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By J. D. Steenkamp

"In July of 2016 and June 2017, major tap-hole repairs were carried out during the annual shutdown of two 63 MVA submerged arc furnaces producing ferrochromium in South Africa. The hot excavations of the tap-holes allowed for a study of the wear profiles. Subsequent thermodynamic calculations allowed for the quantification of the potential for chemical reaction between refractory and slag or alloy contributing to wear in the tap-hole area. Results from both wear profiling and thermodynamic calculations are reported here. IntroductionFerrochrome (FeCr) is an essential alloy in the production of stainless steel (Gasik, 2013). In 2017, 11.7 Mt of FeCr was produced (Pariser et al., 2018.). The main producers were China (39%), South Africa (29%), Kazakstan (12%), and India (8%).A number of grades of FeCr are available to producers of stainless steel, including high-carbon ferrochrome (HCFeCr) (Gasik, 2013). HCFeCr typically contains 60–70% Cr and 4–6% C (Basson and Daavittila, 2013). When the chromium content is lower (50–55% Cr) and the carbon content higher (6–8% C), it is referred to as charge chrome. Charge chrome is typically produced in South Africa due to the grades of ore available.FeCr is produced in submerged arc furnaces (SAFs) and in open arc furnaces (Mc Dougall, 2013) by carbothermic reduction of oxide raw materials. In a SAF the electrode tips are submerged in a porous charge mix. In FeCr production, the electrical energy is mainly liberated by resistive heating of the wet coke bed (Barker et al., 2007; Steenkamp et al., 2017). Thermally conductive lining design philosophies are typically applied in SAFs producing FeCr (Steenkamp, Denton, and Hayman, 2017; Coetzee, Duncanson, and Sylven, 2010; Coetzee et al., 2010).In July of 2016 and June of 2017, major tap-hole repairs were carried out during the annual shutdown of two 63 MVA SAFs producing FeCr in South Africa. The hot excavations of the tap-holes allowed for a study of the wear profiles. Both SAFs were operated on the same site, by two different operating crews, using the same raw materials. The major difference between them was that the SAF excavated in 2016 was an open SAF (referred to as Furnace A) and the one excavated in 2017 was a closed SAF (referred to as Furnace B). In an open SAF, a gap exists between the top of the steel shell and the roof, with the top of the burden being open to the atmosphere and the CO-rich off-gas being combusted as it escapes. In a closed SAF, the roof is attached to the steel shell and the CO-rich off-gas is collected from an offtake on the roof for further treatment and used in downstream processes.The paper presented here reports the macro-scale observations on refractory wear for the two SAFs, and studies the potential for chemical wear of refractory by slag and alloy as a potential contributing factor to the tap-hole wear observed."

Jun 1, 2019

By Mirian Mamani

Estudio sobre los diferentes tipos de depósitos de zinc ubicables en los Andes Centrales. Tras destacar el extraordinario potencial que ofrece Perú, la autora precisa que debido a que los magmas son fértiles, se formaron yacimientos en columnas corticales favorables para incrementar las concentraciones de zinc en las rocas intrusivas y rocas sedimentarias (calizas y dolomitas); se tienen las mejores estructuras (e.g., fajas corridas y plegadas) que favorecieron el emplazamiento de los fluidos y excitación térmica en el tiempo geológico por radiactividad de los depósitos; y lo más importante, que se encuentran en su mayoría preservados debido a que las tasas de erosión donde afloran son mínimas.

