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A Kellogg type computer model of the slag fuming process is applied in reverse to derive some thermodynamic properties of components in lead blast furnace slag. At 1200¦C, the average activity coefficients calculated were 3.40 (S.D. 0.50) for ZnO referred to the pure solid; 0.657 (S.D. 0.022) for PbO referred to the pure liquid; for the ratios y 3.175 y (referred to the Feo.9450, Fe304 pure solids) 4.19 (S.D. 1.15), and for yCaS/ 1CaO (referred to the pure solids) 5.10 (S.D. 2.96). Statistical relationships were derived for these activity coefficients and ratios as functions of the composition of slag, which contained in molar percentages 1.9 - 12.6% ZnO, 19.8 - 24.9% Fe0.9450, 0.9 - 1.6% Fe304, 0.002 - 1.9% PbO, 16.1 - 18.6% CaO, 25.9 - 31.0% SiO2, 4.8 - 5.5% MnO, 9.2 - 10.3% A101.5, 1.2 - 1.4% CaS, and 5.1 - 9.6% "Mgo" (the balance).

Jan 1, 1980

By Fabjanczyk M. W

A limitation to present theoretical roof reinforcement design methods is the inability to derive accurate and quantitative information about the roof rock condition and the action of reinforcement at various excavation stages. To obtain the information required to assess roof rock stability, detailed monitoring of the in-situ behaviour of reinforcement and roof strata is required. Reliable instru- mentation and techniques have been developed for use in underground coal mines to identify the geometry and magnitude of displacements occurring in roof rock and the forces generated in reinforcement. The use of such instrumentation allows an accurate assessment of the in-situ capability of reinforcement and the mode of reinforcing action developed. In-situ monitoring can supply data required for the practical design of reinforce- ment and assess the potential stability of current designs. The use of such data together with mine wide appraisal of rock and stressfield considerations, can allow roof reinforcement to be designed on the basis of a predicted roof Response.

Jan 1, 1986

Despite the research interest on non-cyanide gold lixiviants over the past three decades all the non-cyanide gold processes are still at the developmental stages with limited understanding on solution and pulp chemistry in some cases. This is partly associated with:the difficulties in measuring reliable equilibrium data for various gold(I/III) complexes with non-cyanide ligands; the lack of knowledge on mixed-ligand complexes; and different kinetic stabilities of gold(I) complexes with respect to disproportionation. This paper presents reliable equilibrium data for complex formation, dissolution, precipitation, hydrolysis and disproportionation reactions of gold(I/III) compounds with a range of non-cyanide ligands: S2-, HS-, S2O32-, SO32-, SCN-, SC(NH2)2, OH-, NH3, Cl-. Solubility of gold(III) compounds with non-cyanide ligands follows the order: Cl- > NH3 > OH-. In the case of gold metal the solubility order at a given temperature is MgS > Fe(III) or Cu(II) / Cl- > Cu(II)/NH3 > NaOH, but the solubility increases with increasing temperature. Rate of gold oxidation with different non-cyanide lixiviants depends on the oxidant, ligand and temperature and follows the general order of oxidants: Fe(III) or Cu(II) > X2 or OX- > O2 (X = halogen). In the case of metal ion oxidants oxygen is required to reoxidise Cu(I) or Fe(II). Some of the reported data on chloride and thiosulfate leaching of gold are presented to highlight the effect of additives and the copper, silver and sulfur contents of the starting material on the success of non-cyanide leaching processes.

Jan 1, 2004

By Coppock BW

Sintering of lead and zinc concentrates is practised by Sulphide Corporation Pty. Limited to provide both desuiphurised lump sinter feed, for simultaneous reduction to zinc and lead in the Imperial Smelting Process blast furnace, and sulphur dioxide gas for sulphuric acid manufacture. From November, 1969 a 20 percent increase in production rate has been obtained through improvements in operating technique. A gradual increase in bed permeability was achieved by modifications to the feed mix conditioning equipment and by improving moisture control. However advantage could not be taken of the higher permeability to increase sulphur elimination because the hardness of the lump sinter decreased. Higher throughput, better quality sinter and more stable sintering conditions were however made possible by simultaneously: 1. reducing segregation and compaction in the sinter bed, by narrowing the discharge opening of the main layer feed hopper, 2. reducing the sizing of sinter returns to give a closer size spectrum of particles in the feed mix, and 3. increasing the sulphide sulphur content of the feed mix to give higher bed Temperatures.

