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By R. L. Grant

"Carbon dioxide has been used for extinguishing electrical fires of many kinds (1, 3, 4) 3/ and more recently has been applied to some extent in fighting coal-mine fires (5). This report is concerned with the possibility of an electric current being conducted from a live power source, such as a trolley wire, across the impinging spray of carbon dioxide gas, to a metallic discharge nozzle, and then being grounded through the body of the person holding or touching the container. Rose and. Skinner (5) have described a case in which a fall of roof coal had brought down the trolley without creating a dead shot. The current was conducted in part through the loose coal to the rail, causing ignition of the coal. The fire was successfully extinguished with carbon dioxide.Dielectric data on pure carbon dioxide gas and liquid have been reported by Quinn and Jones (2). For the gas, the dielectric constants range from 1.00971 (35°C., 10 atmospheres) to 1.3072 (70°C., 151 atmospheres); for the liquid, 1.6016 (0°C., 50 atmospheres). Compared with the dielectric constant of air (1.0006, 1 atmosphere), these data, indicate that carbon dioxide in both gaseous and liquid forms is a very poor conductor of electricity, of the same order as air. 4/"

Aug 1, 1942

By F. N. Kissell, C. H. Elder, C. M. McCulloch

The applicability of the "direct method" for determining the methane content of virgin coalbeds was tested. Preliminary results indicate that the direct method, when applied to exploration cores, can be successfully used to estimate coalbed gas content and also approximately predict the total gas emission from a prospective mine located in the coalbed at the exploration site.

Jan 1, 1973

By Edward Kline

A review and synthesis of literature pertaining to biological consequences of submarine mine-tailings disposal (STD) was conducted. STD can result in massive sea floor sediment deposition. STD may also increase suspended sediment, trace metals, and residual milling reagents in receiving waters. These perturbations, which are highly site dependent, invariably smother benthic organisms, and could potentially affect or alter fish, plankton, and benthos through acute and chronic toxicity, bioaccumulation, behavioral changes, smothering, derived secondary effects, and habitat alteration. Much of the available information concerning STD is unpublished and limited to a restricted number of sites. From this information and related research, it appears that benthic smothering is the only major consequence of a properly designed STD system. There have been cases of metal bioaccumulation due to inadequate preliminary evaluation, Also, shallow water habitat alteration has resulted from STD. Reductions in biological production are likely due to benthic smothering. The rate of ecological recovery after termination of an STD operation varies and is difficult to assess, The consequences of STD are site specific. Additional research is needed concerning possible consequences of milling reagents and the broad implications of benthic smothering. Also, methodologies are needed to allow better prediction of benthic recolonization and ecological implications of metal bioaccumulation.

Jan 1, 1994

By R. V. Ramani, R. Bhaskar

"The results .of an experimental and theoretical research study into the spatial and .temporal behavior of dust in mine airways is summarized in the paper. Experiments were performed in mine airways under both controlled and .normal operating conditions. The controlled experiments included the documentation of the concentration and deposition patterns for two types of dust under three different velocities. Real-time dust concentration data were obtained using Real-time Aerosol Monitors (RAM-1) to determine the dispersion coefficient in a mine airway. On the theoretical front, a convection diffusion model of the dust flow phenomenon in mine airways was developed considering dominant mechanisms affecting dust transport and deposition in mine airways. Mechanisms modeled include turbulent and gravitational deposition, coagulation, and dispersion.In this paper, comparative analyses of results of the controlled experiments with the predictions of the mathematical model are presented. In addition to the overall validity, the adequacy of the individual components of the model, such as deposition in the total and respirable range, and dispersion are examined in light of the experimental observations.The experimental data from controlled experiments compared more favorably with model predicted results for similar conditions as opposed to the ·comparative analysis results for in-mine experiments. Specifically, the model· predictions for an 800-meter stretch of a mine airway reveal some significant differences from the behavior noticed in the mine. The deposition was lower than that predicted by the model. Consequently, concentrations were higher than those predicted by the model. The implications of these and other findings for further investigations are discussed in the paper."

