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By K. Sasaki, Y. Oriia, Shigeto Kuroiwa, H. Miki, Yuji Aoki, T. Hirajima, G. P. W. Suyantara

The effect of a sulfite reagent on the floatability of chalcopyrite and enargite was investigated in this paper. The flotation tests using single and mixed minerals were performed under various concentrations of sulfite. The flotation tests using a single mineral showed that the sulfite reagent depressed the natural floatability of both minerals at pH 9. Surprisingly, enargite was floated after the addition of potassium amyl xanthate (PAX) following the sulfite treatment, and the floatability of chalcopyrite depressed under a similar condition. X-ray photoelectron spectroscopy analysis results showed that the sulfate species increased after the sulfite treatment on both minerals. However, the addition of PAX removed this sulfate species and rendered the enargite surface hydrophobic. This phenomenon was not observed on the chalcopyrite surface. FTIR analysis and PAX adsorption studies were performed to support this finding. The flotation of a mixed mineral was in agreement with the flotation of a single mineral, indicating a possibility for selective flotation of chalcopyrite and enargite using the proposed method. Keywords: Flotation, chalcopyrite, enargite, sulfite, potassium amyl xanthate

Jan 1, 2020

By R. C. J. Goode, W. S. Rapson, W. R. Lawrie, L. W. P. Van Der Bosch

W. R. Lawrie (Member): As all the Institute members present are aware, the Ninth Commonwealth Mining and Metallurgical Congress was held in Great Britain from 3rd to 24th May, 1969. The Congress opened in London and the first week was devoted to technical sessions. Several receptions and other forms of entertainment were held in the evenings. The Congress was attended by some 1 200 delegates, many of whom were accompanied by their wives. As can be imagined a large organisation was needed to cater for all the whims of these delegates, to arrange accommodation and to provide transport for the technical trips, for the receptions and for the sight-seeing tours. Papers presented at the technical sessions proved of great interest. It was stimulating to hear of the developments taking place in the various branches of mining and metallurgy. The discussions which developed between men from so many different countries were thought provoking, led to new friendships and most of us made valuable contacts for the future. There were 141 papers presented in the one week. They were given in four separate halls with two, three and sometimes four papers coming up for discussion in each of the three sessions per day in each hall. Among the more interesting subjects were those concerning off-shore drilling and the facilities for production of petroleum and natural gas. Beach mining at Consolidated Diamond Mines drew a large audience. Automation, mechanization and other technical developments were well described and we were brought up to date with modern techniques of mineral prospecting. There was general discussion on the future of the mineral industries together with comments on the consumption and price trends of these metals and minerals. The future of uranium, of vital interest to us in South Africa, came in for much debate. During the first week, besides attending the technical sessions and seeing some of the sights of London, we were royally entertained. There was a banquet, attended by some I 400 people, where we were welcomed by Princess Alexandra, a reception by H.M. Government in the Banqueting House, and we were entertained at the House of Lords on a terrace overlooking the bustling and rather muddy river Thames. Then there was the visit to the Glyndebourne Opera. It is only in London that at 3 o'clock of an afternoon, nearly 1 000 people all togged up in dress suits and long dresses and carrying packets of sandwiches for supper could arrive at a station to catch a train, and not even cause a stir of interest or a raised eyebrow! This is the way we travelled 60 miles to the opera from London. Surely there can be no more picturesque or romantic a setting for an opera than this large 400-year old red brick manor house nestling in the green valleys of the unspoilt Sussex countryside. It was a glorious evening and though we returned somewhat late and tired, not one of us would have missed this experience. After the first week in London there was a choice of tours of one week to London and the Home Counties, Cornwall, a Geological tour to Scotland, South Wales, and North England. These were followed by further one week tours to Yorkshire and Lancashire, Scotland, West Country and Midlands, a Geological tour of Wales, and a Mining and Geological tour to Jurassic Iron Mines. We then returned to London for the final session and closing banquet. Post-congress tours were arranged to Europe and to Ireland. It was a wonderful Congress, a great experience, we made many friends and may there be many more congresses! . L. W. P. van den Bosch (Member): Much has already been said in appreciation of the excellent organisation and arrangements made for the delegates who attended this Congress. This report is confined to a brief discussion of the personal impressions gained from the papers presented and the technical visits attended. The papers covered a wide variety of subjects ranging from highly theoretical observations to practical descriptions of operations. There were three main themes, VIZ: 1. The attention given to research and its forceful application to practical operation. 2. A steady development in mechanization and automation leading to savings in manpower. 3. Improvization, modernization and adaptation of exisitng facilities. Thoughts on these themes can best be illustrated by comments on some of the industries visited. COAL The National Coal Board (N.C.B.) has been most progressive and all of us have heard of the Bevercotes Colliery with its completely automatic mining and coal handling equipment. This was not, unfortunately, on show but there is no doubt that this is one of the greatest advances in coal mining leading towards continuous production. Coal in Britain is fighting for its life against oil, North Sea gas, imported gases and nuclear power. Output is dropping, the less efficient collieries are closing down and efficiencies are steadily rising as the following tabulation indicates: In 1931: 1 million men produced 300 million tons of coal In 1947: 0.7 million men produced 230 million tons of coal In 1968: 0.4 million men produced 160 million tons of coal

