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1. Book review Steels- microstructure and properties, by R. W. K. Honeycombe. London, Edward Arnold, 1981. 244 pp. Rl9,90. (Reviewer: P. T. Wedepohl) 2. New books Decision making in continuous steel casting, by Mark A. Vonderembse. New York, Bowker Publishing Co., 1981. U8 pp. Handbook on continuous casting, by E. Herrmann' Diisseldorf, Aluminium-Verlag GmbH, 1980. 742 pp. Cloth DM 1250, leather DM 1500. Pore structure analysis from a nitrogen adsorption study of porous materials using a volumetric method. User's guide to the FORTRAN programs: PORESl and PORES2, by E. G. K. Woods. Pretoria, CERGCSIR (P.O. Box 395, Pretoria 0001), May 1981. Oil and gas from coal, by Dick Olliver. London, Financial Times (10 Cannon Street, London EC4P 4BY), 1980. £120. The seventies: a review, the eighties, a preview, by W. Hibbard (editor). Oxford, Pergamon, 1981. 120 pp. £12.50. Computers in materials technology, by T. Ericsson editor). Oxford, Pergamon, 1981. 230 pp. £14.50.

Jan 1, 1981

1. Book reviews Stainless Steels '84. London, Institute of Metals, 1985. £39 (U.K.), US$62 (elsewhere) Reviewer: J.B. Oalton Process engineering of size reduction: bal miling, by LG. Austin, R.R. Klimpel, andP.T. Luckie. New York, AIME, 1984. 561 pp. Reviewer: M.J. Lazer 2. Recent publications Hard and superhard materials. New York, Worltech Report Inc. (44 Woodbine Avenue, P.O. Box 212, Northport, 11768 U.S.A.), 1985. 270 pp. $1500.International comparison of standard materials-steel and cast iron, compiled by W. Oto and K. Schaning, and edited by DIN German Standards Institute e.V. Berlin, Beuth Verlag GmbH, 1985. 3rd edition, 416 pp. DM 158. Tin and its uses no. 146. Greenford (England), International Tin Research Institute, 1985. Write your own CV, by Max Kowen. Johannesburg, Legal Personnel Selections (404 Medical Centre, Cor Jeppe and Delvers Sts, Johannesburg 2001), Nov. 1985. 40 pp. R12,50 + GST.

Jan 1, 1986

By R. J. Davidson

The mechanism of gold adsorption on activated charcoal by R. J. DAVIDSON: M.Se., Ph.D. (Rhodes) (Visitor) The adsorption of gold onto activated charcoal is most dependent on the concentration and character of the 'spectator' cations present in the adsorption medium. In the presence of calcium ions, gold is adsorbed as the calcium aurocyanide complex. The degree to which the aurocyanide complexes are adsorbed follows the series Ca> Mt:> H> Li> Na> K, calcium aurocyanide being the most stable complex and potassium aurocyanide the least firmly bound. If a loaded charcoal, where the gold is present as the calcium complex, is treated initially with either sodium carbonate or potassium carbonate solutions, the gold can subsequently be eluted from the charcoal with hot deionized water as either the sodium or the potassium complex respectively. The elution of gold with deionized water appears to be most attractive practically and economically, and has several potential applications in the recovery of gold from dilute solutions.

Jan 10, 1974

By H. S. Sichel

Statistical valuation of diamondiferous deposits By H. S. SICHEL, D.Sc The valuation of diamondiferous deposits depends on (i) the density distribution, (ii) the size distribution of stones and (iii) the selling price structure prevailing at a particular time. In the density distribution the stochastic variable is defined as the number of individual stones found per sample unit irrespective of the stone size. The density distribution is discrete and allows for barren sample units. As diamonds often occur in clusters, a Poisson mixture distribution is derived which is entirely new, as existing discrete distributions cannot represent the stone number frequencies found in nature. For the sizes of diamonds, which are measured by weight, a new compound logarithmic normal distribution is developed. Combination of (i), (il) and (iii) leads to a meaningful appraisal of diamondiferous ground expressed in monetary value per production unit of mining. Finally, confidence limits are calculated which allow for inferences from sampling to recovery.

