelton Inhalation ChamberShahram Bavani, MS, West Virginia University, 1985Use and Potential of Luer Holographic Interferometry and Subsidence Model Study of an Underground.Room and Pillar MineRichard Begley, MS, West Virginia University, 1984Development of a Mechanistic Model for Prediction of Subsidence in a Longwall MineRichard Begley, PhD, West Virginia University, 1990.Redesign of Micro-Orifice Unifonn Deposit ImpactorSteve Behm, MS, University of Minnesota, 1991A Fracture Mechanics Study of Crack Propagation Mechanism in Coal: The Mechanics of Fine FragmentFonnationZ. T. Bieniawski and R. Karl Zipf, Jr., Mining Engineering Department, The Pennsylvania State University,University Park, PA. Final Report, October 1, 1988A Mathematical Model for the Prediction of Ambient Dust Concentrations in Mine AtmospheresR. Bhaskar, MS, Mining Engineering and Operations Research, The Pennsylvania State University, 1984Spatial and Temporal Behavior of Dust in Mines-Theoretical and Experimental StudiesR. Bhaskar, PhD, Mining Engineering, The Pennsylvania State University, 1987Experimental Studies of Dispersion and Deposition of Fane Particles in a Wind Tunnel and Mine AirwayKlaus Bode, MS, Mining Engineering, The Pennsylvania State University, 1991Perf'onnance of the High Yield Technology PM - 100 - Particle 11ux MonitorRobert Caldow, MS, University of Minnesota, 1987Development of Improved Methods for Monitoring and Control of Diesel Particulate in an Underground CoalMineD. H. Carlson, B. C. Cornilsen, P. L. Loyselk, X. Shan and J. H. Johnson, Michigan Technological University,Houghton, Ml. Final Report, June 15, 1991"

Mar 1, 1992

By N. S. Dalal, X. Shi, V. Vallyathan

"INTRODUCTIONThis paper summarizes our recent investigations of the potential role of silicon-oxygen based free radical species in the biochemical mechanism of the lung injury caused by the inhalation of freshly fractured silica. The impetus for this study came from the following observations. Inhalation of crystalline silica is associated with the development of acute and chronic silicosis. Chronic silicosis is characterized by the development of sharply marked concentric fibrotic nodules in the lung. This occurs over a period of several decades with the development of progressive respiratory impairment. In contrast, acute silicosis is manifested by the filling of the alveoli with an amorphous lipoproteinaceous exudate within a short period after exposure, and rapid development of respiratory disability often leading to fatality. Most studies on the pathogenesis of silicosis have focused on the elucidation of cellular mechanisms of cell injury and the development of chronic silicosis. Because pulmonary responses to crystalline silica are distinctly different for · the acute and chronic silicosis, we hypothesized that the acute response is associated with some unique properties of ·freshly formed silica particle surfaces, due to the formation of some reactive chemical species caused by the rupturing or the silicon-oxygen bonds. In occupations involving drilling, tunneling and sandblasting operations acute silicosis can be correlated with this unique surface reactivity of silica. The formation or reactive species was demonstrated, using electron spin resonance (ESR) spectroscopy (Dalal et al., 1986; Fuibini et al., 1987; Hochstrasser and Antononi, 1972). Grinding of quartz crystals under ultra high vacuum (10-10 torr) leads to the formation of Si- and SiO• radicals and these radicals are quenched by exposure to air and other gases (Hochstrasser and Antonini, 1972). ESR signals have also been reported from micronized quartz samples that were evacuated at 413 K (Bolls et al., 1983). In order to find a more direct relationship of such radicals to acute silicosis, we made ESR measurements on quartz dusts freshly ground in ambient air and found- that indeed grinding under ambient environment leads to the formation of the Si• and SiO• type of radicals which decay on storing the dusts in air or in biological buffers (Dalai et al., 1986; Vallyathan et al., 1988). The Si• and SiO radical formation on grinding has also been reported by Fubini et al. (1987). In addition, we recently found that •OH radicals are generated in aqueous suspensions of freshly ground quartz (Dalai et al., 1988; Shi et al., 1988; Vallyathan et al., 1988). We have subsequently carried out detailed cytotoxicity and biological assays on freshly made as well as aged quartz dusts. As summarized below, the results provide new insight into the biochemical mechanism of acute silicosis."

Jan 1, 1988

By Doris M. Hyde

Belize remained relatively insulated from the social and political turmoil that affected some of its Central American neighbors. This stability encouraged new foreign investments that assisted the economy, especially in tourism and agriculture. The mineral sector remained limited to construction-oriented materials. Oil exploration efforts continued by the various concessionaires.

Jan 1, 1987

By George J. Conroy

Techniques for locating trailing-cable faults are discussed, particularly those techniques suitable for use in underground coal mines, which have been the subjects of Bureau of Mines research. The discussion concerns precautions and suggestions for locating faults, rather than detailed descriptions of apparatus.

Jan 1, 1979