May 31, 2019

By Hebert Arias, Christian Mendoza, Mervin Tapia

El Complejo Pasco —ubicado en la Cordillera Oriental de los Andes de la sierra central del Perú, en el distrito de San Francisco de Asís, provincia y departamento de Pasco— está constituido por las unidades subterráneas de Atacocha y Porvenir, la operación a tajo abierto Glory Hole y tres proyectos brownfield ubicados en la periferia de la concesión. Tanto Atacocha como Porvenir son depósitos tipo skarn, con mineralización distal de Zn y Pb(+/-Au) y proximal de Zn+/-Cu, asociados a cuerpos hipoabisales de composición cuarzoandesítica y andesítica. Estudios y exploraciones recientes muestran otros tipos de sistemas mineralizados, como brechas tectónicas con reactivación hidrotermal tardía, un sistema epitermal de sulfuración intermedia en vetas, cuerpos irregulares, entre otros, y un sistema tipo pórfido. La Falla Milpo-Atacocha, de rumbo N-S, juega un rol importante, ya que los intrusivos (Stock Milpo y Santa Bárbara) que generan la mineralización del tipo skarn están controlados por esta falla. Existe otro tipo de mineralización, asociado al sistema NW-SE (Falla 13): un sistema epitermal de sulfuración intermedia. Este trabajo pretende mostrar los últimos avances en las interpretaciones metalogenéticas, producto de un intenso programa de exploración (aproximadamente 80,000 m. DDH / 2018) y de un programa de recategorización de recursos (a través de 60,000 m. DDH), que permitirá hacer posible una operación sostenible de 12 años.

May 22, 2019

By Adrián Martínez

PyGSLIB es una librería de Python con código abierto para la estimación de recursos minerales. Comprende cinco módulos principales que contienen funciones y ejercicios para trabajar con sondajes, modelos de bloques, geometría computacional con funciones implícitas, geoestadística no linear y geoestadística básica. Inspirada en macros de Datamine, tiene como premisas tanto la reproducción de los resultados como la facilitación de la auditoría de los cálculos. Este documento describe la implementación del software y demuestra su funcionalidad con un caso de estudio.

May 22, 2019

By Osvaldo Aduvire

Desde los años 90, en el Perú se han puesto en vigencia una serie de normas para el desarrollo de proyectos mineros sostenibles, a través de programas de monitoreo continuos recogidos en certificaciones ambientales de obligado cumplimiento. En este trabajo se hace un recuento general de la legislación ambiental implicada en el desarrollo de un proyecto minero, así como un análisis descriptivo de la aplicación de legislación general, transectorial y sectorial vigente a considerar en la formulación y desarrollo de un proyecto minero de exploración.

May 22, 2019

By Alonso Marchena, William Martínez, Joel Otero

En Arequipa, Moquegua y Tacna se han definido diversos arcos magmáticos. En los arcos jurásico, paleoceno y oligo-mioceno ocurren pórfidos de distintas características, los cuales presentan diferencias litogeoquímicas (LaN/YbN>20, Sr/Y>40, Eu/Eu*>1, U/Th>0.27, NbN/TaN>0.7). Estos parámetros pueden ser utilizados como guías de exploración, ya que son anomalías desde el punto de vista litogeoquímico. En caso no haya mineralización visible (depósitos ocultos), el empleo de estos trazadores en unidades ígneas (diques, cuerpos subvolcánicos e intrusivos) puede señalar la probabilidad de encontrar depósitos en profundidad.

May 22, 2019

By Jean Salcedo, Víctor Uribe

El método Structure From Motion implica la extracción de una nube de puntos en 3D, es decir, un conjunto de puntos en un sistema de referencia cartesiano en tres dimensiones, a partir de imágenes en 2D como fotografías. El presente estudio está orientado a la extracción y caracterización de las principales estructuras y su uso en la evaluación geomecánica de los taludes de la carretera Huaraz-Casma. Los datos generados se procesaron mediante el uso de software libre (open source), es decir, gratuito y con la posibilidad de modificar su código de programación para la mejora de los procedimientos, por lo que se demuestra que estas herramientas tienen una aplicabilidad y confiabilidad similar al uso de software de tipo comercial.