By Siemag Transplan GmbH

At the Hansa Mine in Dortmund, Germany, coarse run-of-mine coal, up to 60 mm in particle size, has been brought to the surface hydraulically from a depth of 850 m since November 1977. Hoisting is done by a three-chamber pipefeeder, by means of which up to 400 t/h can be lifted. The pipefeeder operates without problems, and has so far shown itself to be efficient and reliable. Vertical hoisting can be carried out by water supplied from the surface, from underground, or from a surface water supply in combination with minewater from underground. Water that flows into the mine, which would in any event have to be pumped to the surface, can be utilized for hoisting operations. The energy costs per ton of coal for a lifting height of 850 m vary between 41 and 62 South African cents, and therefore lie within the range of costs that apply to conventional hoisting.

Jan 1, 1980

Currently the most widely used formula in pillar design is the power formula, which implicitly assumes a volume effect. This assumption is critically examined, and it is proposed .that a limiting strength value, the critical rock mass strength, be used for pillar design instead. A methodology is provided to determine this value. It is suggested that the effects of geometry on pillar strength are well described by a linear function and the power formula, for w/h ratios less than or equal to about 5. This approach together with the use of the critical rock mass strength, removes the volume effect. Various factors that affect pillar strength are examined. The concept of explicitly determining the stability of each component in the pillar system is briefly discussed. It is proposed that pillar design be expanded to a pillar system design procedure that incorporates the interaction of the pillar, roof and floor strata, and the loading system.

Jan 1, 1998

By T. Nyakudarika

The Unki Platinum Mines concentrator, employing an MF2 circuit configuration which includes fully-autogenous primary milling of run-of-mine (ROM) ore, was commissioned in November 2010. The project was Anglo American Platinum?s first PGM concentrator in Zimbabwe and would form a significant contribution to the group?s platinum production. The project financials demonstrated that the project was operating-cost sensitive. After reviewing the metallurgical testwork, mineralogical examinations, and the history of similar operations, it became apparent that the Unki ore characteristics rendered it amenable to autogenous milling. The primary ball mill, structurally designed for 30 per cent steel load, could be operated at the required initial phase throughput with fully-autogenous primary milling, realizing savings in both power requirements and grinding media consumption. The original mill sizing had been done with fully-autogenous milling in mind, but allowing for flexibility and mitigation in case of varied mining fragmentation. Since attaining steady state, target grinds have been achieved. This paper looks at the Unki ore characterization programme, design considerations, and the operational and control philosophy for a successful comminution circuit, and discusses the design to produce a flexible, low opex, mitigated comminution and overall MF2 flowsheet that is easily expanded in line with the potential for optimum exploitation of the orebody.

Jan 1, 2012

By D. T. Jordan, L. C. Coetzee, G. Kalenga, T. Mahlangu, W. J. Shipman

Although online free cyanide analysers are widely available and used in gold leaching operations worldwide, reliable automated free cyanide concentration control is not consistently achieved in many of these operations. Effective cyanide concentration control is complex owing to amongst others, the long residence times and ore feed variations. Model Predictive Control (MPC) has been proven to provide superior cyanide concentration control over traditional proportional-integral-derivative (PID) control, leading to savings in operational costs and reduced leachable gold losses. In the first example reported in this paper, MPC has improved control of the free cyanide concentration by keeping it within the required range 73% of the time during testing, compared to the previous PID controller that only achieved this target 30% of the time. This represents a 143% improvement. Another example demonstrates a 22% reduction in cyanide usage as a result of using MPC. MPC functionality is rarely available on the programmable logic controllers (PLCs) and control systems installed at gold plants, hence it is implemented on a personal computer (PC) networked to the cyanide analyser and plant infrastructure. Mintek has developed an embedded MPC that installs into the Mintek Cynoprobe analyser, adding MPC functionality without the need for additional PC and network infrastructure, reducing installation costs. This allows plants to minimise their expenditure on additional infrastructure while gaining the benefits of superior MPC technology for multiple cyanide dosage points. This paper will present results showing that the embedded MPC performs as well as Mintek’s existing PC-based StarCS MPC controller, making it a viable alternative for infrastructure-constrained gold plants. Keywords: Model predictive control, gold cyanidation