By Anders Erlandsson

"The crude ores from the LKAB mines are sorted and refined into a number of products. As there are a number of different plants the flow of material is often complex.in connection with studies of a proposed extensive investment program it was necessary to get a good measure of the changes which would be caused in the total profit by the different possible investments. A linear programming model was set up to accomplish this, and to cover the consequential effects on the production system. The objective function of the model maximized the total profit, taking into account restrictions in materials balances, blending conditions, production capacities and market. The changes in total profit resulting from the different investment alternatives, together with investment and fixed costs, were used in a series of investment analyses. The application has proved to be very successful and the results come very near to what was expected."

Jan 1, 2014

By A. Schippers, S. Hedrich

Chalcopyrite represents the most important copper resource and is currently mainly exploited using pyrometallurgy. Bioleaching is an environmental-friendly and economic alternative to conventional mineral processing technologies. The technical feasibility of stirred tank reactor bioleaching of copper ore concentrates using acidophilic iron-/sulfur-oxidising bacteria is proven, however, often incomplete due to inefficient chalcopyrite dissolution. A decoupling of bacterial growth from bioleaching activity in one bioreactor by adjusting appropriate temperatures for both process steps allows for almost complete chalcopyrite dissolution. Separation of copper and recovery of other metals from the PLS was possible by implementation of different biological and chemical techniques. The Ferredox process has been proposed to treat limonitic laterite ores for cobalt and nickel recovery by means of anaerobic reductive dissolution with autotrophic, acidophilic bacteria. As a modification, aerobic reductive dissolution of laterites with acidophilic bacteria has shown economic and environmental advantages over anaerobic reductive dissolution. The reductive bioleaching technology has the potential to increase metal recovery in existing mines, and transform unexploited ores and limonite stockpiles into valuable resources. Keywords: Biomining, bioleaching, chalcopyrite, laterite, Ferredox process

Jan 1, 2020

By K. -I. Higuchi, M. Mizutani, K. Haga, A. Shibayama, A. Batnasan

In recent years, the quality of iron ores has decreased due to the increase in the content of impurities, namely quartz, aluminum, phosphorus, and sulfur. It indicates that the removal of impurities from iron ore is an extremely challenging task. In particular, the high amount of phosphorus in iron ore could be a problem for energy consumption and CO2 emission in the steelmaking process. To reduce the impact of phosphorus, mainly two approaches: the utilisation of low-phosphorus iron ore, or dephosphorisation of high-phosphorus iron ore using mineral processing technology, have been suggested. In this paper, the removal of phosphorus from a low-grade high-phosphorus iron ore containing 0.1 mass% P and 57.5% Fe by alkaline roasting and wet grinding is discussed. The iron ore consists mainly of hematite, goethite, and quartz. Effects of sodium hydroxide concentration used as an alkaline source, roasting temperature, grinding time, and particle size on the dephosphorisation of highphosphorus iron ore were investigated. The dephosphorisation efficiency, iron loss, and mineralogical components of low-grade high-phosphorus iron ore under various experimental conditions were characterised by using XRD, SEM-EDS, and particle size distribution analysis. Results showed that the phosphorus content was lowered from 0.1 mass% to 0.034 mass%, while the iron grade reached 59.8 mass% from 57.5 mass% by alkaline roasting with 0.05 w/w NaOH at 300 °C for 2 h, followed by wet grinding in an attritor with water for 30 seconds at room temperature. Under the experimental conditions, the dephosphorisation rate was about 54.7%, and the solution obtained by wet grinding contained 22.7 mg/L of phosphorus and 21.5 mg/L of iron. The recovery rate of iron by this process reached 99.9%. Keywords: Iron ore, phosphorus, dephosphoriszation, alkaline roasting, wet grinding

