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By A. S. Ibrado, D. W. Fuerstenau

"Gold, silver and copper form various complexes with cyanide, of which only the singly charged dicyano form adsorbs appreciably on activated carbon. The adsorption of the dicyano complexes appears to be controlled predominantly by chemical reaction at the surface of a shrinking unreacted core. Metal uptake over time is non-linear, which eliminates control by boundary layer diffusion. The rate of adsorption is not enhanced by a reaction interruption, which suggests the absence of concentration gradients in the pores. Finally, the rate of adsorption increases with decreasing activated carbon size in a manner consistent with the shrinking core model. The results of this investigation accentuate the importance of efficient acid washing of carbon and removing carbon fines from the barren carbon stream. INTRODUCTION With the dwindling reserves of high-grade ores, most of the world’s gold is produced from low-grade ores by cyanide leaching. In the past, leaching was followed by the Merrill-Crowe process, in which gold is precipitated from clarified pregnant solutions by zinc cementation. This process is still being used for high-silver ores, where the cost of carbon stripping becomes prohibitive. For deposits with silver-to-gold ratios of about 4 or less, adsorption on activated carbon would be the usual solution purification step taken. The process simplifies solid-liquid separation and offers a viable solution to preg-robbing organic carbon in some ores. The modern industrial application of carbon adsorption started with the carbon-in-pulp (CIP) process, where carbon adsorption was used mainly as a solution purification step. In 1973, Homestake Mining Company commissioned the first large-scale CIP plant in the U.S.A.1 Later, carbon was added earlier in the circuit to control preg-robbing by adsorbing gold cyanide onto activated carbon as soon as it is dissolved. The scheme is successful because activated carbon is a stronger adsorber than the organic carbon found in preg-robbing ores. This process came to be known as the carbon-in-leach (CIL) process. Numerous research investigations have been performed on the chemistry involved in the CIP process, which at the time of its introduction was not clearly understood. Of these, research on the kinetics of adsorption probably bears the most immediate impact on industrial practice,2,3 where adsorption systems rarely reach equilibrium, if at all, and slight slowdowns in the adsorption rate can translate into significant decreases in revenue. To illustrate this, organic compounds, like flotation reagents, have been known to impair CIP circuits. However, laboratory tests showed that the organic compounds do not significantly affect the adsorption capacity of activated carbon. Rather, the harmful effect may be attributed to a lowered adsorption rate.4,5 Also well known is the faster rate at which fine activated carbon powders reach equilibrium compared to coarse activated carbon, even though the final (equilibrium) amount of material adsorbed per unit weight is the same."

Jan 1, 2015

By K. Heatwole, D. Shier, A. Davis, J. Kidder, S. Sunkavalli

"Acid rock drainage (ARD) is produced when sulfides are exposed to oxygen and water. Oxidation reactions typically result in a depression of pH and leaching of solutes and metals. Many oxidation models have been developed based on oxygen diffusion, but in environments with high permeability, other transport processes (i.e., convection and advection) can play an important role. Multiple sulfide mineral phases with differing oxidation rates should also be incorporated. WROC, a finite-difference model, was developed to account for these factors in predicting ARD. The program includes sulfide mineral oxidation using a shrinking core mechanism, heat transfer by conduction, heat of reaction and oxygen transport by diffusion and advection. The model was validated using data from the literature. After validation, the WROC model was used to simulate several different waste rock scenarios, including different forms of sulfide mineralization and the effect of implementing a waste rock cover. The results demonstrate that including specific sulfide mineral phases can have a significant effect on oxidation and that implementation of a cover can also aid in reducing waste rock oxidation.IntroductionAcid rock drainage (ARD) is a notable environmental concern in areas where rock or other material with acid generation potential is disturbed. ARD is defined as drainage that occurs as a result of sulfide oxidation in rock exposed to air and water. ARD is characterized by low pH, elevated metals concentration (especially aluminum, iron and manganese), sulfate and high total dissolved solids. The low-pH water that results from acid generation is capable of solubilizing heavy metals contained within the rock. The principal sulfide mineral in mine wastes is pyrite (FeS2). Pyrite oxidation is complex and can involve chemical and biological reactions. Oxidation of pyrite by atmospheric oxygen produces one mole of Fe2+, two moles of SO4 2- and two moles of H+ for every mole of pyrite oxidized, as described by Eq. (1)."

