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By Zhisong Chai, Wei Xu

Q&P steels undergo continuous multiple processes, including hot rolling, intermediate heat treatment, cold rolling and continuous annealing etc. The inheritant effect of initial microstructure could affect the final microstructure and mechanical properties of Q&P steels. In this work, effects of different hot rolled microstructure/texture on the final microstructure and properties subjected to Q&P process were investigated in Fe-0.38C-1.58Mn-1.6Si system. Different initial microstructures were generated combing different TMCP and cooling strategies. The microstructure and texture of hot rolled materials were characterized in detail. The hot rolled material was subsequently processed by intermediate annealing, cold rolling and continuous annealing. The comparison reveals great effects of the initial hot rolled microstructures, i.e. inheritance effect. The faster reverse transformation would lead to more sufficient austenitization and it would greatly weaken the inheritant effect of the initial microstructure. Although the difference of final phase fraction for different initial microstructures was not significant, the inheritance effect was mainly reflected in the effect on austenite morphology. For the mechanical properties, no obvious difference in strength was shown for the samples with different initial microstructures after Q&P heat treatment, but there was fluctuation in elongation.

Oct 1, 2019

By Thomas Germershausen

Worldwide BOF-based steel plants are faced with demanding environmental requests and rising energy costs. For cleaning of primary gases from the BOF the scrubbing technology is worldwide adapted. For wet-scrubbers there is a direct relation between pressure loss and achievable clean gas dust content. Subsequently main energy consumers within Gas Cleaning Plants are the driving fans. To evaluate actual performance and to identify optimization measures extensive field measurements at existing Gas Cleaning Plants were performed. The operational results from various BOF plants worldwide will be presented and benchmarked. As a conclusion, advanced control strategies for reduced energy consumption and lower environmental impact were developed and implemented.

Jul 30, 2018

By Marcela Gotelip Barbosa

Pellets are the main iron input to the blast furnace at ArcelorMittal Lazaro Cardenas iron and steel making facility in Mexico. Pellets are made at this facility using the concentrates generated and shipped from their captive mines viz., Las Truchas, Pena Colorada, Volcan Sonora. The concentrating plants, after grinding the ore to the liberation size, use magnetic separation and flotation to reject the silica, sulphur and phosphorous impurities. At Volcan Sonora Mines, the ore is contaminated with phosphorous minerals, and hence, after magnetic separation, the phosphate minerals are floated using anionic carboxylate collector (sodium oleate). Apart from floating the phosphate minerals, the sodium oleate also has some tendency to smear on the iron bearing mineral surfaces leaving a hydrophobic surface, which is expected to reduce the green pellet strength due to absorption of ultrafine sized air bubbles on these surfaces, and further generate higher levels of dust during the induration process. In order to alleviate this industrial problem, comparative studies were carried out on the concentrates from magnetic separation using reagents from synthetic sarcosinate and carboxylate family collectors. Results have indicated that the sarcosinate family members not only were found as replacement to carboxylate collectors, but also reduce the phosphorous content below the values achieved with oleate, thus have considerable benefits in the downstream steel making process. Based on the results, plant runs are being taken up at Volcan Sonora. In this article, the laboratory results obtained on iron grades and recoveries, and phosphorous rejection using both the reagents are presented.

Aug 1, 2018

By Rogerio Martelli

Rolamentos autocompensadores de rolos são a normalmente aplicados em caixas de mancal de Correias Transportadoras nas industrias de mineração. Um dos problemas enfrentados pelos usuários são as repetitivas falhas de rolamentos aplicados nestas posições. Na SKF descobriu-se que os rolamentos autocompensadores de rolos vedados são a melhor aplicação para resolver os problemas típicos encontrados nestes equipamentos. A solução fornecida, nestes casos, é o que a SKF chama de Tríplice Barreira de Proteção, que tem como objetivo combater a principal causa de falhas que é a contaminação por partículas minerais e na presença de umidade. Em uma mina de cobre do Peru esta solução foi implementada e totalmente padronizada para todas as correias transportadoras e os resultados alcançados superaram as expectativas.

