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By G. N. Carlson, C. H. Hazelroth, D. R. Dorrance

"Located on the north shore of the St. Lawrence River at Pointe Noire, Quebec are the agglomeration and ship-ping facilities of the Wabush Mines complex. Here, the specular hematite concentrate from the Scully Mine is received for further processing. Modern facilities for handling the ore, either to the 1plant or to stockpile, provide quick and efficient operation of the ore receiving station. Physical preparation of the ore for balling is accomplished with regrind ball mills, filters, bentonite crushing and drying facilities, pumps and related conveying circuits. Rotating table feeders deliver the reground and de-watered ore from storage bins to balling drums, where green ball or green pellet formation is achieved. The green balls are then conveyed to the indurating section. Three Dravo-Lurgi travelling grates, producing a total of 6,000,000 long dry tons of pellets per year, are used in the indurating phase of the operation. These grates, having 38 windboxes and firing at a temperature of 2,500°F, harden the pellets for shipment to various blast furnaces throughout the world."

Jan 1, 1969

By C. E. Lesher

Two processes for agglomerating fine sized ores with low temperature coke are described. One process (Orcarb) agglomerates ores with limited amounts of carbon; the other (ore-carbon pellets) pelletizes fine sized ores, using low temperature cokes as the binder. Data are presented on the products obtained when taconite, magnetite, and hematite concentrates and several titanium oxide ores were used. Reduction of finely divided oxide ores has long been a major metallurgical problem. Various methods of agglomerating, notably briquetting, sintering, nodulizing, and pelletizing, have been developed and are in industrial use. Carbon is the usual reducing agent for oxide ores and attempts have been made to agglomerate fine ores with coking coal in order to get the metallurgical advantages of intimate contact and increased particle sizes suitable for subsequent smelting or reduction.

Oct 1, 1955

By S. E. Phifer

The Haile gold mine was the largest gold producer east of the Mississippi River before 1942. It was the first gold mine in the Southeast to reopen following deregulation of the gold price by the United States Government. The Haile mine was also the first gold mine in the Southeast to use heap leaching and carbon recovery for gold production. Current production involves mining and heap leaching about 1.8 kt/d (1600 stpd). Carbon is used as a recovery medium. Due to the clay and excessive fines in the oxidized ore, agglomeration using portland cement is required before leaching. Agglomerated ore ranges in screen size from 50 mm (2 in.) to less than 75 µm (200 mesh). The agglomerating step combined with certain other conditions has enabled Piedmont Mining Co. to achieve recoveries of about 90% or better.

Jan 1, 1987

By S. E. Phifer

The Haile Gold Mine was the largest gold producer east of the Mississippi River prior to 1942. It is currently the only producing gold mine in the Southeastern United States. Current development involves the mining and heap leaching of some 1000 TPD. Carbon is employed as a recovery medium. Due to its clayey nature and excessive fines in the oxide ore, agglomeration using Portland cement is required prior to leaching. The ore ranges in screen size from two inches to -200 mesh. The agglomerating step combined with certain other conditions has enabled Piedmont Mining Company to achieve recoveries of 90%.

Jan 1, 1987

By R. K. Komarek, F. E. Jr. Briber, G. M. Hanson, Fred D. DeVaney, J. H. Blake, C. L. Matson, T. E. Ban, N. E. Shields, R. D. Frans, R. B. Greenwalt

