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By Stuart M. Jones

This paper describes the state of the art of grinding in the Copper Industry today including descriptions of the largest equipment and design features which allow processing of as much as 100,000 mtpd in a single mill line. We include a typical flowsheet, control philosophies, and maintenance techniques which result in low cost production which is essential in today's market.

Jan 1, 1999

By Ting Lei, Mingjun Rao, Guanghui Li, Tao Jiang

"With the rapid development of iron and steel industry, the supply of iron ores can not meet the present demand for iron and steel industry in China. Large reserves of oolitic hematite have been discovered with low iron grade (30% ~ 45%) and high phosphorus content (0.4% ~ 1.8%). Traditional processes for utilization of this ore are characterized as either high cost or low dephosphorization. In this study, sodium salts-modified paigeite (SSMP) was added to enhance on the dephosphorization of high-phosphorus oolitic hematite by using reduction roasting followed by magnetic separation. Various parameters, including the amount of SSMP, reduction time,reduction temperature, grinding fineness and the magnetic field intensity were investigated. As a consequence, a magnetic concentrate of metallic iron powder with total iron grade of 93.2% and phosphorus content of 0.08% was obtained under the optimal conditions. The results also provide a potential avenue for the comprehensive utilization of paigeite ore.IntroductionOolitic hematite is currently recognized as one of the most refractory iron ore resources in the world. Over 4.0 billion tons of reserves of such resources have been found in China, and more than 10 billion tons in the long-term. This kind of ore is characterized as low iron grade (30%~45% TFe) and high phosphorus content (0.4%~1.8% P), as well as fine particle size distribution of ferrous minerals (the size distribution varies from 5~30 µm, even less than 2 µm) and the complex association between iron and other gangue elements [1~5]. The unique structural characteristics of the high phosphorus oolitic hematite make it difficult to obtain high iron recovery and good dephosphorization efficiency by using the conventional processes [1,2]. Traditional processes are characterized as high cost and low dephosphorization for oolitic hematite beneficiation [9~15]."

Jan 1, 2012

By L. H. Lewis

The relationships that link microstructural properties of advanced permanent magnet materials with magnetic properties such as the coercivity are often difficult to quantify, especially in materials with nano-scale structures. Recent work on RE2Fe14B-based powders fabricated with rapid- solidification techniques such as inert gas atomization (IGA) and melt-spinning provide insight into the nanostructural features which affect the acquisition and stability of coercivity. In all cases the coercivity is found to be a function of both the scale of the constituent microstructure and of the presence and distribution of minor phases.

Jan 1, 1997

Laboratory trials were performed in an induction furnace to study droplet formation during lance blowing. Compressed air was blown on a molten iron bath consisting of iron alloyed with carbon and silicon. Steel droplets were collected using a specially designed sampler. The average steel droplet composition and the oxide layer thickness were determined using scanning electron microscopy combined with energy dispersed spectroscopy. In addition, the concentration gradient of elements was determined using a microprobe. It should be noted that a special technique had to be developed in order to prepare the droplet sample. The size distribution and composition of the droplets was also determined using the microprobe. It was found that the carbon content in the droplets was lower than the carbon content in the bulk.

Jan 1, 2006

By Roberto Parada

In a long term program for the optimization of the Outokumpu Flash Smelting Furnace at Chagres Smelter many different subprograms are being developed. One of them is the design and application of a sampling method that can allow the direct diagnostic of the quality of the copper concentrates combustion. We present in this paper the evolution of the sampling devices used in a ten months of continuous sampling campaigns and an example for the sulfur elimination and magnetite formation in the flame from 60 cm to 100 cm under the burner. These type of information combined with the appropriate mathematical modeling of the combustion must propose some considerations to correct the classic criteria in the preparation of the charge for the smelting of copper concentrates based only on the mass and energy balance from the chemical and mineralogy composition of the concentrates.