Jan 1, 2020

By N. A. Barcza

Pointing out that South Africa needs to utilize its wealth-creating activities, together with local and international investment, to further develop its industries, the address asserts that the mining and minerals industries, especially in the manufacture of beneficiated products, offer the greatest potential for South Africa to achieve its goal. As many mineral-beneficiation processes are based on pyrometallurgical routes, the address goes on to describe some historical - pyrometallurgical operations and to indicate probable developments in the future. These include growth in the fields of both precious and base metals. After discussing environmental and recycling matters, together with manpower requirements, the address concludes that the major growth in the mining and minerals industries will occur in the manufacture of steel, stainless steel, ferro-alloys (particularly ferrochromium), aluminium, and titania slag.

Jan 1, 1996

In a gold CIP/CIL circuit, adding new circuit water to a final tails thickener and then directing the thickener overflow to the head of the circuit significantly reduces the cyanide concentration at the TSF discharge spigot. The new water is used to dilute the final tails. The dilution and recycle of the tails in this manner may have the added benefit of reducing reagent consumption, in some cases to the point where the reagent savings justify the expenditure and Cyanide Code compliance is achieved at no extra cost. Potential circuit configurations and water recycles can be modelled by splicing a flowsheeting and thermodynamics package, such that changes to the composition of the water can be reduced to chemical speciation with a Gibbs free energy minimisation enabling a complete understanding of the circuit water chemistry.

Jan 1, 2007

By M. Mpofu, M. van Schoor, T. Kgarume, H. Grobler

The South African mining industry has committed to achieving a state of zero harm for its workforce, with a strong emphasis on worker health and safety. Among the major safety concerns are falls of ground, a leading cause of injuries and fatalities. Ground-penetrating radar, a non-destructive geophysical method, is recognised for its ability to image structures, fractures, and geological features within the rock mass. However, ground penetrating radar data is often acquired in local coordinates, posing challenges for visualisation in mine computer-aided design or three-dimensional visualisation software. This study explores the pivotal role of light detection and ranging data in transforming ground penetrating radar data from local survey coordinates to absolute mine coordinates. A comprehensive georeferencing methodology is presented, providing the stepwise progression from the initial georeferencing of ground penetrating radar data to the ultimate integration of ground penetrating radar and light detection and ranging datasets, resulting in the creation of a ground penetrating radar-light detection and ranging three-dimensional model. The proposed approach not only facilitates the integration of but also offers a practical means of visualising the integrated datasets within commonly used computer-aided design or three-dimensional visualisation software. An essential aspect of this integration is the adoption of non-proprietary data formats, specifically American Standard Code for Information Interchange text files, ensuring broader accessibility and compatibility. The potential for integrating diverse datasets to construct insightful models of the underground mining environment is illustrated. Integration of different datasets has the potential to offer a holistic understanding of the mining environment, providing essential information to decision-makers.

Jul 23, 2025

By Jean-Claude Paye

In February 1996 the OECD's Environment Policy Committee will commemorate its 25th anniversary with a fifth meeting at Ministerial level. Environment ministers will be taking stock of the progress made by OECD countries in protecting and managing the environment in that quarter-century, and sharing views on likely challenges and co-operative responses. Ministers can point to many important accomplishments. Scientific understanding and technological tools for establishing and monitoring risks to human health and the environment have improved dramatically since the early 1970s. All OECD countries now have in place comprehensive environmental legislation, supported by specialized institutions for policy design, implementation and enforcement. The results of these efforts are increasingly evident in the form of cleaner air and water, and improved protection of natural areas, notwithstanding the many complex problems that remain.