Jan 1, 2020

By A. E. Landsberg, K. C. Corin, G. Stroebel, J. A. Miller, M. Becker, H. J. J. Gordon

Geometallurgy represents an integrated approach to mine planning and operation whereby the naturally occurring ore variability and its effects on all key downstream activities in the mine life cycle are considered. Process mineralogy is one of the key components of this integrated approach. This paper focuses on understanding some of the mineralogical variability across the Swartberg Cu-Pb-Zn sulfide ore in South Africa and its consequent effects on flotation performance. This process mineralogy project is motivated by the planned changeover and expansion of the Black Mountain Mines concentrator to process solely Swartberg ore compared to the run-of-mine blend currently being treated at the plant. Eight samples spanning the main lithological units of the ore body are described using quantitative mineral-textural data and bulk sulfide batch flotation performance to establish five process mineralogical or geometallurgical units comprising: quartz-pyroxmangite-magnetite, quartz-amphibolemagnetite, quartz-magnetite, garnet-magnetite-quartzite and mica-quartzite ores. Important mineralogical characteristics affecting Cu, Pb and Zn recovery, grade and selectivity specific to the different ore samples are discussed. Ultimately, the use of ore-specific process mineralogical and geometallurgical knowledge allows for better mine planning and plant optimisation. Keywords: Flotation, polymetallic base metal sulfide ore, process mineralogy, ore variability

Jan 1, 2020

By L. Pretorius, S. Uludağ

This paper explores how to apply system dynamics principles to surface mining problems towards understanding the consequences of mining efficiencies. Some simulation examples related to machine and people performance have been used to demonstrate systems engineering concepts to mining engineers. The simulation tool used is Vensim, which is widely used in industrial engineering applicable to systems thinking, and systems dynamics. The science and mathematics behind the system dynamics as well as benefits and typical challenges are discussed to explore the applicability to mining problems. The benefit of having one less drill is easily quantifiable with the developed model which is one of many other measurable benefits, using the developed model. Some of the benefits of the improved quality of drill holes are not fully quantified as this depends on the mine specific inputs. There are examples of quantifying this in the other industries using system dynamics tools.

Sep 1, 2021

By G. D. Rosales, P. F. A. Braga, S. C. A. França, C. P. Pinto

The growing market demand for lithium is mainly due to its use in the manufacture of batteries for electric or hybrid vehicles and portable equipment (smartphones, tablets, power tools, notebooks, etc.). Currently there is great interest in finding new sources of lithium and technologies for its utilisation. Li-S batteries have received attention due to their theoretically high specific energy density, which is 3 to 5 times greater than that of Li-ion batteries. Unlike Li-ion batteries, of which the main raw materials are lithium carbonate and lithium hydroxide, the main raw material for Li-S batteries is lithium chloride. The anode used in Li-S batteries is metallic lithium, produced by a molten lithium chloride electrolysis process. The extraction of lithium from pegmatites such as spodumene, previously abandoned in the 1990s for being uneconomical, has become attractive due to the increase in prices as well as the need for greater lithium purity of products made from lithium-bearing minerals. The main methods used for lithium recovery from spodumene ore include the sulfuric acid process, the alkaline process (lime or limestone as raw material) and the chlorination roasting process. Thermodynamic modelling using HSC software 5.1 was conducted to predict different reactions that could occur during chlorination roasting of the spodumene/MgCl2+CaCl2 system. Lithium extraction from the solid obtained after the chlorination roasting was also investigated. The results of thermodynamic analysis provided a better understanding of the chlorination roasting process for lithium extraction. Metallurgical tests with a mass ratio of 1:6 (spodumene:chlorides) and molar ratio of 2:1 (MgCl2:CaCl2) allowed over 95% recovery of the lithium contained in the spodumene concentrate. Keywords: Spodumene, lithium chloride, chlorination roasting

