Search Documents

By Charles Findlay, Stephen Krickovic

A methane emission rate study was conducted in 1969 on a longwall section of a Lower Kittanning coalbed mine in central Pennsylvania. The longwall face was mined with a drum shearer between developed headings on the head end and headings on the tail end that were driven with a ripper-type continuous miner as needed. The study was conducted over 22 consecutive shifts (7-1/3 days). The average methane emission rate from the Lower Kittanning coalbed during mining at the face and developing the headings at the tail end of the face was 34 cfm. Caving of the gassy overlying strata as the result of mining at the face increased the methane emission to rates ranging from 702 to 1,049 cfm.

Jan 1, 1971

To rapidly limit and interrupt high dc fault currents with minimal arcing in the mine atmosphere. Approach Design a dc switching sys-tem which uses a pressurized, liquid metal-filled, change-of-state device combined with a conventional interrupter and commutating switch. Direct Current Interruption Switching and interruption of large direct currents imposes severe loads on fuses, contactors, and circuit breakers in mine power systems. This problem is much more pronounced with de than with ac because of the lack of a natural current zero in dc. Dc interruption is characterized by persistent arcing that can foul contact tips and con-tribute to interrupter failures. To reduce maintenance and prolong the service life of these units, a commercially viable dc switching system has been developed by the Bureau of Mines through a research contract with the University of Pittsburgh. This system rapidly limits and interrupts high fault currents when used in combination with conventional interrupters.

Jan 1, 1983

By M. J. Ferrante

Relative enthalpies of cuprous iodide (CuI) were measured at the Bureau of Mines to provide thermodynamic data for the advancement of min-eral technology. Enthalpy measurements between 298.15 and 1,396.3 K were made with a copper-block drop calorimeter. The temperatures of transition were measured by differential scanning calorimetry (DSC). Reversible transitions were determined at 643 K with a standard enthalpy of transition [(6Htr)] = 0.74 kca1/mol, at 679 K with a [6Htr = 0.65 kca1/mo1, and at 868 K] with a standard enthalpy of fusion [(6H~) = 1.895 kca1/mol.] Tabulated values are listed at selected temperature increments from 298.15 to 1,600 K for the standard relative enthalpy (HO -H298), heat capacity (CpO), entropy (SO), and Gibbs energy function [-(Go -H298)!T]. The enthalpy data are also given in the form of equations and combined with thermodynamic data from other investigations to derive values of standard entha1pies of formation [(~HfO)], Gibbs energies of formation [(6GfO)], and logarithms of the equilibrium constants of formation (log Kf).

Jan 1, 1987

By T. G. Carnahan

The Bureau of Mines conducted laboratory-scale weathering research on a leach residue containing elemental sulfur and mixed metal sulfides. Experiments were performed to determine pH and impurity element concentrations in the effluents as functions of time and to determine the effects on effluent concentrations of mixing the residue with dolomite tailing material. Four 800-day tests were conducted simultaneously. Soluble metal concentrations, especially zinc and copper, were excessive in the effluents from washed and unwashed samples of the residue. Concentrations of up to 20 g/l of Zn and 12 g/l of Cu were obtained. The pH values of the unwashed and washed residue effluents at the completion of the experiments were 2.8 and 1.9, respectively. Sulfuric acid from oxidation of pyrite caused the pH decrease. Mixing unwashed residue with dolomite tailing to maintain a near-neutral pH minimized the heavy metals content in the effluents. The pH in the dolomite tests increased slowly after the first 360 days and attained values of 7.8 and 8.2, respectively, for tailing containing 1 pct leach residue and for tailing devoid of leach residue. Dissolved zinc and copper did not exceed 0.10 g/l of Zn and 0.001 g/l of Cu.

Jan 1, 1982

By Oscar Lee

"Flotation is generally regarded as a process that is only applicable to metallic minerals. However, its scope is now known to be greater than this, because some of the nonmetallic minerals are floatable, such as graphite, sulphur, and fluorite. Recent observations show that limestone may be added to the list of floatable nonmetallic minerals. Such work is being done on a laboratory scale at the Southern Experiment Station (Tuscaloosa, Ala.) of the Bureau of Mines, Department of Commerce, where experimental magnetic concentration of the low-grade iron ores of the Birmingham district is in progress. Certain experiments have demonstrated that the limestone may be floated from the magnetic log-washer tailing, and then incorporated in the iron concentrate.If the loss of lime could be prevented, some ores though low in iron and high in insoluble contain enough lime to make their concentrates self-fluxing. Since this loss in the magnetic log-washer can not be avoided, the Time must be recovered from the tailing by some method and added to the magnetic iron concentrate before sintering. Then the resulting concentrate will be self-fluxing.While seeking a suitable means of treating the tailing for recovery of lime, flotation was tried. It was at once evident that this method had possibilities, during the early part of the investigation, soap solution made from a common soap was used as a flotation reagent. The froth obtained was a fairly good lime concentrate. This result was an important clue, and led to tests with the use of such reagents as oleic acid and sodium oleate. Later, cresol, creosote, coal tar and other similar flotation reagents were tested in combination with the oleic acid and soap solutions. As a result, oleic acid and cresol used together were found to be satisfactory.The tailing from the magnetic log-washer is in excellent physical condition fur flotation. The iron ore had been ground in a ball mill to 100 mesh for magnetic concentration. Hence the bond between the lime carbonate and the other constituents of the tailing was well broken."