Jan 1, 1996

By M. Timucin

Phase relations within the condensed Cu-Cu2S-PbS-Pb region of the Cu-Pb-S ternary were investigated. The boundaries of the ternary liquid-miscibility gap were redrawn, and the directions of the tie-lines were established by the quenching of samples equilibrated in evacuated and sealed silica capsules at 1473 K. The activities of lead in sulphur-saturated Cu-Pb alloys along the boundary of the miscibility gap were measured by the dew-point technique at 1473 K. From the tie-line distributions, measured lead activities, known activities of the Cu2S-PbS join, and the ternary Gibbs-Duhem integration, consistent sets of activities for lead and copper and partial pressures of sulphur were obtained along the ternary miscibility gap at 1473 K.

Jan 1, 1989

By B. Aydin, A. S. Aloglu, S. Kahraman, E. Saygin

"The coal strength parameter is used in operations such as the selection and design of mechanical excavators and coal crushing/grinding equipment. However, coring or cutting prismatic specimens from coal for the standard strength tests is difficult, and sometimes not possible. For this reason a method for the indirect determination of coal strength from easy tests would be useful. In this study, the predictability of coal strength from the needle penetration test was investigated. This is a very easy and practical test method. Point load and needle penetration index (NPI) tests were carried out on coal specimens from Çayirhan coalfield in Turkey. The point load indexes were converted to the uniaxial compressive strength (UCS) values by using the general conversion factor. The UCS and NPI values were evaluated using regression analysis. A strong linear relationship was found between the two parameters. The conversion factor for the UCS-NPI ratio is 0.35 for the tested coal samples. It is concluded that the UCS of coal can be predicted from the NPI.IntroductionKnowledge of coal strength is important for the selection and design of mechanical excavators and coal crushing and grinding equipment. Uniaxial compressive strength of coal is used in designing pillar dimensions in room and pillar mining. Coals always contain bedding planes and cleats; they are also brittle and fragile. Therefore, coring or cutting prismatic specimens from coal for the standard strength tests is difficult, and sometimes not possible. For this reason, a method for the estimation of coal strength from easy tests would be useful.The needle penetration test is a nondestructive index test that is applicable both in the field and the laboratory and does not require any special sample preparation. The test has been used for the estimation of physical and mechanical properties of weak or soft rocks (Okada et al., 1985; Yamaguchi et al., 1997; Takahashi, Noto, and Yokokawa, 1988; Uchida et al., 2004; Aydan et al., 2006; Aydan, Watanabe, and Tokashiki, 2008; Aydan, 2012; Erguler and Ulusay, 2007; Park, Obara, and Kan, 2011; Ulusay and Erguler, 2012; Aydan and Ulusay, 2013; Aydan. Sato, and Yagi, 2014). This study investigates the predictability of coal strength from the needle penetration test."

Jan 1, 2017

By L. Forbes, G. Forbes, J. Wang

Bubble size measurement is a vital part of flotation system analysis and diagnostics. Over the years, a great many different bubble size analysis tools have been developed. However, all of them rely on ex-situ measurement and in-pulp sampling techniques. This paper evaluates the Mettler Toledo ParticleView™ Measurement probe as a novel method for in-situ bubble size measurement. This device is then compared to the conventional Anglo Platinum Bubble Sizer (StoneThree). It was found that the in-situ bubble size analysis technology appears to be a more user-friendly and reliable option for determining bubble size in flotation. However, the current instrument design is not suited to industrial applications. Keywords: Bubble size measurement, bubble coalescence, PVM probe