Jan 1, 2015

By Joseph O. Cook

I know this is, at best, a frustrating period for the coal mining industry. About 20,000 miners have been laid off, mostly in the Appalachian and mid-western areas, and several mines are working less than 5 days a week; however, the industry is experiencing modern growth and, at least, there is the potential for future growth. The coal industry is probably only operating at about 80 percent of its present capacity, and it is certainly capable of helping this country solve its energy problems. Growth, as a rule, does not come easy, and growth in the coal industry is no exception to this rule. Many formidable challenges have to be overcome. As we all know, mining relies very heavily on the earth sciences, which have advanced significantly in the past few years, but we are always working in a changing environment which in most cases is a hostile environment. Large quantities of material are quickly extracted and rapidly moved in, generally speaking, a very confined area. The very nature of the mining business directly and constantly impacts our environment during this period in which the Nation and the world has become increasingly smaller and more concerned about protecting our environment. In addition, growth brings about an expanding work force which is increasingly younger and less experienced.

Jan 1, 1980

By I. Moreno-Ventas, G. Ríos, J. C. Fernández-Caliani, M. Bacedoni

"This paper delves into the constraints on the nature, origin and thermal evolution of the accretions formed in the uptake shaft of the flash smelting furnace operated by Atlantic Copper in Huelva, Spain, outlining recommended practices for preventing accretion buildup. The accretions were investigated using quantitative electron probe microanalysis, X-ray diffraction and digital imaging techniques, and the experimental data on mineral composition, crystal chemistry and textural relationships were interpreted in terms of thermodynamic phase equilibrium in the SiO2-Fe-O-S system. The results suggest that two distinct types of accretions were formed by the fractional crystallization of two coexisting immiscible melts, under changing conditions of oxygen partial pressure (pO2). The type I accretion of magnetite + delafossite ± cuprite ± tridymite ± metallic copper crystallized from a fractionating copper-rich melt at pO2 above about 10-5 atm, while the type II accretion of magnetite + fayalite + metallic copper + chalcocite derived from a melt with lower copper concentration when pO2 levels dropped below that critical level. Phase compositions and textures were consistent with a cooling history of both compositionally contrasting liquids from about 1,250 °C, the liquidus temperature of magnetite, to eutectic or near-eutectic temperatures of around 1,100 °C. The maintenance of appropriate temperatures — above the liquidus temperature of magnetite — and oxygen partial pressure levels may be critical for the prevention of accretion buildup. IntroductionCopper flash smelting with oxygen-enriched air, an autothermal process developed half a century ago by Outotec (Espoo, Finland), formerly Outokumpu, currently accounts for about 50 percent of the world’s primary sulfide-based copper (Schlesinger et al., 2011). The partial reaction of copper sulfide concentrates produces two separate molten streams, copper-iron-sulfide matte and iron oxide-rich slag, and releases sulfur dioxide (SO2) gas. The matte is sent to converters to remove the remaining iron and sulfur, leaving blister copper with grade of about 99.5 percent copper (Cu), which is cast into anodes for electrolytic refining.The SO2-rich gas generated by the oxidation of sulfide feed particles contains a significant proportion of dust that is entrained in the process off-gas. The gas from smelting is transferred into a waste heat recovery boiler, where it is cleared of dust and cooled before it is converted into sulfuric acid. If the process is not operated properly, the dust-bearing gas may form accretions between the uptake shaft of the flash smelting furnace and the waste heat recovery boiler, causing severe problems in the gas handling system (Swinbourne, Simak and Yazawa, 2002; Miettinen, 2008; Stefanova et al., 2012). Removing the dust accretions usually requires a greal deal of time, effort and resources. Understanding the buildup of accretion may help in reducing the problems and optimizing the process"

