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By Basil Dimitriades

The association of automotive fuel composition with exhaust reactivity was studied in an experimental program that involved testing with different automotive engines and with gasolines of varied composition. Results showed clearly the exhaust reactivity to increase with increasing levels of polyalkylbenzenes in the fuel. No other systematic patterns of high significance were detected in the association of exhaust reactivity with several broadly defined groups of fuel components. For the purposes of this study, had it been possible, fuel composition should have been defined and expressed in terms of component groups such that the potential for exhaust reactivity would be the same within each group and different from group to group. Classification of fuel components in terms of the paraffins-olefins-aromatics groups does not meet the latter requirements. For appropriate classification of fuel components more information is needed on the combustion .of hydrocarbons in the multicylinder internal combustion engine. Statistical analysis of the mass emissions data showed significant car and fuel effects on hydrocarbon, carbon monoxide, nitric oxide, total aldehydes, and formaldehyde emission levels and on total photochemical reactivity. Car-fuel interactions were not significant at the 90-pct level. Correlations were found between mass emission parameters and fuel composition.

Jan 1, 1973

By M. J. Ackerman, C. R. Waine, W. M. Merritts, L. P. Mokwa

Tests were conducted in the Pocahontas No. 4 coalbed in southern West Virginia to determine if successful degasification techniques, developed during an earlier study in the Pittsburgh coalbed, would be effective in removing methane from those usually more gaseous coals. Specially designed long-hole drilling equipment and Bureau of Mines continuous recording devices were used to measure the quantity and methane content of the ventilating air during the investigation. Infusions were made with water at normal waterline pressures ranging from 200 to 220 psi or at pump pressures ranging from 400 to 650 psi. Results of the tests showed that methane emissions from free-flow bleeder holes were as much as 131 cfm. Infusions of some of the holes increased the methane emission from other holes and from the exposed coal surfaces near the working areas as much as 1,540 cfm. The methane content in the main return-air currents after infusion was reduced more than 86 percent of the amount recorded before tests were made.

Jan 1, 1963

By Joseph J. Wallace, Lloyd Williams, D. A. Reynolds, James J. Dowd, R. F. Abemethy

"SUMMARY AND CONCLUSIONS1. The investigation shows that the most important beds in Allegany County, from the standpoint of known recoverable reserves are: Lower Bakerstown, Upper Freeport, Upper Bakerstown, Upper Kittraing - less important beds are: Sewickley, Waynesburg, Pittsburgh, and Barton. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 tons per acre-foot of coal in place, are estimated to be 556 million short tons, as of January 1, 1951. Of this total, 304 million short tons is in beds 23 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager to permit making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total eat ted reserves.3. Recoverable reserves of coal have been estimated in beds 28 inches and more thick. This thickness is about the minimum now being mined by hand-loading onto conveyors in the Appalachian region. The weighted average recovery for all beds in Allegany County, as determined by this investigation, is 49.8 percent. This percentage is based on the total thickness of coal (less partings 3/8 inch or more thick) in the bed rather than on the thickness of the coal mined. Based on the weighted average percent recovery for all beds in Allegany County, the recoverable reserves are estimated to be 152 million short tons as of January 1, 1951.4. The Allegany County coals are low-volatile bituminous in rank.5. The Allegany County coals are strongly coking."

May 1, 1953

By J. T. May

The Federal Bureau of Mines investigated the extraction of lithium from hectorite-type clay deposits found on the Nevada-Oregon border. Two clay samples were used in the investigation; one contained 0.36 pct Li and the second contained 0.64 pct Li. The purpose of this laboratory-scale research was to determine how these clays responded to different extraction techniques. Extraction techniques investigated were sulfuric acid leach, sulfuric acid bake-water leach, and roast-water leach procedures with cholorides, sulfates, carbonates, and combinations of these reagents. The processing characteristics of the clay samples showed significant variations, and no one technique was effective for both materials. Lithium extractions near 90 pct were achieved during these exploratory studies.

Jan 1, 1980

By A. C. Fieldner

The Bureau of Mines has recently conducted a study of results obtained in analyzing similar samples of coal and coke by 25 laboratories throughout then country, in comparison with results obtained in the Bureau's coal laboratory at Pittsburgh. The purpose of this work was primarily to obtain a comparison of the methods of coal analysis used by the laboratories of the American Gas Association. Therefore, four standard samples of coal end one of coke ware prepared in the Bureau of Mines coal laboratory at Pittsburgh, and portions sent to each laboratory. At the same time, a like number of standard samples were submitted to 12 commercial laboratories rot affiliated with the Association, for the purpose of comparing their analyses with the results is obtained by the U. S. Bureau of Mines and the American Gas Association. Tire comparison is based on the average of 24 analyses by the Bureau of Mines on each kind of coal, and the accompanying curves show the deviation from this average analysis, together with deviations from the check limits of the American Society for Testing Materials.