Metallurgically, the term agglomeration is used to describe processes whose goal is to form balls, briquettes, nodules, flakes, or other sized shaped particles from loose, usually fine, incoherent particles. In practice it includes such varying processes as the briquetting of coal dust and other substances, the balling and induration (heating) of such nonmetallics as cement, fluorspar, lightweight aggregates, etc. It includes such widely used processes as the sintering of nonferrous concentrates, such as those copper, lead, zinc, etc. The agglomeration of specific nonferrous metal concentrates is discussed in detail in the section of this handbook devoted to that particular metal. Agglomeration processes are of particular value to the iron and steel industry where the nature of the primary reduction process, the blast furnace, requires for best results a burden essentially free of fines. This is a change that has taken place since about 1960. Prior to that time many fine unsized ores were fed to the furnace. The development of the pelletizing process gave to the industry a chemically controlled closely sized product that increased the produc¬tion rate and reduced the costs so much that unsized fines are seldom used in modem furnaces. Steel plants produce many fine sized waste products such as fine dust (fine ore coke and gangue) and mill scale. These products, which have a valuable iron content, are usually sin¬tered directly at the plant for reuse. Fine sized ore concentrates are usually pelletized at the mine and shipped as pellets to the steel plant. Common practice in some areas producing natural high grade ores is to screen the ore at the mine to about 3/8 in. The oversize is shipped "as is" and constitutes blast furnace feed. The / in. may be shipped to the steel plant where it may be sintered or otherwise agglomerated. At some mines the fines may be pelletizied prior to shipment. With the development of large ocean ore carriers, and with the transportation of slurried concentrates or fines, a trend has developed of constructing large pelletizing plants or other types of agglomeration plants near large consumption centers (i.e., in the Netherlands or Japan) where ores of many types are brought together, ground if necessary, blended, and agglomerated. As an indication of tonnages of agglomerated materials produced, for iron materials alone (the largest share of the total) production in 1970 in the U.S. was Million gross ton Sinter 40.7 Pellets 43.1 Briquettes, nodules, & others 0.1 Total 83.9 During the 1960s, U.S. production of sinter rose from 40.3 million gross tons in 1961 to a high of 48.7 million in 1964, then settled back to almost the 1961 figure in 1970. Pellet production rose steadily from 14.4 million gross tons in 1961 to the 59.9 figure for 1975. Worldwide, sinter production in 1966 was estimated at 340 million mt (mainly in Europe, Russia, Japan, and the U.S.) and pellet produc¬tion the same year at 64 mt (primarily Canada and the U.S.). World pellet production capacity rose to 200 million tons in 1976.

Jan 1, 1985

By Brij M. Moudgil

Flotation was introduced in phosphate rock processing in the late twenties and since then it has been an important part of the concentration process. More than two thirds of the rock produced in Florida is upgraded by the flotation process. Since no crushing or milling steps are involved in the material preparation, the flotation plant feed is coarser than in most other mineral flotation systems. During hydraulic processing of the rock, particles in the size range of -14, +150 mesh constitute the flotation feed. This size fraction is further classified by hydraulic sizers, stationary screens and vibrating screens into a coarse (-14, +35 mesh) and a fine (-35, +150 mesh) flotation feed. The flotation techniques for concentrating the fine feed as practiced by the Florida Phosphate producers have been standardized over the years, however, methods for upgrading the coarse feed differ from plant to plant. In this paper an effort has been made to present relative merits of the techniques employed for concentrating the coarse phosphate rock..

Jan 1, 1977

By Gleison Vinicius Ricardo, Luiz Cláudio von Sperling Cotta, Artur Frederico Fonseca da Cruz, Evandro José de Castro Lopes

Binders are important raw materials in the iron ore pelletizing process. The bentonite, most usual, has been used in plants of this process since the forties due to its good performance in the agglomeration of ultrafine ore, although the silicon content in bentonite impairs the total iron content of the pellet, reducing its market value. This article studies the bentonite consumption reduction and improvement of the chemical quality of pellets by the addition of an organic binder in the productive process of Vale Vargem Grande pelletizing plant. By evaluation of variables as, drop test of green pellet, green pellet, dry pellet and fired pellet compressive strength tests, tumble index, percentage fraction of lower than 5 mm and total iron content in fired pellets, it was possible to approve the technical availability of the organic binder auxiliary in Vargem Grande pelletizing process. Nonetheless the positive influence of total iron content increase due to the reduction of bentonite consumption, it could also verify no impact on the physical quality of the pellets under the same production rhythm, approving once again the use of organic binders in pelletizing process.

