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By Robins R. G

The dissolution of metallic copper powder in aqueous solutions of cupric sulphate under the influence of ethylene gas was investigated. The dissolution reaction stoichiometry obtained was: Cue+(aq) + Cu(s) + 2C2H4(g) = 2(CuC2H4)+(aq) The rate of formation of the copper (I)-ethylene complex in the above reaction was studied in a laboratory autoclave and the effect pH, temperature, ethylene partial pressure and initial concentration on the dissolution rate was measured experimentally and expressed theoretically in terms of several simple conceptual kinetic models. The results led to the selection of optimum conditions for the reaction and the suggestion of an "ion-molecule reaction" mechanism to explain the very low activation energies for the reaction system. The area of application of this reaction lies in the direction of refining impure copper such as cement copper. Several experiments were performed in which an acidified solution of cupric sulphate under ethylene pressure was used to dissolve copper from the cement copper powder in the form of the copper (I)-ethylene complex, followed by the release of gas pressure to disproportionate the complex and precipitate a purer metallic copper.

Jan 1, 1987

We are all no doubt aware that with today's high costs it is more important than ever to get the maximum possible return on capital invested in the mining industry. Screening is an important and often costly process in the size classification of industrial minerals and for this reason alone it is essential for both managers and operators to fully understand what type of screening equipment is best suited for a particular application and why. The advent of elastic materials such as rubber and polyurethane have added a new dimension to the process of screening. It is important to understand why the physical properties of these materials can be of benefit in the screening process, and recognise which type of screening applications best take advantage of these orooerties.

Jan 1, 1984

By Locke CA

Geophysical signatures of the Taranaki and Tongariro volcanoes reflect similarities in their age, composition and hydrothermal histories, but also reflect differences in host rock settings and edifice evolution. The Taranaki volcanoes have strong positive gravity anomalies showing that their edifices largely consist of dense andesite which reflects substantial lava production or dyke injection during construction and that large sub-edifice dykelstock complexes occur. In contrast, the Tongariro volcanoes have strong negative gravity anomalies indicating low density edifices of volcaniclastic material; no sub-edifice intrusions can be identified, probably because of the lack of density contrast with host basement rocks. Strong positive magnetic anomalies over the younger cones can mainly be attributed to near-surface andesite lavas or dykes whereas subdued magnetic effects are associated with hydrothermally altered zones within both edifices and sub-edifice intrusions.

Jan 1, 1995

The far reaching consequences of designing pillars for coal mines, while retaining concern for safety and economics, are cause for the search for refinement of the existing engineering methods to continue. Coal pillars, while having various functions within the overall mine plan, are the basic structural elements that assure the stability of a mine. Reliable coal pillar design methods take into account criteria which the pillars should meet in specific applications. These applications include typical mining situations such as the partial extraction room and pillar method with and without subsidence considerations, high extraction rate room and pillar, longwall mining chain pillars, and barrier pillars. However coal pillars are onlyu one element of a three element roof-pillar-floor system, weakest element of which system usually determines the stability of the excavations; however, the mining engineer can ony change dimensions of a pillar, properties of the surrounding strata remain beyond his control. The state of the art approach in pillar design places emphasis on recent developments in research. A widely encountered problem in certain coal fields is where pillars are underlain by weak floor strata. The resultant pillar design constantly maintains the perspective of the reliability of the design.

Jan 1, 1991

A non-contacting under-belt capacitance and gamma-ray backscatter technique has been developed for the on-line measurement of moisture in coal. In this technique, moisture was correlated with radio frequency susceptance and conductance determined using an under-belt capacitance sensor in which a fringing electric field Interrogates a layer of coal on the conveyor belt directly above the sensor. To compensate for variations in the density and thickness of the coal layer, an under-belt gamma-ray backscatter gauge was used to measure an equivalent volume of coal.A plant trial of the technique was conducted at Stockton Borehole Colliery, SW Australia, where the gauges were installed on the coking coal product conveyor. Product moistures, in the range 7 - 14%, were determined with r.m.s errors of 0.50 and 0.25 wt% using on-belt and static off-belt gauges, respectively. The difference in the on-belt and off-belt gauge measurement accuracy was attributed to sampling errors in the calibration of the onbelt gauge.

