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By T. G. Joseph

ABSTRACT: The Canadian oil sands provide some of the harshest mining conditions in the world. Asoperations demand ever bigger tools, the toll on large mobile mining equipment is high, with structurallife often half of that expected. Soft ground conditions predominantly lead to fatigue failure scenarios, poor stability, and inconsistent payload evaluations. These challenges are not solely a concern for Canadian oil sands mines; there are far-reaching implications for surface mining equipment in any poor ground-operating environment. This paper focuses on the basics of payload evaluation, motion response and a simple estimate of structural life for haulers.

Jan 1, 2011

By L Munholand, G. Soucy, P. Quintal

This work presents early results from the first study to optimize the hydrodynamics of a Plasma Lift Reactor (PLR). The PLR is designed to break down organic contaminants in aqueous solutions. New experimental results are presented for air/water tests and for plasma degradation of organic contaminants in Bayer liquor. In addition, a multiphase Computational Fluid Dynamics (CFD) model has been developed which predicts the hydrodynamic behavior in the PLR. These results of this work suggest the PLR is effective at reducing contaminants in the Bayer liquor and that the CFD model adequately describes the hydrodynamic flow.

Jan 1, 2005

By C. E. Dowker

"IntroductionMechanization underground at the Buffalo Ankerite mine in Deloro township, Porcupine district, had reached a high level by 1944, both in equipment available, and in the use of this equipment, for all stoping operations. Power feed leyners and the latest type of stopers for drilling, slushers for moving ore and fill, and tugger hoists for all servicing, did much to halt rising stope costs, and in some cases decreased them. On the other hand, little beyond the use of mucking machines and power feed leyners had been adopted in the effort to reduce level development costs, or to increase the advance per man-shift.Faced with ever increasing level development costs, caused by rising prices of equipment and supplies, coupled with increasing wage demands for less physical effort, it was realized that more mechanization of development work was essential. The objectives of such further mechanization were:(1) Decreased development costs(2) Increased footage per man-shift(3) Less physical effort by development crews, with greater take-home pay (4) A more satisfied and stable labour force"

Jan 1, 1950

By M. du Plessis, D. F. Malan

"Crush pillars are designed to be in a crushed state whilst being formed at the mining face. The residual stress state of these failed pillars provides a local support function in mining stopes and is used in the majority of the intermediate depth South African platinum mines. On mines utilising crush pillars, the pillar dimensions are selected to achieve a width to height ratio of approximately two. This is not achieved in most cases as a result of practical mining problems and poor pillar-cutting discipline. Furthermore, pillar dimensions are seldom adjusted to compensate for the various factors governing crush pillar behaviour. The pillars should, however, be in a crushed state whilst being formed or whilst still in close proximity to the mining face to prevent potential damaging seismicity.An underground investigation was conducted into the behaviour of the crush pillars in a trial site on the Merensky Reef at Lonmin Plc. The aim of this investigation was to examine the mechanism of pillar crushing and the related rock mass behaviour. The underground test results and pillar behaviour are compared to a limit equilibrium model to investigate if the model provides a useful approximation of the behaviour of the crush pillars. This paper details some of the preliminary findings.INTRODUCTIONOn most mining operations, the design of crush pillars is based on trial and error. As the pillar strength is unknown, the pillar sizes are adjusted to obtain the correct behaviour. Crush pillar dimensions are generally selected to give a width to height ratio (w:h) of approximately 2:1, (Ryder and Jager, 2002). Several factors affect the behaviour of the crush pillars and in many cases satisfactory pillar crushing is not achieved. This results in a seismic hazard in many of the mines using crush pillars. If pillar crushing is not initiated whilst the pillar is being formed at the mining face, as the mining face advances and the pillars move to the back area of a stope, some pillars may burst while oversized pillars may punch into the footwall. If pillars are designed in such a way that they are fractured during cutting by the face abutment stresses so that the pillars will already have yielded and reached their residual strength, further compression of the pillars will be associated with an increase in load and stability will be ensured, (Ozbay and Roberts, 1988). The stiffness of the strata must therefore be greater than the post-peak stiffness of the pillar (Figure 1) or violent pillar failure and hanging wall instability will occur. The pillar design should be aimed at determining pillar dimensions for which the post-peak curve of the pillar is as flat as possible."