Jan 1, 1972

During the last few years the quality requirements on roads and railroads have become more accentuated due to the desire to minimise maintenance costs. This has, in turn, led to increasing requirements in the preparation of ballast materials and pavement aggregates. As the access to natural gravel in northern Europe is decreasing (due to lack of availability or by law restrictions) the use of crushed rock material is becoming more and more important. The aim of this paper is to derive and describe a universal method for the prediction of particle size distributions from compressing crusher machines such as jaw- and cone-crushers. Based on a closely defined physical model, expressions which define the size reduction process are derived. Conditions for simplifying assumptions are clearly outlined. The choice and mix of breakage functions is a central subtopic iò the analysis of the crusher machine processes. Known breakage functions are reviewed and evaluated. A new concept for determination of a true breakage operator which is related to physical properties of the crusher device and the size distribution of the feed material is introduced. Finally experimental tests are compared to numerical calculations. The method described in the paper can be a useful tool when designing crushing plants or when optimizing the output of compressing crusher Machines.

Jan 1, 1995

The theory of declining optimimum cut-off grades is more than 25 years old, but for a number of reasons it is still not widely used in industry. A lack of faith in the veracity of estimated grades is not in itself a reason to abandon any attempt to optimise cut-off grades. The use of declining cut-off grades has been thought to cause high-grading, but in fact this is only true if an artificially high discount rate is used in the calculations. Perfect application of an optimum cut-off grade should ensure that only ore generating more than a minimum net return is mined, and that as much as possible of the ore capable of generating that return is mined. Therefore differing mining costs in different parts of some underground mines necessitate local modifications to cut-off grade. Optimisation of cut-off grade is of necessity an iterative process. Integration of that process into a feasibility study need not be excessively time-consuming. A number of approximations can be made to speed the optimisation (any attempt to achieve a high level of accuracy is probably doomed to failure by a lack of precise cost and price projections). A procedure is outlined for optimising cut-off grade during planning of a typical underground mine.

Jan 1, 1991

By Daniels E. J, Morgan W. A

In response to the increase in consumption of galvanised steel for automobiles in the last decade and the problems associated with remelting larger quantities of galvanised steel scrap, a process is being developed to separate and recover the steel and zinc from galvanised ferrous scrap. The zinc is dissolved from the scrap in hot caustic using anodic assistance and is recovered electrolytically as dendritic powder. The dezinced ferrous scrap is rinsed and used directly. The process is effective for zinc, lead, and aluminum removal on loose and baled scrap and on all types of galvanised steel. The process has been pilot tested for batch treatment of 900 tonnes of mostly baled scrap. A pilot plant to treat continuously loose scrap, with a design capacity of 48 000 tonnes annually, has been in operation in East Chicago, Indiana since early in 1993. The first 450 t of scrap degalvanised in the pilot plant have residual zinc below 0.01 per cent and sodium dragout below 0.01 per cent. Use of degalvanised steel scrap decreases raw materials, environmental compliance costs, and opportunity costs to steel- and iron-makers. Availability of clean degalvanised scrap may enable integrated steel producers to recycle furnace dusts to the sinter plant and EAF shops to produce flat products without the use of high quality scrap alternatives such as DRI, pig iron, or iron carbide. Recycling the components of galvanised steel scrap saves primary energy, decreases zinc imports, and adds value to the scrap. The quantities of zinc available by the year 2000 from prompt and obsolete automotive scrap will approach 25 per cent of zinc consumed in the major automotive production centres of the world. Zinc recycling from galvanised steel scrap, either before or after scrap melting, will have to be Implemented.

Jan 1, 1993

Robertson Diasol have developed a spectral gamma-gamma tool fully able to withstand borehole conditions. Spectral data is digitally recorded across 256 channels depending on energy levels of the photoelectric effect. Data processing is being developed with the objective of calibrating channel amplitudes to mineral type which will lead to a direct log of selected mineral grade as a continuous trace with depth.

