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By D. B. Dow

The appearance of water in an oil field is the forerunner of various difficulties, and probably represents the greatest technical problem that the producer must face. Water conditions bear-directly on the quantity of oil recovered, and the length of the life of a field. Presence of mater increases the cost of operation, for example, gifting costs. On account of the corrosive action of oil-field waters on pumps and other equipment, frequent replacement of equipment is necessary. Furthermore, water may affect the marketability of the oil produced, as detrimental emulsions of water in oil (?B.S.?, "cut oil", etc.) are often formed. The writer has recently completed a study of oil-field emulsions. The present paper deals with the factors responsible for the formation of emulsions. This will be followed by another dealing with methods now utilized for dehydrating oil-field emulsions, and by a third dealing with the physical chemistry involved in the formation and resolution of such emulsions.

Jan 1, 1925

By M. M. Wong

A brief investigation was made to determine the feasibility of electro-refining beryllium in a KCI-LiCI-BeC12 bath. Thin, platelike crystals of beryllium metal were produced by electrolyzing technical-grade beryllium metal beads (about 94-percent purity) as the soluble anode. Operating cell conditions were: Temperatures of 450° to 600° C.; an inert atmosphere; bath compositions of (1) 38.1 mol. percent KC1, 54.8 mol. percent LiCl, and 7.1 mol. percent BeC12 and (2) 36.7 mol. percent KC1, 52.7 mol. percent LiCl, and 10.6 mol. percent BeC12; cell voltages of 0.30 to 0.80; and initial cathode current densities of 50 to 435 a./sq, ft. Current efficiencies ranging from 87 to 96 percent were obtained. Qualitative spectrographic analyses of the metal products indicated that impurities were reduced. This technique offers the possibility of producing a grade of beryllium purer than that now generally available, which may have better mechanical properties.

Jan 1, 1960

Water infiltration control techniques are designed to reduce the total volume of water entering an underground mine, and thus, reduce the volume of mine water discharge During the development of underground mines, water may be encountered in various quantities This water must be pumped from the mine during active mining, and in many situations, the weight of water removed will be more than the total weight of mineral extracted After abandonment of the mine, infiltrating water either floods the mine workings or discharges from the mine (27, 127) Infiltrating water may enter underground mines from above, below, or laterally through adjacent rock strata Earth fractures such as faults, joints, and roof fractures resulting from surface subsidence are commonly primary causes of water entrance Into abandoned underground mines Factors affecting the quantity of water entering a mine will be the depth of the mine, location of water bearing strata, and ground water flow patterns Investigations of the quantity of water entering underground coal mines have found the average rate of infiltration to range from approximately 6,262 to 10,280 liters per hectare per day (670 to 1,100 gal/acre/day) (27) Water flowing through underground mines flushes pollutants from the mine and may result in their discharge to the environment A reduction in the amount of flow usually results in a reduction in total pollution load discharging from the mine The techniques discussed in this section can be used to reduce the volume of surface and groundwater available to enter the mine system and transport pollutants The selection of a control technique will depend upon the characteristics of the mine system and the expected cost effectiveness of the technique In order for water infiltration control to be effective in controlling mine drainage pollution, the reduction in mine water flow must not be accompanied by an increase in concentration of pollutants (127) REFERENCES 2, 27, 51, 58, 127, 132

Jan 1, 1975

By S. P. Sandoval, A. E. Clark, S. W. Yopps, J. S. Gomer

The U.S. Bureau of Mines conducted Cu exchange tests for six common clays under simulated in situ leaching conditions. Regression equations were obtained from the data expressing the Cu exchange capacity as a function of Cu concentration, pH, and temperature. Using these equations, an analysis was made of the impact each clay could have on overall Cu recovery. The results suggest that Ca and Na montmorillonite clays could have a major impact on Cu recovery and that attapulgite and illite clays could have a smaller, but still significant, impact. Kaolinite and ripidolite clays pose little threat to loss of Cu from in situ leaching solutions.