Oct 1, 2019

By Ramiro da Conceição do Nascimento, Horst Guenter Feldhagen, Rafael Piumatti de Oliveira

Mixed hydroxide precipitate (MHP) is a nickel intermediate product that has economical benefits to downstream leaching of lateritic marginal ores. Usually, this product is subsequently processed and refined to produce nickel by hydrometallurgy, but an alternative route can be made integrating hydrometallurgy and pyrometallurgy. Assessing the overall consumption of ferroalloys to obtain stainless steel, as an increasing practice performed in China, the synergy of nickel extraction from laterites by leaching and precipitation asMHP with the production ofMHP agglomerates applied as rawmaterial to furnaces of ferronickel production is a very attractive practice. This work aims to further the technological development of an agglomerated product feasible to hydro-pyro integration. The agglomeration experiments were performed by traditional pelletizing (firing the pellets) and cold bonded pelletizing (aging the pellets by appropriate stocking). Appropriate compositionswere prepared withMHP, additives and binders for each of these routes. A specific study of binder composition was made to find an adequate melting point. The produced pellets were tested to prove their properties by crushing strength tests. The standardization applied to iron ore was followed. The best result of crushing strength was 98.52 daN/pellet. The agglomerates with approved crushing strength for use in electric furnaces were smelted to produce alloys containing nickel; the agglomerates were characterized by scanning electron microscopy. The alloy obtained was metallic ferronickel with sulphide precipitates. Therefore, MHP pellets can be precursors of nickel alloys, which have to be refined to obtain the desirable composition.

Jul 6, 2020

By J. J. Antony

The Cactus Gold Mine is a joint venture comprised of Middle Buttes Partners Ltd. (CoCa Mines, Inc.--operator, T. Congdon and W. Carey) and Compass Mining, Inc. The project includes 2.4 sq. miles of contiguous mining claims and leases in the Mojave Mining District, Kern County, California, approximately B5 miles northeast of Los Angeles. The property is readily accessible year round by all-weather roads and is within 6 miles of the main line of the Southern Pacific Railway.

Jan 1, 1988

By C. A. Holley

The generation of coal fines is a growing problem which has serious environmental and resource recovery Impact. Several methods of agglomeration are studied including the production of briquettes for the consumer market. Simplified process flow diagrams, "order of magnitude" plant capital cost and operating costs are presented.

Jan 1, 1986

By Ataollah Nosrati

Agglomeration of fine mineral particles is an important step in heap leaching processes employed for a cost-effective hydrometallurgical extraction of value metals from low-grade ores. In this study, the effect of acidic binder composition and feed ore particle size on binder dosage requirement and isothermal, batch agglomeration behavior of siliceous goethite nickel laterite has been investigated. Agglomeration tests performed with tap water and 30, 44 and 98% w/w H2SO4 solutions as binders revealed the key role of binder formulation in controlling ore particle wettability, nucleation and granule growth behavior. Both lower binder acid content and higher dosage led to greater wetting, nucleation and granule growth rates. Variation of feed ore fine/coarse particles? mass ratio dramatically impacted on binder dosage requirement for effective particle wetting, nucleation, and growth agglomeration behavior. Increasing fine (-150 µm) fraction mass content in a -2 mm feed ore, led to higher binder dosage requirement and enhanced nucleation, however the overall agglomeration rate/granule size growth decreased. In contrast, the presence of coarse (5 ? 15 mm) particles in feed ore led to (i) lower binder dosage requirement, (ii) enhanced initial agglomerate size growth rate, and (iii) reduced coalescence. For dry agglomerates of similar sizes, competent coarser feed particles led to remarkably higher compressive strength than did finer feed particles. Microstructure analyses indicated that the granules containing coarser particles exhibited a distinctive, competent core/shell (fines) structure which led to their structural reinforcement. The appropriation of the findings for optimizing agglomeration behavior for enhanced heap leaching of complex, low grade laterite ores are discussed in this context.

Sep 1, 2012

By S. Kawatra, K. Lewandowski

Heap leaching efficiency is reduced by poor solution flow characteristics (channeling and ponding), which result from fines migration. Agglomeration of the ore can immobilize fines, but copper leaching requires an acid-resistant binder to stabilize the agglomerates. Until now, there has not been a satisfactory way to evaluate whether a binder was effective, other than squeezing a handful to see if it “feels right”. We have developed procedures to quantitatively determine whether a binder gives good performance in an acidic solution, and have identified several binders that will be suitable for copper heap leaching.