Jan 1, 2020

1. Book reviews Mill Operators' Conference. Parkville (Australia), Australasian Institute of Mining and Metallurgy, 1982. 425 pp. Reviewer: B. K. Loveday Off highway truck haulage. Newman Combined Group, the Australian Institute of Mining and Metallurgy and the Institute of Engineers in Australia. Sep. 1982. Reviewer: B. J. Vorster Environmental engineering in South African mines.Johannesburg, Mine Ventilation Society of South Africa, 1982. 974 pp. Reviewer: A. N. Brown Underground Operators Conference. West Coast Tasmania Branch. Australasian Institute of Mining and Metallurgy. Reviewer: D. R. Aspeling 2. New publications Electric steelimaking in the eighties: challenges and opportunities. Rotterdam, Balkema, 1982. 362 pp. $50.00 or £33. Tungsten: a review, by P. M. Harris and D. S. C. Humphreys. London, Institution of Mining and Metallurgy (Occasional Paper 2), 1983. Members: £3, nonmembers £6. The platinum industry - prospects in recovery. London, Shearson{American Express Ltd (St. Alphage House, Fore Street, London EC2Y 5DA), 1983. £75. The best of E&MJ mining and processing idea book' New York, Engineering and Mining Journal, 1983. 128 pp. Free with subscription to Engineering and Mining Journal. Mining 1983. Harlow (U.K.), Longman Group Limited, 1983. 500 pp. £39.50. Ooncise guide to world coalfields. London, World Coal Resources and Reserves Data Bank Service (14/15 Lower Grosvenor Place, London SW1W OEX), 1983. 380 pp. £45. 3. Canadian publications Asbestos, by G. O. Vagt, 9 pp. Ooal and Coke, by J. A. Aylsworth, 16 pp. Orude oil and natural gas, by R. L. Thomas, 12 pp. Phosphate, by G. S. Barry, 8 pp. Rhenium, by S. A. Hamilton, 3 pp. 4. Mintek reports Report 2102D The recovery of magnesite from dump fines from the Strathmore Mine. (First issued Feb. 1981.) Report 2106D The evaluation of drill cores and a bulk sample from a deposit of andalusite near Thabazimbi. (First issued Mar., 1981.) Report 2108D Evaluation of a grinding aid in batch grinding, classification, and gravity concentration. (First issued Jul. 1981.) Report 2109D The evaluation of an andalusite deposit from Kleinfontein, Groot Marico. (First issued Apr. 1981.) Report M7D The beneficiation of chromite ore from the Ma-l seam near Marikana. (First issued Nov. 1981.) Report M62 A preliminary investigation into the extraction of zinc by direct oxidative leaching of high-manganese sphalerite. Report M76 A mineralogical investigation of a refractory gold ore, and of a sulphide concentrate and calcined tailing from that ore. Report M85 List of unrestricted Mintek publications issued from 1966 to 1982. Report M97 Reduction in metal consumption by the use of alternating lines of higher and lower lifter bars in a rod mill. Report M98 Multivariable control and optimization of the operation of a milling circuit at East Driefontein Gold Mine. Report M101 The potentiality of heat-treated balls in the grinding of gold ores. X-ray diffraction The Southern Transvaal Section of the South Mrican Chemical Institute is to present a mini-course on 'X-ray Diffraction: Theory and Application' in Johannesburg on 18th and 19th October, 1983.

