Search Documents

By John H. Johnson

This report covers research which is directed toward the measurement and control of underground mine diesel emissions. The report consists of three separate reports presented as Sections 1, 2, and 3. Section 1 "Emissions Measurement Apparatus" (EMA 1) discusses the selection and evaluation of instruments and procedures to be used as part of a diesel tailpipe emissions dilution and measurement apparatus. The instruments selected for gaseous pollutants are the Energetics Science Inc.* E.S.I.) 2000 for CO, the E.S.I. 7000 for NO and N02, and the Fuji ZFP5 for C02. Particulate matter is presently measured with the Celesco 1013 Smoke Opacity Meter. The raw exhaust concentration of one of these constituents is used Lo calculate the dilution ratio. Either a modified high range E.S.I. 2000 CO instrument or a Daco Products Cobra C02 instrument can be used, but neither is totally satisfactory. The study also indicated that it may he possible to increase the sample collection time from 15 seconds to the total 30 seconds over which the engine can be loaded without increasing the probability of damaging the vehicle hydraulic systems. Section 2 "The Effect of Fuels, Catalysts and a Filter Trap on Drift Pollutant Concentrations" discusses research in the Mine Air Quality Laboratory. A Wagner ST5D LHD with a Deutz F8L714 engine was used to compare three exhaust aftertreatment devices and a muffler-only system. The effect of these four systems on CO, C02, NO and N02 and on total, soluble, sulfate, and solid particulate matter was measured in the drift and on the LHD. The filter trap successfully reduced particulate matter for both fuels without significantly increasing the concentrations of any of the other constituents. The PTX catalyst was effective in reducing CO, and soluble particulate, but significantly increased N02 and solid and sulfate particulate matter. The Oxy Cat catalyst tested didn't seem to he working on the gases, and it significantly increased sulfate, soluble arid solid particulate concentrations. Section 3 "Diesel/Coal Particulate Matter Characterization by Laser Raman Spectroscopy" covers basic research on a method for determining the percentage by weight of diesel particulate on a filter containing a diesel-coal mixture. Signal-averaged Raman spectra provide the necessary precision. The method developed is non-destructive and uses as-received filters requiring no sample manipulation. Particulate with diesel contents in the range of 10 to 50% by weight have been analyzed with accuracies better than 6%t of the mean value. A number of samples containing diesel-coal mixtures were characterized by the procedures developed and the results are analyzed in light of various spectral and other system variables including coal rank and form and diesel engine operating conditions.

Jan 1, 1982

By L. B. Berger

The Haldane gas-analysis apparatus used by the Bureau of Mines is patterned after the device developed by Haldane 4/ and differs from it only in structural modifications that have been added to facilitate operation and simplify construction. The apparatus was developed to permit determination of carbon dioxide, combustible gases, and oxygen with a degree of accuracy not attainable with apparatus of the types ordinarily used for the analysis of fuel gases, flue gases, and similar mixtures. The Haldane apparatus is used by the Bureau of Mines chiefly in the analysis of air samples collected in coal and metal mines and other underground workings and is applied also in the analysis of many other types of gas mixtures when accurate determination of certain constituents is desired.