Jan 1, 1992

By James H. Russell

The Bureau of Mines, U.S. Department of the Interior, in cooperation with the Department of Energy, has attempted to increase the activity of nickel catalysts for converting synthesis gas, derived from coal, to a substitute natural gas. This report describes the effects of low-level additions of B, Ca, Ce, Co, Mn, Mo, Pd, Re, Ti, Y, Zn, and Zr on the methanation activity of Raney nickel. The methanation rate at 320° C and the resistance to poisoning by 2 ppm H2S were used to compare catalysts. The effects of the additions were small, and the experimental variances were large, necessitating the use of statistical methods to identify significant effects. Co, Ti, Y, and Zn improved the resistance to H2S poisoning, but only Co improved the methanation rate In some individual catalysts containing Ca, Mo, or Mn, both the methanation rate and resistance to H2S poisoning were improved.

Jan 1, 1980

By Ramie H. Thompson

1.1 BACKGROUND In many underground coal mining operations the use of electromagnetic field equipment, particularly communication systems, not only increases the overall efficiency of the mining operation but can be directly linked with mine safety considerations. The use of electromagnetic field producing equipment in underground coal mining operations can only be expected to grow. Several new communication systems have already been proposed. In addition, high-frequency producing equipments for many diverse uses in mining operations are under study. The use of these equipment in underground mining operations is hampered by the possibility of their electromagnetic fields interacting with the electric blasting cap operations commonly carried out in the mines. Such interactions can have at least two results bearing directly on mine safety: o premature initiation of the cap, either in its normal shot location or during hookup or transportation; o dudding of the cap so that normal firing operations do not cause irritation; thereby leaving unexploded high explosives after normal firing. Since the consequences of a premature initiation could, particularly in coal mines operations, result in catastrophe involving human life, the overall approach to prediction of possible hazard must be, as far as possible, of a "worst case" nature. The general problem of predicting possible RF hazards for any electroexplosive device (EED) is best treated by reference to Appendix A of

Jan 9, 1983

By Frank E. Cash

Since ventilation adequate in quantity as well as quality is of paramount importance to the health and safety of men working underground in coal mines, mining officials, employees, and State inspection departments should give it the closest possible attention. MINING LAW OF ALABAMA The law governing, and regulating the operation of coal mines in Alabama was enacted in 1911 and amended or revised in 1923, 1925, 1930, and 1935. The original law and subsequent revisions were progressive steps in safeguarding the health and safety of underground employees.

Jan 1, 1939

By Ivan F. Avery

The design productive capacity of natural-gasoline and cycling plants in the United States on January 1, 1960, was 54.6 million gallons per day, according to the Bureau of Mines biennial survey. This represents an increase of 5.8 million gallons per day during the 2-year period since the last survey. The major increases occurred in Louisiana, Oklahoma, New Mexico and Texas. In Utah, natural gasoline capacity was reported for the first tine at 320 thousand gallons per day as of January 1, 1960. The total number of plants increased from 584 on January 1, 1958, to 596 on January 1, 1960. However, the operating plants decreased from 558 to 555 in the same period.