Jan 1, 2020

By E. M. W. Skinner

Various models of near-surface kimberlite pipe emplacement have been proposed over the years. These include a top-down, phreatomagmatic model, a bottom-up, embryonic pipe model and three top-down explosive dyke models. AU of these models consider kimberlites as essentially the same rock type. However, different kimberlites have different pipe shapes and contain different rock types with very specific mineral assemblages and textures and therefore are likely to have been emplaced by different processes. Some authors have considered local geological differences as the principal reason for the contrasting geology but others argue that, while geological differences might contribute locally the petrographic peculiarities of particular kimberlites may be due mainly to inherent compositional differences specifically in the ratios of juvenile CO2 and H2O.

Jan 1, 2010

Cutting strong rock with a drag bit assisted by high-pressure water jets By M. HOOD. B.Sc. Hons. (Min. Eng.). B.Sc. (Mech. Eng.). A.M.I.M.M. (Visitor) Experiments are described that led to the discovery that coherent high-pressure water jets directed immediately ahead of drag bits while they are cutting strong rock reduce the magnitudes of the forces on the bits significantly. Tests were carried out to assess the effects of the pressure of the water jets on bit-cutting performance. The pressure was varied between 10 MPa and 50 MPa, the water flow rate being a constant 30 I/min. Over this pressure range, the force on the bit was reduced to the extent that the depth of cut of the bit was at least doubled with the point of impingement of the jets optimized. Forces on the bit were found to be particularly sensitive to the point of impingement of the water jets relative to the bit. The optimum configuration was found to be with two jets, one directed towards each corner of the bit and impinging on the rock approximately 2 mm ahead of the leading edge of the bit. Experiments in which a drag bit and high-pressure water jets were used to cut strong abrasive quartzite in the underground mining situation have demonstrated a potential increase of up to five times in the average depth of cut due to reduction of the forces on the bit. The results from the underground tests indicate that the life of the bit is improved significantly - by a factor of approximately two - when highpressure water jets are used.

Jan 11, 1976

Mining executives often have a difficult task determining what the strategic objective of the business should be as this can be impacted by the prevailing market conditions. In addition, they have no mechanism to quantitatively 'test' the impact of this strategic decision on the business and understand the underlying dynamics. During the commodities bull run of 2003 to 2008 the strategic objective may have been to grow the long term value of the business (NPV) through increased tonnage, acquisition and finding new reserves, which all came with an increasing fixed cost base. Now with the financial crisis upon us and the collapse of commodity prices and demand, executives have adjusted their strategies as 'cash is king' and short-term cash flow, in some instances at the expense of long terms value, is the order of the day. For many mining companies, mine closures, reductions in production and cost cutting exercisers are now the focus. In many instances, management do not have an ability to rapidly test different strategic alternatives to 'test' the impact on value, unit costs, reserves and profitability at the operational level and optimize the underlying trade-off variables. Economic modelling of the complete business value chain is a means of linking the operational 'reality' and strategic choices, so that the full impact can be assessed. This paper describes some of the challenges facing mining executives and how economic modelling can be applied to make decision making more rigorous.

Jan 1, 2010

Orange Free State Branch Minutes of a General Meeting held at the Welkom Mine Canteen on Wednesday, 21st November, 1973, at 4-.00 p.m. Present Mr E. T. Wilson (Chairman) in the Chair, 15 Fellows and Members, 12 Associates, Graduates, and Students, and 11 Visitors (Total 38). Book review Symposium on Environmental Engineering in Coal Mining The 20 papers presented at the symposium cover some 14 subjects related to environmental engineering in coal mines, such as dust, heat, gas emissions, ventilation, noise, and lighting. Competition for students Each year the Institute offers a prize (or prizes should the entries warrant it) of up to Rl00 for the best paper or dissertation on a topic appropriate to the interests of the Institute. A.8. & T.8. Trust The A.S. & T.S. Trust has been formed with the specific object of establishing a worthwhile source of funds which can be used to further the progress of science and technology in South Africa. Nim reports Report No. 1573 A pilot-plant investigation of a flotation model. Report No. 1597 The role of sulphur in the flotation of sulphide minerals. Report No. 1599 The analysis of silicate rocks and metallurgical slags by X -ray-fluorescence spectrometry. Report No. 1607 The analysis of ion-exchange resins by X-ray- fluorescence spectrometry. Report No. 1617 An electronic differential precision thermometer.

