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By Maria I. De Rosa

The U.S. Bureau of Mines performed experiments to determine the hydrogen cyanide (HCN) concentrations and smoke particle characteristics during the combustion of flexible polyurethane foams and other nitrogen-containing materials, for the development of a test parameter. The experiments were conducted in an approximately 2O-L furnace at set furnace temperatures of 250° and 1,000° C for a 14-min duration, with an airflow through the furnace of 10 L/min. The variables studied as a function of time were the gaseous and aerosol HCN concentrations, the smoke particles average diameter (dg) and particle concentration (no), and the product of the smoke particle diameter and concentration (dgno). Carbon monoxide, carbon dioxide, and oxygen concentrations, sample mass weight loss, and furnace temperatures were also studied; analyses of nitrogen and cyanate content of the material were carried out. Results show that dgno correlates directly with the HCN concentrations, which depend on the nitrogen and cyanate contents of the material.

Jan 1, 2010

By N. S. Dalal, X. Shi

"This study reports a new property of the important NAD(P)H-dependent flavoenzymes, glutathione reductase, lipoyl dehydrogenase and ferredoxin- NADP oxidoreductase, that can catalyze a one electron reduction of metal ions such as chromium(VI) and vanadium(V). During the enzymatic reduction process, molecular oxygen is reduced to H2O 2 , which reacts with the reduced metal complexes to generate hydroxyl radicals. Since the hydroxyl radicals have been suggested to play an important role in Cr(VI) toxicity, this study provides a basis for a recent observation that Cr(VI) mutagenesis is strongly oxygen dependent. These results also point to an enzymatic pathway for the metabolism of some metal ions and concomitant generation of hydroxyl radicals. l. INTRODUCTIONThe purpose of this communication is to report that some important NAD(P)H-dependent flavoenzymes (glutathione reductase, lipoyl dehydrogenase and ferredoxin-NADP+ oxidoreductase) can catalyze one electron reduction of metal ions such as chromium(VI) and vanadium(V) and simultaneously reduce molecular oxygen to generate Hi02 and, eventually, the ""OH radical. This finding is significant because (i) the known substrates for the flavoenzymes are organic species and not metal ions, and (ii) the report on the enzymatic formation of the ""OH radical provides a new pathway for understanding the mechanism of genotoxicity of some non-ferrous metal ions. For example, it has been suggested that OH radical is likely to be the major species responsible for Cr(VI) genotoxicity [1-5). The 'OH radical is generated through the reaction of Cr(V) complexes with cellular Hi02 [4,5]. Cr(V) itself is known to be generated from Cr(VI) in various biological systems, in particular, microsomes [ 6), mitochondria [7] and mitochondrial electron transfer chain complexes [8]. However, no specific enzyme responsible for the Cr(V) generation has been identified except possibly glutathione reductase [4]. In this study we have used ESR and spin trapping techniques to show that the flavoenzymes can generate Cr(V) and provide a catalytic redox cycle for 'OH formation in such reactions. Herein we present our results on Cr(VI) and summarize those on other systems. Correspondence address: N.S."

Jan 1, 1990

By Charles L. Parsons, R. B. Moore, S. C. Lind, O. C. SCHAEFER

Early in 1912, from information received by the Bureau of Mines, it became evident that quantities of valuable radium-bearing ore from Colorado were being exported for manufacture in foreign coun- trics and that at least part of the manufactured product was being returned to this country and sold at a price entirely incommensurate with that received by the miner and the prospector. Consequently, in line with its efforts to increase efficiency in the mining and treat- ment of mineral resources, the Bureau of Mines undertook an inves- tigation of conditions. Results of this preliminary investigation were published, in the summer of 1913, as Bulletin 70, which gave an out- line of the radium deposits of the West, the conditions of mining, the wastes involved, and the status of the production of radium from its ores. At about this time newspapers and medical journals were publish- ing statements regarding the value of radium in cancer therapy. These reports, although many of them were exaggerated, brought out clearly the remarkable virtue of the gamma rays for the treat- ment of cancer and other malignant growths. In view of the fact that the largest known supplies of radium ore in the world are in the States of Colorado and Utah and on the public lands of the United States, it was deemed highly important for the Bureau of Mines to study the production of radium in detail. Such study, it was hoped, would enable the prospector and miner to obtain a fairer price for the ores and would furnish information necessary in case Congress appropriated funds to develop methods for extracting radium from ore on the public lands under Government supervision, to be supplied at cost to the hospitals of the Army, Navy, and Public Health Service.

