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By L. B. Pankratz, R. Barany, W. W. Weller

Experimental determinations were made of the heats of formation at 298.15 ° K of cuprous ferrite and cupric ferrite ; the heat capacity of cuprous ferrite was measured over the temperature range from 50 ° to 298 ° K and the entropy at 298.15 ° K was evaluated ; the heat contents of cuprous ferrite and cupric ferrite above 298.15 ° K were measured to 1,500 ° K and 1,100 ° K , respectively . These thermodynamic values were combined with other pertinent data to obtain heat and free energy of formation values at high temperatures . The stability of the two ferrites with respect to their constituent oxides is discussed . Thermodynamic values are included for the decomposition of cupric ferrite to form cuprous ferrite , magnetite , and oxygen .

Jan 1, 1964

By Robert E. Barieau

This report gives the principles of the method used by the Helium Research Center of the Bureau of Mines when solving nonlinear-regression problems and contains the mathematical equations necessary to accomplish the following objectives: the evaluation of the parameters in such a way that the sum of the weighted squares of the residuals of an experimental observable is a true minimum, regardless of the functional relationship between the variables and these parameters; and the evaluation of all variances and covariances of the parameters by means of the usual approximation of the law for the propagation of errors.

Jan 1, 1967

By R. V. Ramani, K. V. K. Prasad, M. Swaminathan

"Engineering design involves, in addition to numerical calculations, considerable amount of expertise and judgement. The expertise and judgement is required to conceptualize and idealize the problem, select a suitable mathematical model for the problem and to interpret the model results in terms of stipulated design constraints. In recent years, knowledge based systems (KBS) have provided the capability to integrate the qualitative experiential and expert knowledge with ~he quantitative knowledge for improved analysis and design of systems. A possible KBS architecture for mine ventilation system design was discussed by Ramani and Prasad · (1987). The expert system (ES) component of the KBS supports the analysis and interpretation phases of the ventilation design process with an algorithmic program used for the solution of alternate designs. The purpose of this paper is to discuss the data and knowledge needs for developing such a system and a formal means of their representation on the computer. A number of ES shells were evaluated to explore possible development and delivery environments for the system. A brief summary of this evaluation is also provided.INTRODUCTIONLuxbacher and Ramani (1979) have discussed the design process of mine ventilation systems and have provided the interrelationships that exist between ventilation, strata control, drainage and material handling systems and mining methods. They have also outlined the importance of correct analysis of the problem, choice of the right solution method and a rigorous interpretation of the solutions. The expertise required for analysis and interpretation phases was identified as the key element in developing effective and efficient ventilation system designs. Such expertise is embedded in the right choice of questions to be asked of the user as well as in directing the user to a wide array of alternative methods that may satisfy the design requirements. With advances in artificial intelligence applications in recent years, particularly expert systems, the integration of expertise into traditional mine planning and design algorithms has been facilitated. These planning and design aids, employing the integration of numeric and symbolic logic and called coupled systems, are powerful tools for engineers to tap the benefits of experts (Kitzmiller and Kowalik, 1985; Fenves, 1985). The purpose of this paper is to discuss the means of representing knowledge for the design of mine ventilation systems through the use of a coupled system. The KBS is visualized as consisting of the following components:"

Jan 1, 1989

By W. W. Adams

Three hundred and twenty-eight mines and quarries, representing 36 States, took part in the twelfth yearly accident-prevention contest conducted by the United States Bureau of Mines and known as the National Safety Competition. Four underground mines and one open-cut mine (which represents the quarry and open-cut mine group), each the leader in its group, were awarded the ?Sentinels of Safety? trophy. Relative standing in the contest" was determined by the number of days lost from accidents in proportion to the total number of man-hours worked. Since 1925, when the National Safety Competition was inaugurated, an increasing interest has been taken in it by mining and quarrying companies as a means of stimulating mine and quarry safety by competition among similar plants. Each participating plant can, on a basis of its standing and record in the contest, determine to what extent its safety program is succeeding or to what extent it needs strengthening. With this information, each company that has a low standing in the contest can intensify its safety-promotion efforts the following year to obtain a lower rate and possibly win the trophy or achieve honorable mention in the competition. Except for 1929, the National Safety Competition of 1936 represented more man-hours of employment than any other year since the yearly contests began.