Aug 31, 1989

By E. C. Tarpley, H. M. Cooper, R. F. Abernethy

"INTRODUCTION The determination of moisture in coal is an empirical test, because the time, temperature, and equipment are specified. The essential features of the equipment, and details of the procedure are given in A.S.T.M. Designation: D271-44 5/. According to the specifications, the following features should be incorporated in the equipment used:1. Oven must have uniform temperature in all parts.2. Oven must be constructed with minimum of air space.3. Oven must have means of changing the air two to four times per minute.4. Air must be dried over sulfuric acid (sp. gr. 1.84).The analytical procedures governing most of the nation's coal purchases are those given in A.S.T.M. Standards referred to above. These standards are general and of such scope as to cover all ranks and types of coal. In cases where only the moisture is required, a faster method than the standard procedure is desired.The semi-automatic moisture tester manufactured by the Brabender Corp. has proved itself in many industrial processes where the rapid estimation of moisture is of vital importance. With the approval of A. C. Fieldner, chairman, A.S.T.M. Committee D-5, and through the courtesy of Lowell Malan, chief chemist, United Electric Coal Companies, who loaned the tester, tests were made to determine the feasibility of using this instrument to determine the moisture in coal."

Jun 1, 1948

By J. F. Barkley

During the present war emergency, under the urge of the Federal Government to store coal, the following; questions are arising n the minds of coal users: (a) Will the coal lose any of its heating value in storage? (b) Will it slack and give a smaller-size coal? (c) Will its burning characteristics change in any way? (d) Will it catch fire from spontaneous combustion? (e) What precautions should be taken when storing coal? In regard to the loss of heating value of coal in storage, tests made by the Bureau of Mines show that the loss commonly has been overestimated. Various types of storage tests were made on New River, Pocahontas, Pittsburgh Gas, and Sheridan Wyoming coals. The following is quoted from Bureau of Mines Bulletin 136, Deterioration in the Heating; Value of Coal During Storage, by H. C. Porter and F. K. Ovitz:

Jan 1, 1942

By Laurance L. Oden

Titanium-enriched smelter slag produced commercially by Quebec Iron and Titanium Corp., Sorel, Quebec, was evaluated as feed material for a process developed by the Bureau of Mines to prepare rutile. Glass-forming agents including P205, B203, and two binary mixtures were added individually to the as-received and preoxidized smelter slag, and the nonferrous tramp oxides were effectively partitioned into the resulting noncrystalline phase. Iron in the ferrous oxidation state was moderately soluble in the glass of reduced specimens but less soluble under oxidizing conditions. The solubility of iron oxide in phosphate glass exceeded the solubility of iron oxide in borate glass. Effective conversion of titanium oxide to rutile was not achieved in the high-iron commercial smelter slag, and 20 to 30 pct of the titanium remained as pseudobrookite, a mixed iron-titanium oxide.

Jan 1, 1973

By H. Kenworthy

The investigations described in this report were undertaken to demonstrate, on a laboratory scale, the possibility of recovering several million pounds of tin plus tungsten contained in stockpiled and currently rejected slags from the Longhorn tin smelter at Texas City, Tex. At the same time, it was anticipated that the treatment procedures developed might be applicable to slags from other tin-smelting operations. Results of the laboratory work show that it is possible, by pyrometallurgical means, to separate the tin and tungsten into products of intermediate grade that may be returned to the smelter circuits for further upgrading. Several methods of treatment were investigated. The methods that proved effective were: Fusion reduction, chloride volatilization, sulfide volatilization, and carbide formation. Over 90 percent of the tin and tungsten could be removed from the slat by any of these methods. Each type of treatment has advantages and disadvantages, and it could not be determined from the small-scale work which method was the more meritorious. Tungsten and (in some types of treatment) tin-bearing products were diluted by iron, the separation of which will require additional studies. Prevention of a portion of the iron from reporting with the tin or tungsten is a distinct advantage and possibility that will require inure laboratory work to develop the needed techniques for its accomplishment. Tin products from single treatments of stag ranged up to 75 percent in tin content but were more generally under 35 percent. Tungsten products were usually under 15 percent; but segregated portions could be selected, at a sacrifice in recovery, that contained up to 50 percent tungstic oxide equivalent.