Jan 1, 2007

Agglomeration Drum Selection and Design A model has been developed by for drum agglomeration which allows selection of geometry and power input. Specific aspects considered are: calculation of total operating volume, solids residence time based on drum geometry and operating parameters, selection of the drum aspect ratio, selection of proportion of critical speed, calculation of rotating power requirements. The model uses solids total residence time to calculate the required operating volume. The burden density is calculated from the solids bulk density, agglomerate packing and the fluid density. Power is calculated using a modified Liddell and Moys correlation for burden position and shape, and the operating drum speed. A further power allowance is made to allow for accretion drop off during drum rotation. Results from the model (especially power and per cent operating fill) have been verified from industrial installations of significant size. Predicted and observed power draws are within five per cent when burden slip and bypassing are not significant. When these are significant (at fills above 15 per cent) the actual power draw will be less than the model prediction. Under these circumstances the quality of the agglomerates will be poor.

Sep 13, 2010

By Ellis H. Gates

BENEFICIATION of the manganese oxide ores at Three Kids Mine near Henderson, Nev., has evolved over a period of years. Commercial application of the process is on a secure basis, and an effective working hypothesis has been formulated to help solve the problems encountered in flotation. An outstanding difference between the Manganese Inc. operation and other flotation processes is the necessity for high recovery of slime mineral values. Part of the manganese minerals in the Three Kids ore deposit occurs as primary slime or as minerals that are easily slimed by grinding. High recovery of this slime portion is essential to an economic over- all manganese recovery. The aim of much of the research at Manganese Inc. was to recover these slimed and finely ground minerals by flotation.

Jan 12, 1957

Agglomeration for Copper Heap Leaching Agglomeration of ore is a method which can be used to eliminate the migration of fine grained particles throughout a leach heap. Without agglomeration, fine ore particles are able to migration within the heap, clogging flow channels and producing large areas where access of the solution is poor. In order to gain the benefits of agglomeration and improve agglomerate strength even further in copper heap leaching, an economical, acid-resistant binder is needed. However, most binders have been used without any systematic reasoning. A set of novel testing methods were developed, including a soak test, percolation flooded columns, and larger long-term leach columns. The soak test compares the degree of breakdown when agglomerates are subjected to an acidic environment. While the percolation flooded columns and larger long-term leach columns evaluate the flow of leach solution throughout the ore bed. Systematic studies have been completed on a wide range of binders using these novel testing procedures. It was found that for a low grade chalcocite ore, which was rich in silica, from a southwest US mine, polyacrylamides reduced the fines migration the best in the novel soak test. The non-ionic binder, in particular, was found to reduce fines migration as much as 93 per cent. Several of the binders tested were shown to increase the hydraulic conductivities of the agglomerated ore up to 2.5 mm/sec, compared to a hydraulic conductivity of only 0.25 mm/sec when no binder was used. These binders also prevented 'slumping' of the ore, which indicates a decrease in breakdown of the agglomerates. The use of a binder also showed no interference with leaching reactions in long-term leaching experiments.

Sep 13, 2010

By P. D. Chamberlin

Agglomeration for the heap leaching of gold and silver ores can be defined as the process of attaching fine ore particles (less than 100 mesh) to coarser particles so the fines are immobilized and uniformly distributed throughout the heap, thus making the heap more porous and uniformly permeable to the flow of a leaching solution. Agglomeration techniques and equipment to be described include drum and disc agglomerators, stockpile and belt agglomeration, and the use of vibrating deck and reverse running conveyors.

Jan 1, 1986

By C. Edward Capes

Fine particles in liquid suspension can be agglomerated by a number of mechanisms. Well-known methods include the addition of electrolyte to reduce the zeta potential and allow mutual adhesion arid the use of polymeric flocculants to bridge between the particles. A more recent technique, "spherical Agglomeration", is the subject of this paper. The process involves the addition of a second liquid which is immiscible with the suspending liquid and preferentially wets the particles to cause particle adhesion by capillary liquid bridges. Progress in the application of spherical agglomeration to a number of distinct technological fields is reviewed in this paper. The areas of interest include the formation of dense, highly spherical agglomerates, the separation of solids from suspension and the fractionation of complex, multi-component solids mixtures, such as ores. Some of the more interesting recent applications in the energy and environmental fields, such as the beneficiation of' coal and tar sands, are highlighted.