Jan 1, 1923

By Robert J. Anderson

"Introductory Statement.In founding any kind of castings, even with the best practice, scrap castings are produced because of rejections for certain defects. Casting los¬ses are a serious source of financial loss in iron and steel foundry practice as well as, in brass and bronze, but they are particularly serious in aluminum foundry work because of the high value of aluminum. The indications are that in many aluminum foundries in the United States, the casting losses are at times high, and in some plants they are entirely too high when compared with average practice. Of course, defective castings have a residual value for remelting, but if much machine work has been done on a casting before it is scraped, the labor costs alone may exceed the value of the metal and even that of the rough casting.In a foundry, the monetary losses incurred through the production of waster castings can be ascertained from calculations based upon adequate scrap-loss reports. Such reports, when properly kept and interpreted are a valuable aid in finding foundry costs, but they are primarily useful in diagnosing the causes for casting losses. Many aluminum foundries in the United States do not keep adequate records of strap losses; as a result the causes for defective castings can not be traced, nor preventative measures adopted. However, some of the large aluminum foundries keep excellent records, and it has been found that these involve little extra expense for clerical work. If a foundry man will study his daily production of defective and waster castings, he will be able to trace the causes or losses and then make such corrections in his plant practice as will effect a considerable reduction in these losses -- as much as 50.0 per tent in some foundries. If all the present casting losses of the United States could be reduced 50.0 per cent, by eliminating only the readily preventable defectives, a saving of several million dollars would accrue. In the aluminum-foundry industry alone, the saving would amount to about $600,000."

Apr 1, 1920

By W. S. Sanner

A High Splint coal was carbonized in a low-temperature, fluidized-bed sys-tem to study the effects of thermal cracking on the products of decomposition. The coal was fluidized in recycle gas at 485° to 600° C, and the products were cracked at 600°, 700°, and 800° C in a bed of fluidized coke. Yields of tar, pitch, paraffins, and olefins decreased as carbonization temperature increased. Thermal cracking of the tar vapors produced the highest tar yields at 600° C, and light oil yield increased at cracking temperatures up to 700° C. At an 800° C cracking temperature, the yield of light oil decreased.

Jan 1, 1969

By A. J. Barry

Five makes of expansion-type shells and two types of bolts (mild-steel and high-strength) were used in 30 tests made in sandstone and shale roof, The results show that the anchorage obtained in both the sandstone and shale were stronger than either type of bolt. That is, the yield loads of both bolt types were exceeded before excessive anchor slip occurred. A relationship for evaluating the anchorage effectiveness of 3/8-inch-diameter, expansion-type bolts is presented. A comparison of test results indicates that the anchorage effectiveness of 5/8-inch- and 3/4-inch-diameter expansion-type bolts did not differ appreciably.

Jan 1, 1957

By M. J. Kovalik

Illinois No.6, a high-volatile B coal of low fluidity, was blended with fluidized-bed char and coke breeze to improve the strength of the coke obtained from carbonizing this coal. Twenty-one tests, selected from those made in the small-scale Hanson carbonizer, were carbonized in the BM-AGA 13-inch-diameter, cylindrical retort, with a coal charge of about 90 pounds; the strength of the cokes was determined by the standard ASTM tumbler test. Using the same procedure, 10 tests were made with High Splint, a high-volatile A coal from Harlan County, Ky. Carbonization of the blends produced larger and stronger cokes than did the Illinois No.6 coal singly. The optimum blend contained 6 percent each of char and coke breeze. Further improvement in coke strength was realized by either preheating this blend prior to carbonization or by adding a small pro-portion of a premium blending coal. The former method could possibly eliminate the use of premium coking coals in blends with Illinois No. 6 coal to make an acceptable metallurgical coke. Except for no improvement in coke strength by preheating, results for High Splint coal showed behavior similar to that of the Illinois No.6 coal.

Jan 1, 1973

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of the significant coalbeds of Beaver and Lawrence Counties, Pa. Washability analyses were made on seven coalbed samples, none of which were of metallurgical quality as received. Five of the samples could be sufficiently upgraded to produce acceptable products, and the remaining two samples could not be upgraded to metallurgical quality because their sulfur contents could not be lowered to meet the standard. For steam or power generation, one sample was of low sulfur content as received, one sample could be upgraded to low sulfur content, and three samples could be upgraded to medium sulfur content. The original sulfur content of the remaining two samples can be appreciably reduced by removal of the sink 1.58 speci fic gravity material; however, these coals would be classified as medium sulfur coals both before and after removal of the sink material.