Jan 1, 1957

By M. R. Geer

Traditionally, fine coal is more troublesome than the coarser sizes at every step of the coal-preparation process--screening, cleaning, dewatering, and drying. Therefore the present trend toward a higher proportion of fines in the run-of-mine product, brought about by changes in mining practice necessitated to increase productivity, has added greatly to the task of preparing coal for the market. One of the more difficult and costly problems involved is that of recovering fine solids from the washery water. These fine solids should be recovered in the interest of conservation, and they must be removed to provide recirculating water of proper quality. If there is a plant effluent, it must meet increasingly stringent requirements against stream pollution. Vacuum filtration has been used for years at a few plants to recover the extreme fines, but its additional cost discouraged general adoption until recently. Now, with growing emphasis on better solids recovery, filtration is becoming more widespread. Many coal slurries filter readily, giving high cake rates and clean filtrates. Others, however, particularly those containing either a high proportion of material finer than 200-mesh or an appreciable amount of clay, are much more difficult to filter. Many of these refractory slurries can be rendered more filterable by flocculation. A previous report of Bureau of Mines research dealing with flocculation alone was published in 1940.5/

Jan 1, 1959

By James S. Browning

The Bureau of Mines conducted laboratory batch and small-scale continuous selective flotation tests of barite-fluorspar ores from two deposits near Marion, Ky., to determine the technical feasibility of recovering commercial grade fluorspar and barite concentrates. The lignin sulfonate-sodium fluoride method of floating the fluorspar successfully produced acid-grade fluorspar concentrates. Flotation of the barite from the fluorspar tailing using petroleum sulfonate collector yielded concentrates suitable for use in compounding oil-well drilling mud. The fluorspar and barite recoveries were about 82 and 85 percent, respectively.

Jan 1, 1963

By R. L. Hopkins, H. T. Rall

A continuous method has been developed for preparing thiolacetic acid . Acetic anhydride and hydrogen sulfide are passed concurrently over an amine ion- exchange resin , under 20 - psi pressure . The thiolacetic acid , a product of the reaction , is flashed continuously from the crude reaction mixture and is purified by fractional distillation . The yield of thiolacetic acid is in excess of 80 percent based on the acetic anhydride charged . INTRODUCTION In the synthesis of reference compounds needed in the identification of sulfur compounds in petroleum , thiolacetic acid has become an important reagent because of its use in the synthesis of thiols by addition to appropriate olefins : R - CH = CH₂ + CH3 - COSH R- CH2 - CH2 - S - COCH R - CH2 - CH₂ - SH + CH3COONa NaOH (1 ) The commonly used procedures for its preparation , as described by Clark and Hartman (1 )4 and by Ellingboe (2 ) , are based on the batchwise reaction of acetic anhydride with hydrogen sulfide :

Jan 1, 1964

By J. D. Tolman

In view of present interest in a revival of gold mining enterprises, papers dealing with the development of small gold properties are apropos. The present paper deals with the operation of a small gold property in the exploration and development stage, mining and milling 25 tons of ore daily, and indicates what may he expected in the way of mining costs under northern climatic conditions, by practicing rigid economy, at a property where disproportionate overhead costs are unavoidable bacause of the small rate of production. The output of this prospect is treated in a small amalgamation plant which has been described in a previous circular.. HISTORY Prospecting in the district was begun in 1909, and by 1911 the adjoining mines, Hollinger and McIntyre, were in operation. Actual work was begun on the Rochester claim in July, 1922, and carried on through 1924. The property was closed until 1928 when the present company took it over, together with the other holdings of the Canadel Mining Co. A small mill was started as a pilot plant on March 24, 1929, and is still in operation.

Jan 1, 1931

By M. J. Lempel

A theoretical study of the heat-transfer characteristics of a dilute gas-solids mixture in an externally heated tube is reported. Detailed equations are developed describing the system, and a numerical method is presented to solve the equations using a digital computer. The methods are applied to a system containing fine coal particles entrained in hydrogen, flowing through a hot tube. Heat-transfer coefficients and several other physical constants are evaluated in detail.