Jan 1, 1915

By Frederick C. Trutt

A guide to the development and utilization of an interactive mine-power-system fault program (Z-bus by algorithm) is presented. Theoretical foundations, as well as implementation considerations are discussed with respect to the mine-power system. Alternative Kron reduction techniques are presented along with a triangular-storage method for storage conservation. Program capabilities include the analysis of balanced and unbalanced (line-to-line, line-to-ground, and line-to-line-to-ground) fault situations using symmetrical component theory. To account for phase shifting in delta-wye transformers and zero-sequence network constructions, transformer and load configurations are specified by the user. The positive-and zero-sequence connections needed for network conformity are automatically constructed with the required impedances.

Jan 1, 1979

By S. M. Runke

The pegmatite investigations at the Rapid City, S. Dak., Experiment Station during; the pact 3 years have been primarily a study of recovering beryl from nonlithium-bearing pegmatite rock by continuous-testing methods. Beryl concentrates containing 25 to 88 percent beryl were produced from rock that ranged in beryl content from 0.1 to 2.5 percent. The beryl recovery ranged upward from 70 percent but averaged better than 80 percent. Although promising results have been obtained with flotation methods for upgrading these concentrates to standard specifications, additional work is needed to improve and simplify the procedure. In addition, it was demonstrated that several potentially useful coproducts could also be recovered from pegmatite rock. The principal coproducts were mica, feldspar, and quartz. A heavy-mineral product also was made from pegmatites containing tin, tantalum, and columbium. The recovery if these minerals in products meeting the specifications of the commercial users has been reserved for future study. The investigations also included studies on extraction of beryllium from both high-grade beryl and flotation concentrates of medium beryllium content. The procedure investigated consisted of sintering beryl or beryl flotation concentrates with limestone, acid curing the resulting sinter with sulfuric acid to dissolve the beryllium, and water leaching to extract the beryllium. Over 90 percent of the beryllium was extracted by this procedure. Most of the optimum conditions and quantities of reagents were determined for dissolving the beryllium. As aluminum and iron also were taken into solution by the acid, further research is needed on methods of recovering high-grade beryllium salts from the solutions containing these elements.

Jan 1, 1957

By J. A. Organiscak

The U.S. Bureau of Mines investigated the relationship of bituminous coal seam parameters and the amount of airborne respirable dust generated at longwalls. Dust and coal samples were obtained from 20 longwalls operating in geographically representative coalfields throughout the United States. Statistical analyses of coal seam parameters and airborne respirable dust measurements indicate a likely causal relationship between seam type and respirable dust. Low-ash, high-volatile coal seams were associated with higher airborne respirable dust levels. A negative linear correlation (significant at the 95-pct confidence level) was observed between the seam's ash content and airborne respirable dust, explaining up to 18 pct (R2 = 0.18) of headgate dust level variation and up to 15 pct of tailgate dust level variation. Volatile matter was found to have a positive linear correlation with tailgate dust level, explaining 16 pct of the variation. Further data examination indicates that these relationships with dust are most likely nonlinear, because of improved R2 values over the linear correlations. However, a notable portion of longwall dust production is influenced by other operational parameters, so additional research under more controlled conditions is needed to determine the seam's causative functions.

Jan 1, 2010

By Donald E. Redmon

This Bureau of Mines report reviews injury experience in the nonmetallic mineral industries (except stone and coal) for 1966-67. For each of the years, 23 tables summarize disabling work injuries by department, source of injury, extent of disability, part of body injured, and nature of injury. Correlative information on employment, worktime, and operating activity is also presented.

Jan 1, 1973

By William H. Schiffbauer, Ph. D. Mowrey

Proximity warning devices can improve workplace safety by alerting workers when they are in a hazardous area near moving equipment. Industrial work sites often present extreme challenges to safety-based proximity warning devices. Many commercially available types of proximity warning sensors and systems can be rendered useless when covered with mud, ice, snow, ore, rock, and other material. The list includes radar, ultrasonic, capacitive, and visual types of sensors and systems. Addressing these shortcomings, NIOSH personnel have developed a patented active proximity warning system called HASARD (Hazardous Area Signaling and Ranging Device) which employs lowfrequency, low-power magnetic fields which are quite impervious to severe environmental conditions. A shapeable wire loop antenna which provides the marker of dangerous work areas, has been mounted on a continuous mining machine and was mounted inside 1.3-cm thick angle iron. This loop antenna was exposed to more than six months of active underground coal production, which included being covered by and scraped over with tons of rock, sprayed by a continuous stream of water, and immersed in thick mud. After six months the loop antenna showed signs of wear, but was still capable of performing its intended function. The HASARD system is now being applied to other industrial applications and is showing much promise, especially in harsh environments. This paper details the system, describes the tests that have been done, and mentions other areas where it can benefit the safety of industrial workers.