Apr 1, 1926

By W. Blake, J. K. Whyatt, T. J. Williams

Researchers at the U.S. Bureau of Mines collected and analyzed over core measurements and other indicators of in situ stress characteristics at the Lucky Friday Mine, Mullan, ID. An analysis of these data revealed that significant local variations in in situ stress are present in this mine and that these variations existed prior to mining. High stresses were found to be associated with the most competent strata and a locked section of a fault. An estimate of the predominant stress field was developed for mine-wide modeling. The estimate shows that the greatest principal stress was oriented north of northwest. This information should provide a basis for mine-wide structural modeling of the Lucky Friday Mine and should generate important insights into localized stress conditions, which may significantly affect both local and mine-to-mine variations in seismicity induced by excavation.

Jan 1, 1995

By Gregory J. Chekan

In order to reduce waste and improve resource conservation, mine planning, and development, the U.S. Bureau of Mines is investigating multiple seam interactions associated with longwall mining. Longwall gate entry and panel stability have been influenced by previous mining in coalbeds above and below a mine in Virginia that operates in the Lower Banner Coalbed. Directly superjacent, approximately 115 ft, the Upper Banner Coalbed has been partially worked by room-and-pillar mining. Directly subjacent, approximately 730 ft, the Tiller Coalbed has been worked by partial room-and-pillar retreat mining. The study mine has experienced problems during development of gate entries in areas of overmining and undermining. It is anticipated that stress fields associated with adjacent mining may further affect gate entry stability and face advancement during the extraction of the longwall panel. To assess overmining and undermining effects on ground stability, the Bureau gathered geotechnical information at the site. Headgate entries and pillars were instrumented and monitored to study loading behavior as the longwall face approached and passed potential problem areas. Measurements indicate that although increases in average pillar pressure were greater than predicted values, previous mining in adjacent coalbeds had little effect on headgate stability.

Jan 1, 1989

By Maria I. De Rosa

The U.S. Bureau of Mines performed experiments to determine if the primary gas toxicities evolved during the early (-300° C) and later (>400° C) combustion stages of mine conveyor belts could be predicted by a smoke particle characteristic. The experiments were conducted in an approximately 20-L furnace at set furnace temperatures of 150°, 250°, and 1,000° C, with a furnace airflow of 10 L/min. The variables studied, as a function of time, included hydrogen chloride and carbon monoxide concentrations, the average smoke particle diameter (d8 and number concentration (no), and the product of the average smoke particle diameter and concentration (dgn0) Other variables included the sample and furnace temperatures and the sample mass weight loss. Results show that the inverse of the smoke particle diameter-concentration product (ldgn0), correlates directly with the hydrogen chloride and carbon monoxide toxicities released in large quantities during the early and later stages of combustion.

Jan 1, 1989

By Seth C. Schaefer

The Bureau of Mines has determined the standard Gibbs energies (AGf°) of CoS1.035 (cobalt sulfide) and Ni2.515S2 (nickel sulfide) with high-temperature galvanic cells using stabilized Zr02 (zirconia) as the electrolyte. Potential measurements were obtained for the cell Pt, CoS1.035, CoO, S02(g, 1 atm)//Zr02//02(g, 0.0114 atm), Pt, with the overall cell reaction C0S1.035(c) + 1.535 02(g, 0.0114 atm) = CoO(c) + 1.035 S02(g)¬ These results, combined with the best available data for ?Gf° of CoO and S02 from the literature, give the standard Gibbs energy of formation of CoS1.035 for the reaction Co(c) + 0 5175 S2(g) = CoS1.035(c) ?Gf° = -38.890 + 18.87 x 10-3T ± 0.185 kcal/mole (866.0 - 1,104.9 K), where temperature (T) is expressed in kelvins. Similar measurements were obtained for the cell Pt, N12.515S2, NiO, S02(g, 1 atm)//Zr02//02(g, 0.0122 atm), Pt, with the overall cell reaction Ni2.515S2(c) + 3.2575 02(g, 0.0122 atm) = 2.515 NiO(c) + 2 S02(g). Combination of these results with data for ?Gfo of NiO and S02 from the literature yields the standard Gibbs energy of formation of Ni2.515S2 for the reaction 2.515 Ni(c) + S2(g) = Ni2.S1SS2(c) ?Gf° -65.377 + 24.67 x 10-3T ± 0.541 kcal/mole (968.6 -1,053.7 K).