Jan 1, 1967

By W. D. Ludemann, E. A. Loria, E. A. Rowe

The isothermal recrystallization of electrorefined vanadium has been studied as a function of annealing time , temperature , and prior deformation . Specimens were cold- rolled from 30- to 75 - percent reduction in thickness , then annealed from 700 ° to 1,200 ° C at time periods ranging from 1 minute to 96 hours . The course of recrystallization was followed by means of hardness , metallographic , and X- ray techniques , and a recrystallization diagram was constructed . Interpretation of the data indicated that there was around 50- percent softening due to recovery ( first stage of softening) before recrystallization began . The defining of recrystallization limits with respect to the amount of deformation was precisely established for electrorefined vanadium . More than 30- percent reduction was necessary for recrystallization to occur at 850 ° C. With 60- percent reduction , it was initiated at 750 ° C and completed at 950° C. The activation energy for recrystallization , as derived from the data , was 95,300 cal per mole for 60 - percent reduction and annealing at 750 ° to 900 ° C. Recrystallization by the mechanism of nucleation and growth was the principal process during the second stage of softening . minor part of the second stage of softening took place as strain- induced boundary migration , which was observed in specimens reduced 30 percent , bent in L- shape , and annealed at 950 ° C. Grain size decreased significantly only with the largest reductions and annealing between 750 ° and 950 ° C. Grain growth was expressed by the empirical relation D = KKtt"" ,, the exponent being the same at 60- percent reduction and annealing from 750 ° to 900 ° C. Accordingly , the activation energy for grain growth was 75,000 cal per mole .

Jan 1, 1964

By Kenneth M. Earl

In its investigation of deposits of strategic minerals, the Bureau of Mines did some development drilling at the New Galena Deposit in an endeavor to find an additional source of supply of lead. In Bucks County, lead and zinc minerals have been found in shales over a largo area west and northwest of Doylestown. Considerable mining has been done in the vicinity of New Galena on the North Branch of Noshaminy Creek, 3 miles northwest of Doylestown. It has not been possible to obtain a satisfactory history of the New Galena mine, as there is much disagreement in statements. Most of the mining was done in open pits. Two shafts were sunk to shallow depth; one of these became part of the main pit' which is 256 foot long, 50 to 75 feet wide, and 20 to 44 feet deep. Small pits 8 to 10 foot square wore sunk on the ore zone, which extends some 1450 feet to the southwest. The rock containing the minerals is either black or gray shale. The gray material closely resembles limestone. The following minerals have been reported from the mine: quartz, ankerite, calcite, galena, sphalerite, pyrite, chalcopyrite, and bornite. Some of the galena has yielded 10 to 15 ounces of silver and 10 cents in gold per ton. The average grade of the ore as mined is not known. To investigate the downward extension of the ore shoot, the Bureau drilled two holes aggregating 373.9 feet, No additional ore was developed by this work.

Jan 1, 1950

By STUART R. BRINKLEY, Ruth F. Brinkley

This same phonomonon of diffraction may be transposed into the X-ray domain. All that is necessary is to reduco, in the samo proportion, the wavo length of the light and the diameter of the particlo; thus, with radi- ations whose wave length is of the ordog of angstroms, the dimensions of the active particles go from 10 to 100 A that 18, the dimensions of col- loidal particlos. The evidence of this fact is shown by the following experimental schomo (fig. 1a): A narrow beam of X-rays passes through a thin layer of a modium containing micelles; the photographic film is placed a few centimeters behind the sample, and a small absorbing screen stops the direct beam in order to prevent its fogging the film. The intersect of the direct beam is surrounded by a narrow spot whose blackness decreases with the distance from the center. We will call this the spot of central diffusion (fig. 1b). The phenomenon, in spite of its relatively reat intensity, has been observed only by a few authors, who have simply given a qualitative description without attempting any quantitative de- ductions. This is due to the fact that observation of this phenonenon is not possible with the apparatus generally used to obtain X-ray diagrams, because the parasite foggings in the vicinity of the incident beam are sufficiently important to hide those produced by the sample. With the monochromator, however, used by us to obtain Debye-Sherer diagrams, this parasitic diffusion can be totally suppressed. In this way our attention was again directed to the spot of central diffraction, and we were led to make a detailed quaititative study of it.. then several papers have been published on this subject. Hosemann, using methods of calculation outlined by us, has extended them to the special case of fibrous substances, Kratky, on the other hand, starts from an entirely different theoretical point of view; ho examines the case, not of scattered particles, but of closely packed particles. 6ince We will now describe the experimental methods, summarize the calcu- lations needed in the elaboration of diagrams, and finally review the first results obtained in the vast domain of these new physical-chomical studies.