Jan 1, 1961

By J. H. Field

Capital and operating costs have been estimated for removing sulfur dioxide from flue gases of a powerplant of 12,000-kw. capacity by liquid-purification processes, using limestone, ammonia, or sodium sulfite as the reactant. The annnonia and sodium sulfite processes yield end products that may be marketable. Coals containing about 1.5 and 5.0 percent sulfure have been considered. The sulfur dioxide content of the gases to be treated is 0.083 and 0.30 percent, respectively. Estimates have been made for 90-percent removal of the sulfur dioxide from both gases. A third instance has been considered in which 70 percent of the sulfur dioxide is removed from the flue gas of 0.30-percent concentration. The scrubbed gas would contain 0.09 percent sulfur dioxide, which might be within the permissible limit for discharge to the atmosphere in most areas. Although it is unlikely that flue gases with sulfur dioxide concentrations of less than 0.10 percent would require purification, a cost estimate for such a gas is included because an estimate is available for a British plant employing the limestone process at these conditions. Capital investment and operating costs, with no credit for products, are lowest for the limestone process for gases of both concentrations. Crediting the ammonium sulfate and sulfur produced in the ammonia process at their market prices at the end of 1956 of $32 and $28 per ton, respectively, the operating costs of the ammonia process become the lowest for purification of the gas containing 0.30 percent sulfur dioxide. The operating costs of the sodium sulfite process for purifying gas of high sulfur dioxide content approach those of the limestone process when the byproduct sulfur dioxide is credited at $14 per ton. Even if credit for products is allowed for the ammonia and sodium sulfite processes, the operating costs are higher than those of the limestone process for the gas of low sulfur dioxide content. Because of the large quantity of materials that would be produced by removing sulfur dioxide from a relatively small number of plants, credit for products should be allowed with extreme caution.

Jan 1, 1959

By Michael D. Fenton

Detailed comprehensive assessment of the performance of Afghanistan's mineral industry during 1987 is virtually impossible, owing to the paucity of reliable published information. It was evident, however, that the level of civil disorder, now in its eighth year since the arrival of significant numbers of Soviet troops, was in actuality little removed from open civil war. Insurgents controlled substantial areas of the country and imperiled any industrial activity in many places. Assistance programs by the U.S.S.R. and other Eastern European nations were directed at developing the country's meager mineral industry, but the economy was generally viewed as chaotic. The inflation rate was somewhere between 20% and 30%; major food shortages contributed to the discontent of the population, and numerous villages were devastated by Soviet and Afghan Government campaigns to destroy the insurgents and cut their supply routes. Moreover, proposals by the Soviets and the Kabul Government aimed at reducing tensions with the rebels and scaling down the warfare seemingly were taken by the opposition as signs of weakening by the Soviet-backed Government, and rather than reducing aggressions, seemed to heighten insurrectionist activities. Efforts to entice the substantial number of Afghans who have fled to nearby areas of Pakistan and Iran to return to their country seemingly were failures, and indications near yearend that the Soviet Union might soon begin withdrawal of its occupation force of nearly 120,000 did little if any to reduce disorder.

Jan 1, 1989

By Bradley V. Johnson

The Bureau of Mines constructed a microminer--a scaled-down (5-by 5- by 11-foot) continuous-mining machine of the drum type with a unique triaxially controlled head--for use in a research program to study the effects of continuous-mining-machine parameters on the generation of respirable dust. This report describes field research with the microminer at the Bureau's Experimental Mine at Bruceton, Pa. Experiments were conducted to determine the effects of depth of cut, rotational speed, and sump and shear rates on the generation of respirable dust. The cutting forces were also monitored and compared with depth of cut. There appears to be a reduction in the amount of respirable dust generated when the depth of cut is increased or rotational is speed lowered, Variation of other machine parameters seems to have little effect on dust generation.

Jan 1, 1975

By Peter F. Steidl

As part of the Bureau of Mines methane control program, the Upper Free-port coalbed was studied in Fayette County, Pa., where this coalbed lies about 650 feet below the Pittsburgh coalbed and contains the largest remaining reserves of any coalbed in the county. Coal and overburden isopachs, structure and joint pattern maps, and a fence diagram were prepared using data from gas and oil exploration logs and coal outcrops. These maps will aid in deter-mining the need and/or feasibility of degasifying the Upper Freeport coalbed in the study area. Much of the coalbed in this area is under 600 to 1,400 feet of overburden. By correlation with data from the Pittsburgh coalbed, the gas content at depths of this order is estimated to be between 140 to 300 cf/ ton of coal, for a total of 190 to 400 billion cubic feet of methane in this coalbed in Fayette County.