Jan 1, 1983

By R. G. B. Pickering, B. Ebner

The hard rock gold and platinum mines in South Africa have seen little development in the technology of mining. Holes are still drilled in the rock—though the latest water hydraulic rockdrills will complete that task in two minutes compared with the eight hours for hand drilling. Charging up is with far safer explosives and with available initiation systems it is no longer necessary to run up the face lighting each fuse. Movement of rock in the stope is predominantly by means of scraper buckets and scraper winches — these were first introduced in the 1920s.Support is still mainly rock, either in sit pillars or backfill, or alternatively wood. Just as themining process has changed very little it is hardly surprising that the productivity of mining is also relatively unchanged. Major efforts have been made to mechanize the mining process. However, most of the narrow reef mines where ‘trackless mechanized mining’ was introduced in the early 1980s have reverted to conventional mining. In the wider reefs mechanized mining is the option of choice, unfortunately most of the gold and platinum mines have very narrow reefs that are not suitable to’ off the shelf’ equipment. The move to introduce room-and-pillar mining into the narrow UG2reefs is at the expense of mining more waste with the reef, fortunately it appears that appropriate waste and reef separation processes are available. Room-and-pillar mining followed by long holedrilling and blasting of a narrow slot of reef out of the pillars currently appears to offer the best of both worlds—maximum reef recovery with minimum waste dilution. All these mining methods are still dependent on blasting to break the rock. The cyclic nature of mining by blasting places severe constraints on the rate of face advance that can be achieved and consequently the utilization of the invested capital. For narrow reef hard rock mining to break out of these constraints and to really make progress in the 21st century it is necessary to follow the lead of the soft rock mining industry and change the technology of mining. In the underground coal mining industry, coal cutting has been proved to be the most cost-effective solution. In narrow reef hard rock mining the future must be based on the development of non-explosive methods of rock breaking that in turn are integrated into continuous mining systems. Non-explosive so that the mining operation can be conducted on a continuous basis, with nodelays for the removal of blasting fumes. Continuous mining also maximizes the return on the capital invested in developing the mine. Rock cutting will define the stope width and that in turn will be designed to minimize waste dilution; it will also minimize damage to the hanging and create a safer environment. Mechanization makes it possible to automate the mining process and further improve safety by positioning the operators in a safer environment. This paper defines the work to evaluate cutting processes carried out by Sandvik TamrockVoest Alpine. The evaluation was in the UG2 and the pyroxenite and norite typical of the Merensky Platinum Reefs. A novel form of mining machine is proposed that will utilize existing technology. Finally the paper describes the interaction between Sandvik Tamrock Voest Alpineand Lonmin Platinum and the initiation of an agreement to develop and trial a prototype hard rock narrow reef mining machine.

Sep 1, 2001

By C. M. G. Wortley

One of the major deliverables of the AMIRA P754 Project, which was sponsored by several major mining companies, was a code of practice and guidelines for metal accounting for the mining and metallurgical industry. These had the objective of improving the auditability and transparency of metal accounting from mine to product, thus assisting in good corporate governance. The overriding objective of mass measurement for metal accounting is to establish the mass of the particular material or component present at a specific time, or the mass flow of that component over a defined time period, to a defined accuracy suitable for metal balancing. As such, it is the first measurement in the chain that includes sampling, sample preparation and analysis, each of which introduces its own errors. Materials often contain moisture, the proportion of which must also be established in order to obtain the dry mass. They may also have to be measured as a volume or mass/mass flow of slurry, or in stockpiles or storage areas, in which case the relative density must be measured. Both the density and moisture measurement often introduce significant error. Whereas a great deal of effort has been directed at sampling, sample preparation and analysis to improve accuracy and establish the error, the same can seldom be said for the mass determination, including the moisture and density measurements. The possible major causes of error are highlighted and methods of reducing them discussed. Mass measurement can be classified into those measurements necessary for custody transfer and primary accounting of the input and output streams to a plant or operation, and measurements required for secondary accounting, or management control. The latter include intra company transfers and plant area performance, and those required for plant control only. This paper is concerned only with primary accounting measurements. The code and best practice state that the equipment should be certified (as sized) as is required for custody transfer. The most accurate and precise of the various possible methods is the static measurement of mass on a weighbridge, platform scale or a weigh bin. If static measurement is not possible, which is often the case for ore fed to a plant, possible alternatives are electromechanical conveyor belt weighers or in-motion weighing of rail trucks. In all cases the material must be adequately sampled to enable a representative moisture content to be determined to calculate the dry mass. Where material is flowing inside conduits, only certain types of the multiplicity of flow meters available may be used and, in the case of slurries, very few flow meters are suitable. As most flow meters measure volume or velocity, the density of the material must also be measured. The basic requirements in order to achieve satisfactory results for the mass, of the component of interest, are listed, as well as common problems and pitfalls encountered in practice. The measurement of the mass of stockpiles and in-plant stocks, often required for metal accounting, is often the largest source of error in metal balances. The reasons for this and methods for reducing and managing the effect are discussed.