Dec 1, 1946

By N. S. Dalal, X. Shi, P. M. Gannett

"Chromates are known to induce tumors (1, 2), mutations (3), and DNA damage (4-6). However, the underlying biochemical mechanism(s) is (are) not fully understood (6). Recent studies have indicated that hydroxyl (·OH) radical may play an important role (7-11). The mechanistic studies of Cr(Vl)-related ·OH radical generation in biochemical systems have shown the reaction of a Cr(V) species with hydrogen peroxide (H20 2 } through a Fenton-like mechanism to be one of the important steps (9-11): Cr(V) + H20 2 - Cr(VI) + ·OH + OH-. (1)In biological systems the Cr(V) species are generated via the reduction of Cr(VI) by a variety of components, such as microsomes (12), mitochondria (13), mitochondrial electron transfer complexes (14), and at least three flavoenzymes (glutathione reductase (GSSG-R),3 lipoyl dehydrogenase, and ferredoxin-NADP+ oxidoreductase) (9, 15, 16). In the case of flavoenzymes, Cr(V) formation is accompanied by the reduction of molecular oxygen ( 0 2 ) to H20 2 • The Cr(V) species then reduces H20 2 to generate •OH radicals and Cr(VI) (16).To understarid the mechanism by which Cr(V}-generated ·OH radicals cause cytotoxicity, Aiyar et al. (8) investigated the reaction of Cr(VI) and H20 2 to generate ·OH radical and its reaction with 2'-deoxyguanine (dG) to form 8-hydroxy-2'-deoxyguanine (8-0HdG}:"

Mar 1, 1992

New Continuous Personal Dust Monitors (CPDM) submitted to NIOSH for approval to sample coal mine dust must accurately measure respirable coal mine dust in mine environments. There are two steps in the process which may be done in any order. The manufacturer is required to submit the results of a comparative underground coal mine dust sampling study, where the candidate CPDM is compared to an approved coal mine dust sampling device (currently the Coal Mine Dust Personal Sampling Unit (CMDPSU)). This testing shall follow the guidelines outlined below and shall demonstrate through weighted regression analysis that the mean coefficient of variation with bias correction is equal to or less than 12.8%. The other step involves laboratory testing to determine the electronic and environmental stability. This testing must be conducted by a private, commercial, academic or other laboratory approved by NIOSH.

Jan 1, 2009

By F. P. Haver

The Federal Bureau of Mines investigated aqueous electrolysis as a means for reducing lead chloride prepared by ferric chloride leaching of galena concentrate: NaC1 PbS + 2FeC13 ? PbC12 + 2FeC12 + S°. During electrolysis, metal was produced from solid lead chloride in contact with the cathode rather than from lead in solution. Relatively high current densities--up to 300 amp/ft2--were possible when operating in this way. A very simple cell, having a horizontal lead cathode at the bottom and a vertical graphite anode at the top, was employed. Lead chloride crystals, covering the cathode, were converted to metal powder during electrolysis, and chlorine gas or FeCls was produced at the anode, depending on the electrolyte composition. Electrolytes tried included aqueous solutions of HCI, NaCl, NH4Cl, and FeC12-NaC1. Optimum results (96-pct current efficiency, 0.23 kwhr/lb Pb) were obtained with 20 pct HC1 at 25° C, using a current density of 15 amp/ft2 and an electrode spacing of 1 inch. When the current density was increased, the energy requirement increased also but only to 0.41 kwhr/lb at 150 amp/fr3 and 0.58 kwhr/lb at 300 amp/ft2.

Jan 1, 1978

By Thomas L. McVay

Laboratory batch and pilot plant flotation tests were made to determine the feasibility of recovering commercial grade kyanite from a quartzite- kyanite rock from the Graves Mountain, Ga., deposit. Best results in laboratory and continuous tests were obtained using sodium carbonate for pH control, citric acid for quartz depression, and oleic acid as the kyanite collector. Over 80 percent of the kyanite was recovered in a concentrate analyzing 56.8 percent Al203 and 3.8 percent hydrochloric acid soluble Fe203. Subsequent treatment of the flotation concentrate by magnetic separation reduced the acid soluble Fe2O3 to 0.6 percent and increased the alumina content to 59.2 percent. Acid leaching of the concentrate gave a product analyzing 59.7 percent Al203 and about 0.1 percent Fe203. As a result of the beneficiation research, a commercial kyanite flotation plant was completed in September 1962 by private industry.

Jan 1, 1963