Jan 1, 1937

By C. R. Bopp, N. A. C. Smith

"For a period of several years, beginning with 1915, there has been a continuous change in the quality of motor gasoline. The average volatility has decreased, this to the fact that higher boiling fractions of the crude oil have been included in the gasoline. This change in quality was made necessary by the tremendous increase in the demand for motor fuel, caused by the development of the motor car, and during the war was an absolute necessity to avoid gasoline shortages. The Bureau of Mines has kept in close touch with this situation by making surveys from time to time of the gasolines sold throughout the country, as this information is of value to manufacturers and users of motor cars and also indicates when any changes are required in the Government specifications. The Bureau has just completed a gasoline survey and is in a position to make public the fact that there has been very little change in the quality of motor gasoline in recent months.During the period from January 17 to February 3, 1920, 81 samples of actor gasoline were collected by representatives of the Bureau of Mines in seven districts of the United States. The cities selected for this survey were New York, N. Y., including Brooklyn; Washington, D. C.; Pittsburgh, Pa.; Chicago, Ill.; New Orleans, La.; Salt Lake City, Utah; and San Francisco, Cal., including Berkeley. In every case the samples collected were taken in such a manner as to represent material actually being sold as motor fuel, and to include samples from each refinery marketing in the district."

Jan 1, 1920

By Benjamin W. Haynes

Analytical procedures are described for the quantitative determination of 16 elements (As, Ba, Be, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sb, Se, TI, and Zn) and 7 ionic species (NH4, C032-, CI-, F-, NO3-, P043-, SO42-), identification of major and minor mineral components, and measurement of physical properties associated with manganese nodules and nodule processing reject waste materials. Compound identification methods discussed include X-ray diffraction, infrared spectroscopy, scanning and transmission electron microscopy, selective area electron diffraction, and optical and reflected light microscopy. Methods for elemental analysis include atomic absorption spectrophotometry, inductively coupled plasma emission spectroscopy, neutron activation analysis, fluorescent X-ray spectrography, and ion chromatography. Thermal gravimetric analysis, ultraviolet-visible spectrophotometry, ion specific electrodes, and standard wet chemical procedures are briefly discussed. Physical properties determined in manganese nodule materials include grain size distribution, specific gravity, triaxial shear, permeability, maximum density, Atterberg limits, and slurry density. The results of a round-robin analysis of an ammonia process waste material and manganese nodule standards demonstrate the applicability of the discussed methods. Tests discussed for the evaluation of the waste materials for disposal options include the Environmental Protection Agency (EPA) EP toxicity test, the ASTM shake extraction test, and the U.S. Army Corps of Engineers EPA seawater elutriant test.

Jan 1, 1983

By Herbert H. Fields

The Bureau of Mines has been promoting health and safety in mining since its establishment in 1910. One area of research covers methane control in coalbeds; this report describes a multipurpose borehole used for both degasification and the production of commercial-quality gas. The multipurpose borehole was drilled into a barrier pillar, and seven horizontal degasification holes and one pressure point hole were drilled radially out from its perimeter. On January 28, 1974, after 505 days of degasification, a compressor was installed to the exhaust stack of the multipurpose borehole (1), and pipeline--quality gas was introduced into a commercial pipe-line. As of February 4, 1975, over 171 million cubic feet of gas had been purchased by the gas company. The in situ pressure at a depth of 200 feet into the coalbed and the average gas flow and water flow from the degasification holes as they were completed and closed off were 203 psig, 1,200,000 cfd, and 6.8 gpm, respectively. Twenty-four hours after the seven holes were connected through individual pipes to the atmosphere, the total gas and water flows and the in situ pressure dropped, respectively, to 971,000 cfd, 1.3 gpm, and 18 psig. Five hundred days later, the corresponding values were 620,000 cfd, 0.15 gpm, and 10.5 psig. Daily flows have been as high as 800,000 cfd, and as low as 360,000 cfd, during the last 500 days. On February 4, 1975, after 882 days of degasification, 576 million cubic feet of gas had been removed from the Pittsburgh coalbed; apparently a much larger area of virgin coal is being degasified than is defined by the holes. This study indicates that horizontal boreholes drilled into a coalbed from the bottom of any shaft will effectively remove gas from the Pittsburgh coalbed,

Jan 1, 1975

By B. W. Madsen

Research by the Bureau of Mines has shown that treatment of open pit waste by crushing and sizing followed by flotation of the fines and leaching the coarse fraction results in greater metal recoveries than obtained by leaching only. Tests with a chalcocite-bearing quartz monzonite mine waste sample that had been crushed to minus 6 inches and screened on 1/2 inch yielded copper and silver recoveries of 71 and 22 percent, respectively, by the combined flotation-leaching process, compared with 48 percent of the copper and no silver recovered leaching the run-of-mine material. Copper was more readily leached from the coarse material with the minus 1/2-inch fines removed than from material with the fines included. The improved leaching was attributed to improved permeability and the associated improved circulation of air to the interior of the ore column. Cost estimates showed that the proposed intensive treatment of mine waste will require a greater capital investment and higher annual operating costs than conventional milling and dump leaching process. However, the income from the additional metal production offsets the increase in capital investment and operating costs, resulting in additional profit.