Jan 1, 2017

By S. Castro, L. Gutierrez

A classification of flotation processes carried out in concentrated electrolyte solutions, e.g., seawater, is proposed using the most obvious features of these processes: low or high content of Mg2+ and Ca2+ ions, pulp ionic strength, and pH. The first distinguishable group is the processes carried out in NaCl/KCl solutions, about 0.5 M in the case of salt flotation of inherently hydrophobic minerals, and at concentrations about 10 times higher in the flotation of potash ores. In the flotation of sulfide ores, such as nickel or copper ores, with xanthate-like collectors, the xanthate collector is apparently not affected by pulp ionic strength and only adjustment of frother may be required. Content of Mg2+ and Ca2+ ions in seawater is the main difference between such systems and fresh water. The presence of these metallic ions can adversely affect flotation in the pH ranges over which these ions hydrolyse. The successful flotation of Cu-Mo ores typically requires depression of pyrite at high pH values achieved with the use of lime. However, in seawater, flotation of Cu-Mo ores requires removal of the hydrolysis products of the Mg2+ and Ca2+ ions or the use of a pyrite depressant that can be effective over the pH ranges that are much below the pH of hydrolysis. Mg2+ and Ca2+ ions also affect flotation of phosphate ores with fatty acids. In this case, the depression mechanism is not caused by precipitating magnesium hydroxides on the mineral surface but by precipitation of collector insoluble salts, and the same ions are responsible for depression in both cases. In the seawater flotation of Cu-Mo sulfide ores and phosphate ores, the practical solution involves either removal of Mg2+ and Ca2+ ions prior to the flotation or complexation with other reagents.

By J. J. Casey

This paper is one of a series of presentations organized by the Conference of American Society of Civil Engineers with the goal of making significant progress toward an equitable and effective allocation of risks in construction undertakings among the principal parties - owner, contractor and designer. The role I have been assigned is principally one of identification of risk while others will devote greater attention to the allocation of these risks and the contractual arrangements necessary to properly make these allocations. Construction projects are joint undertakings by parties who bring different skills and interests toward a common effort, much as this conference does. A project is not an adversary proceeding and does not benefit from establishment of an adversary mode, as our lawyer friends seek in the resolution of legal issues. Accordingly, I urge upon this Conference the adoption of two basic precepts and guidelines as the criteria for sharing of the risks inherent in construction undertakings toward achievement through mutual effort the common goal of a successful project completed in the shortest time and at the least overall cost. These precepts are: (1) that all risks are rightfully the owners unless transferred to or assumed by another party for a fair compensation; and (2) that the principle guideline in determining whether a risk should be so transferred should be whether the receiving party has both the competence to fairly assess the risk and the expertise necessary to control or minimize it. The sponsors of the conference have provided certain guidelines to the authors. There is, however, no constraint in expressing one's bias and I suspect that my contractor's outlook may be inherent in my comments. The guidelines have suggested that I indicate whether the risks identified are ones that can or should be shared or borne by one party alone. In doing so, I will attempt to follow the precepts I have recommended.

Jan 1, 1979

By Jürgen. F. Brune, CLAIRE STREBINGER, ADITYA JUGANDA, Gregory E. Bogin Jr

The abstract highlights the risk of methane gas explosions in underground coal mines and the potential of computational fluid dynamics (CFD) modeling to simulate such events and assess their impact on mine ventilation. The study focuses on developing CFD models for large-scale explosions in longwall mines, specifically simulating methane gas explosions resulting from face ignition during coal cutting. The research demonstrates the integration of a combustion model into a longwall mine ventilation model and shows how the availability of explosive gas mixtures significantly affects flame propagation and explosion pressure.

Mar 27, 2022

By Herbert F. Nyberg

The Black River Falls Mine is owned and operated by Jackson County Iron Company, a wholly owned subsidiary of Inland Steel Company. It is located in vest central Wisconsin, seven miles east of the city of Black River Falls. This is the first taconite plant in the state of Wisconsin. Iron mining started in this area in 1856 but soon failed due to the low grade ore and crude methods of mining and transportation. Inland Steel Company acquired the property in 1939. Some drilling and test work was done in 1940, but the economics of developing the property at that time were not favolable. Improved methods of concentrating and pelletizing in the 1960's made it possible to build the present plant. Due to the limited ore reserve of 45,000,000 tons with expected recovery of 33% it was necessary to limit the capacity of the operation to 750,000 TPY with a life of 20 years. There was some concern about an operation of such limited capacity. A million ton operation was considered the minimum size plant for a profitable operation.

Jan 1, 1976

By D. M. Hausen

A quantitative x-ray diffraction method has been developed for the analysis of alteration minerals in wallrock. Alteration data are plotted and contoured (analogous to geochemical data). Alteration trends outlined by this technique correlate closely with geochemical anomalies, and in some cases attend well beyond the perimeter of anomalous base metal values. "Monomineralic contouring," applied originally to porphyry-type mineralization, has been extended to other types of mineralization, including volcanogenic massive sulfide deposits. Equipment and techniques used in the quantitative measurement of alteration mineralogy are discussed.