Jan 1, 1969

By D. R. Douslin

This report describes an inclined-piston pressure gage that operates from a zero-pressure datum level. The gage is adaptable to accurate vapor-pressure measurements in the low and intermediate pressure range, 0.01 to 40 mm (mercury). Residual friction in the oil-lubricated piston-cylinder combination is eliminated by a unique oscillatory method that is free of end thrust on the piston and allows the full sensitivity of the gage to be realized. The axial component of the weight-to-area ratio of the piston is determined by measuring the angle of inclination with a goniometer that can be read to 1 sec. Accuracy of the gage proper is estimated to range from 0.001 to 0.012 mm from lower to upper pressure limits. Its highest practical sensitivity is about 0.0005 mm. As a test, the vapor pressures of ice and water were measured in the range -30° to +20° C.

Jan 1, 1963

By R. E. Perry

In connection with a program of coal research at the Southern Experiment Station the Bureau of Mines, in cooperation with the University of Alabama and the various coal operators, conducts washability studies of coal from beds in Alabama and other Southern States in which commercially important deposits occur. One of the main objectives of a washability study is to obtain technically and commercially important data necessary for determining the best methods for preparing and utilizing the Nation's limited reserves of coking coal. Such information is important to conservation because it facilitates selection of preparation methods that will provide maximum yields of coal with low ash and sulfur contents.

Jan 1, 1958

By E. O. Binyon

The Blue Metal corundum-andalusite deposit, in the Buckskin Mining district, Douglas County, Nev., was explored by the Bureau of Mines in 1945. The results of that work were presented in Report of Investigations 3895, exploration of the Blue Metal Corundum Property, Douglas County, Nev. published in August 1946. That report also describes the property in detail, giving location, ownership, history, geology, and data on beneficiation tests. Further exploration was carried on in April and Way 1947, the results of which are presented in this report. The work consisted of 175 feet of drift and crosscut, bringing the total to 398 feet of underground working, as shown in figures 1 and 2. The 23-foot drift, which was the last work of the initial project, was extended 99 feet northward along the shear zone, and three crosscuts, spaced at approximately equal intervals along the drift, were driven to country rock on the hanging and foot walls of the zone.

Jan 1, 1948

By W. L. Hunter

Eleven steelmaking heats are described in this Bureau of Mines report in which acid practice was used to produce carbon steel from pre reduced iron ore pellets. Furnace slags obtained with no flux addition to the charge became quite viscous as they cooled, which precluded pressure casting from a ladle. Lime was added to the furnace charge at two levels to eight of the heats to modify slag characteristics in the furnace, and to the ladle in two heats to further modify the ladle slag cover. Selected ingots from nine heats were successfully rolled on a commercial mill to produce No. 10 reinforcing bar.

Jan 1, 1974

By Robert H. Lambeth

The Madison RARE II study area has four prospects with identified resources. These are listed in table 1 and are described in the following text. A high potential for Sillimanite exists at the Placer Creek occurrence (fig. 1, no. 7) and potential for phosphate rack in all areas underlain by the Phosphoria Formation. Some prospects exhibit minor potential for copper, lead, zinc, silver, and gold in the southern portion and very minor potential in the northern portion. Deposits in the northern end also have low potential for rare earth, asbestiform anthophyllite, or kyanite group minerals (including sillimanite).

Jan 1, 1982

By Berenice B. Mitchell

THE STATISTICAL tables in this chapter present, country by country, the mineral production of the world in 1949-50. The figures are on a mine basis, unless otherwise indicated, except for cement, coke, and steel, which are measured at the processing plant. The tables are essentially a retabulation, by countries, of the 53 commodity world tables appearing in the various chapters of this volume. For lack of comprehensive information, data for the following minerals are excluded: Andalusite, aplite, asphalt, boron, bromine, calcite (optical), calcium chloride (natural), carbon dioxide, clay, columbium (niobium), diatomite (kieselguhr), dumortierite, emery, garnet (abrasive), gem stones (other than diamonds), germanium, greensand, grindstones, helium, indium, iodine, kyanite, lithium, magnesium compounds (other than magnesite), meerschaum, mineral pigments, monazite, natural gas, natural gasoline, oil shale, olivine, perlite, pumice, quartz crystal, radium, sand and gravel, selenium, sillimanite, sodium salts (other than common salt), stone, strontium, sulfur (byproduct), tantalum, tellurium, thallium, topaz (industrial), tripoli) uranium, vermiculite, wollastonite, and zirconium. In addition, a few minor geographic areas for which no statistics are available, are also omitted from the tabulation; it is believed that no significant quantities of minerals are mined in any of these areas. The statistics in these tables were derived principally from questionnaires sent, in cooperation with the United States Department of State, to the governments of each country. Supplementary sources were United States consular reports, the Imperial Institute's Statistical Summary of the Mineral Industry of the British Commonwealth and Foreign Countries, other official publications of various countries, the United Nations Statistical Yearbook, the Year Book of the American Bureau of Metal Statistics, Minerais et Metaux, business magazines, and company reports. Where official data were not available, esti-