May 22, 2019

By Jesús Frisancho, Rosmery Delgado, Enrique Callo, Juan Calizaya

El complejo volcánico Ciénaga-Mirador está conformado por flujos de lava, flujos piroclásticos, tobas de composición andesítica, dacítica y riolítica; asociados a pórfidos daciticos dioríticos y brechas freáticas e hidrotermales con matriz de óxidos. Estos depósitos conforman un borde de caldera y domos a lo largo de fallas EW; la mineralización se presenta en forma de oro libre acompañado con óxidos de hierro, asociados a cuerpos de sílice masiva, “vuggy” y arenosa. Se realizaron dataciones U-Pb en zircones en la Universidad de Otawa (Canadá). Las edades de las rocas intrusivas fueron entre 13.85 ± 0.16 Ma y 14.05 ± 0.24 Ma. Se procesó data de espectrometría de reflectancia (TerraSpec) y las alteraciones hidrotermales fueron reconocidas como sílice-alunita-pirofilita, paragonito-muscovita, muscovita-dickita y caolinita-montmorillonita-illita, las cuales definieron un depósito epitermal de alta sulfuración con transición a pórfido. Con la caracterización petroquímica de magmas fértiles a partir de rocas volcánicas e intrusivas y la ocurrencia mineral a escala distrital y regional se define a Ciénaga-Mirador como un depósito epitermal de Au-Ag y pórfido Au con bajo potencial de desarrollo.

May 22, 2019

By José Calderón

Poderosa tiene sus concesiones en las provincias de Pataz y Bolívar en la región La Libertad y son parte de la zona de amortiguamiento (ZA) del parque nacional Río Abiseo (PNRA) y de la zona de transición (ZT) de la reserva de biosfera Gran Pajatén (RBGP). Esta área natural protegida (ANP) es uno de los dos únicos sitios en el Perú que tienen carácter de patrimonio cultural y natural de la humanidad (doble caracterización dada por Unesco). Poderosa ha firmado un convenio de cooperación interinstitucional con el Servicio Nacional de Áreas Naturales Protegidas por el Estado (Sernanp) del PNRA, el mismo que le ha permitido contar con su asesoría, mejorar los instrumentos ambientales y cumplir a cabalidad los compromisos socioambientales.

May 22, 2019

By Michael Valencia, Alonso Marchena, Fredy Arcos, Miguel Chumbe

Cobrepampa es un depósito de cobre ubicado en Acarí (Caravelí-Arequipa). La mineralización se emplaza en pórfidos dioríticos pertenecientes al intrusivo Cobrepampa (Superunidad Linga) y está constituida por bornita, calcosina, covelina y calcopirita y en la zona de oxidación cuprita, crisocola, malaquita y hematita. El magmatismo es calcoalcalino con alto K. El intrusivo Cobrepampa evoluciona por fraccionamiento y contaminación en una corteza más delgada que la superunidad Linga. Petromineralógicamente se tiene epidotización con diseminaciones de calcopirita, pirita y bornita, gangas de cuarzo y calcita con hematita acicular. Las inclusiones fluidas muestran temperaturas de homogenización de 165.5 - 266.43 °C y salinidad 3.5 - 16.8 % eq. peso NaCl de un mesotermal o epitermal, pero que por sus características geomineralógicas sería un mesotermal. Por tanto, Cobrepampa presenta más de un evento de mineralización: una con magnetita y actinolita, y otro mesotermal de vetas de cuarzo con sulfuros.

May 22, 2019

By Juan Pablo Cedillo, Ernesto Feijoo

Se efectuó un análisis y simulación para la explotación de un placer aluvial, su forma y su delimitación por periodos, para la extracción del mineral (oro) con beneficios económicos constantes. Para ello, se empleó una malla regular de exploración y se obtuvo muestras de diversos estratos del placer, a diferentes profundidades. Los resultados de la simulación delimitan las zonas de explotación por periodos, los mismos que varían según la matriz de iteraciones para el ingreso de los valores en el software SimSched. Así, según estos periodos, se puede conocer la cantidad de material que se debe extraer para obtener una ganancia constante durante la vida útil de la mina.

May 22, 2019

By Kevin Heather, David Portocarrero, Stewart Redwood, Erika Dávila, Hubert Gamarra

La mineralización en el proyecto Antakori (Regulus Resources Inc.) —parte del conjunto de depósitos de Cu-Au-Ag del Mioceno del norte del Perú— es el resultado de los siguientes sistemas hidrotermales sobreimpuestos: 1) un sistema tipo skarn cálcico de Cu-Au-Ag ; 2) un sistema tipo pórfido de Cu-Au; 3) un segundo sistema pórfido de Cu-Au; 4) un sistema epitermal de alta sulfuración Cu-Au-Ag-As-Sb; y 5) un último sistema epitermal de intermedia sulfuración Au-Ag-Zn-Pb-Cu. La diferenciación y conocimiento de dichos sistemas hidrotermales permite establecer criterios de exploración para orientar la perforación hacia zonas mejor mineralizadas.