Jan 1, 1975

By A. B. Coates

During the last three years the use of ethylene glycol dinitrate4 (E.G.D.) as at low-freeze (L.F.) agent in place of nitropolyglycerin has become common in the manufacture of explosives of the dynamite type. The usual proportion of D. G. D. in the explosive "oil" is 25 per cent; the remainder, 75 per cant, is regular nitroglycerin. These proportions were probably selected as a continuation of the practice of 25 per cent nitropolyglycerin and 75 per cent regular nitroglycerin.

Jan 1, 1929

By Gary E. Sherman

To aid the U.S. Army Corps of Engineers in their Resource Development Navigation Study of ten existing or proposed port sites in Alaska, the Bureau of Mines examined the potential for mineral development around three Alaska port sites: Iliamna Bay, Kotzebue, and Nome. The mineral deposits near Iliamna Bay include gold, copper, and iron. Development of minerals in this area will require the discovery of new deposits or the definition of additional are reserves at known deposits. The mineral deposits near Kotzebue are primarily gold, copper, coal, lead, and uranium. Based on the character of these deposits, it appears that development of a small-scale mine supplying coal for regional use is the most likely scenario in the near-term. The mineral deposits near Nome are primarily gold and copper. Development of small underground gold mines is possible, however it appears that expanded offshore gold dredging will have the greatest impact on the flow of freight and goods through the Nome port in the near term.

Jan 1, 2011

By R. B. Ladoo

"Present Situation:At the beginning of 1920 a general feeling of optimism was noted in many talc-producing districts. The industry seems to have recovered from the temporary depression of the first half of 1919 and many mills are running at capacity production with their entire output for 1920 contracted for. The imports of talc for 1919 were only slightly larger than in 1918 by weight and probably no more by value. Thus foreign competition has not begun to be seriously felt. Several new companies in this country have been organized, some to operate new deposits and others to continue the work done by others.An interesting phase of the present situation is the possibility of increased use of talc in paint. There is a shortage of barium sulfate used as a paint filler. Since, for some uses, talc is considered second only to BaSo4 as a filler for paint, it is possible that part of the shortage could be relieved by an increased use of talc.A series of physical tests upon all pigment materials used in the manufacture of paints is being conducted for the Paint Manufacturers Association of the United States. It is important that all types of talc be represented in these tests. Producers of finely ground talc, 200 mesh and finer, are urged to submit samples of at least two pounds each of these grades that are available to paint makers with trade name and quality data, to the Institute of Industrial Research, 19th & B Streets, N. W., Washington, D. C., where the tests are being conducted."

Jan 1, 1920

By A. T. Coumbe

This compilation of statistics covering competitive fuels consumed for heating of residential and commercial buildings is in response to numerous requests for data of this nature to show the relative changes in the demands for the different fuels in recent years. The figures presented cover the amounts of various fuels ant electric energy reported as used for heating dwellings and commercial buildings. However, the totals for gaseous fuels and electricity necessarily include amounts consumed for both cooking and lighting purposes, as these associated household uses could not be readily broken out. [ ] SOURCES OF FUEL AND POWER STATISTICS Liquid fuel: Mineral Market Reports of the Bureau of Mines covering annual Pales of fuel oil and kerosine. The fuel oil figures include grades 1 to h, reported as sold for space heating. Kerosine and grade 1 fuel oil delivered as range oil ore also included. Gaseous fuel: "Gas Facts" published by the Bureau of statistics of the American Gas Association. Thin source was used as It is believed that the data shown are representative of the actual market