Jan 1, 2006

By Aichun Zhao, Rui Wang, Yihong Li, Yanping Bao, Yafeng Ji, Jiansheng Liu, Xiao Hu, Qingxue Huang

The slag entrapment under different conditions of 80t blowing argon ladle furnace was investigated by physical simulation. The water was used to simulate liquid steel and liquid paraffin was for slag. The processing of slag entrapment under different blowing structures was analyzed and the critical velocity and critical droplets diameter of describing it was obtained. Based on the experiments, the relationship between the interface flow velocity and the critical blowing rate CBR was deduced. In the real process, it is suggested that the bottom blowing rate is from 40 L/min to 180L/min when the interface tension is 0.12~1.2 N/m during the soft argon blowing.

Jan 1, 2016

By Toshiyuki Kozuka

CdTe semi-conducting materials have been expected as solar cell materials because its theoretical energy conversion ratio is very high. The actual efficiency still low, however, many research works have been done in order to improve the efficiency. And crystal orientation is one of possibilities for that. In this work, a new method using intense magnetic field for a control of texture of CdTe crystals will be proposed, where the CdTe film was electro-deposited under an intense magnetic field. CdTe is less affected by magnetic field, because of its cubic structure, but Cd or Te has hexagonal structure, which is sensitive for magnetic field. In this paper, crystal orientation of Cd or Te film, which can be utilized as basic layer for CdTe deposition, will be developed.

Jan 1, 2006

By Pascal Gardin

The purpose of the paper is the mathematical modelling of flows inside steel continuous casting mould. For CFD validation of flow oscillation prediction, unsteady calculations with a realizable k- model were performed in a billet caster with rectangular section. Self sustained and regular oscillations were obtained. Calculated flapping frequency is very close to what is mentioned in literature. For slab caster configuration, flow oscillation is influenced both by lower roll, which creates very small frequency oscillation (0.012 Hz for our water model), and upper roll, which creates slightly higher frequency oscillation (0.05 Hz). The two rolls interact and it is possible to detect both frequencies in the nozzle jet region. Numerical results are in good agreement with measurements for fluctuating velocity spectra and provide explanation for interaction of rolls. To improve flow stability inside the mould, it is established that gas injection in the nozzle has a very positive effect.

Jan 1, 2006

By Zviad Kovziridze

Structure of celsian ceramics in BaO-Al2O3-SiO2system is studied with electron microscope in the entire temperature region of baking interval. The process of the pores filling and the full consolidation of material growth at comparatively high temperatures of baking intervals are described.

Jan 1, 2006

By Geir Wedde, Anders Sorhuus

"Vast quantities of energy are released as heat to the environment from industrial operations. Many countries target waste heat recovery to mitigate CO2 emission. Exhaust gases from industries such as primary aluminium smelting, carry a substantial portion of the waste heat generated. For a cost efficient capture of more valuable heat (higher exergy), heat exchangers should operate on the exhaust gases upstream of the gas treatment plants. Heat exchange surface would be exposed to dust laden gases with risk of fouling. Heat exchangers of innovated design and operation have overcome the potential of excessive fouling rates. Heat exchangers of the ""shell and tube"" design have been demonstrated for exhaust gases from ferroalloy as well as primary aluminium smelters. In addition to the heat recovery, gas cooling results in smaller gas treatment plants with lower costs and reduced emission. The aluminium experience is exampled in the paper.IntroductionIndustrial usage of energy continues to grow as a result of increasing volumes of production, a trend that is likely to continue in the coming decades as living standards keep rising globally. World energy consumption (Figure la) is to grow 49 % by 2035 (ref. 2010) as reported by EIA [1]. The industrial sector consumes somewhat more than 50% of the total world energy consumption predominantly the energy increased demand comes from non-OECD countries in Asia. The industrial consumption by production of metals iron and steel accounts for 14 % and for non-ferrous metals 3 % mostly for aluminium production (Figure lb). Aluminium production will be discussed in this paper as an example of an industry with large quantities of waste heat to recover"

Jan 1, 2012

By Leonid M. Lerner

High temperature aluminum Alloy 8009 is a rapidly solidified/powder metallurgy aluminum-iron-vanadium-silicon alloy. This alloy in combination with hard oxide aluminum film has unique engineering properties which may recommend its use in compressors and impellers for aerospace applications. Various anodizing processes (including Sanford Low Voltage DC+AC Process) for these task will be evaluated and normal chemical composition, physical properties, and macrostructures of 8XXX aluminum alloys will be presented.