Jan 1, 1977

By J. A. Eisele, D. L. Pool

"The Bureau of Mines has developed a particle agglomeration technique to improve the flow of leaching solution through heaps of low-grade gold-silver ores which contain clays. Benchscale experiments and industrial practice have shown that the percolation rate of cyanide leaching solution is greatly enhanced by mixing the ore with Portland cement as a binder, moistening the mixture, mechanically tumbling to form agglomerates, and aging before heap building and leaching. A slight modification ofthe technique allows its application to precious-metal-bearing tailings, which cannot normally be treated by heap leaching because they are too fine. IntroductionMany low-grade gold and silver deposits and tailing materials from former mining operations in the western United States are potential sources for precious metals. These sources are too low grade or too small to support the capital cost of a conventional cyanidation plant but have stimulated the development of lowcost procedures, such as extraction of the precious metals by heap leaching with cyanide. The Bureau of Mines has investigated methods to improve the recovery ofgold and silver by heap leaching these low-grade materials.For heap leaching to be successful, the crushed and stacked ore must have good permeability so that uniform distribution of the cyanide leaching solution through the heaps can be achieved. Some of the most difficult gold and silver ores to treat by heap leaching are those containing excessive amounts of clays, or fines generated during crushing. Excessive amounts of slimes, generally minus 50-micrometre or 270-mesh Tyler sieve size particles, in the heap feed will slow the percolation of the leaching solution, cause channelling, or produce dormant or unleached areas within the heap, resulting in long leaching periods and low extractions. In extreme cases, the clays or slimes can seal the heap and cause the leaching solution to run off the sides of the heap rather than through it."

Jan 1, 1987

By G. Velarde

Agglomeration has as main objective to form a uniform and highly permeable heap for leaching. An inaccurate dosage of moisture during agglomeration leads directly to poor agglomerate quality and segregation of particle sizes during stacking. This causes a heterogeneous distribution of the leach solution inside the heap which invisibly and practically permanently affects the recovery. Unfortunately, only when this becomes serious and the mineral contains an excess amount of fine particles and/or clays then the poor permeability of the pile becomes obvious. This paper is based on the experience of Minera Cerro Verde in the development and application of a quantitative method to control moisture during agglomeration. As the amount of fine particles/clays varies, the quantity of moisture has to be altered in real time. The measurement of agglomerate electrical conductivity is used for it. This concept is based on the sharp change seen in conductivity when the mineral passes its absorption limit. A liquid conductive film then begins to form over the surface of the particles, which leads to the formation of agglomerates through liquid bridges, which are also electrical bridges. Moisture is adjusted to reproduce a value of conductivity established previously and is the guiding parameter. Moreover, moisture amount added to reach this conductivity parameter provides information about the fines/clays relative content for best leaching management.

Jan 1, 2004

By R. Hogg

"The basic population balance models for agglomeration processes are reviewed and procedures are described for extending their applicability to systems with size-dependent rate constants and to the formation and growth of porous agglomerates from rigid, solid particles. Simplified procedures for the further extension of the models to include simultaneous agglomerate growth and breakage arc also described. IntroductionThe association of small particles into clusters or agglomerates is a significant factor in many facets of particle processing. Agglomeration processes are widely used to facilitate handling, storage and utilization of fine powders. Processes such as coagulation or flocculation are used to aid solid-fluid separation in dispersed particulate systems. Agglomeration also occurs as an accompaniment, often unwanted, to other particulate processing operations such as fine grinding, mixing and blending, transport and flow.Reliable agglomeration models are needed for improved understanding of the processes in general and of the complex role of numerous, interacting variables as well as for direct application to the design and control of industrial processes such as flocculation, granulation and pelletization. Ideally, the models should account for the primary forces responsible for agglomerate ·formation and growth, the effects of external forces on process dynamics, the development of agglomerate structure and its role in the process itself, and the effects of concurrent processes such as structure modification (e.g. compaction) and agglomerate breakage or degradation.In its most general form, the process of agglomeration involves taking discrete, independent particles, bringing them into contact with one another, promoting (or allowing) interparticle adhesion to occur and then causing structure rearrangement, usually under the action of external forces. The relative importance of these steps varies with the nature of the particulate system being agglomerated and with the kinds of agglomerates being produced. Coagulation or flocculation of particles dispersed in fluids is generally dominated by the contact and adhesion steps. In the granulation of powders, on the other hand, particles are already in contact so that structure rearrangement is the principal step."

Mar 1, 1992