Jan 1, 1938

By Manuel Gomez, V. F. Parry, John B. Goodman

"INTRODUCTION The need for an accurate and precise analytical method for determining moisture in coals of high water content has been recognized by the coal industry as well as the fuel technologist. Interest in this particular phase of coal technology extends back to the early work of German investigators on the brown coals of Central Europe. Studies by these workers led to the establishment of a direct immiscible liquid-distillation method 4/ as the accepted moisture determining technique in European laboratories. Direct moisture determining methods, those methods that utilize various techniques to drive off the water from a given sample of coal and either collect the water in a calibrated receiver or selectively trap the water driven off in a suitable absorber, have found little favor in the United States. They have been treated merely as research tools.5/ The problem of moisture determination in low-rank coals of the United States has not been given much consideration because such coals contribute only about 2 percent of the total United States production. With renewed activity in low-temperature carbonization and with the growth of interest in coal and coal-tar hydrogenation, the American coals of lover rank containing 20 to 40 percent bed moisture will be subjected to extensive investigation. If the low-rank coals of the United States are to be accurately appraised, the need for qualitative and quantitative analytical proceeded becomes more pronounced. These coals, especially the lignites of Texas and North Dakota, are highly susceptible to oxidation, a process that proceeds to a greater or less extort when low-rank, high-moisture coals are treated by oven-drying methods. The extent of this atmospheric oxidation has been described and evaluated by numerous workers. 7/In many respects, the problem of moisture determination in low-rank coals, those found in the United States and the high-moisture coals of Central Europe, is similar. Conversely, the problem of moisture determination assumes a different aspect when the coals of the eastern and the middle-west sections of the United States are considered. Present methods, the loss in weight gravimetic-type procedures, serve adequately to test these low-moisture coals. The determination of moisture in coals containing 20 to 40 percent water should be approached from a direct method rather than from an indirect gravimetic-type procedure because of the oxidative tendencies of these coals and the demonstratrated inability of a loss-in-weight technique to remove all the water in a given sample of coal."

May 1, 1953

By Robert M. Doerr

The research objective was to determine the effect of vanadium alloy additions on the oxidation behavior of cobalt-nickel Alloys. Eighteen alloys were reacted with 0 2 at 0.5 arm and 1,351°, 1,389°, and 1,429° K. The alloy compositions consisted of Co-Ni master alloys (0, 22, 50, 70, 91, and 100 wt pct Ni) with V additions of 0, 0.9, and 2.7 wt pct. Large early deviations from, or changes in, the parabolic rate constant were encountered, but the reaction rate in most cases declined approximately in accordance with the parabolic rate law. Relatively, the vanadium degraded the oxidation resistance most at the highest nickel contents. In some cases, melting of the oxide was inferred from microscopic evidence and X-ray diffraction measurements disclosed the presence of low-melting vanadates.

Jan 1, 1970

By Tyler Blake

This report describes a study designed to evaluate a pro-posed modification in the cap lamp battery cord intented to reduce the incidence of snagging and catching of the cord. A three phase evaluation was performed comparing a prototype with the standard, currently available cord. First, a ?pull test? equipment was run. The second evaluation was a body conformity study. The third evaluation involved subjects performing common tasks in a low seam coal mine simulator. The results of these evaluations clearly demonstrated significant safety advantages of incorporating coiled cord into the design of the cap cord. The coil cord presented less of a snagging hazard, allowed the wearer more time to respond to a snag, and transmitted lower levels of force to the helmet when snagged. The research team recommended that cap lamp cords be commercially developed which incorporate coiled cord at the battery and helmet.

Jan 1, 1980

By R. E. Simpson

Beginning in 1972, fully grouted resin bolts were used in underground mines. An estimated 20 million resin bolts will be installed in 1980 owing to their apparent support improvement in most roof-bolt applications. Inorganic cements were tested to replace the resin at a lower cost while retaining the advantages of a grouted bolt. Although other inorganic materials were considered, all but portland and gypsum cements were rejected for reasons of availability, performance, or cost. Portland and gypsum-type cements were tested by the Bureau of Mines to select a fast-hardening, low-cost material that would anchor a roof bolt adequately to meet safety standards. An alpha-gypsum cement, accelerated with potassium sulfate, was selected as the best material because it had adequate pull strength at a desired set time of less than 5 minutes and was readily available.

Jan 1, 1980

By R. E. Chaney

This report summarizes the research on the Strategic and Critical Materials Program tasks conducted at the Idaho National Engineering Laboratory (INEL) between May 1984 and April 1985. The work is divided into two areas: 1. Production Technologies - Tasks directed at developing advanced extraction technologies ? Biologically-Assisted Minerals Processing ? Metal/Gas Reactions and Thermal Plasmas ? Dehydration of Aluminum Chloride Hexahydrate (completed). 2. Conservation/Substitution Technologies - Tasks directed toward establishing the technical processing base which will permit the use of advanced materials ? Joining of Rapidly Solidified Alloys (RSA) ? Joining of Silicon Nitride-Based Ceramics ? Nondestructive Evaluation of Ceramic and RSA Joints and Materials ? Substitute Catalytic Materials for Platinum.