Jan 1, 2015

By O. Rabeau, M. Legault, F. Fallara

"Abstract - The development of robust 3-D geological models involves the integration of large amounts of public geological data, as well as additional accessible proprietary lithological, structural, geochemical, geophysical, and diamond drill hole data. 3-D models and maps have been available, particularly in the petroleum industry, for more than 10 years. Here, we demonstrate how robust 3-D maps can be used as interactive tools for mineral deposits exploration. In particular, we show how the interrogation of 3-D data sets can constrain exploration targets at depth. The main advantages of this technique for the mining industry are the homogeneity of data treatment and the validation of geological interpretations, taking into account geophysical and geochemical data. Data integration and cross-correlation of geology and geophysics can be achieved in two dimensions in any good GIS package. However, the added strength of 3-D analysis is the integration of separate data sets in three dimensions to build more complete, more realistic models, and in delineating areas of high economic potential at depth. Furthermore, these models can be modified and improved at any time by adding new data from ongoing drilling and geoscientific surveys. This paper presents two examples of 3-D models used for mineral exploration: the Joutel VMS mining camp and the Duparquet gold camp, Quebec. In both examples, the creation of the model is discussed and queries specific to the relevant exploration model are introduced. Eight potential exploration targets are generated at Joutel and seven at Duparquet. Although the targets defined are dependent on the details of the chosen queries, it is apparent that this technique has the potential to generate promising exploration activity that can engender new targets. Sommaire - Le développement de modèles 3-D géo-intégrés fiables implique l’intégration de grandes quantités de données géologiques publiques ainsi que des données lithologiques, structurales, géochimiques, géophysiques et de forages en provenance du secteur privé. L’industrie pétrolière dispose de modèles et de cartes 3-D depuis plus de 10 ans. Ce manuscrit présente un exemple d’utilisation de modèles et de cartes tridimensionnels détaillés comme outils interactifs dans l’exploration de dépôts métallifères. L’emphase est mise sur le processus d’interrogation des données en 3-D pour la définition de cibles d’exploration en profondeur. Les avantages principaux de cette technique sont l’uniformité du traitement des données et de la validation des interprétations géologiques, tout en tenant compte des données géophysiques et géochimiques. L’intégration de données et la corrélation de la géologie et de la géophysique peuvent être accomplies en deux dimensions dans n’importe quel logiciel SIG. La plus grande force de l’analyse 3-D demeure cependant la possibilité de construire des modèles complets et réalistes permettant de cibler des secteurs à haut potentiel économique en profondeur. De plus, ces modèles peuvent être modifiés et améliorés de manière interactive en ajoutant de nouvelles données provenant de forages et de levés géoscientifiques en cours. Ce manuscrit présente deux exemples de modèle 3-D géo-intégrés développés pour l’exploration minérale : le camp de SMV de Joutel et le camp aurifère de Duparquet, Québec. Dans les deux cas, la construction du modèle est décrite et les requêtes spécifiques à chaque type de gisement sont présentées. L’exercice a permis de définir huit cibles d’exploration potentielles à Joutel et sept à Duparquet. Bien que les cibles identifiées dépendent des contraintes utilisées pour les requêtes choisies, cette technique permet de générer de nouvelles cibles qui pourraient relancer l’activité d’exploration dans les camps miniers " matures " ou dans des secteurs moins explorés."

Jan 1, 2006

By N. Thompson

The Right Hon. Viscount Long, late Secretary of State for the Colonies, in his inaugural address to the Empire Mining and Metallurgical Congress in London last June said: "I am more and more? convinced by every day experience that the development and strengthening of the Empire must depend upon individual effort and action, and that it is useless to look to Governments for assistance." I am inclined to agree with Viscount Long, to this extent, that the initiative must come from individual effort, but Government assistance is necessary to put the results of that effort and action into effect. It is perhaps fitting at a gathering of this kind to remind ourselves of the part the mining industry has played, not only in the development of the British Empire but in the world at large, in the promotion of modern civilization. We do know that all human progress has been coincident with the early discoveries in the recovery and treatment of metals and, as the centuries have passed, the human race has become more and more dependent on these sciences as factors of all progress, and no nation has ever become powerful and prosperous that has lacked adequate mineral supplies, or having these, has allowed them to be exploited by other nations.