Jan 1, 1990

By de Lassar de Pressigny Y

IRSID has in its laboratories two experi mental counter-current reduction furnaces allo- wing the simulation of the physico-chemical conditions of reduction in any gas-solid coun- ter-current process, including the blast furnace and direct-reduction shaft-furnaces. The counter current is realized by an electric furnace mo- ving along a laboratory tube filled with the material to be tested. The reducing gas stream in the tube travels in the same direction as the furnace After reduction, twenty samples, with dif- ferent degrees of reduction and which can be related to different levels of an industrial furnace, are taken from the tube and subjected to various quality tests. Experiments were realized to determine the behaviour of various types of industrial pellets when reduced under either blast furnace or shaft furnace conditions. The results show the large influence of the reducing conditions on any pa- rameter characteristic of the quality of the pellets : reduction efficiency, swelling, cru- shing strength and disintegration.

Jan 1, 1974

The late 1960's and 1970's saw the initial development of the coal resources of the Bowen Basin of Queensland. The projects developed relied on large scale, open-cut operations using draglines for overburden removal and, in the majority of cases, project viability could be established based solely on those open-cut operations. Many of the mines developed in the 1980's have the same characteristics.Unlike these mines, the German Creek Mine has limited open-cut reserves at low overburden to coal ratios, and planning of the complex involved a large open-cut mine capable of developing early cash flow, with phased introduction of underground mining to replace open-cut capacity as the strip ratio increased.

Jan 1, 1985

By Kay JR

In 1984 a new Regional Geological Mapping Program (RGMP) was commenced by the Geological Survey of Queensland (GSQ); the new program was in response to the withdrawal of the Bureau of Mineral Resources from regional mapping. Areas for mapping were selected in northern and south-eastern Queensland on the basis of potential for mineral discoveries, level of company interest, inaccuracies in the first edition mapping and interests of other organisations (government and universities) in joint projects.Geological provinces of particular interest in northern Queensland are the Hodgkinson Basin, parts of the Georgetown Inlier not covered by earlier BMR-GSQ mapping, Broken River Embayment, Burdekin Basin, Lolworth-Ravenswood Block, Campwyn Block and Anakie Inlier. The 1:250,000 sheets covering these areas of interest are shown in Figure 1 including those already completed, those in progress and those planned for future investigation.A flow chart showing the various phases for RGMP projects is shown in Figure 2. Data collection has two facets: (i) field recording and (ii) office work including air photo interpretation, study of company reports, literature research, petrography and various laboratory studies. Two main strands of information collected are represented by a data base and compilation sheets. Compilation sheets are generally at 1:25,000 scale and are available for purchase. The current data base is very fragmentary and can be accessed only by direct contact with the relevant geologist or via written reports. A more accessible field data base is in the process of being introduced this year; this field data base (REGMAP) is based on standardised data recording and computer storage.

Jan 1, 1986

This paper briefly discusses the negotia- tion of the more important provisions in agree- ments for exploration and mining rights with Pacific countries. LAND RIGHTS Land rights are complicated and sometimes controversial in many of the Pacific countries. In some countries, a company will have to deal with land owners directly; in others, the government will act as intermediary. Inevit- ably, a company will have to deal with both. Mining companies need to be sensitive to the culture and particular interests of the land owners and of their history in defending their rights. The issues are too complicated to be dealt with here. Some mining companies have spent, and will continue to spend, considerable time trying to understand them. It will " require patience, perseverance, sensitivity and unflagging optimism. The better advised companies will ensure that their local repre- sentatives get to know the land owners, under- stand their concerns, and will pursue a policy of keeping them informed on a regular basis of all of the company's activities and proposed activities. Good community relations are the keystone for good mining operations in the Pacific. Most countries will require the submission of an environmental impact statement so that they will know in advance what effects a pro- posted mining operation are expected to have on the environment and how it is intended to deal with them. They will also want to approve the company's environmental reclamation and rehabilitation plan. Let's face facts right away - mining, by its very nature, is not going to improve the environment. There will be waste discharges, emissions and deposits. They will affect the land, air and water and hence human, marine and animal life and vegetation. There will be sounds and odours and the esthetics of mining operations, though perhaps pleasing to geolo- gists and mining engineers, will not please Others.