Jan 1, 1953

By W. J. Fene

It is often desired to obtain samples of air in places where collection by ordinary methods is not feasible, as in shafts amore means of descent or ascent are not provided, in sewer manholes, in gas or water wells, in empty oil tanks, and in sealed areas in mines. Heretofore, when such sampling was required, it was necessary to utilize the aspirating method, which was not always satisfactory; and to obtain samples of air in deep shafts, it was necessary to use long sections of rubber tubing, which was not always available. DESCRIPTION OF NEW DEVICE A new method or "device" employs a common snap-type mousetrap to break the neck of a vacuum tube at the place where it is desired to collect the sample (see fig. 1). A mousetrap is mounted on one end of a block of wood 11-3/4 by 3 by 3/4 inches in such camper that a lead weight attached to the trigger hall spring the trap when the device is given a sharp jerk. A vacuum tube is placed on the other end of the block and held in place by a strong rubber band. A strip of corrugated rubber is placed on each side of the grooved block to prevent the tube from clipping when the sample is taken. An adjustable shoulder, provided with a rubber cap, is pieced se that the neck of the vacuum tube will rest on it. The shoulder is made adjustable to accommodate various sizes of tubas and to keep the neck of the tube from breaking tee far back from the point. A metal handle is fastened to one end of the block, with a hole in the end through which the brass wire used for lowering the device is tied. The device is enclosed by a strong wire-gauge covering, hinged on one side and so arranged that it can be locked shut on the other side. This covering prevent: breaking of the tube while it is being lowered or raised in a shaft or other place. Brass wire of not less than 22 gage should be used for lowering the device. A detailed drawing of the device is shown in figure 2.

Jan 1, 1940

By A. H. Warner

Sphalerite crystals occur sparingly in minor faults and pockets in a coarsely crystalline dolomite on the Brown-Tipton farm near Greenville in Greene County, Tenn. After several visits by U. S. Bureau of Mines engineers and U.S. Geological Survey geologists, a survey was r: the in the fall of 1944. Upon their recommendations, trenches on the Brown farm under Bureau of Mines supervision. In each case, the bed most favorable for zinc deposition was exposed. In the finished trench bottoms no zinc minerals are visible.

Jan 1, 1950

By H. H. Schrenk, Carlton E. Brown

"INTRODUCTION The angle at which a hole is drilled has long been thought to affect the amount of dust disseminated into the air during wet drilling. The amount disseminated has been reported as increasing rapidly with the approach of the angle of the hole to the vertical (up) position. 4/ This has been explained commonly as being caused by a decrease in contact of water with the face of the drill hole; increase in amount of sludge dropping through the air; and increase in amount of sludge running down the drill steel and being thrown into the air by the rotation of the drill steel and by leakage of air from the front head of the drill.The steep up angles of the holes drilled are responsible, at least partly, for the higher dust concentrations found in such places as raises, compared with those at level faces, where most of the holes are drilled at angles farther from the vertical (up) position. The mining industry is coming to realize more and more the importance of the angle of the drill hole as a contributing cause of the high dust concentrations found in some raises. Much work is being done to counteract the effect of the angle of the drill hole on dust dissemination. The rate of rater flow through drill steels is being increased by the use of water tubes of larger diameter or by higher water pressures to obtain better contact between water and the face of the drill hole. Traps are being developed to catch the sludge from the drill hole and allow it to drain down through a special pipe before it drops through the air or runs down the drill steel. Drills that permit little or no air to leak from the front head along the drill steel are being designed and used. Care is being taken to prevent the exhaust from the drill dispersing the sludge into the air."

Feb 1, 1938

By K. O. Bennington

The thermodynamic properties of aegirine, of composition [(Na0.869Fe30+7362 Fe20+16Mn0.03Ca0.1121)(A10.141Sil 9738)(06)], were experimentally determined at the Bureau of Mines as part of its efforts to advance minerals technology. The standard enthalpy of formation determined by hydrofluoric acid solution calorimetry is AHf298 = -641.12±0.73 kcal/mol. The standard enthalpy of formation from the oxides is AH298 = -37.136±0.509 kcal/mol. Low-temperature heat capacities were determined by adiabatic calorimetry from 19.1 to 304.6 K. The derived standard entropy is S298 = 38.03±0.14 cal/mol?K. The heat capacity was measured over the range 348 to 1,198 K by differential scanning calorimetry. These experimentally determined data were combined with data from the litera¬ture to calculate the Gibbs energies of formation and equilibrium constants of form¬ation over the temperature range of the measurements. Standard enthalpies of forma¬tion are given as functions of temperature. The standard Gibbs energy of formation at 298.15 K is AGf298 = -600.36 kcal/mol.