Jan 1, 1989

By Tran T

The kinetics of cementation of silver chloro-complexes from sodium chloride solutions onto copper and zinc was studied using rotating disc electrode system. The activation energies were found to be 10.8 and 30.5 k7/mole, in a 3M NaCl solution on copper and zinc discs, respectively. Higher dissolution factors were obtained on zinc disc, due to hydrogen evolution, whereas, copper dissolved close to the predicted values. Scanning electron microscope studies were conducted both on copper and zinc- cdiscs-to evaluate the deposit morphology and its effect on reaction kinetics. Two stage deposit growth was observed both on copper and zinc discs. Smooth, coherent initial deposit followed by tree-like secondary dendrites formed on copper, whereas, scattered bulbous initial deposit followed by porous dendrites was typical on zinc disc.

Jan 1, 1992

By Nag D. K

The Dolphin Scheelite orebody is located near the old mining town of Grassy on the south-east comer of King Island in Tasmania. Surface open cut mining of the Dolphin deposit was conducted for a number of years, then the proximity of the sea and adverse stipping ratio led to underground mining. As a result of the variable orientation and dimensions of parts of the orebody a number of mining methods were practiced at the Dolphin mine until 1990 when a combination of high processing and surface site costs coupled with low tungsten prices led to the cessation of operations. In this paper the different mining methods practised are examined and critically reviewed. The more successful mining methods were developed with experience and improving equipment technology to the extent that the underground operation produced ore at the lowest unit cost during the final years of operation.

Jan 1, 1995

The Lake Rotokaua sulphur deposit, near Taupo, New Zealand, is a lacustrine sedimentary ore body, 220 acres in area and from 7 ft to 96 ft thick, containing, within the area drilled to date, some 20 million long tons of ore averaging 25% elemental sulphur in unconsolidated tuffaceous diatomaceous clay, overlain by about 120 ft of pumice sand and by the shallow Lake Rotokaua. An additional amount of perhaps 4 million tons of sulphur is regarded as probable in the area remaining to be drilled. Current economic studies cover the problems of mining an unconsolidated water-saturated formation with some residual thermal activity nearby; conservation and restoration after mining in a scenic recreation area; beneficiation of the ore and extraction of high- purity sulphur, principally for fertilizer manufacture. The deposit has additional importance as a pointer to possible further discoveries in the Thermal Region.\

Jan 1, 1971

By Harper B

The mining industry has developed a comprehensive view of the need to have production personnel well trained in the use and maintenance of mining equipment. A strong commitment from the industry to this view has been instrumental in creating an efficient, profitable and productive industry based on modem production processes, sophisticated equipment and a multi skilled workforce. As the industry continues to develop, and the skills and knowledge needed by productive workers continues to expand, the training processes adopted by the industry will need to develop in parallel, not only making use of the latest advances in learning theories, instructional design and technology, but also using these knew ideas in more efficient ways.

Jan 1, 1998

Like almost any other 19th century mining area, the West Coast saw its 20th century scrapping era when machinery which had been installed in seemingly inaccessible places was somehow dragged out again. Fortunately there were some spots so remote that they defied even the most zealous of these pioneering recyclers. One of these was Big River, a mining locality in a rugged landscape straddling the headwaters of the Grey and Inangahua rivers. As a result there remains an internationally important collection of mining equipment including a poppet head, two steam winding engines, a pair of boilers, part of an aerial cableway with its loading system, and remnants of a stamp battery along with its associated gold smelter, cyanide tanks and zinc boxes. There are also assorted building remains associated with 60 years of mining and settlement. Since their abandonment in 1942, these relics have all somehow survived a further half century in a far from favourable climate with two or three metres of rain a year, frequent snowfalls and hot summer temperatures. The rate of decay during the past few years has been alarming.