Jan 6, 1974

By J. van der Walt, A. Whillier

Reference is made to the approach to mine cooling in which the service water is used as one of the means of distributing refrigeration, and attention is drawn to various engineering disciplines or functions necessary for effective distribution and reticulation of cold water from refrigeration plant. The demand for service water is intermittent, the peak flow-rates being typically two to three times the average flowrate. The refrigeration plant, on the other hand, must preferably be operated steadily throughout the day and night, with the result that a large storage dam for cold water must be incorporated into each system in order to even out the surge in demand for water. These dams should be operated as constant-temperature, variable-volume reservoirs. The conventional cascade system involving dams on each level is not the best for sending water down mines, and schemes are described that avoid the need for such dams. Reference is made to various tests that were carried out, and to several large systems that were installed. Management and organizational problems that could arise as a result of new technological developments in mine cooling are referred to, and cost figures are quoted to indicate the large potential savings, In addition to the improved environmental conditions, that can be achieved through the use of integrated water systems.

Jan 1, 1979

By P. G. H. Pistorius, D. S. Konadu, G. Lubbe

The aim of this investigation was to determine whether the composition of a shielded-metal arc-welding electrode coating affected the low-temperature impact toughness of austenitic stainless-steel weld metal. It is generally accepted that increases in the δ-ferrite and nitrogen contents result in a decrease in toughness at low temperatures. Weld metal from electrodes with a basic coating also generally exhibit better toughness than those from rutile (acidic) electrodes. An increase in basicity was expected to decrease the number and size of inclusions, which in turn provides a tougher weld metal. Three commonly available potassium–rutile E308L electrodes were used, complying with the E308L-16 and E308L-17 specifications. Analysis of the electrode coatings showed very similar chemistry and basicity. Significant differences in the inclusion contents of the weld metals were observed: the E308L-17 weld metal had a lower inclusion content (1.4% by volume) than the E308L-16 weld metal (3.7%). The former had higher impact toughness at all temperatures, despite a slightly higher nitrogen content. Regression analysis confirmed that the inclusion content had a significant effect on the impact toughness at all temperatures.

Jul 2, 2022

By D. Krebs, Tero Korhonen, X. Yang, A. Kirpala, N. Heino

At present, over 85% of the world’s rare earth oxides are produced from the bastnäsite ores, found mainly in China. Meanwhile, the ion adsorption ores are the most important sources for heavy rare earth production. As the demand for rare earth materials in the world increases, other forms of rare earth deposits will become new potential resources of rare earth production in the future. In this paper, flotation performance of a steenstrupine ore from the Kvanefjeld deposit for rare earth recovery was studied through laboratory bench testwork. The effects of various factors including grinding size and collector dosage on recovery and selectivity of the selected rare earth elements, La, Ce and Y, were investigated. A rare earth concentrate with the grades of La 2.8 wt%, Ce 5.1 wt% and Y 1.0 wt% at recoveries of 80.5% La, 79.8% Ce and 55.3% Y was obtained in optimum conditions. Further potential to improve the efficiency of REE flotation was discussed. Keywords: Rare earth elements, flotation, steenstrupine, Kvanefjeld deposit