Jan 1, 2006

By Xiancong Zhao, Hao Bai, Qi Shi, Zhancheng Guo

Reducing electricity cost is important for energy intensive industries such as the iron and steel industry. With the implementation of time-of-use (TOU) electricity price, plenty of attention has been paid to the optimal management of byproduct gases. The time-of-use (TOU) electricity price is the practice of implementing different prices for different times of use. It is possible to reduce electricity cost by adjusting the amount of product gases stored or used for power generation throughout the day. In this paper, a novel mixed integer linear programming (MILP) model concerning the TOU electricity price is proposed to optimize byproduct gas use. Compared with previous models, this model considers the optimal load shift between gasholders and boilers under TOU electricity price. The case study of a steel plant demonstrates that the electricity purchase cost can be reduced by more than 30% after optimization.

Jan 1, 2016

By K. A. Lewandowski

Agglomeration of ore can be used to immobilize fine particles during heap leaching by agglomerating them into granules. Without agglomeration, the fine ore particles can migrate within the heap, clogging flow channels and producing large areas where access of solution to the ore is very poor. The benefits of agglomeration are well-known in gold heap leaching operations, which can be effectively agglomerated using binders such as Portland cement due to the alkaline leaching solutions used. However, agglomeration has not been very effective in the heap leaching of copper ores, because these ores require an acidic leaching solution. Acid destroys the effectiveness of most binders, causing the agglomerates to disintegrate as soon as the leaching solution is applied. In order to gain the benefits of agglomeration in copper heap leaching, an economical, acid-resistant binder is needed. The two issues that needed to be addressed were: 1) Lack of effective methods for evaluating binder acid resistance before performing expensive, time-consuming, full-scale heap leaching tests, and 2) The vast majority of known binders react poorly to acid conditions, and so a basis was needed for determining which binders are most likely to be acid-resistant. In this paper, the development of two new tests for evaluating binder acid resistance in the laboratory are described. The ?soak test? determines the degree to which agglomerates disintegrate and release fines on contact with acidic solution, measuring the relative quantities of fines released by agglomerates made with different binders under controlled conditions, and serves as a rapid means for comparing large numbers of binders. The ?percolation test? measures several different parameters to determine how a binder is likely to perform in heap leaching: 1) the degree of ?slump? and compaction of agglomerates as they are wetted by acidic solutions; 2) the hydraulic conductivity of the agglomerate bed; 3) the migration of fines through the bed as the solution flows through it; and 4) the quantity of liquid retained in the agglomerates after they are drained. Using these tests, a broad spectrum of binders were examined. Soak testing determined that the most acid-resistant binders were nonionic polymers. Five of these binders were further evaluated using percolation testing.

Jan 1, 2006

By Jackson Jenkins

The second survey of world copper SXEW plants has been completed. Solvent extraction and electrowinning data published in 1996 has been updated and leach data from seventeen plants is now included. The following pages list the results of the thirty- two plants that responded to the survey. Selected information is summarized in graphical form.

Jan 1, 1999

By Susumu Okabe

Mitsubishi Continuous Copper Converter employs the top blowing lance system for the continuous supply of reaction gases into the molten bath. In order to avoid the excessive refractory wear caused by the melt splash without loss of the reaction efficiency, the furnace design and the blowing condition should be optimized. Empirical equations which correlate the splashing rate on the' side wall with the dimensions of the furnace, lance position, lance size, gas velocity and bath properties were obtained by by the physical model study, and compiled into a computer program. The computer program is effectively utilized for the analysis of the actual operation and for the optimum design of new furnaces.