Jan 1, 1925

This paper deals mainly with the modernization in the coal loading system at the loading piers of the Dominion Coal Company, Ltd., Sydney, Nova Scotia. The history of the operation is briefly outlined, and the construction of the Company's new pier is described in considerable de-tail. Particular attention is paid to the bins and conveyors, and to the loading tower. The paper concludes with a description of the S.S. Cape Breton Miner, built specifically for the coal trade, and the unloading facilities at Lakeview, Ontario. Coal Shipping at Sydney C OAL from the mines operated in Cape Breton by the Dominion Coal Company, Limited, has been shipped from the International Piers, situated on the east side of Sydney Harbour, for over sixty years. There were three piers, of which two were active-ly used in the shipping of coal until 1964. Nos. 2 and 3 were high piers about 600 feet long, of wooden construction throughout. They were founded on' rock-filled cribs and creosoted piles driven into the harbour bottom, and each had two decks which carried standard-gauge railway tracks.

Jan 1, 1965

By Peter F. Pullen

The need to apply the latest available technology to develop better tools and methods to meet problems in the mining industry was recognized by six of Canada's leading mining companies. As a result, MIROC (Mining Industry Research Organization of Canada) was chartered to identify problem areas in Canadian mining and to have research carried out to develop the tools and equipment to meet these perceived needs. The initial activity of MIROC has been in the environmental field, with improved clothing and protective devices being developed by contractors. Work clothing for miners is now being field tested. Respiratory protection and a new personal light source combined in a new "space-age" helmet are about to be issued for testing. Further developmental work is being carried on to offer these units and probably other personal protective devices on an individual basis as well as in a combined package.

Jan 1, 1979

By H. Yoshida, H. Hatta, T. Suzuki

"The effect of the copper and magnesium contents and quenching rate during quenching on the age hardening behavior of 2000 series aluminum alloys was investigated. For the higher copper-containing specimens as conventional alloys, like AA2024, precipitation of the stable phases increased as the quenching rate decreased under the as-quenched conditions. The maximum hardness after the artificial aging of air cooled(AC) specimens was much lower than that of the water quenched(WQ)specimens. On the other hand, for the lower copper-containing specimens, coarse precipitation did not increase even in the case of the AC. The age hardening behaviors of the WQ and AC were very similar such that the maximum hardness and aging rate were almost the same. Many parts of the fine precipitates that increased the hardness were thought to be the GPB zone or fine S’ phase for the WQ and relatively coarse S’ phase for the AC. From the calculated CCT(continuous cooling transformation)diagrams, the lower copper-containing specimens could maintain the copper and magnesium in the solid solution state during the AC, so they could be quenched at a rather slower quenching rate like the AC.INTRODUCTIONThe 2000 series aluminum alloys, containing copper and magnesium as the major chemical components, are some of the well-known heat treatable aluminum alloys. These alloys have a high quenching sensitivity, thus the age hardening ability of these alloys decreases with as low quenching rate. To prevent the decrease of the age hardening ability, quenching is done by a method such as water quenching, which is not very efficient in an industrial situation, because the method requires such large equipment. For these alloys, reducing the quenching sensitivity helps them to be produced in a rather convenient way. For example, 6000 series alloys such as A6063 have low quenching sensitivity, thus they could be quenched by only air cooling just after extrusion and they do not need water quenching. Based on these reasons, investigations of these alloys with high copper and magnesium contents have been conducted in the past to find a way to lower the quenching sensitivity by adding transition elements such as manganese, chromium and zirconium (Kanno, Suzuki, & Itoh, 1986; Suzuki & Itoh, 1986; Kanno, Sakuma, Muromachi, & Watanabe, 1988). However, very few studies have focused on the quenching sensitivity of the lower copper and magnesium containing alloys because of their usage for structural components with high strength, and most of the past studies have used only the fast quenching method like water quenching. On the other hand, from our recent results, there is a possibility to lower the quenching sensitivity of 2000 series alloys with lower alloying elements. In this paper, the effect of the copper and magnesium contents with lower alloying elements and quenching rate, especially in case of slower quenching rate than conventional quenching method, on the age hardening behavior of the 2000 series alloys is investigated by the hardness measurement, structure observation and thermal analysis."