Jan 1, 1977

By C. H. Elder

Coal degasification boreholes drilled from the surface have been success-fully hydraulically stimulated to increase the flow of gas from the coal. This Bureau of Mines report describes the hydraulic stimulation procedure for a coalbed, the equipment required, and design criteria for the treatment. Three examples of stimulation treatment show from fivefold to twentyfold increases in gas production. The tests were conducted in the Pocahontas No. 3 coalbed, Buchanan County, Va., the Pittsburgh coalbed, Washington County, Pa., and the Mary Lee coalbed, Jefferson County, Ala. Two sites where the coal was hydraulically stimulated and exposed by subsequent mining show no adverse effect on mining operations through the treated zones. The induced vertical partings were confined to the coalbed and did not in any way affect either roof or floor rock.

Jan 1, 1975

By David W. Houseknecht

Probabilities of encountering coalbed discontinuities during vertical or horizontal drilling in a specific coalbed can be estimated based on analysis of mined-out areas of the coalbed where the size, shape, orientation, and distribution of discontinuities are known. The result-ant probability estimates can be applied to cost-risk evaluations of drilling programs proposed for exploratory, developmental, or methane drainage purposes in undeveloped areas of that coalbed. Data compiled from mine maps of the Beckley Coalbed in southern West Virginia were used to estimate the probabilities that discontinuities would be encountered in two illustrative hypothetical drilling programs--one for drilling vertical boreholes and the other for drilling horizontal boreholes. Analysis based on a mined-out area of the Beckley Coal bed indicated that vertical methane drainage boreholes spaced 1,000 feet apart in a square grid pattern would each have a 29 percent probability of encountering a discontinuity in a geologically unexplored area of the coalbed. It was also determined that exploratory vertical drilling could locate most of the discontinuities if a borehole spacing of 2,500 feet were used. For horizontal drainage boreholes in the Beckley Coalbed, the analysis indicated a linear relationship between hole length and the probability of encountering a discontinuity.

Jan 1, 1982

By R. E. Head, Virgil Miller

"INTRODUCTIONRecent investigations at the Intermountain Experiment Station of the Bureau of Mines at Salt Lake City indicate that metallurgists have given little attention to the occurrence of jarosite minerals in the oxidized ores of lead and silver. These investigations have also emphasized the importance of knowing when these minerals occur in the oxidized ores, especially those containing lead, silver, and gold, as their presence is a material factor in selecting a suitable kind of treatment. Since the question of the occurrence of jarosites in oxidized ores has come to the attention of the Bureau of Mines, investigation has indicated that plumbojarosite and argentojarosite are quite common. These two minerals appear to be widely distributed and probably escaped recognition by persons who had attempted to treat certain oxidized lead ores in which the jarosite minerals represented a material portion of the metal content.Consideration of the physical characteristics of the jarosites also indicates that in many cases failure to treat some of the oxidized lead ores with success has been directly due to the fact that the greater portion of their lead and silver content was present as plumbojarosite and argentojarosite. The data and the description of these minerals given in the body of this paper indi¬cate that attempts to recover lead and silver from ores in which appreciable amounts of the metals occur as plumbojarosite and argentojaeosite would be unsuccessful if confined to gravity methods of concentration. There are un-doubtedly considerable tonnages of oxidized lead ores in the various mining regions of this and other countries, and it is quite probable that in some of these ores the metal content of lead and silver may be largely anglesite (lead sulphate) and cerussite (lead carbonate) but that they will also contain cerargyrite (silver chloride), argentojarosite, and plumbojarosite. The treatment of such ores therefore presents an important problem, since a product is discarded from ores from which the recoveries of lead and silver have been below 70 per cent which is probably too low-grade to warrant aftertreatment by any process now in use."