Jan 1, 1978

By K. Severin, B. Flanigan, P. Marion

"Plutonic-related" gold deposits in Interior and SW Alaska (Tintina Gold Belt) vary significantly in size, grade, vein/deposit morphology, depth of emplacement, distance from causative pluton and metal association. Metal associations such as Au-Bi and Au-As- (Sb-Hg) are a good empirical indicator of the depth of emplacement and distance from causative pluton. These associations have been used successfully in exploration. Results from several analytical techniques also suggest a phenomenological cause for these metal associations. Gold and bismuth have paired mineralogy at high temperatures and, thus, are best correlated at deposits that are deep and/or close to causative intrusions.

Jan 1, 2003

By J. D. Vincent

The Henderson mine site is located at Red Mountain on the eastern slope of the Rocky Mountains, approximately 50 miles west of Denver, Colorado. The mill site is on the west slope of the Rockies and mine and mill will be connected by an underground railroad. All designs were for a 30,000 ton per day molybdenite processing plant with provisions for future expansion up to 50,000 ton per day if required. This plan did not just happen, but slowly evolved over the course of about three and one-half years. Many plants cannot afford such a delay, but the Henderson project will take about 10 years from the time it was first discovered until production starts, and these 3 !1 years were well spent in determining the best possible plant site and flowsheet. This paper describes some of the problems and the decisions made in arriving at the final location and flowsheet. The paper does not go into the specific details of how protection of the environment went hand-in-hand with all other project considerations. This particular aspect of the planning has been well-reported on other occasions and considerable information on it is readily available.

Jan 1, 1972

By K. Kim, T. M. Yegulalp

A new explanation of the scale dependency of rock strength is presented based on the theory of extremes. A brief review of past work on specimen size and strength relationship is followed by an introduction to the fundamentals of the underlying theory of extremes and its relationship to the scale effect. It is shown that the weakest link theory is directly related to extremal statistics and that parameters of strength distributions of rock can be derived as a function of the specimen size. Three sets of Brazilian test data are used to demonstrate the use of this approach.

Jan 1, 1994

By Jurgen Weissflog

Why, where and since when using shiftable conveyors? Advantages of this equipment The ever increasing demand for bulk materials such as ore, coal, lignite, oilsand, oilshale and bauxite requires mainly an opencast operation. To exploit these materials huge amounts of overburden and partings must be transportes by means of conveyors, trucks or trains. When analyzing the various opencast mines it can be established that there exist only two basic types of mining systems, i. e., the discontinuous strip mining system as used in the USA (Fig. 1) and the continuous mining system as is commonly applied in Europe. The reason why these two mining methods have been developed parallel to and independently of each other to such a high technical standard results from the varying geological conditions of the mineral deposits.

Jan 1, 1983

By F. Mielli

Over the last three years there has been an increase in mining congress and conferences focusing on water management. Water in mining is a key concern for mine managers and operations, and we are now seeing this operational dilemma escalated to the level it deserves. According to Frost & Sullivan research, mining water and wastewater treatment and its related technologies will be a U$3.6 Billion global market in 2016, which translates the importance of this issue. Looking at the current mining trends, some factors increased the importance of water in mining operations, including: ? Future mining investments will be located in geographical locations where water is scarce (water stressed areas) ? A decline in grade will increase the intensity of mineral processes and therefore increase the use of the water ? Increased sustainability and regulations will extend the control/monitoring of water during the entire mine life cycle representation of the mine water flow system. A water balance has several benefits/objectives in a mine operation: ? Mine planning/simulation of mining scenarios/climate change Production optimization ? Minimizing strategic and operational risks ? Social license to operate ? Water-smart mine planning ? Target: water neutral mines ? Benchmarking within and between sites ? Sharing knowledge/technology transfer ? Reporting/communications ? Permitting/Compliance

Feb 23, 2014

By K. Ananthpadmanabhan

Hydrolyzable surfactants such as fatty acids and amines undergo, in addition to micellisation and precipitation, various associative interactions in aqueous solutions to form ion molecular complexes such as acid-soap, dimers etc. depending upon the solution conditions such as pH. The interaction of these collector species with the mineral surface and with other dissolved species in solution will play a significant role in determining the interfacial processes such as adsorption and flotation. Marked differences in the hydrophobicity imparted to the mineral surface depending upon the solution conditions such as Ph can be attributed to possible differences in surface activities of the above complexes. This aspect of solution chemistry of flotation systems is discussed here for two widely used collectors namely, oleic acid and dodecylamine. Equilibrium species distribution diagrams based on the available literature .data and on estimates of energy of interactions between molecules, have been obtained for oleic acid and dodecylamine solutions.