Oct 30, 2017

By Francisco Morganti

Weight reduction is the main target of all carmakers, which results in a continuous development of new steel grades. Latest 3rdgeneration advanced high-strength steel grades (AHSS) are complex materials with special chemical compositions and multiphase microstructures. The pickling, annealing and galvanizing processes of these grades aresomewhatdifferent due to the changed chemical compositions and microstructures. Therefore, these innovative steel grades place new demands on the plant technology of pickling, annealing and galvanizing lines. The most significant challenges for the pickling process are sludge occurrence during pickling, varying pickling times, weld ability of the materials, changed visual appearance and required high surface qualities. The most important topic concerning annealing line is a precisely controlled and very flexible heating and cooling process in the furnace.One of the new requirements in galvanizing linesis the prevention of surface faults caused by bare spots, which can occur since these materials feature a higher content of alloying elements like silicon or manganese. Prevention is possible with the special pre-oxidation technologies.Due to the higher strength of the material also the mechanical equipment has to be designed differently in these lines. This paper describes the influences of the changed chemical composition and material characteristics of modern steel grades on the pickling, annealing and galvanizing process and gives an overview about the technical solutions.

Oct 30, 2017

By Samuel Filgueiras Rodrigues, Clodualdo Aranas Jr., Gedeon Silva Reis, Eden Santos Silva, Fulvio Siciliano

When austenite is deformed above the Ae3 temperature, partial amount of it transforms dynamically into ferrite by a displacive mechanism. After unloading, it retransforms back into the stable austenite by a diffusional process. This influences the rolling load which decreases under isothermal condition or does not increase with decreasing temperature as rapidly as expected under cooling. Plate rolling simulations under isothermal and continuous cooling conditions were carried out on a 0.09 wt.% Nb X-70 steel. Pass strains of 0.2 were employed together with interpass times of 10 s, and 30 s for the cooling conditions and 0.3 with interval of 10 s at 900 °C for the isothermal experiments; strain rate of 1 s-1 was used during the simulations. The mean-flow-stress (MFS`s) behavior of both conditions indicates that dynamic transformation and dynamic recrystallization were taking place during straining. The critical strains for the initiation of dynamic transformation fell around 0.06 while the critical strain for DRX was 0.12. It has been shown that ferrite is formed due to the applied deformation of roughing passes and increases its volume fraction throughout the finishing rolling stage. Under cooling conditions, the ferrite formation is also favored as the temperature approaches the Ae3 line. Such ferrite forms when the driving force for dynamic transformation is higher than the total free energy barrier preventing its formation. This obstacle consists of the free energy difference between austenite and ferrite as well as the lattice dilatation work and shear accommodation work. The addition of Nb retards the retransformation of the ferrite into austenite. Moreover, holding times after rolling increases the amount of austenite available for microstructure control on subsequent stages. The dynamic transformation (DT) mechanism can be used to design improved rolling schedules

Oct 1, 2019

By Edmar de Souza Silva, Antonio Augusto Gorni, Emanuelle Garcia Reis, Daniel Bojikian Matsubara

Controlled rolling followed by accelerated cooling, known worldwide as TMCP, aims to increase mechanical properties without toughness deterioration. The process principle is to promote the plate cooling with water jets along the range of the austenite transformation temperatures. The accelerated cooling process is only fully effective when controlled in an integrated manner, as it alone cannot ensure significant improvements in the final properties of steels. Plate surface quality depends on some parameters that must be controlled before the start of the plate accelerated cooling. Good flatness is essential to avoid irregular water accumulations during cooling. After the reheating process, the slab should have uniform temperature, uniform austenitic grain size and easily removable scale. The slab thermal and microstructural heterogeneities are inherited by the rolled plate and tend to increase further during the accelerated cooling. This results in flatness problems, high level of internal stresses and mechanical property variations. The descaling strategy is an extremely important factor and must be determined with great caution. It is important that scale thickness and distribution is uniform to ensure homogeneous cooling over the entire plate surface. Otherwise, there will be an uneven temperature distribution, which can cause serious problems of flatness, surface quality and mechanical properties.

Oct 1, 2019

By Mirko Jurkovic, Thomas Hueper, Jens Kempken

The high competition scenario pushes the steel producers business. Zero defect requirements from customers force the operators for additional efforts in process control and quality management. PQA® has been developed as an advanced process and quality management assurance solution. It is focusing on the analysis of process data, equipment information, inline quality measurement devices and trend analysis. The paper describes the structure of the advanced process and quality management assurance solution PQA®; it gives insights on the expert know-how, process and quality evaluation and points out the benefits like cost reduction, improvement yield and customer satisfaction increase.