Jan 1, 1985

By C. W. Davie

"This paper is the second of a series of progress reports4 on a study of the hydrometallurgy of manganese which is being conducted in an endeavor to make possible utilization of the large deposits of low-grade domestic manganese ores that occur in several States.There are at least four processes in which a knowledge of the action of SO2 gas on manganese oxides at elevated temperatures may prove of value.One of these involves dissolution of manganese from ores. The Bureau of Mines has investigated the hydrometallurgy of manganese by a process in which SO2 gas, a waste product at many smelters, is passed into water to form a solvent for manganese. Although several manganese minerals were readily dissolved, rhodochrosite (MnCO3) was attacked but superficially.5 Recent experiments have shown that a roast at 650 to 9000 C. converts the manganese of rhodochrosite to a form that is quickly dissolved by a weak SO2 solution.6 Introduction of smelter gases containing much as 5 per cent SO2 during such a roast would not add much to the cost of the operation, and might result in the formation of considerable water-soluble manganese sulpate.Another case involves a subsequent step in the hydrometallurgical process, namely, the formation of oxides of manganese with simultaneous evolution of SO2 by the heating of the MnSO4 produced by evaporating its solution.A third has to do with the roasting of zinc sulphide ores containing manganese as a preliminary to leaching. During purification of the solutions to be used for the electrolytic deposition of zinc the iron must be oxidized to make possible its removal. Manganese dioxide has been used for this purpose,7 and since manganese compounds are present in some zinc concentrates,8 it is of interest to learn what happens to the manganese in a zinc sulphide or on roasting, and what portion of the manganese in the roasted product might be available for oxidation."

Oct 1, 1930

By R. S. Dean

"INTRODUCTION The metallurgical research program of the Bureau of Mines has been somewhat disorganized, but generally advanced by the increased activities of the war period. The present report is for the purpose of summarizing the work of the Bureau in this field for the past 15 years and indicating its future plan.Fifteen years ago the Bureau turned from its pioneer work on the physical chemistry of steelmaking to an emphasis on raking a pure steel synthetically, rather than by refining, that is, :producing each of the steel 'constituents in the pure state and combining them by simple melting. Such a procedure permits the use of less high-grade ores, not only of iron, but of the ferroalloy metals, such as manganese and chromium,This program has led to extensive work on iron-ore concentration, agglomeration, reducibility of ores and agglomerates, direct reduction of iron ores and concentrates by a wide variety of processes; special refining processes for iron, the production of pure mangenese, chromium, and cobalt from low-grade ores by electrolytic processes, the production of ferrochromium, ferronickel, and ferronickel-cobalt from low-grade domestic ores, and the development of many special alloys to effectively use the new products.The status of the work in each of these fields and the future program of work, together with a bibliography of papers and patents by the Bureau staff on each of these subjects, are given."