Jan 1, 2018

By M. Vaillé, B. Bossé, N. Durupt, A. Michaut

Imouraren is a sedimentary uranium deposit (> 150,000 tU @ 800 ppm), located approximately 100 km North-Northwest of Agadez (Niger); its depth reaches 110 to 170 meters. For low-grades ores, heap leaching is commonly considered as the appropriate technology for metal recovery. More precisely, the ore is crushed (≤ 300 mm) and agglomerated before being stacked. In this case, sulfuric acid can be added during agglomeration and/or irrigation (for three months to a year) to improve uranium recovery. It is known that mineralogical, chemical and physical properties of the uranium ore impact recovery, yet many challenges remain to increase recovery using this process. For example, ore heterogeneity and spatial variability (e.g., variation in uranium, carbonate and/or clay contents) can affect heap leaching performances (i.e., metal recovery, acid consumption or neutralization, percolation rate). However, laboratory column tests using composite ore sample that do not consider ore heterogeneity are widely used to anticipate recovery. Consequently, a new approach that consists in using Imouraren drill core ore samples was recently investigated. This latter also enabled a better assessment of the main parameters that influence uranium recovery and proposed a new predictive model to optimize mining operations.

Jan 1, 2020

By Champoux. G., E. Ghali, W. Zhang, G. Monteith, A. -M. Lafront, G. Houlachi

The efficiency of the electrowinning process of zinc depends on the performance of oxygen evolution reaction, anode quality and corrosion resistance of lead anodes. Original surfaces of rolled commercial lead-silver anodes were examined using conventional polarisation methods in acid zinc sulfate electrolyte with manganese sulphate at 38 °C. The self-discharge method (potential decay) following 5 h polarisation at 50 mA cm-2 was considered to evaluate electrochemical activity, oxygen overpotential and anode stability. The influence of silver content is compared to that of the microstructure, the fabrication process and the composition of the corrosion products. Polished anode samples have also been examined for microstructural and corrosion performance studies. The experiments show that the duration of the plateau at 1600 mV versus SHE, the potential level (active corrosion state/stationary state) and the rate AEco/At during the decay could be a good indicator to compare the corrosion rates of the anodes in industrial zinc electrolytes.

Jan 1, 2008

By Imre Gombköto, Barnabás Csoke

"Raw material management means not only mining and processing of primary raw materials like ores, but means also collecting and processing secondary sources of raw materials. Recycling is one of the most developing field of raw material management in Europe, and its solutions are derived from mineral processing roots and principals. Complexity and challenges of the field of recycling results innovative solutions of material processing- Since European Union identified 20 raw materials as critical (CRM) due to lack of primary sources within the border of the EU, recycling become more recognised as source of different raw materials. WEEE is the waste streams contains many of the critical elements and along them at least 15 different species of plastics of which recycling is delayed by a lack of effective separation technique. Most paper deals with separation methods based on different specific gravity, triboelectric charge or surface properties of plastic species. Plastics however have differences of thermal properties and thermoplastics, duroplasts and elastomers can be recognised. The experiments described in the paper aimed to determine thermo adhesive behaviour of plastic species often identified in WEEE streams for separation purposes. According to the results, some plastic types as PS, PP. PC or PVC and PET pairs are possible to easily separate from each other, however different additives are changing thermo adhesive properties of most of the plastics that makes industrial process difficult to develop. Along thermo adhesive behaviour, combination of physical interaction can be used to enhance separation selectivity.INTRODUCTIONPlastics has a relatively long term of history as a light, multi-functional material in construction, packaging, automotive industry and electric and electronic products. There are a numerous types of plastic species can be used for various applications therefore they amount are growing from year to year. This quantity however become part of the waste stream and while metal recycling has been done for decades due to its economic value - cheap plastic parts are less desirable as secondary products. In 2013 an annual 5% of plastic production growth has been estimated with a base data of 265 million tonnes at 2010 (Guiqing & Zhenming, 2013). Since landfill requirements are increasing while—especially in Europe where actual regulations are trying to deflect waste from landfills - landfill capacities are decreasing, costs are become more and more expensive, Applications like energy production based on plastics as a fuel or recycling are some of the options can be applied. Direct incineration of plastics are applied at many plants - in most cases where waste consist of dangerous substances are incinerated because plastics high calorific value helps correct average mixture composition enable operators reaching high enough temperature for combined power and heat generation while most of substances—like PAH, PCB or dioxins—are destroyed. Another path is using low temperature reductive cracking due to pyrolysis process, however the chance having higher concentrate of carcinogen substances in the products are higher since it applies around 400°C during the process."