Oct 1, 2019

By Péricles Bosquetti

Estudou-se o comportamento dos aços inoxidáveis AISI 304 e 316, quanto à corrosão causada pelo caldo da cana-de-açúcar nos processos que simulam a sua extração. Devido a inviabilidade de realização dos ensaios de imersão utilizando o próprio caldo da cana-deaçúcar de pH médio de 5,5, pela deterioração do caldo e da variedade da concentração devido a variedade da cana, do tempo de maturação e das condições ambientais expostas, foi utilizado o ácido cítrico, que é o precursor do ácido transaconítico, sendo este o ácido encontrado em maior concentração no caldo da cana, utilizando-se uma solução de 10% em massa, apresentando pH em torno de 5,0 [1]. As amostras permaneceram imersas por vários períodos de tempo, sendo que para tornar o ensaio acelerado, a solução foi submetida à ebulição durante todo período que as amostras ficaram imersas. Ao final de cada um dos períodos, os corpos de prova foram limpos, pesados e avaliados na relação de perda de massa por área, tendo-se medido a massa inicial bem como a área superficial inicial das mesmas. Foram obtidos resultados interessantes que mostram o ataque diferenciado da solução ácida a estes dois aços inoxidáveis, onde se observou a presença de “pites”, cujo tamanho e quantidade dos mesmos foram diferentes, sendo que o AISI 304 foi o que sofreu maior ataque.

Aug 16, 2017

By Robert Horwood, Richard Harvey

The copper stave was a development of the Blast Furnace cooling system intended to utilise the high heat transfer properties of copper within a fully covered shell cooling solution. They were originally conceived as being able to provide a permanent cooling lining for use primarily in the higher heat zones of the Blast Furnace. Despite a large number of campaign successes around the world the everlasting concept has not proven universal, with some plants having suffered issues in two particular areas: stave bending (leading to water leaks at back of the stave) and stave wear (erosion on the hot face). Primetals Technologies have in the past been approached to provide assistance to a number of Blast Furnace operators who were experiencing operational issues with the copper stave furnace cooling systems of others. Through knowledge gained resolving these issues, and with the positive experiences of their own copper stave designs, Primetals Technologies have worked towards developing a new concept in copper stave design capable of providing a more robust solution to cope with the greater productivities of modern ironmaking. This paper will provide an outline to the concepts that have driven the design of this new technology.

Oct 1, 2019

By Rene Grabowski

Optimization of workflows and intelligent stock management; Slab stacking improvement by automated transport orders; and System automatically registers any slab movements even in manual operation. Case story: Steel producer ArcelorMittal Eisenhüttenstadt GmbH in Germany uses Primetals Technologie’s new stock yard logistics system in its finishing department. An exact image of its slab storage at any times is given by the warehouse logistics system to the company. It not only enhances the composition of the stacks of slabs, but also automates recording of manual restacking operations. Therefore the solution improves workflows and simplifies stock control. Cycle times have also been reduced due to the fact that the slabs can be charged to reheating furnaces ahead of the rolling mill due to less restacking operations within the slab storage. The expandable, modular system is based on the Siemens Simatic IT and Primetals Technologies’ IT4METALS Logistics product platform. It provides a large number of organizational and commercial features in the form of sophisticated graphics and tabular evaluations. For example, it can show how many crane movements have been made per shift for any category of slab, so that the time and cost for each operation can be calculated accurately.

Aug 16, 2017

By Hervé Thomasson

Siemens VAI has made an important Research & Development effort since 10 years on laser welder field. The last step of this program was in 2010, the evolution of its laser welder range by implementing the solid state technology with laser cutting and welding. Since this step, 8 welders were produced by Siemens VAI. Now after more than 1 year of industrial feedback, the results are showing a high level of performances on very demanding processing lines for a large range of products from Silicon steel to High Strength Steel with DP and TRIP grades. This laser welder concept using laser cutting and welding through solid state laser source is also proposed by Siemens VAI for pickling lines and tandem mills with significant advantages compared to standard solution.

Jul 30, 2018

By Alisson Paulo de Oliveira, Altair Lucio de Souza, Jacson Morais Borges, Cleiton Arlindo Martins

A customized version of the Microsim-PM software for one Steckel rolling mill was built and adapted for specific mill parameters. The focus of this study is to use this model, which predicts the austenite grain size distribution evolution during rolling, to understand and quantify metallurgical issues happening during hot rolling. This will allow the steel mill to optimize the rolling process and chemical composition before the first industrial trial. Materials rolled for final thicknesses of 4.75, 6.30 and 12.5 mm of a carbon manganese steel and a microalloyed steel were selected to tailor the equations used by the model and to accurately reproduce the reality of the Steckel mill. This paper analyses the results from the customized model and compares them to mill data and final microstructure. Measured and predicted Mean Flow Stress (MFS) values are compared. After rolling, the material is subjected to accelerated cooling using laminar cooling. These cooling curves obtained from mill data are also considered to analyze the final microstructure characterized for all the cases using EBSD. The quantification of the microstructure allows for a better understanding of the relationship between chemical composition, process parameters and mechanical properties.