Jan 1, 1981

By A. F. Jolly

As a part of ongoing research into the sulfidation partitioning of selected complex minerals, the U.S. Bureau of Mines conducted research designed to selectively recover Cu from sulfidized chalcopyrite (CuFeS2). Ferric chloride (FeCI3) solutions leached >90 pct of the Cu and <20 pct (sometimes < 10 pct) of the Fe in the sulfidized concentrates. Cupric chloride (CuCI2) leaches were even more selective, solubilizing essentially 100 pct of the Cu and < 5 pct of the Fe. In contrast, leaching non-sulfidized CuFeS2 with either FeCl3 or CuCl2 showed that somewhat more Fe than Cu dissolved. These studies demonstrate that Cu is substantially more leachable from sulfidized CuFeS2 than from nonsulfidized CuFeS2? The Cu-and Fe-bearing constituents generated as sulfidation products, CuS (covellite) and FeS2 (pyrite), respectively, are differentially dissolved. The solubility of Fe from pyrite in sulfidized CuFeS2 is much lower than the solubility of Fe from complex nonsulfidized sulfide where Fe and Cu are bound in the same crystal lattice. Thus, the Cu dissolves selectively, producing a high-Cu filtrate from which Cu can be recovered by cementation or by electrolysis. Flotation of CuS-FeS2 mixtures indicates partitioned phases can be physically separated if effective liberation can be achieved. Magnetic separation tests yielded less promising results.

Jan 1, 1991

By R. C. Hickman

"INTRODUCTION The most productive area of the eastern Virginia pyrite belt lies to the north of the village of Mineral., in Louisa County. The largest producers of pyrite ore in the area were the Armenius, Boyd Smith, and the Sulphur mines.The Boyd Smith mine started production about 1890 and operated more or less continuously until 1922, when competition from the Gulf States and Spain closed the pyrite mines in Virginia. There are no reliable records of production or value of minerals produced.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the most effective utilization of our mineral resources to the end that they take the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, Oliver C. Palston, chief, analyzes samples and performs beneficiation tests.The project was under the immediate supervision of Mitchell H. Kline, chief, Raleigh Division, Mining Branch, Bureau of Mines.LOCATIONThe Boyd Smith property is reached from Mineral, Va., by traveling north on State Route 522 about 2-1/2 miles. An unsurfaced road, winding in a northwesterly direction, loads to the Boyd Smith headframe, which is about half a mile from State Route 522 (fig. 1). The tract comprises 181 acres."

Aug 1, 1947

By Robert A. Jankowski, Ellsworth R. Spencer, Jay F. Colinet

Longwall mining is the most productive method of under- ground coal mining in the United States (U.S.), and record levels of production have been reached in recent years. These ever-improving production levels have the potential to generate significantly higher quantities of respirable dust. Consequently, the longwall industry continues to struggle with controlling dust liberation and maintaining compliance with the federally-mandated respirable dust standard. In response, longwall operators have increased the application of primary dust controls, airflow and water flow, in an effort to improve respirable dust control and reduce worker exposure. Pittsburgh Research Center (PRC) personnel conducted dust surveys at 13 longwalls operating throughout the U.S. and collected information to: identify current operating practices on these longwalls, identify the types of dust controls in use, document the levels at which these controls are being applied, and measure the respirable dust levels present. This data was analyzed to quantify the dust levels generated by the major sources on the longwall section and to evaluate the relative effectiveness of the control technologies in use.

Determine the extent to which remote-sensing techniques, primarily lineament analysis, can be used to identify geologic structures that may affect the location and migration of subsidence over abandoned underground coal mines in the Colorado Springs, CO, area. Compile data using a geographic information system (GIS) to allow efficient and reproducible comparisons and analyses. Background The basis for evaluating abandoned mine land (AML) sites with remote-sensing techniques comes from past and ongoing Bureau ground control research using remote-sensing data to identify potential hazards caused by geologic structures (faults, joints, etc.) above active underground coal mines. Research showed that lineament (linear feature) analysis of Landsat Multispectral Scanner (MSS) images could indicate locations of fractures and fracture trends that had varying, but significant, impacts on the stability of mine openings. Such geologic structures should be identifiable over abandoned mines as well. If fractures are present, even if they arc not faults, they should represent areas of potential instability over these mines and, therefore, should tend to localize subsidence when it occurs, particularly for deep and moderately deep portions of mines.