Jan 1, 1987

By Robbilliard K. R, Floyd J. M

The problems facing the metallurgical industry from the viewpoint of the range of unacceptable residues, flue dusts and slags currently produced from the electrolytic zinc process, electric arc furnace scrap treatment, and blast furnace operation in lead smelting and the Imperial Smelting Process (ISP) are addressed. The application of the Ausmelt technology is discussed and analysed for the pyrometallurgical treatment of zinc plant residues, steel plant flue dusts and lead blast furnace and ISP slags, as well as the more complex issue of smelter modernisation to avoid production of zinc plant residues in the future. Processes developed from pilot work are described and indications of the economics of treatment of electrolytic zinc plant neutral residue and jarosite are given.

Jan 1, 1993

By Chander S

Properties of surface films on chalcopyrite and pyrite differ due to variations in the mechanism of oxidation of the two minerals. In the case of chalcopyrite the first step in the oxidation is the release of iron as ferric ions, which hydrolyse depending upon conditions prevalent in solution. The iron oxide/hydroxide layer formed by hydrolysis of ferric ions is quite porous and easily detachable from the surface of chalcopyrite. When the surface oxide layer is detached a sulphur-rich layer is exposed making chalcopyrite hydrophobic. The thickness and properties of the sulphur-rich layer determine its flotation response, both in the absence and presence of collectors. In the case of pyrite, on the other hand, iron is released as ferrous ions which require much higher pHs to hydrolyse. These ions remain adsorbed on the surface of pyrite making the surface hydrophilic. When the iron species are complexed with chelating agents such as ethylene diamine tetra acetic acid, pyrite was hydrophobic. Siderite forms in the presence of carbonate ions, which might be present in several flotation systems. Siderite nucleated on isolated sites at the surface. The presence of such a precipitate is likely to influence the interaction of pyrite with various reagents thereby altering its flotation behavior. To determine the mechanism of oxidation, kinetics of oxidation of chalcopyrite and pyrite was studied using several electrochemical techniques, namely, cyclic voltammetry, polarisation and impedance spectroscopy. Floatability of the minerals was investigated by measurement of contact angles on mineral electrodes and by Halimond tube flotation. Impedance spectroscopy was especially useful for estimating various properties of surface film for both the minerals. Properties such as charge transfer resistance, porosity, and capacitances of the surface films on the two minerals are compared under several conditions of oxidation. These properties were found to be a strong function of the rate and the extent of oxidation.

Jan 1, 1993

Introduction.History of Stope Filling at Mount Isa.The Need for a Systematic Fill Programme.Reasons for Filling.Fill Materials and Tonnages.Rough Mullock Fill.Quantities Readily Available.Fill Pass Development.Stope Preparation.Drainage.Hydraulic Sand Fill.Initial Experiments with Mill Tailings.Surface Layout.Operation Procedure.Underground Pipe Lines.Life of Sand Pipes and Cones.Drainage.Old Tailings Dam Sands.Quantity of Fill Placed.Pillar Tonnages.Conclusion and Acknowledgment.INTRODUCTIONFilling practice outlined in this paper refers exclusively to the Black Star section of the mine. The stope filling necessary early in the life of the Black Rock and portions of the Rio Grande sections is not to be confused with the current filling programme.

Jan 1, 1953

Recovery of tin and copper from concen trates containing cassiterite, stannite and chalcopyrite was studied in laboratory-scale tests designed to simulate continuous operation of the matte fuming process in which tin is recovered as SnS fume while copper accumulates in the matte. Charges made up of 300g of mixtures of the concentrate and siliceous flux were added at a uniform rate in pelletized form to crucibles containing 300g of matte and 50g of slag (both of which were recovered from previous tests), while blowing through the matte with air or oxygen-nitrogen mixtures at a rate of 3 to 5 1/min. Accurate material balances enabled the effects of process operating conditions on tin recovery and sulfur utilization to be deter- mined. When operated correctly, the matte fuming process gave tin recoveries exceeding 90 percent in spite of wide variations in the copper content of the matte and in the operat- ing conditions. Deterioration of tin recovery was associated with undersaturation of the slag with respect to silica, and with high partial pressure of sulfur dioxide (greater than approx- imately 0.2) brought about by oxygen enrichment of the blowing air. The utilization of sulfur varied widely in low grade mattes. Copper in excess of approx- imately 10% promoted formation of SO2 by the commonly accepted reaction: FeS + 1-120 2= FeO + S02 while in copper-free and lower grade mattes a substantial fraction of the oxygen was consumed in the alternative reaction FeS + i 02 = FeO + z S2.