Jul 1, 1946

By Kenneth O. Bayard, John D. Sullivan

"This repot continues the series of papers being prepared at the Southwest Experiment Station of the Bureau of Mines in cooperation with the department of mining and metallurgy, University of Arizona, on factors involved in the leaching of ores. A list of previous publications is given in the bibliography at the end of this paper.Four factors are essential to the leaching of any copper-bearing ore: (1) A solution that will attack the copper minerals must get into the body of the ore particles; (2) the copper minerals must be dissolved by the solution; (3) the solution containing the dissolved copper must find its way out of the voids of the rocks into the main solution; and (4) the copper in solution must be recovered by some means of precipitation.This paper considers the third step -- the extraction of the water-soluble copper. From leached ores. The usual commercial practice in leaching copper ores consists of: (1) Crushing the ore to pass through a screen with approximately one-quarter or one-third inch openings; (2) charging the crushed ore into a fat; (3) adding, usually by upward percolation, a solution that will attack the copper minerals; and (4) washing the copper-laden solutions out of the ore with solutions weaker in copper than the pregnant solution, and finally with water. A countercurrent system of leaching and washing is usually employed. In some plants the solutions are circulated during leaching and washing, and in others they are not. In some plants the wash solutions are added by upward percolation, while at Chuquicamata the so-called ""piston-displacement"" method of washing is employed.The following condensed resume of the leaching cycle of the plant of the Inspiration Consolidated Copper Co. is given to present to the reader a picture of the steps involved in a typical leaching cycle. This plant was recently described in detail.4 The ore, crushed to pass openings 11/2 inches in diameter, passes over a screen with ¼-inch openings. The undersize from the screen goes to a Dorr howl classifier that removes the primary slime from the circuit. The overflow from the classifier is treated in a slime-leaching plant. The oversize of the ¼-inch screen passes through rolls, where it is crushed to pass a 3/8-inchscreen. The undersize from the 3/8-inch screen join with the coarse material from the classifier, and the combined products become the feed to the leaching vats. There are 13 concrete lead-lined leaching vats. The complete leaching cycle is 13 days. Eight tanks are under acid-iron content at all times; three are being washed, one tank is being filled, and the one is being excavated. The electrolyzed solution from the tank house, to which amount of new acid has been added, is put on the oldest tank of ore under need This solution travels from tank to tank and finally emerges from the newest ore"

Apr 1, 1931

By W. L. Brien, O&apos

Molybdenum alloys with good strength properties at elevated temperatures were produced by the powder metallurgical internal oxidation method previously applied to tungsten and known as oxyreaction strengthening. Commercial molybdenum powders were blended with 0 to 10 pet of a reactive powder, ZrMo2. The effects of composition, blending procedure, and sintering conditions on strength properties at elevated temperatures were studied. Strengthening was attributed to zirconium in solid solution with molybdenum and to the presence of submicrometer particles of Zr02. Several alloys had tensile strength and stress-rupture properties com-parable with those of the best commercial alloys. The maximum tensile strengths obtained were 92 kpsi at 1,200° C and 53 kpsi at 1,316° C. The maximum stress-rupture life at 30 kpsi and 1,200° C was 145 hours.

Jan 1, 1974

By S. H. Lorain

Mechanized dirt-moving equipment has greatly increased the scope of prospect trenching by lowering the costs and increasing the speed of such work. Where the soil covering was more than 3 or 4 feet deep, operators were quickly discouraged and abandoned surface exploration in favor of shaft sinking, drifting, or diamond drilling; wildcat trenching was seldom undertaken, even where the soil covering was thin. Although power shovels, trench diggers, and draglines are useful under special conditions, caterpillar-mounted angledozers will usually do the same type of work and have a far wider range of adaptability. They are therefore incomparably the most generally useful equipment for the purpose. Since 199 the Bureau of Mines has been engaged in a widespread search for minerals useful to the war program; this work required a great deal of pioneer exploration in areas where known outcrops were marginal or subcommercial by pre-war standards. Engineers in charge of field operations were quick to perceive the applicability of mechanized trenching on a fairly large scale, particularly in the Northwestern States, where completely exposed vein-outcrops are rare. Probably no other organization to date has done a comparable amount of angledozer prospect trenching under such a wide range of conditions. The following comments and accompanying cost tables are based on work performed chiefly in Idaho, under a variety of physical and climatic conditions. The most important applications of the angledozer for such work may be described under three heads:

Jan 1, 1944

This study estimates costs of producing bituminous coal and lignite by strip-mining methods in 12 hypothetical mines. Basic costs are developed by geographic area, rank of coal, and output capacity. Seam thickness and depth and type of overburden are considered typical for the area in which the hypothetical mine would be located. The cost analyses are based on the use of new equipment, the prevailing union wage scales, and the payment of all miscellaneous costs including royalties, contributions to the miners' welfare fund, and license and permit fees. All model mines are considered to have a life span of 20 years. Capital costs of bituminous strip mines with a capacity of 1 million tons per year range from $12.7 million in the Appalachian region to $16.0 million in the Interior province. The corresponding selling price, assuming a discounted cash flow return of 12 percent on investment, is $5.40 and $6.95 per ton, respectively. For bituminous coal strip mines producing 3 million tons annually, a capital investment of $24.9 million will render a selling price of, $3.46 per ton in the Interior province, whereas a similar mine in the Appalachian region requires a capital investment of $28.0 million to produce coal selling for $4.01 per ton. Subbituminous strip mines of 5 million tons of output per year range in capital costs from $28.7 million in the Southwest to $13.9 million in Wyoming and Montana. Coal produced in the Southwest would sell for $3.03 per ton, while coal from Wyoming and Montana would sell for $1.83 and $1.64 per ton, respectively. The capital costs for the strip mining of lignite range from $6.4 million for an output capacity of 1 million tons annually to $20.7 million for an annual capacity of 5 million tons. The corresponding selling prices of $3.01 and $2.12 per ton, respectively, Indicate the advantages of a large-capacity strip mine.

Jan 1, 1972

By Robert D. Perry

This report describes methods of reclaiming abandoned or inactive tailings ponds and dams. The investigated sites were selected tailings deposits adjacent to metal mines in the southwestern United States and the Pacific Northwest. The basic data developed for each site consisted of the following: a review of existing literature: a site visit that included sampling of the tailings and surrounding materials; laboratory and engineering studies; and development of reclamation plans. Laboratory tests determined the gold and silver content of each tailings deposit and the chemistry of the tailings and surrounding materials. Reclamation plans that include approximate costs were developed for five tailings deposit sites. These ranged in size from 52,000 to 103,000,000 tons. Our conclusions on the remining potential of each site are based on the tailings assay and other technical data. This study concludes that remining as a reclamation tool is feasible at certain sites. Included in this report is a remining program as part of the overall reclamation plan for two sites. Our preliminary results indicate that remining as a reclamation tool is feasible for only one of them.

Jan 1, 1981

By Michael Hamilton

Mineral resources have been identified at seven properties in the, Middle Fork Judith study area (fig. 1, and table 1). Commodities consist of silver, gold, copper, lead, zinc, and marble. Eleven properties (fig. 1 and table 2) have potential for discovery of silver, copper, lead, zinc, or sapphire resources. Of principle interest are the mineral deposits within contact zones between the Yogo intrusive complex and the surrounding Paleozoic sedimentary rocks. Contact alteration zones along the southern slopes of Yogo Peak have been prospected in a 2- to 3-mi (3.2-to 4.8 -km) long belt within the study area.

Jan 1, 1982

By G. T. Fisher

The material requirements of carbide cutting tools for machining steel and cast iron are dependent on WC bonded with Co, with additions of TaCand TiC. The Bureau of Mines is conducting research to devise substi-tute materials, based on Ni-alloy-bonded TiC, for C-5-grade cutting tool applications. This substitution would result in less dependence on foreign sources for Co, Ta, and W, and use of lower cost materials. In this preliminary study, the Bureau investigated the effects of composition and processing variables on the transverse rupture strength and hardness of Ni-alloy-bonded TiC to identify compositions that exhibit promising mechanical properties. Further systematic modification of these compositions by soild-solution strengthening additions would subsequently be evaluated to obtain cutting tool materials with requisite properties and performance for C-5 applications. Compositions for evaluation were prepared by a powder metallurgy method of cold-pressing and liquid-phase sintering. Complementary analysis of compositions included chemical analysis, X-ray diffraction, energy-dispersive X-ray spectro-scopy, and density measurements. Based on results of this investigation, promising compositions were determined to be 59.37TiC-25Ni-5Mo-lO.63Mo2C, 59.68TiC-25Ni-3.33Mo-1.77Mo2C-6.67W-3.55WC, and 59.35TiC-25Ni-l.67Mo-3.54Mo2C-3.33W-7.1WC.