Jan 1, 2016

By Peter Moon

THE mineral industry of Canada relies heavily upon the talent of its technical men. It is vital to the well-being of the industry that its supply of young, trained men be adequate. At the present time, the industry is acquiring only 200 new graduates a year. The shrinking supply is far below present and future requirements. Other industries and research organizations are competing for engineers and scientists. Dr. J. B. Mawdsley (1), Past-President of the Canadian Institute of Mining and Metallurgy, has recently outlined a program designed to attack the problem. Dr. J'. C. Sproule (2), another former President of the Institute, has stated that: "The need for selection of trainee material is commonly recognized, but little is done about it." The following paper contains a short discussion of occupational interests, and outlines research, using psychological knowledge and measuring techniques, aimed at the identification of desirable recruits for the mineral industry.

Jan 1, 1963

By V. L. Mitsopoulos

This paper provides a summary of tailings disposal techniques and the improvements that have been made through the introduction of thickened tailings disposal. The general properties and characteristics of thickened tailings are described, as is a design process for selecting appropriate technologies for thickening, pumping, transporting and storing tailings. The factors affecting the selection of an appropriate disposal site and operational considerations for the effective utilisation of tailings storage areas are also documented.

Jan 1, 2006

By T. B. Williams

Most geologists have felt the need of a longer base than is ordinarily available when using a Brunton compass or other convenient instrument for taking strikes and dips in the field. To overcome this difficulty a lath or stick with straight parallel sides is frequently used. This accessory adds to the accuracy of the work, but it is a decidedly inconvenient one for the geologist to carry, especially if he be heavily loaded or is travelling on horse-back or through thick brush on foot. The writer has abandoned its use in favour of a sturdy two-foot carpenter's rule. The rule preferred is manufactured by J. Rabone and Sons, Birmingham, England. It is provided with a good level-bubble set in one of the limbs, and a scale, of the protractor type, graduated to five degrees through 180 degrees, attached to the main joint at the middle of the rule. (See Figure 1). For an instrument of its kind it is very accurate, and, in addition to the uses mentioned below, it 'is a handy thing to have around any camp. It is frequently used when plotting roughly in the field and for a protractor when one is not available. When not in use it may readily be carried in the top of the high-boot or legging. Ordinary strikes are measured as illustrated in Figure 1, the compass being held against the rule, which is in a horizontal position. Dips may be measured in a corresponding way by holding the Brunton compass against the extended rule, which is thus used merely as a straight edge. It is usually much more convenient, however, to ? use the rule only for this purpose, in which case one foot of the length rests as a straight-edge against the rock surface. This adaption is shown in Figure 2.

Jan 1, 1929

By G. F. Vander Voort

Over the past twenty years, steelmakers have introduced improved practices for reducing the inclusion content of steels. The success of these practice changes can be monitored in a variety of ways. Chemical analysis of the bulk sulphur and oxygen contents provides a relatively simple means to assess the impact of these changes. However, microscopical test methods are still needed to assess the nature of the inclusions present. Traditional chartbased measurement methods have wide acceptability, and their data are well understood by both purchaser and producer for heat acceptance purposes. However, these methods do have inherent weaknesses which limit their usefulness for quality control, SPC, and database applications. Image analysis-based chart measurements are an improvement over manually generated chart ratings, but the data still do not lend themselves to databases and statistical comparisons. ASTM Committee E-4 on Metallography has developed a stereologicallybased image analysis standard test method, E 1245, which provides the necessary data in a form which is easily databased and analyzed statistically. This paper describes E 1245 and shows how data from different heats and melting practices can be compared statistically to ascertain valid test differences.