Jan 1, 1992

By Charles Vaught

This paper discusses the fact that US coal mining organisations are losing the knowledge they need in order to be able to respond to emergencies. The authors note that knowledge management provides a useful perspective from which to view the problem, but that the debate about what constitutes knowledge should be broadened to include a debate about what constitutes management. It is argued here that knowledge is actually shared knowing distributed across group members; that such knowledge can be managed by cultivating it; and that narrative is the medium through which this may be done. The paper then examines NIOSH research that has attempted to use such an alternative knowledge management approach to help potential mine emergency responders better deal with the predicaments they are likely to encounter on-site.

Jan 1, 2006

By L. C. Headley

Surface areas of two synthetic and three natural consolidated porous samples were obtained by the Orr low-pressure permeametry technique. The results suggest that the Orr technique is a useful substitute for the low-temperature gas adsorption (BET) method for determining the surface area of rock samples. It was more rapid than the BET method, and the surface-area values obtained were larger but agreed better with BET values than values calculated from the Kozeny-Carman equation. Efforts were unsuccessful to demonstrate the influence of channel-size distribution on pressure-flow rate curves by means of experimental data and a parallel channel model.

Jan 1, 1971

By Fred N. Kissell

Tracer gas decay curves were experimentally obtained in a full-scale model coal mine working face area. The concentration of tracer gas was found to decay in exponential fashion but with a change in slope. This change in slope is attributed to eddy zones in the face area. A simple theory was developed that allows one to calculate the approximate amount of gas in the eddy zones and thus estimate the size of the eddy zones.

Jan 1, 1974

Locating subsurface conductive solutions is important for many applications, including in situ mining and environmental protection. Drilling boreholes for sampling is expensive and can increase contamination by mixing water from different aquifers. Various noninvasive geophysical methods are available, but previous comparisons were hampered by different methods being used at different sites or at different times. The U.S. Bureau of Mines (USBM) compared methods at one site using the same conductive solution to improve the reliability of the comparisons. Locating deep (> 100 m) solutions is most difficult, SO the USBM selected methods applicable for such depths. Objective Improve the ability to locate subsurface conductive solutions by evaluating and comparing applicable geophysical methods. Approach The experiment was performed cooperatively with other agencies to increase the number of methods studied. The USBM, the University of Arizona, Sandia National Laboratories, and Zonge Engineering and Research, Inc., conducted cooperative field tests of six electromagnetic (EM) geophysical methods to compare their effectiveness in detecting salt water brine of conductivity 3.6 S/m collecting at the water table, 157 m subsurface. The brine was injected through two boreholes. The test site was the University&apos;s San Xavier experimental mine near Tucson, AZ. Geophysical surveys using surface and surface-borehole, time-domain electromagnetics (TEM); surface controlled-source audiofrequency magnetotellurics (CSAMT); surface magnetic field ellipticity, surface-borehole, frequency-domain electromagnetics (FEM); and crosshole FEM were conducted before and during brine injection. A total of 110,000 I. of brine was injected over one week, but the effective target volume of brine was much smaller because of mixing with ground water and dispersion.

Jan 1, 1994

By C. B. Manula, R. L. Sanford, R. A. Rivell

Part I. DATA INPUT ALTERNATIVE 1

Jan 1, 1974

By G. B. Atkinson

Properties of catalysts prepared from intermetallic compound precursors were investigated by the Bureau of Mines as part of its mission to decrease U.S. dependence on foreign sources for scarce catalytic materials, such as nickel, cobalt, and chromium. Methods were developed whereby catalysts with surface areas of 30 to 40 m2/g were prepared from intermetallic compounds. Activity of these catalysts for the methanation reaction and methanol synthesis was deter-mined using a fixed-bed, single-pass, flow-through reactor. Catalysts prepared from rare-earth-nickel intermetallics had specific activity for methanation that was five times greater than that of commercial catalysts and were equal to or better than commercial catalysts with regard to sulfur tolerance. Under identical reaction conditions, catalysts prepared from thorium-copper intermetallics produced more than 10 times as much methanol as a commercial low-pressure catalyst and exhibited a high degree of catalytic stability.

Jan 1, 1982

By L. G. Marsh

The manufacture of lubricating oils from wax-bearing crude petroleums involves the removal and recovery of the paraffin wax contained in the lubricating distillates. During this process several intermediate products are formed, among them the mixture of waxes and oils known to the refiners as "foots oil." Because of its complex character, foots oil is little understood, and therefore methods of handling it in refineries are often inefficient. The Bureau of Mines is studying the manufacture of lubricating oils, and during the work has investigated the redistillation of foots oil. This report gives in brief the results of the investigation, and recommendations based upon it.

Jan 1, 1926