Jan 1, 1996

By Yusuf R

Many heap and dump leaching processes involve competitive, complementary and sequential reactions between multiple minerals and reagents. A comprehensive model has been developed to deal with these complex chemical interactions which is based on diffusion control of the reaction rates. All of the mineralogical and chemical data are obtained from representative samples of the ore or the chemical literature. These properties have been incorporated in a general way, making the model applicable to a range of ore-process systems. The simulation is used to predict the absolute reaction rates and can be used before any leach tests are carried out on the ore itself. The applicability of the model and some tests of its validity are presented.

Jan 1, 1984

Maintaining and improving the economics of open pit mining in the future requires understanding of the characteristics of open pit mining that are different to other mining or business activities, designing mines in the first place to be less susceptible to changes in these important characteristics, and adopting strategies which yield reliable returns despite unforeseen change. Planning and production personnel require guidelines and performance standards that are based on sound economics not solely on production criteria. The guidelines adopted for long-term implementation must assume a declining price for mineral products along with declining real costs, with research efforts directed at development of both evolutionary and revolutionary ideas aimed at implementation. Decision-making must focus on risk and probability criteria rather than just simple return-on-investment criteria, and the approach for management of personnel must support the higher level of communication essential for fast decision-making in the new environment of continual change.

Jan 1, 1992

By Nethery JE

At the Red Dome and Mungana deposits in north Queensland, Australia, it is proposed that mineralisation and alteration developed as a "telescoped" overprinting continuum, ranging in style from hypothermal to epithermal, reflecting the major changes that developed in the regional setting over the period circa 325 - 290Ma. Regional assessment suggests that this also applies to many other precious and base metal deposits within a 401an length of the host Siluro-Devonian Chillagoe Formation. A ten stage paragenetic sequence of structural preparation, multi phase intrusion and associated mineralisation, alteration and brecciation is postulated for the Chillagoe district.

Jan 1, 1995

By Grey D, Turner R, Capsanis J

Coal fines are recognised to have a major impact on the cost and efficiency of the recovery of saleable coal. Fines affect the productivity of the whole mining cycle because of the low yields obtained in washing this material as well as affecting the moisture content and handling characteristics of the final product.In 1990, Coal and Allied Hunter Valley Mine initiated an internal study into coal fines based on the assumption that a reduction in fine coal in ROM material will lead to increase yields in the preparation plant. The initial results of this study indicated that the level of fines in the ROM coal can be reduced by more than 40 per cent by simple changes in blast design and implementation.

Jan 1, 1992

For several years, the Geology Department of the University of Canterbury has hosted a series of postgraduate projects in the field of coal studies, supported principally by the Ministry of Energy and to a lesser extent by private companies. These projects have involved mainly West Coast Coalfields, and my own studies have focussed on inorganic geochemical aspects of West Coast coals. Because of the large number of potentially important analyte elements in coal, and the wide diversity of coals occurring in the West Coast region, this project has required a substantial amount of work to be spent on sample collection, sample preparation, development of analytical methods, and actual analysis. Considerable problems must be faced at the sampling stage: Can sufficient information be obtained from whole-seam composites, or should seams be sampled in plies. Ply analysis is preferable, but results of proximate analyses are usually available for composites only. Where multi-seam drillhole samples become available (eg Greymouth Coalfield, where some holes yielded more than six sampled seams), the ply option involves a dramatic increase in the number of samples. I have attempted to strike a workable compromise between geographical coverage of coalfields, and detailed sampling of individual seams at each locality. In many cases, sample material has been used jointly with Jane Newman who has carried out petrographic studies.