Apr 1, 1928

By Edward L. McHugh, Charles Sabine, Jami Dwyer, David G. Long

Slope failure accidents were responsible for about 12% of U.S. surface mine fatalities between 1995 and 2003. Small surface movements on a mine highwall may be precursors of failure that, if detected, could provide sufficient warning to enable workers and machinery to be withdrawn to safety. Radar interferometry offers the necessary precision to detect these movements. Radar has some advantages over other methods in its ability to cover large surface areas for true two-dimensional monitoring day and night under almost any weather condition. Radar’s active transmit/receive mode of operation provides for more direct sampling than do passive optical methods that depend on solar illumination. Improvements in microprocessor speeds and capacities have led to the development of a number of small, portable, ground-based systems; such systems are now being deployed at several locations around the world. As part of an ongoing study of monitoring technologies, researchers from the National Institute for Occupational Safety and Health and Brigham Young University, Provo, UT, cooperated to assess the feasibility of using interferometric radar to monitor mine slope stability. Field tests of a device incorporating prototype equipment were successful in that small, centimeter-scale displacements on rock slopes were detected.

Jan 4, 2006

By B. S. Covino

The Bureau of Mines, U.S. Department of the Interior, is conducting research to devise substitute corrosion-resistant materials by using ion implantation to form alloyed regions near the surfaces of metals. These alloys were prepared by implanting 25-kev Cr+ and/or Ni+ ions into iron. Their resistance to corrosive attack was evaluated by determining their anodic polarization behavior under potentiodynamic conditions in a solution containing sodium chloride, boric acid, and sodium borate. These electrochemical studies have shown that the general corrosion resistance of ion-implanted alloys was comparable to nominally equivalent bulk alloys. The pitting-corrosion resistance of the ion-implanted alloys was superior to that of iron, although not as good as that of most of the bulk alloys tested.

Jan 1, 1980

By M. B. Cooke

An analytical method for the determination of the gum-forming material in gasoline has been developed by the Bureau of Mines, during a study nor in progress to determine the best rays for elimination of such constituents from gasoline. This method is similar in principle to that previously described by Smith end Cooke,2 which involved evaporation of e sample of gasoline in a small glass dish. The evaporation was started on an actively boiling steam bath and completed in an air oven at 105°C. In the improved method described below, the stem bath has been replaced by a steam heated oven in which an inert atmosphere is maintained. Air is excluded from the oven, consequently the precision of the determination is increased. Furthermore, evaporating dishes different from those previously described may be used.

Jan 1, 1925

By Bernard Porter

Differential thermal analysis measurements were used to characterize a phase diagram for the KF-YF3 system at compositions between 0 and 60 mole-percent YF3, A congruent melting point compound was observed at 3KF?YFs, which melts at 965°±5° C and undergoes solid-state decomposition at 725°±2° C. One peritectic and two eutectic compositions are also defined.

Jan 1, 1969

By A. W. Henderson

The growing importance of halide metallurgy for preparing high-purity metals has stimulated research to extend halogenation reactions to the direct extraction of metals from low-grade sources. This Bureau of Mines investigation involves a pioneering study of chlorination reactions in the presence of a fluorine donor. Tin slags containing tantalum and columbium and a zircon concentrate containing a relatively high ratio of hafnium to zirconium were studied. Direct chlorination of these materials at 500° C. yields only a 5-percent conversion of tantalum and columbium or zirconium and hafnium to anhydrous chlorides. This investigation showed that small additions of calcium fluoride to the reaction increased the recovery of tantalum and columbium to 95 percent and the recovery of zirconium and hafnium to 27 percent. These results were achieved with ratios of calcium fluoride to mineral or slag of only 0.2. Silica, the major impurity in the materials studied, was found to be converted to silicon tetrafluoride during chlorination in direct proportion to the quantity calcium fluoride added to the charge. However, large additions of calcium fluoride decreased the volatility of the resulting halides of tantalum, zirconium, and hafnium. Smaller amounts of calcium fluoride also favored recovering minor metal constituents in the zircon concentrate (uranium, thorium, and rare earths).

Jan 1, 1962