Jan 1, 1987

By Cliff McCartney, Michael A. Trevits

The National Institute for Occupational Safety and Health (NIOSH) is conducting a program of research to evaluate and improve remote mine seal construction technology for mine fire control and suppression. The main focus of this work is to develop reliable technology that will remotely seal a mine opening from floor-to-roof and rib-to-rib. NIOSH, in partnership with Strata Mine Services Inc.1, is evaluating the capability of a two-component phenolic foam-based product, called Rocsil®1, that is intended for cavity filling, air and gas sealing, and consolidation of highly fractured strata. Rocsil® can be rapidly applied, has a quick cure time, a high expansion rate, good compressive resistance and excellent anti-static properties. When the resin and catalyst are mixed, an immediate foaming reaction occurs followed by rapid expansion up to 30 times the original volume. By virtue of its fire-resistance properties, Rocsil® foam has application for sealing underground mine areas undergoing heating from spontaneous combustion and it could be useful for remote mine seal construction to aid in mine fire control and suppression. This paper presents an overview of remote mine sealing technology, introduces the use of Rocsil® foam for remote mine seal installations, offers a case study of the use of this rigid foam material to remotely construct a temporary in-mine seal and discusses technology improvements. Disclaimer: The findings and conclusions in this report are those of the authors and do not necessarily represent the views of NIOSH.

By Rudolf E. Greuer

The existing computer programs for the simulation of ventilation systems under normal ventilation conditions are reviewed and a suitable program for including the influence of mine fires is selected. New program parts are written for the consideration of methane productions in coal mines, heat and gas productions of mine fires, temperature and air composition changes in ventilation systems, and the ventilation forces resulting from the latter. Other program parts are provided for the detection of danger zones and reversed air currents and for the inclusion of recirculated air currents in the network analysis. Existing program and new program parts are combined. The resulting new program can be used for a multitude of assignments. It is designed for the practical ventilation engineer and should be applicable to all types of ventilation emergency plans, in particular mine fire plans. The organization of the program and its mathematical basis are described. A FORTRAN IV listing and several flow diagrams are included. Eight executed examples are discussed, input and output for these examples explained. Storage requirements and execution times are estimated.

Jan 1, 2011

By B. J. Moore

This publication contains analyses and related source data for 675 natural gas samples from wells and pipelines in 24 States and 5 foreign countries. The samples obtained and analyzed during calendar year 1980 are included in tables 1-4. Those samples included in tables 5-7 were collected during the years 1960 through 1979. However, permission to publish the analyses of those samples was not given until the past year when the operators were again contacted to seek release of the information. All of these samples were collected as a part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted in the United States by the Bureau of Mines since 1917. In late 1965, the survey was expanded to include foreign gasfields. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4862 and 576. The results of the investigation of the occurrences of helium are published annually to make the information available as soon as possible to the gas industry and the general public. Twenty-two previous publications have presented the results of 12,152 gas analyses made prior to 1980. The first three, Bulletins 486,' 576,5 and 617,6 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1980. The other

Jan 1, 1981

By F. M. Goodwin, John Campbell, G. W. Jones

"INTRODUCTION In cooperation with the Boston Edison Co. and the Boston Consolidated Gas Co. of Boston, Mass., a survey has been conducted continuously since 1929 by the Bureau of Mines to determine the general hazards of combustible gases and vapors in manholes of the Boston Edison Co. The New England Telephone & Telegraph Co. also has cooperated in the investigation, and tests have been made in its manholes from May 1, 1933, to October 15, 1937. Yearly reports. 6/ on the results obtained since the beginning of the survey have been published.The methods and procedure of conducting the survey in 1937 were the same as heretofore."

Jan 1, 1939