Oct 1, 2019

By Douglas Glenn Stalheim

Production of structural steel with a minimum yield strength of 700 Mpa produced as hot rolled coil has become increasingly popular due to cost considerations when compared to quench and temper equivalent product. This grade when produced as hot rolled coil requires the use of microalloy precipitation strengthening mechanisms. This is typically a combination of niobium and titanium microalloys. While the metallurgical concept of structural steel precipitation strengthening mechanisms has been well researched and published, actual implementation into the production process can be very challenging. In addition to achieving a minimum yield strength of 700 Mpa, in many applications additional mechanical property attributes of formability as measured by hole expansion testing along with low temperature toughness properties are now required. Achieving a balance of all the mechanical properties in a stable and repeatable performance in production using microalloy precipitation strengthening mechanisms further increases the challenges. This paper will discuss the metallurgical/process strategies required to successfully produce 700 Mpa minimum yield strength hot rolled structural steel coil. In addition, the role and goals of both niobium and titanium in this product design will be presented.

Oct 30, 2017

By Mauricio Monteiro Machado, Neyda de la Caridad Om Tapanes, Ana Isabel de Carvalho Santana, Rodolfo Salazar Perez, Rodrigo Ribeiro Soares, Roberta Gaidzinski

Vasos de pressão são equipamentos empregados nas mais variadas indústrias, sendo responsáveis por significativa parcela do orçamento. Os materiais mais utilizados para a construção de vasos de pressão para a indústria de óleo e gás são as ligas de aço carbono e em alguns casos se justifica o emprego de ligas de aços inoxidáveis. O objetivo deste trabalho foi estudar as características dos vasos de pressão, materiais de fabricação e o custo de aquisição de vasos de pressão por parte da Petrobras. Para o desenvolvimento foram utilizadas duas ferramentas de processamento de dados: a Lei de acesso à informação que permitiu a criação de uma base de dados, e o Planejamento de experimentos que possibilitou avaliar a influência do tipo de material e outras variáveis sobre o preço do vaso de pressão (variável de resposta). Os resultados estatísticos demonstram que, para as faixas analisadas o comprimento entre tangentes (CET) e o Diâmetro (D) possuem uma influência estatística direta sobre a variável de resposta Preço. Finalizando, o estudo conseguiu conciliar aspectos construtivos com os fatores financeiros, sendo de grande valia para os fabricantes de vasos de pressão.

Aug 1, 2019

By Sandra Goulart-Santos

Os aços galvanizados são amplamente utilizados devido à sua excelente resistência à corrosão. Além disso, esses aços apresentam alta qualidade superficial, o que é um requisito importante para aplicações exigentes como as da indústria automobilística. Dentre os parâmetros de processo importantes para a qualidade dos revestimentos está o teor de alumínio no banho de zinco. Nesse estudo, foi utilizado o simulador do processo de galvanização a quente (HDPS), para investigar a influência do teor de alumínio efetivo do banho na qualidade superficial do revestimento galvannealed (GA), sendo avaliados os teores de 0,09% e 0,14%. Para acompanhar os estágios de formação das fases Fe-Zn foram realizadas interrupções do ciclo de galvanização ao longo das etapas de imersão no banho e de tratamento térmico de galvannealing. Utilizando a técnica GDOES, foi possível acompanhar as variações da concentração de alumínio ao longo do revestimento durante a formação das fases Fe-Zn. Os resultados das simulações mostraram que o alumínio efetivo mais baixo no banho favoreceu a cinética de formação das fases Fe-Zn durante o tratamento térmico e diminuiu a ocorrência de regiões com aspecto brilhante no revestimento, melhorando a qualidade superficial.