Jan 1, 1984

By Charles H. Shapiro

[In July, 1924, the Bureau of Mines, through its Petroleum Experiment Station, undertook a field study of methods used in oil-field shops for dressing and tempering fishtail bits. The purpose of this work was to suggest chances that would be helpful to the bit-dresser in turning out better treated, harder, and tougher bits, and thus cut down the excessive loss of time caused by too frequent changing of bits. It was the intention to eliminate as much as possible the guess work connected with dressing and tempering bits under the method of judging temperature by eye, by developing; practical methods of controlling temperature. If there were some possible means of accurate temperature control, then it would be an easy matter to bring all bits to the proper temperature for maximum hardness rued toughness, thus doing away with the source of most of the trouble experienced in the present method of bit tempering. Shortly after the Bureau of Mines began its study, a chop In the Stroud, Oklahoma, oil field announced method for tempering fishtail bits that Would increase the drilling footage of each bit treated. The method accurately regulates, by the use of a bath of molten salt, the temperature to which a bit is heated before being quenched to produce hardness. There is nothing new in using silt baths for the, heat treatment of steel, but this was the first attempt to introduce it into the oil fields for use in hardening bits, and for this purpose it proved to be admirably adapted. In tempering, by the old system it is not possible to measure the temperature of the heated bit by means of an electrical instrument for that purpose, whereas this is an easy matter with the now method. If heating steel to slightly above the critical point rind quenching suddenly will bring out its best properties, their here is a method of accurately bringing the steel to that point.]

Jan 1, 1925

By J. F. Messerly

The purity of three specially prepared samples of benzene was determined with an adiabatic, low-temperature calorimeter with automatic control of shield temperature. Extensive measurements were made on each sample to determine how variations in operating procedures affect melting-point and freezing-point as well as purity data obtained by the calorimetric method. Detailed results of the investigations are presented, and effects of different operating procedures are discussed, together with problems encountered in interpretating experimental results.

Jan 1, 1963

By Terry J. Close

In 1985, at the request of the U.S. Bureau of Land Management, the U. S. Bureau of Mines studied part of the 56,623-acre South McCullough Mountains Wilderness Study Area (NV-050-435) in order to evaluate its identified mineral resources. The area studied is located in Clark County, NV, about 30 miles southwest of Boulder City. No mineral resources were identified. The study area contains the eastern part of the unorganized McCullough Mountain (McClanahan) mining district which has had no recorded production. Between 1911 and 1982, 23 lode claims were located in the part of the mining district that is in the study area; four of these claims are currently held by assessment (1986). A total of 11 mineral sites were found and examined during the U.S. Bureau of Mines investigations; 26 mine workings were examined. Of the 11 sites, four are within the study area, and seven are nearby. Of the seven nearby sites, six are adjacent to the west boundary and consist of precious-and base-metals bearing vein occurrences in metamorphic rocks. The seventh site is near the east study area boundary, and consists of a tungsten-bearing vein occurrence that is also in metamorphic rocks. The four sites within the study area consist of vein occurrences in metamorphic rocks that contain silver, gold, arsenic, lead, zinc, and copper. The veins at these four sites are too small and low grade to be classified resources; however, there are indications that three of the sites may have silver and gold resources at depth. Detailed delineation of the veins, and determinations of tonnages and grades are needed. This would entail additional mapping and sampling, trenching and drilling, and opening inaccessible workings.

Jan 1, 1987

By F. P. Haver

Because of increasing concern with air pollution, the Bureau of Mines has developed a hydrometallurgical procedure to obtain elemental sulfur from chalcopyrite (CuFeS2) by means of the following reaction: CuFeS2 + 3FeCl3 ? CuCl + 4FeCl2 + 2S. Under optimum conditions, 99.6 percent of the copper and 71.6 percent of the iron were extracted in 2 hours from a typical mill concentrate containing 75 percent CuFeS2 and 15 percent pyrite (FeS2). At the same time, 68.2 percent of the sulfur in the concentrate was oxidized to the elemental form. The leach was highly selective; gangue minerals, including pyrite, were not attacked, thus accounting for the relatively low recoveries of iron and sulfur. To obtain these results, the concentrate was ground to 98.9 percent minus 325 mesh, and 300 grams was treated with 1 liter of boiling ferric chloride (FeCl3) solution. The FeC13/CuFeS2 ratio was 2.7. Cement copper containing 99.9 percent copper was recovered from the leach solution by cementation on sponge iron. Excess iron, dissolved during leaching and cementation, was removed from the stripped solution by crystallization. Ferrous chloride (FeCl2?4H2O), obtained as a byproduct, was converted to high-purity ferric oxide (Fe203) and HCI by an oxidizing roast. The hydrochloric acid was then electrolyzed to obtain chlorine, which was used to regenerate the leach solution. The leach residue, which contained ~50 weight-percent elemental sulfur, was treated with an organic solvent to recover the sulfur and cyanided to reclaim gold and silver.

Jan 1, 1971