Jan 1, 1998

By Kenichi Moriyama

The Sumitomo Toyo Copper Smelter started operation in 1971, as an epoch-making smelter at which 9996 of the charged sulfur could be captured. In the past ten years, the amount of treated copper concentrate has-been increased from 1,300 l/ day to 1;900 t/ day by the extremely effective application of the oxygen enrichment for a flash smelting furnace and converter furnace. The sulfuric acid production capacity at the acid plant has also been increased up to 1,900 t/ day corresponding to the increase of copper concentrate smelting rate without installing an additional acid plant. Furthermore the sulfur fixed ratio is kept at a high level, more than 99.996. despite the SO. strength fluctuation of the wide range of 596 to 1396 which is attributed to the combination of flash smelting furnace and, P.S. converter. These -operational results at the? acid plant were achieved by several modifications. and two examples are briefly described as follows; (1) Converter modifications in order to cope with the high SO, strength -gas (2) Introduction of the anodically protection shell and tube type acid coolers In addition. the quality of sulfuric acid has been positively increased. For example, the concentration of iron and arsenic, which were the main Impurities in ?sulfuric acid, was successfully .reduced.

Jan 1, 1995

By Peter M. DiGiacomo

In situ leaching technology requires information about how injected fluids flow in the rock in relation to the localization of the valuable minerals to be leached. In oxidative leaching of sulfide copper ores, flow channels can be determined by the observation of residual iron oxides. In contrast oxide copper ores do not leave a detectable residue after leaching. Method is developed that allows a selective labeling of the leach residue with fluorescent compounds. The fluorescent zones can be detected in corings after the leaching operation.

Jan 1, 1981

By F. W. H. Dean

A very sensitive sensor for the detection and measurement of hydrogen in solid steel is described. This technique is non-invasive and uses a collector to sweep the hydrogen emanating from a steel surface and feed to it sensor. This method is particularly sensitive, resolving fluxes to < 2 pI cm?2 S?I, with a linear measurement up to 1000 pI cm&apos;2 S?I, The collector is held on the steel substrate by magnets and it is shown that emanation of hydrogen from the steel is controlled by bulk diffusion of the hydrogen through the steel. The technique is demonstrated to have an excellent response time and reproducibility.

Jan 1, 2001

By Ibrahim Yusufoglu, Cem Kahruman, Mert Zoraga

In this study, a strontium sulfate mineral (celestite) was converted to strontium oxalate in solutions containing ammonium oxalate as a reactant. The experiments were carried out under isothermal conditions. The effects of stirring speed, ammonium oxalate concentration, particle size and temperature on the conversion rate were investigated. During the conversion process, definite volumes of solutions were taken from the reactor after different reaction times for the determination of sulfate ions using ICPOES. Fractional conversions of strontium sulfate were determined at different times and fractional conversion vs time diagrams were generated. It was found that the conversion of strontium sulfate was increased by increasing the ammonium oxalate concentration and temperature in addition to decreasing the particle size. The effect of stirring speed was negligible on the reaction rate. It was observed that above 328 K, a protective layer of strontium oxalate was formed on the strontium sulfate particles. X-ray Powder Diffraction technique was used for characterization of solid substances.

Jan 1, 2014

By K. Moriyamo

Operation improvement efforts at Hyuga Smelting Co., Ltd. have focused on calcining capacity in the reduction rotary kilns ("the kilns"), whose limited feed rate capacity had capped production at around 18,000t-NiN since 1995. To improve the kilns&apos; feed rate capacity of 80 wet t/hr, attempts were made to increase the gas flow in the kilns by increasing the capacity of the off-gas fans. However, as the increased gas flow resulted in only limited improvement of the kilns&apos; feed rate, a scoop feeder was installed on each kiln to add coal to the middle of each kiln&apos;s interior to gain a higher efficiency of thermal supply and conversion. With these gas flow and coal charge addition operations, the kilns&apos; feed rate capacity increased up to 120 wet t/hr, with burner fuel efficiency increasing by approx. 10% (approx. 5% in total with the additional coal included). As a result, production was raised to a level of 22.000t-Ni/Y Keywords: reduction rotary kiln, scoop feeder, additional coal charge.

Jan 1, 2004