By A. W. Fahrenwald

The logic leading to the development of the experiments in this paper already has been stated in Part I,3 but is briefly as follows: The results of the batch-grind experiments in which time of "grind" and fineness of finished product were the variables, strongly indicated (1) that batch grinding involving a single grind could not be operated under any condition to give maximum mill efficiency, (2) that the, sieve analysis of the feed charge in the mill materially affected the efficiency of the mill, and (3) that the percentage of finished product in the mill is a vital factor in ball-mill efficiency. A laboratory closed-circuit grind technic designed to simulate present closed-circuit grinding suggested itself, in which: a ball mill and a classifier constitute the grinding unit. The features of the closed-circuit grinding system are: (1) Short large diameter mills, (3) rapid flow of pulp through the mill, (3) continuous automatic removal of finished product from the system, and (4) high circulating loads. The high circulating load is a result if the short length of the Mill - that is, of the time the charge remains in the mill - and the small percentage of finished material produced during each circuit of the feed through the mill.

Jan 1, 1930

By Arthur L. Miller

Recent studies suggest that trace metals emitted by internal combustion engines are derived mainly from combustion of lubrication oil. This hypothesis was examined by investigation of the formation of particulate matter emitted from an internal combustion engine in the absence of fuel-derived soot. Emissions from a modified CAT 3304 diesel engine fueled with hydrogen gas were characterized. The role of organic carbon and metals from lubrication oil on particle formation was investigated under selected engine conditions. The engine produced exhaust aerosol with log normal-size distributions and particle concentrations between 105 and 101 cm-3 with geometric mean diameters from 18 to 31 nm. The particles contained organic carbon, little or no elemental carbon, and a much larger percentage of metals than particles from diesel engines. The maximum total carbon emission rate was estimated at 1.08 g h-1, which is much lower than the emission rate of the original diesel engine. There was also evidence that less volatile elements, such as iron, self-nucleated to form nanoparticles, some of which survive the coagulation process.

Jan 1, 2007

By D. I. Bleiwas

The Bureau of Mines determined demonstrated tin resources and costs associated with tin production in order to evaluate the potential for tin production from 18 market economy countries (MEC's). Data were collected from tin producers, in most cases during on-site visits. The analyses evaluated the relative economic and resource position of 146 mines, deposits, or regions in January 1984 dollars. The demonstrated resource of recoverable tin within the nations studied is approximately 2.8 million metric tons (mt). Of this total, over 73 pct is recoverable from the Southeast Asian countries of Malaysia, Thailand, and Indonesia, which in 1983 accounted for almost 60 pct of the world's tin production. Brazil has joined the Southeast Asian countries as a major low-cost, high-volume supplier of tin and is likely to continue to expand its production. Given the 1984 market structure, over 60 pct of the tin in demonstrated resources was economically recoverable. Historically, the International Tin Council (ITC) has helped maintain relatively stable tin prices through a buffer stock and sales quotas. In late 1985, exhaustion of buffer stock funds led to suspension of tin trading on the world's major tin metal exchanges.

Jan 1, 1986

By C. H. Riggs

This report describes the development, oil recovery, and potentialities of productive formations in the Hall-Gurney field, Russell County, Kans. It is presented as part of a general program to aid and promote increased recovery from petroleum reservoirs. The report is based on studies of well logs, drill cuttings, and oil-and water-production histories of individual wells and leases. The geological interpretations follow closely those in published literature with only slight local modifications. Oil and water analyses, made at a Bureau of Mines research center, were supplemented by many analyses obtained from oil-producing and service companies. The Hall-Gurney field, in south central Russell County, Kans., (fig. 1) was discovered in 1931 but was not developed extensively until 1941. By 1960 the rate of oil production from the field had declined to the extent that many wells were abandoned. In some areas natural productive forces have effected good recovery. However, in other areas inefficient waterflooding, both natural and accidental, has adversely affected recovery potentialities.