Jan 1, 2009

By P. R. Jochens, D. D. Howat, R. B. Atmore

INTRODUCTION The Miller chlorination process has assumed a preeminent position in the refining of gold bullion, a position it has maintained for over half a century. In the early sixties considerable interest was aroused by the idea of producing a consistently high grade bullion at the mine smelthouses themselves. However, as the use of chlorine in industrial plants is associated with considerable hazards, oxygen was considered a natural alternative, apart from bing less expensive than chlorine. Partial refining at the mine smelthouses would considerably decrease the requirements made on Rand Refinery Limited as well as indicating the possibility of reducing final refining costs. An added factor would be the purer silver chloride obtainable, after prior removal of the base metals by oxygen injection, which would facilitate the production of high-purity silver. The free energies of formation of the oxides of the metals;- silver, copper, lead, zinc, iron and bismuth indicate that, with the exception of silver, these metals should be capable of removal as oxides by oxygen injection. Rose1 had shown that during injection of gold bullion, considerable loss of silver to the boraxsilver slag occurred and, furthermore, that copper removal was not efficient and oxide attack on the refractories was severe. Plant test work2 had confirmed the difficulty of copper removal, but had shown that zinc and lead were almost completely removed. The difficulty of copper removal by oxygen injection warranted further investigation. Also, the high decomposition pressure of silver oxide suggested that by suitable control of the slag composition it might be possible to reduce to very small proportions the silver carried into the slag as oxide. The oxidation of copper by oxygen injection and subsequent dissolution of the oxide in a slag may occur according to the following reactions; Reactions 4 and 5 were considered because of the relatively high solubility of oxygen in molten silver and silver alloys. Thermodynamic data indicate that there is little possibility of any reaction involving the formation of CuO occurring at temperatures above 1 000 °C. To ensure that the operative reactions 1 and 4 take place to the maximum extent, the following factors He significant. (a) an increase in the activity of the copper in the bullion, (b) an increase in the partial pressure of oxygen in the system, (c) an increase in the activity of the oxygen in solution in the metal, (d) a decrease in the activity of cuprous oxide in the slag. From practical considerations, the operative variable most easily susceptible to control is the composition of the slag. SOLUBILITY OF COPPER OXIDES IN BOROSILICATE SLAGS Very scanty information exists on systems containing copper oxides but the indications are that slags containing considerable amounts of boric oxide would possibly prove to be the best solvents for cuprous and cupric oxides. This is attributed to the fact that the activities of copper oxides are much lower in boric oxide slags than in slags in which silica is the main network former. The number of possible slags containing boric oxide was limited by consideration of liquidus temperature, viscosity, corrosive action on refractories, volatilization, and ultimately cost (for industrial application). Slags in the systems soda-boric oxide-silica and lime-boric oxide-silica were selected paying due attention to the above limitations. Additions of 5, 10 and 15 per cent cupric oxide were made to the finely ground, premelted slags. These mixtures were then reground and 2g quantities held in re crystallized alumina crucibles at temperatures of 1150°C and 1 250°C respectively for 30 minutes. The crucibles were removed from the furnace, rapidly cooled, cut in half longitudinally, and a thin section taken from one half was subjected to microscopic examination.