Jan 1, 1998

By W. R. Bacon

"IntroductionTHIS IS a brief discussion of certain regional and economic aspects of the Coast Range of British Columbia. Between Portland canal and the 60th parallel of latitude, only the eastern margin of the Range is in Canada. The solely British Columbia interval extends from Portland canal to Burrard inlet. Personal observations in various parts of this area form the basis for much of this paper.Regional GeologyGranitic RocksSome of the best, most continuous exposures in the Coast Range are found at sea level. Reconnaissance study of the coastline has shown that the Range is predominantly granitic in character, but there simplicity ends, for the term 'granitic' as applied to the Coast Range covers a variety of mineralogical compositions. Actual granite is quite uncommon, occurring mainly in irregular or dyke-like masses that do not achieve batholithic dimensions. It is commonly pinkish, relatively homogeneous, and exhibits few of the deformational features that are obvious in much of this plutonic complex.Most of the granitic rocks of the Range fall well within the compositional limits of quartz diorite and granodiorite. The problem of resolving the great mass of these rocks into smaller coherent units is in general a difficult one. As noted above, granitic rock of uniform composition and texture is found in restricted areas and can be outlined without much difficulty. One such body occurs on the southern shore of Nelson island."

Jan 1, 1955

"Real-time, on-stream analysis of the metal content of process slurries is an essential prerequisite for process monitoring and advanced control of mineral processing circuits. On-stream X-Ray Fluorescence (XRF) sensors for base metal applications are available commercially and form the basis of many plant monitoring circuits. To date, these commercial technologies have been insufficiently sensitive to measure precious metals such as gold and platinum group elements, typically present at part-per-million (ppm) and sub ppm levels. CSIRO has developed a novel X-ray based technology, called UltraGold, which enables detection of gold in slurries on a real-time basis with a precision below 100 parts-per-billion. This technology is based on the use of advanced X-ray optics, extensive Monte Carlo computer modelling for analyser design, high accuracy X-ray spectrum fitting where the X-ray intensities are matrix corrected. In this paper, we will introduce this technology and discuss the results of a proof of principle study performed in the laboratory with plant slurries (tailings and concentrate) from an Australian beneficiation plant. Finally, we will discuss further planned improvements. As projected grades in (gold) mining around the world fall and several large-scale mines approach the limits of their economic reserves, this method can enable significantly reduced operating costs by rapid analysis to improve circuit efficiency and hence improve recovery significantly.INTRODUCTION This paper describes a study undertaken to explore the feasibility of applying CSIRO?s UltraGold XRF technology to the on-stream measurement of gold in process slurries. The provision of rapid, accurate information of gold grade in feed, tailings and concentrate streams would facilitate significantly improved process control and early detection of plant upsets, resulting in substantial cost-savings. CSIRO have patented X-ray fluorescence (XRF) techniques for the analysis of key elements in slurries present at part-per-million (ppm) and sub-ppm levels. Conventional, commercially available on-stream XRF instruments generally have detection limits in the tens of ppm range, precluding their use for analysis of elements like gold that are mined and processed at much lower concentrations."

Jan 1, 2017

By J. H. Archibald

"This paper describes the use of vector analysis for determining the intersection of mineral deposit veins. The mathematical evolution of the analysis is outlined.IntroductionMany mineral deposits can be characterized by sets of intersecting veins. Often a vein will have a steep dip and may intersect with another similar vein. Finding the intersections of these veins is usually done by graphical means. Structural geologists, by the methods of descriptive geometry, can usual ly predict where intersections of veins will occur. This method normally requires accurate drafting and layout of the problem and does not always lend itself to solution in the field.Another method for solving this problem involves the use of vector analysis, which is easily adapted to hand-held programmable calculators. It is assumed at the outset that the reader is familiar with the dot and cross products used in vector analysis. Two excellent references are cited at the end of this note for convenience.A plane, in general, is defined by three points. The points of interest here are the points where three vertical drillholes penetrate the vein, or plane, in question. The elevations of these three points are best referred to sea level. This requires knowing the elevation of the collar of the drillhole above sea level and the drillhole depth from the collar to the vein. The elevation of the intersection point is then found by subtracting the hole depth from the collar elevation. These three points now define the plane of the vein. A similar set of three points will define a second vein, and it is our object to show analytically their intersection if it exists."

Jan 1, 1983

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003