Jan 1, 1963

By M. J. Kovalik

Lower Sunnyside seam coal from Utah was blended with various proportions of char and high-temperature coke to improve the quality of the coke obtained from carbonizing this coal. The Hanson 5-pound carbonizer was used as a "screening test" for the larger scale Bureau of Mines-American Gas Association (BM-AGA) tests, which were correlated with industrial production. Eighteen carbonization tests were made in the BM-AGA 13-inch retort, with a coal charge of about 90 pounds; the cokes were evaluated by the standard ASTM tumbler test. Carbonization of blends containing char and coke breeze yielded less fissured and blockier cokes of significantly higher ASTM I-inch tumbler indices as compared with the value for the straight Sunnyside coal. It was found that the simultaneous addition of char and coke breeze yielded stronger cokes than that obtained by the addition of either one of these additives. Addition of a small proportion of Pocahontas No. 3 or Sewell coal to an optimum blend improved the resulting coke strength further.

Jan 1, 1969

By D. Bienstock

A rig was constructed to burn 100 to 125 lb of coal per hour at 4,000° F in a cyclone burner with oxygen-enriched air preheated to 1,500° F to ascertain the problems in the coal-fired MHD generation of power. Potassium carbonate was added to the coal at several concentrations up to 1.23 g-moles/kg of coal (17 lb K2C03/100 lb coal). Boiler-tube materials maintained at wall temperatures of 800° to 1,500° F were exposed to the combustion effluent of 1,800° to 2,500° F. Practically complete removal of sulfur dioxide from the stack gas was achieved with the seed addition. Nitric oxide formation followed theoretical expectations at combustion temperatures with some decomposition of the NO occurring as the gas cooled flowing through the system. Nitrates in the fly ash were less than 1.7 percent of the total fixed nitrogen. With aqueous extraction of the fly ash a maximum recovery of 75 percent of the potassium was obtained. Haynes 25 was unattacked at a wall temperature of 1,500° F in combustion gas at 2,500° F; the stainless steels 310, 316, and 446 were resist-ant at a metal temperature of 1,100° F in gas at 2,100° F.

Jan 1, 1970

By Raja V. Ramani, Sachin Shankar

"Re-entrainment refers to dislodgement of particles deposited by both atmospheric and nonatmospheric processes and their subsequent insertion into a flowing field. Formation of sand dunes, snow drifts, soil erosion and fugitive dust emissions are a few examples of the natural occurrence of re-entrainment. Re-entrainment studies have been done for the estimation of potential hazards from nuclear fallouts. The phenomenon of re-entrainment has been utilized for the cleaning of wafers and filters. Re-entrainment is associated with both surface and underground mining activities. However, studies on dust re-entrainment in mine atmospheres are limited. Understanding the re-entrainment phenomenon is important because dust particles lying seemingly harmless on the ground and adhering to numerous surfaces can get re-entrained and become a health and safety hazard.There are significant differences in the kind of re-entrainment encountered in underground mines and those in other fields of interest. These major differences are air velocity, direction of air flow, particle size, amount of particles, and time of exposure. While numerous studies have been done in other fields to identify the role of interacting variables and their contribution to the mechanisms of re-entrainment, no similar reported work is available for dust in mine atmospheres.In this paper, recent research efforts on re-entrainment are reviewed. The most suitable form of representing re-entrainment in underground coal mine atmosphere is presented. Various approaches to studying re-entrainment phenomenon in mines are also outlined.In the mineral industries, formation of dust particles of widely varying sizes is a natural outcome of the fragmentation required in mining the solid resources. Fine particles in mine atmospheres, particularly in the respirable size range, are a threat to the health and safety of the miners when present in high concentrations. In 1980 the National Academy of Sciences (NAS) Committee on the Measurement and Control of Respirable Dust in Mines recommended that the spatial and temporal characteristics (of fragments produced in coal mining) need to be understood so that the exposure of workers to the dust can be controlled. Recently several studies have been performed to understand the fundamental behavior of the airborne respirable dust in mine airways (Bhaskar, 1987; Qin, 1988; Polat, 1989; Bode, 1990)."