Jul 30, 2018

By Markssuel Teixeira Marvila

A incorporação de resíduos em materiais de construção, tais como em tijolos cerâmicos, é uma grande alternativa para o correto descarte de resíduos industriais. Nesse contexto, o objetivo desse trabalho é a avaliar a possibilidade da incorporação de resíduos provenientes da indústria de rochas ornamentais (calcário) em tijolos cerâmicos, uma vez que o Brasil é um dos maiores produtores mundiais desta classe de rochas e ainda não existem alternativas plausíveis para o descarte destes dejetos. Para realizar esse estudo foram confeccionados e queimados a 900ºC, corpos de prova contendo 0%, 10%, 20%, 30% e 40% de incorporação de calcário em massa cerâmica. Após período de secagem, os corpos de prova foram ensaiados para avaliação dos seguintes parâmetros: retração por secagem, absorção de água e resistência mecânica. Avaliando estas propriedades e comparando com os valores estipulados por norma, constata-se a possibilidade da incorporação de resíduo proveniente de rochas ornamentais em até 20% da massa cerâmica. Assim sendo, uma alternativa para o descarte destes rejeitos industriais estudados é incorporar em tijolos cerâmicos, devendo seu teor de incorporação ser limitado em 20% afim de não descumprir as exigências normativas.

Oct 30, 2017

By Daniel Mapa Clemente

Processing of tin slags in reduction furnaces was studied in order to optimize tin recovery and reduce recirculation rates of slags containing thorium and uranium oxides. A theoretical approach considering a mass balance of the process was developed and adjusted by experimental results in order to predict the final slag composition. A metallic phase (FeSnSi) was discovered trapped in the slag due to high apparent viscosity, raising the FeO and SnO2 contents of the slag sample. This FeSnSi alloy is rich in tin and its recovery would help to reduce the slags recirculation. High contents of ZrO2 were found in the slag, restricting it from reaching complete fluid phase. Through an analysis of the slag in the CaO-FeOx-SiO2 and ZrO2-CaO-SiO2 phase systems it can be concluded that final slags should be modeled aiming fluid phase at working conditions and additions should be planned in order to control ZrO2 levels.

Oct 30, 2017

By Isaias Moreira de Freitas

Componentes de alto custo como rodas ferroviárias estão em pleno desenvolvimento a fim de aumentar o desempenho em operação. Para isso, diversos materiais microligados têm sido testados para obter melhores propriedades mecânicas e metalúrgicas. Esses materiais estão fortemente sujeitos a fraturas devido às solicitações térmicas e mecânicas durante o trabalho. Muitas dessas fraturas frágeis são ocasionadas por propagação de trinca, impacto, fadiga ou alguma falha metalúrgica. Essas fraturas e riscos operacionais vêm aumentando gradativamente com as maiores cargas transportadas. Portanto, novos materiais e processos produtivos devem ser exaustivamente testados a fim de garantir alto desempenho e confiabilidade. O objetivo deste trabalho é avaliar as propriedades dos materiais atuais e de diferentes composições de aços microligados de rodas ferroviárias de vagões, fabricadas pelos processos de fundição e forjamento. As amostras foram submetidas a ensaios metalográficos, mecânicos e de tenacidade à fratura. Foram avaliadas rodas convencionais, microligadas ao vanádio e microligadas ao nióbio. Nas rodas forjada e fundida, foram observadas propriedades de tração e dureza similares, e superioridade para o microligado em relação ao aço convencional. As rodas forjadas apresentaram melhor resistência ao impacto e a tenacidade a fratura, destacando-se a microligada ao nióbio.

Aug 16, 2017

By Rafael Lioji Kogake

O Alto Forno n° 2 é responsável por cerca de 40% da produção de gusa na CSN. Uma das principais utilidades responsável pela transformação do minério de ferro em gusa é o ar soprado que é fornecido por dois turbo sopradores da Central Termoelétrica n°2. Para que ocorra o processo de transformação do minério é necessário que o ar soprado seja aquecido. Isto é feito através dos regeneradores, os quais aquecem o ar para cerca de 1.300°C. Como cada regenerador tem um tempo de campanha, é necessário fazer a troca do mesmo a cada 1 hora. Nesse momento de mudança de regenerador, uma parte do ar soprado é desviado para o regenerador que está entrando em operação e ainda está vazio. Com isso, há uma perda pontual de produção indesejada, além de causar instabilidade no processo. A solução encontrada para reduzir este problema foi aumentar a vazão de sopro durante o período de troca de regeneradores, garantindo assim uma maior produção e melhor estabilidade do Alto Forno 2. Este trabalho apresenta o estudo do problema em questão, a metodologia utilizada para a sua implementação e os resultados alcançados.

Jul 31, 2018