Jan 1, 1985

By Goto T, Sato K, Mori N

A field investigation by making use of the seismic method has been carried out in order to comprehend the mechanism of rockburst and gas outburst and their predictive measures. The seismometers were so arranged both on the surface and underground as to enclose a mining panel. Seismic signals detected by the array were recorded and processed by the 32-kwords computer system. At present the system is available for analysing the source location and Richter's scale of each event and for visualizing the distribution of seismic foci and released energy at any mining stage. The magnitude distribution of events can be regarded as a comparable index of the seismic activities among mining panels. An analysis of the spatial density distribution of seismic energy in the mining panel can be useful to distinguish a highly stressed zone from stress released areas. The energy released curve or the rate of energy release determined from seismic data is also a good indication of the seismicity.

Jan 1, 1980

With mining development on hold and other underground works in a slowdown, the development of nuclear wa te repositories takes centre tage on the American rock engineering scene. Three repositorie for commercial spent fuel-in salt, tuff, and basalt-are in the phase of site characterisation and conceptual design, and one pilot project for defense high-level wa te in salt is under construction. A repository design for crystal line rock has recently been postponed.Because of strict quality assurance requirements throughout design and construction, and because of the need to predict and ascertain in advance the satisfactory performance of the underground openings, much intellectual energy has been expended to analyse underground openings in the unusual circumstances of the repository environment. In the long term, these efforts will lead to an improved understanding of rock behaviour and improved methods of underground analysis and design. For the shorter term, a formalised ground control plan was developed, the principles of which may be applied to other types of projects.This paper summarises the status of underground design and construction for nuclear waste repositories and presents some details of the ground control plan and its individual elements.

Jan 1, 1988

By B Siddall, A Gunstone

The use of a partial secondary crushing circuit provides a flexible way to optimise existing SAG comminution circuits limited by rock competency or enables optimal processing of an ore through second hand equipment not specifically selected for that ore. This paper details the process involved in designing a partial secondary crushing circuit using the recent installation at Mt Rawdon Gold Mine in Queensland as an example.

Jan 1, 2004

By Hayes P. C, Matthew S. P

The product morphologies formed on the reduction of dense wustite crystals are classified into three types, A) porous iron, B) porous wustite covered with dense iron, and C) dense wustite covered with dense iron. The mechanisms of formation of these structures and the effects of impurity elements on the product morphologies are discussed.

Jan 1, 1985

By Y L. Ma, M Chen, W Bruckard

With the extensive exploitation and gradual depletion of high-grade copper reserves, the mining industry is paying more and more attention to the hydrometallurgical extraction of copper from lowgrade and arsenic bearing copper ores. Hydrometallurgical processing, such as heap leaching, column leaching and bioleaching, provide a viable alternative to the traditional pyrometallurgy due to its harmony with the environment, moderate capital investment, and low operating costs. However, the slow leaching kinetics of enargite (Cu3AsS4) and chalcopyrite (CuFeS2) remain problematic for commercial leaching practice. The formation mechanism and the nature of the passivating layers during leaching is still a matter of debate in hydrometallurgical research. In this study, the dissolution mechanism of enargite and chalcopyrite in sulfuric acid solution was investigated using a range of electrochemical and spectroscopic analysis methods. Electrochemical oxidation of enargite demonstrated an obvious passivation region from 500 to 750 mV (Ag/AgCl). The formed passivation film was found a n-type semiconductor behaviour, which is different from the original enargite with a p-type behaviour. The results of X-ray photoelectron spectroscopy (XPS) suggested that a nonstoichiometric film Cu(3−x)As(1−y)S4 (x>>y) accumulated on the electrode surface, which accounted for the obvious decrease in current density in the passive potential region. For chalcopyrite, three important potentials of 550, 680 and 730 mV which are related to the formation and dissolution of passivation film were observed based on the cyclic voltammetry (CV) and potentiodynamic polarisation. Raman and X-ray absorption near edge structure (XANES) spectra studies of the chalcopyrite electrodes after being treated under these three potentials indicated a metal-deficient sulfide of Cu1−xFe1−yS2 (y>>x) might be responsible for the passivation phenomenon. Hence, it is concluded that the passivation of enargite and chalcopyrite are similar which are caused by metaldeficient sulfide surfaces although the compositions of the metal-deficient sulfide are different.

Aug 24, 2022