Mar 1, 1992

By F. E. Block, Stephen D. Hill

The necessity for measuring radiation dose is encountered in studying both the beneficial and damaging effects of ionizing radiation on materials . It is also necessary to know the radiation dose absorbed by the reactants in order to evaluate the efficiency of reactions or processes that are promoted by radiation . Thus , a significant effort was made at the Albany cobalt 60 facility to investigate techniques by which the exposure radiation dose can be determined . Methods including ferrous sulfate , ceric sulfate , and methyl methacrylate chemical dosimeters , ion chamber dosimetry , and an absolute radiation calorimeter were investigated . Isodose curves were constructed for several standard source configurations using the dosimetry techniques which were investigated .

Jan 1, 1964

By J. E. Tiffany, Z. C. Gaugler

An active list of permissible explosives was published in December 1943 as part of the Bureau of Mines Report of Investigations 3736 under the title "Active List of Permissible Explosives and Blasting Devices Approved Previous to June 30, 1943." This list included 180 brand names. Changes in the list that have been authorized to December 31, 1945, placed 10 additional brands of permissible explosives on the active permis- sible list as a result of tests and changes in brand names.. Twelve permis- sible explosives were transferred from the active. to the inactive list. The present list contains 178 brand names. The brand names of the permissible explosives placed on the active list are as follows: American 3-A By test. Apcol No. 1-B Do. Black Diamond No. 11-B DO. Black Diamond No. 55 DO. Coalite G-1 DO. Coelite K-1 Do. Do. Coalite L-1 Coalite IS-1 Columbia B-2 DO. By change in name. By test. Monobel AA The permissible explosives transferred from the active to the inactive list are as follows: Anthracite B, L. F. Big Red No. 8 Independent No. 1, L. F. Independent No. 2, L. F. Independent No. 3, L. F. Independent No. 4, L. F. Independent No. 5, L. F. Independent No. 9, L. F. Independent No. 9-C, L. F. Independent No. 10, L. F. Independent No. 11, L. F. King No. 9

Jul 1, 1946

By P. T. Brooks

Semipilot scale tests were made to demonstrate a newly developed electrorefining process which could be extrapolated to commercial scale in producing high-purity nickel and cobalt from crude nickel metal and high-grade ferronickel. The new process comprises application of solvent extraction techniques to remove and separate cobalt and iron from nickel and the electrodeposition in diaphragm cells of pure nickel and cobalt from chloride-based purified electrolyte. Using water insoluble organic amines, the solvent extraction operations enabled production of commercial-sized nickel and cobalt cathodes of higher purity than that of commercial electrolytic metals. The solvent extraction operation for separation of cobalt from nickel was made simpler than the conventional method. Furthermore, the solvent. extraction operation for iron removal made possible the electrorefining of ferronickel without the prohibitive loss of nickel resulting from the method ordinarily used for iron removal.

Jan 1, 1970

By William H. Pomroy, Annie M. Carigiet

This U.S. Bureau of Mines publication is an analysis of underground coal mine fire incidents occurring in the United States during the 15years from 1978 through 1992. The fire data used in this analysis were obtained from U.S. Mine Safety and Health Administration mine fire investigation reports. Fires were analyzed by year, State, coalbed thickness, mine size, mining method, ignition source, burning substance, location, equipment involved, detection method, time of day, time of year, number of injuries and fatalities, method of extinguishment, and evacuation measures taken. In all, 164 fires are included in this report, or an average of 10.8 fires per year. The most fires occurred in West Virginia, Kentucky, and Pennsylvania, respectively. However, the fire incidence rates for these States, expressed as the number of fires per million tons of coal mined, were the lowest, second lowest, and fourth lowest of all underground coal producing States. The most common ignition source was electricity; the most common burning substance was coal; the most frequent fire location was the belt entry; the most common equipment involved in fires was the conveyor belt; and the most common extinguishing agent was water.

Jan 1, 1995

By E. R. Bauer

Noise-induced hearing loss (NIHL) continues to be a concern of the mining industry. A new noise standard (30 CFR, Part 62) is aimed at reducing NIHL in mining through engineering and administrative noise controls. However, the difficulty and expense of implementing engineering controls can make administrative controls an attractive alternative for reducing worker noise exposure. Over the last three years, the National Institute for Occupational Safety and Health (NIOSH) has conducted worker noise exposure surveys in underground and surface coal mines and in coal preparation plants. The surveys revealed numerous possible administrative controls and an approach to implementation and analysis. The surveys have shown that worker dosimetry, time-motion studies and equipment noise profiling are important aspects of effectively utilizing administrative controls. A description of the approach for selecting, implementing and evaluating administrative controls and a list of possible administrative controls are reported.

Jan 1, 2007