Jan 1, 1953

By R. L. Montgomery

Heats of solution of cerium metal and cerium (III) chloride in hydrochloric acid were measured. The standard heat of formation of the aqueous cerium (III) ion at 25° C is -166.1 ± 0.3 kcal/mole. Heats of solution of cerium (III) chloride in hydrochloric acid are consistent with the existence of a complex CeC1++ having a stability constant of 1 and a heat of complexing of 5.4 kcal/mole.

Jan 1, 1962

By Joseph W. Town

The Bureau of Mines conducted studies related to SO2 air pollution to determine attritioning rates, SO2 sorption rates, and sulfur loads that could be obtained on commercial alkalized alumina sorbent pellets. Fluidized-bed attritioning rates ranged from 0.025 pct/hr for alkalized alumina with a crushing strength of 4 kg to 0.075 pct/hr for 0.5 kg crushing strength mate¬rial. Airlift attritioning rates ranged from 0.50 pct/hr for 3 kg crushing strength alkalized alumina to about 3 pct/hr for 0.5 kg material. Attritioning rates for the commercial alkalized alumina were comparable to those obtained for sorbent pellets prepared in the Bureau of Mines laboratory. Sorption rates were related to S02 concentration in flue gas, temperature, and presence of nitrogen oxides in the gas stream. Sorption rates at 300° C were 0.35 X 10-6 gS/gp/sec (grams sulfur per gram pellet per second) in 0.045 pct so, gas, 5.1 x 10-5 gS/gp/sec in 0.34 pct SO2 gas, and 65 X 10-5 gS/gp/sec in 10 pct SO2 gas. For the 0.34 pct S02 gas, sulfur loads of 0.10 gS/gp (the projected load for regeneration) were obtained in 47 min at 130° C and in 116 min at 300° C. The presence of either NO or NO2 in the 0.34 pet S02 gas increased the SO2 sorption rates 2 to 3 times at 300° C, but had no effect at 130° C.

Jan 1, 1969

By William A. Vogely

STRIKES in the steel and copper industries adversely affected production in the minerals industry in 1959. Because of an excellent first half of the year and rapid recovery of production after the steel settlement, most statistical indicators were higher than the recession-recovery year 1958. Domestic production of metals declined by 9 percent, but nonmetals (except fuels) increased by 8 percent. Ferrous-metal mine production was down 8 percent, and base-metal mine production was off 11 percent. Employment was high during the first half of the year, but averaged lower than in 1958. Stocks continued to decline as a whole, but crude metal ore stocks actually increased. The indexes of stocks at yearend were still high as compared with 1955. Prices were firm throughout the year. A new index of average unit mine value is presented for the first time in this review; it showed a very slight decline in average mine realization for 1959. The percentage share of supply from imports increased in some commodities, due in large part to the shutdown of domestic iron, steel, and copper industries.

Jan 1, 1960

By H. A. Tucker

This Bureau of Mines investigation was conducted to determine the appropriate quantities of rare-earth methals (REM) in the form of silicides to add to an alloy steel for the purpose of increasing toughness and ductility. The work was conducted in a vacuum induction furnace with the rare-earth additions required to deoxidize and desulfurize a simulated basic oxygen furnace (BOF) vacuum-degassed steel initially containing 0.013 to 0.016 percent sulfur. The product proved to be as good or better than the best basic electric furnace steel of the same composition made by the steel industry. Twenty-three experimental heats of 5 Ni-Cr-Mo-V steel were made, cast into 50-1b ingots, and hot-worked in a press and a rolling mill to ½ inch plates which were then heat-treated to 130/150 ksi4 yield strength. Impact and tension tests showed that the addition of 0.025 to 0.100 percent, or ½ to 2 lb per ton, respectively, of rare-earth metals when compounded with silicon were appropriate for increasing toughness and ductility. These quantities resulted in retained cerium contents between 0.014 to 0.025 percent, and increased the Charpy V-notch energy absorption and the percent reduction of area significantly as compared with base heats at the same sulfur content levels. All the test heats, including those with additions of REH of as much as 4 lb/ton, had greater Charpy V-notch energy absorption values than the base composition could have developed at the starting sulfur range of 0.013-0.016 wt pct.

Jan 1, 1968