A Seminar to discuss 'Reactivity of Line in Steel Making' was held in the auditorium of Iscor's Headquarters Building in Pretoria on the 5th August, 1971. The Institute organised this Seminar on the occasion of the visit of Dr Obst of the Rheinische Kalkstein Werke GMBH, Wuelfrath, West Germany. The latter is one of the largest lime companies in the world and Dr Obst is in charge of their research laboratory. He and his co-workers have earned a reputation for their research into reactivity of lime in steel making. This work is also of great importance to the steel industry in this country, particularly with the changes which are occurring with the introduction of basic oxygen furnaces. Some 80 persons representing most of the major steel companies attended this Seminar. Dr Obst presented his most interesting paper which he illustrated with projector slides. This paper is printed in full in this journal. This was followed by several contributions and active discussions. The first contribution was made by Dr T. B. Beeton of the Research and Development Department, Iscor. He gave a brief summary of the studies on reactive lime carried out at Iscor since 1968. Their work was particularly related to the selection and definition of the various reactivity tests and the correlation of these with plant results. He demonstrated that the DIN methods, particularly the Din (40°) test, gave the best results and reported that good agreement had been reached between Iscor, Highveld and Northern Lime on future test procedures. Mr B. Lowther of The Northern Lime Company then dealt with problems associated with the production of high reactive lime. The rotary kilns at The Northern Lime plant at Lime Acres are particularly suitable for the production of high-reactive lime, because this type of kiln lends itself to accurate control of temperatures and retention times. Several problems, however, exist. Because of the long haul distances and the deterioration of reactive lime by absorption of CO2 and water, high reactive lime is not suitable for most customers. To constantly be changing kiln conditions to produce relatively small quantities of high-reactive lime, therefore, causes problems. Highveld Steel at present is the only company requiring high-reactive lime and a satisfactory product is now being produced at a cost because kiln capacity is reduced and fuel costs are higher. Dr P. R. Jochens, of the National Institute for Metallurgy then submitted data to show how the reactivity of soft burnt reactive lime deteriorated due to long railage hauls. Detailed sampling of trucks had been carried out leaving the lime works and on receipt at Highveld and it was demonstrated that there was deterioration in the top layers of the truck. This top layer protected the balance of the lime which is still in good condition on arrival at Highveld. Exposure to atmosphere by further handling and storage into the bunkers at Highveld, however, resulted in further severe deterioration in the lime reactivity and the lime when finally fed to the Basic Oxygen Furnace is reduced to one third to one quarter of the original reactivity value. The same deterioration does not occur with normal run of kiln lime, which is burnt harder, but still has a satisfactory reactivity for most purposes. Mr A. A. Hejja of the Department of Metallurgy, Witwatersrand University then made a contribution on the metallurgical aspects of the use of lime of different reactivities in the Basic Oxygen Furnace and the effect on desulphurization efficiencies. He gave a wealth of data on actual tests which had been carried out and came up with the surprising conclusion that the deterioration of high-reactive lime due to transport did not have as serious an effect on the efficiency of desulphurization as one would have expected. The efficiency was good provided high-reactive lime in the first instance had been produced, irrespective of whether it had deteriorated thereafter. Poor efficiency was obtained only when the lime in the first instance was produced in an unreactive form. The temperature rise in the Basic Oxygen Furnace also has a definite effect. If lime is introduced when the temperature is too high, soft burnt reactive lime becomes hard burnt and unreactive before it can dissolve in the slag. Use of ferromanganese slag assists dissolution of lime. There was a great deal of discussion following these contributions. Particular interest was expres8ed in the special lime described by Dr Obst. This consists of a mixture of fine lime which is premixed with fluxes and either briquetted or pelletised. The question of injecting finely ground lime as an alternative was also discussed. Both these systems eliminate the necessity for highly reactive lime. With smaller lime particles, larger surfaces are exposed thereby ensuring more rapid dissolution in the molten slag. The discussions generally were lively and informative and all present derived benefit from learning of the experiences of others. The valuable contribution made by our German visitor, Dr Obst, was particularly appreciated. The instantaneous English-German translation service which was provided, greatly facilitated discussions.