Jan 1, 1978

By Roger P. Ashley

The main problem in geochemical exploration for gold ore bodies in the 40 km2 hydrothermally altered area at Goldfield is to decide which of the many silicified ledges exposed are most likely to yield deposits with additional subsurface exploration. We conclude that the most efficient way to search for exploration targets is to collect rock samples from the ledges and analyze for the following elements in decreasing order of priority: gold, lead and silver, bismuth, and mercury. These elements form relict hypogene aureoles restricted to the ledges and are not appreciably redistributed during supergene leaching.

Jan 1, 1978

By Li Zhang, Jing Zhao, Chuanwei Zang, Shuanlin Wang

The application of gob-side entry retaining (GER) in steeply pitching seam longwall mining with a hard roof has always been a difficult problem. Based on the simplified roof beam mechanical model, the traditional gob-side entry retaining by packing (GERP) roof structure evolution process and its problems with use in steeply pitching seams are analyzed. Therefore, based on the unique characteristics of the gangue rolling and accumulating in the steeply pitching seam, this contribution proposes an innovative method of gob-side entry retaining by roof cutting (GERRC) in steeply pitching seam and details its technical process. The roof structures of the GERRC and the GERP are compared. Taking the Chang Gouyu Coal Mine as a case study, field experiments were carried out. This research finds that the GERRC can both overcome the impact of rolling gangue on roadside support and make the rolling and stacking gangue become a roadside support. The roof structure of the GERRC is in a one-time statically indeterminate state, which is conducive to the stability of the roadway. In the field test, the total displacement of the roadway roof and floor is 97 mm, the supporting pressure of the serried single props is less than 28 MPa, and the props have no obvious bending phenomenon.

May 6, 2020

By D. Zim

Mining activity in South America is a growing enterprise. One of difficulties found in many areas of the South American continent, especially in north Chile and south Peru, is the shortage of water supply. In order to overcome this difficulty some mining companies proposed to transport the water from Pacific Ocean up to the mountains. This can be accomplished by the use of stainless steel pipelines, but this is a cost prohibitive solution and is also subject to severe pitting corrosion in a saline environment. The use of mild steel may be a lower cost solution than stainless steel as the material of construction for pipelines but it is subject to corrosion anyway. The corrosion in this case can be internal or external corrosion although cathodic protection as well preventive maintenance usually is enough to mitigate external corrosion without the need to shut down the pipeline. The same is not true about the prevention of internal corrosion. It is not practical, sometimes not even possible, shutdown a pipeline to carry out an inspection and fix sections where potential failures are detected. It is possible avoid corrosion caused by sea water within the mild steel pipelines by applying a proper chemical program designed to virtually eliminate dissolved oxygen in the water commonly called deaeration.1 This type of treatment obviously involves additional capital investment since it requires the construction of one deaerator with the first pumping station and additional equipment at each point where the water can come into contact with oxygen. Deaerators will increase operational costs and subsequent injection of chemicals will be required in the case of multiple degasification facilities thus increasing the consumption of chemicals. grams based on oxygen scavengers, the objective of the present study is to develop a new water treatment capable of preventing mild steel corrosion in aerated sea water. The new treatment must be able to prevent both generalized and localized (pitting) corrosion and overcome the necessity to construct and operate deaerators.

Feb 23, 2014

By J. Larsson

In the pursuit of increased safety the mining industry has worked to develop systems for remote control and autonomous operation of both stationary and mobile equipment. This paper reports on a newly developed system for teleoperation and autonomous tramming of LHD (Load-Haul-Dump) mining vehicles that not only increases the safety of the operators, but also has the potential to increase productivity.

Jan 1, 2010

By R. Y. Wan

Newmont Gold Company has advantageously used the capabilities of mineral oxidizing bacteria to develop a process for pretreatment of low grade sulfidic and carbonaceous-sulfidic refractory gold ores. The biooxidation process results in the oxidation of the sulfidic minerals with increased exposure of gold for subsequent gold recovery. The biooxidized carbonaceous-sulfidic ores cannot be heap leached with cyanide because of the "preg-robbing" characteristics of the carbonaceous matters in the ores. An alternative heap leach process using ammonium thiosulfate was developed to extract gold from the "preg-robbing" biooxidized ores. The ammonium thiosulfate leach process has been successfully practiced both in laboratory and pilot plant testing. Satisfactory test results encourage the continuation of process development.

Jan 1, 1996