Jan 1, 2020

By Y. J. F. Haven, G. H. J. Kitson, D. G. Beadle

I have read this paper with considerable interest. By using an automatic instrument to assess the dust samples taken in South African collieries, the authors are ahead of the gold mining industry, which still uses the laborious method of microscopic assessment, with its limited accuracy, of the half-a-million dust samples taken each year. As the authors state, the result obtained from the photoelectric assessment of the samples is approximately proportional to the surface area of the respirable dust. However, modern theory is that, in assessing coal dust, it is the respirable mass which is important in determining the danger to health. Thus Table II of their paper is of considerable value in showing the relationship between the P.E.R. value and the mass concentration measurement. Unfortunately this table only gives the mean relationship. The important point is to know the scatter around this mean. If the scatter is small, then this mean value (for different operations) would have considerable value in converting from respirable surface area to respirable mass, but if the scatter is large, then such a conversion, using a fixed factor, will have little value. In the text the authors mention the range of values as being between 3 to 24, but without a statement on the number of samples used to determine this range and their distribution, this is a rather nebulous statement. I hope, in their reply, that the authors will give, in statistical terms, some statement on the overall correlation between these two parameters. I might add that at present a member of my staff is working on similar relationships for dust samples taken in gold mines. Another factor which may well be most important in determining the danger of dust levels in coal mines is the composition of the dust, specifically its quartz content. I understand that the authors have some information on this point, and to make their results of greater value in International comparisons of dust levels and the concomitant development of pneumoconiosis, it will be extremely useful if they could place this information on record. Even though, as I have said above, modern theory postulates that respirable mass is a better parameter to use than respirable surface area, the problem remains of how to measure this parameter with short time sampling, which, as the authors point out, is their preferred strategy for dust sampling and dust control. I know of no easily portable instrument, independent of external power supplies, which can, in 5 to 10 minutes, collect sufficient dust to enable it to be weighed accurately. Thus the authors' implied intention of continuing to sample by their present techniques and using their present parameter to report the results is, in my opinion, an entirely valid decision.

Jan 10, 1968

The 96th Annual General Meeting of The South African Institute of Mining and Metallurgy was held in the Gold Room of the Transvaal Automobile Club in Johannesburg on Wednesday, 11th August, 1993. OBITUARIES The President announced the deaths of the following members of the Institute during the past year. Life Fellow E.F. Laschinger. Other Members R.K. Boright, J.S. Jacobi, R.D. Power, J.H. Cannon, C.J. du Plooy, L.B. Mcrae, C.P. Rossouw, A.L. Sillars, A.W. Heugh, R.K. Briggs, P.J. Stark, and C.S. Stott. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, all rose and observed a moment of silence.

Jan 1, 1993

By H. J. E. Hamel

Some aspects of the deformation behaviour and temperature rise during instantaneous compression loading of high purity aluminium By H. J. E. HAMEL The influence of deformation speed on the deformation behaviour of high purity aluminium was investigated. By varying the initial height-to-diameter ratio a considerable influence on the deformation behaviour could be noticed. Lubrication of the specimen end faces was found to have an influence on the flow behaviour and on the roughness of the specimen interface at pressing platens. The results of temperature measurements during deformation agree with work-hardening behaviour of the specimens. Flow curves calculated with the measured temperature rises do not agree with results obtained at lower strains by other workers. The possible reasons are discussed.

By J. S. Preston

The properties of some recently developed solvent-extraction reagents for the separation of cobalt and nickel sulphate solutions are reported. New commercial extractants based on alkyl phosphonic and alkyl phosphinic acids are described. These reagents show much improved selectivity for cobalt compared with established extractants. Some novel extractants developed at Mintek for the selective recovery of nickel in the presence of cobalt are also described. These reagents, which are based on mixtures of carboxylic acids and non-chelating oximes, are of interest in that no commercial nickel-selective reagents are currently available. Graphs showing metal loading and stripping, and pH-functionality, are presented. together with details of the metal separations achieved in batch countercurrent- extraction experiments with the various reagents.

Jan 1, 1983

By E. G. Galvez, E. Mate, L. A. Cisternas, C. Cruz, L. Cortés, M. E. Osorio

Designing and optimising flotation circuits are critical for mineral beneficiation plants, and therefore several procedures have been published. The modelling of flotation circuits with the objective of design and optimisation is problematic in that different approaches are used for the modelling of flotation units and regrinding units. Usually, regrinding models are based on particles characterised by their size, while flotation models are based on species characterised by fast and slow classes. The relationship between particle size and liberation can be used, but it requires laboratory studies that are time-consuming and costs are high. It is therefore not surprising that few studies on flotation circuit design and optimisation include flotation units and regrinding units simultaneously. In this paper, it is proposed to model the regrinding stage using species characterised by fine-slow, medium-fast, and coarse-slow flotation species. In deep, the regrinding model is derived from a population balance approach based on flotation species. The fraction of these species at the feed and product of the grinding unit is determined by flotation tests. Then, based on these data, the model parameters can be determined by a regression estimation procedure. A local ore was used to validate the model. Keywords: Modelling, flotation circuit, grinding circuit, process design

Jan 1, 2020