Jan 1, 1980

By Menne D. M, Ladyman R

Camel Creek Mine operated by Lynch Mining Pty Ltd is located 65 km west of inghain and 160 kin north west of Townsville in North Queensland. (Figure 1). The Camel Creek gold mineralisation was discovered in mid-1987 in an area previously known for its tin workings. Mining commenced in January 1989 after an oxide reserve of 1.2 million tonnes @ 2.1 g/t gold had been delineated. The first gold pour was in May 1989. The mine developed into a medium sized open cut operation, with full site facilities. The initial mining rate was 500 000 tpa utilising run-of-mine (ROM) heap leaching to recover the gold. By the end of 1990 the wider orehodies were mined and efforts were focused on the narrow orebodies, of width typically less than three metres. Smaller earth moving equipment was employed to selectively mine the narrow orehodies leading to a decrease in the mining rate to 200 000 tpa. The Red Gold deposit (80 000 tonnes « 3.0 g/t to 18 in vertical) was mined in mid-1990 and ore was hauled approximately 8 kin to the Camel Creek heap leach operation. The ore was hauled in a dedicated campaign after being stockpiled. The cost of dedicated ore haulage ensured that only the more exceptional of the remote orebodies could be mined in this manner. The Golden Cup orebody, some 20 km from Camel Creek, was too distant to permit ore haulage. However, this prospect contained sufficient gold (initially 90 000 tonnes @ 3.0 g/t) to warrant the installation of a small mobile adsorption facility. Construction of the second heap leach operation commenced in late-1990. Gold production commenced in early April 1991. Mining of several smaller orebodies remote to the second heap leach facility has been undertaken and further mining is planned. This paper outlines heap leaching practice at Camel Creek Mine and summarises the success of the Golden Cup heap leach.

Jan 1, 1994

Authority to Prospect 57P lies within the Surat Basin',' an eastern lobe of the Great Artesian.Basin, a major Mesozoic . downwarp that,had its inception'in Triassic time. The northern edge of the Mesozoic Surat Basin overlaps the southern extension of the Bowen Basin, a 'major structure that warped do*nWard in varying degrees from Permian time into Early'Triassic time: The axis of the Bowen Basin may be superimposed on the axis'of a still older structure, the Tasman Geosyncline, that probably originated in Ordovician time culminating in Late Carboniferous time.Within. or bordering the area the geologic record 'clearly marks.major differences in the stratigraphy and structure related, to"the successive evolution of these three distinct structural units. Three major phases of sedimentation have been recognised; one related to the development of the Tasman Geosyncline froi'n. Devonian to.Early Permian time (Horton group), one related to-the development of the Bowen Basin from Early Permian to_Early Tri= assic time (Bowen group), and one related to the development of the Great Artesian Basin from Triassic to Cretaceous time (Great Artesian . Group).

Jan 1, 1962

By Aitchison J, Clarke G

A reappraisal of the stratigraphy, new regional kinematic analysis and thermobarometric data allow a new interpretation of the metamorphic zoning and tectonic structure of the Upper Eocene high-pressure metamorphic core complex of northern New Caledonia allow a three steps evolution to be proposed : 1) subduction and understacking of previously thinned continental crust elements; 2) subduction blocking due to the crustal thickening; 3) crustal thinning and extensional detachment during the diapir-like uplift and unroofing of the eclogitic core. Steps 2 and 3 may be partly contemporaneous. Such a model accounts for the thermobarometric and radiochronologic data, and also for the weakness of substratum deformation during the emplacement of the ophiolitic nappe.

Jan 1, 1995

By Bennet A. G

An overall review of the selection of rock strength and deformation characteris- tics for the design of the Melbourne Under- qround Rail Loop (MIJRL) rock tunnels is presented. Particular emphasis is placed on aspects of in-situ testing, including large diameter plate bearing tests. Material on the interpretation of test results for use in the design of the tunnel linings and openings is included, with a brief discus- sion of desiqn methods.

Jan 1, 1981