May 22, 2019

By José Arce

El sistema AG-DAS entró en operaciones en 2015 y su aplicación tiene diversas ventajas sobre el método de polarización inducida convencional. El concepto del sistema fue el uso de múltiples receptores de dos canales, que registran la señal completa con sincronización de tiempo por GPS. La tecnología DAS (sistemas de configuración distribuida, por sus siglas en inglés) brinda mayor confiabilidad en la detección y modelamiento tridimensional de mineralización metálica con geometría compleja a profundidades de hasta más de 800 metros.

May 22, 2019

By S. Annavarapu

"Fragment size distributions play an important part in the design and planning of block cave mining operations. Though several methods have been proposed for estimating fragment size distributions in advance of mining, the calibration of these estimating procedures to field measurements has been a challenge. The Block Size Estimator (BSE) program was developed for providing an assessment of primary fragmentation expected in a block cave mine using drill-core piece length data and joint characteristics from the exploration and geotechnical evaluation programmes. In order to validate the results from the BSE program, the drill-core piece length data and the joint characteristics in different rock types from the DOZ block cave mine in Indonesia were used to help generate fragment size distributions in different areas of the mine. The predicted fragment size distributions were compared with the fragmentation observed at the drawpoints during operation of the mine.This paper presents the details of the validation of the fragment size estimates by the BSE program using fragment size distribution data from the drawpoints at the extraction level at the DOZ block cave mine, and the challenges encountered in developing reasonable correlations between the estimated and measured fragment size distributions. IntroductionThe assessment of fragmentation is an important aspect of the design and planning of the block cave mining method, and forms an integral part of the design of the excavations at the extraction level and the selection of material handling systems for transporting the ore to the processing stations. Secondary blasting requirements can also be estimated based on the fragment size distributions developed for the block cave (Laubscher, 1994).Several methods of estimating fragment size distributions in block cave mines have been developed based on joint set parameters estimated from structural data from oriented core drilling campaigns and mapping of available excavations and outcrops. The BCF program (Esterhuizen, 1999) estimates the fragmentation using a combination of empirical, analytical, and rational methods to model the behaviour of materials during the primary and secondary fragmentation processes. The program JKFrag uses advanced tessellation of joint traces to create rock blocks and then generate fragment size distributions (Brown, 2002). Nickson, Coulson and Hussey (2000) presented the details of processing of the geotechnical data from the Mont Porphyre project, including an assessment of block sizes from the data collected on the core logging sheet. The distance between natural fractures was used to create distributions of block lengths, and a distribution of potential block sizes was estimated assuming that the blocks had equal dimensions in all directions. The results agreed closely with the results of the BCF program. Hadjigeorgiou, Grennon, and Nickson (2002) demonstrated the use of oriented borehole data to provide characteristic block size distributions for a mining project using a software package called Stereoblock, which generates a three-dimensional joint network for a given volume and calculates the volumes of blocks created by the intersections of these joints, simulated as circular planes. The distributions of joint orientation and joint spacing generated from statistical analysis of the oriented core data are used for the creation of the Stereoblock model. The diameter of the circular planes representing the joints is determined based on the mean and standard deviation of the joint trace length obtained from scan-line mapping."

May 1, 2019

By Staff

"In 2018, the total estimated value of nonfuel mineral production in the United States increased by 3 percent from 2017 to $82.2 billion. The estimated value of metals produced domestically decreased by 4 percent, and the estimated value of indusrial minerals produced domestically increased by 7 percent (Table 1).Some idle U.S. metal mines and processing facilities restarted in 2018, including two primary aluminum smelters in Indiana and Missouri, a rare-earths mine in California and a zinc mine in New York. In contrast, four iron ore mines in Minnesota and a pelletizing plant in Indiana were shut down. Increased oil and natural gas drilling activity in 2018 led to increased production of some industrial mineral commodities that are used for oil and gas drilling, including barite and industrial sand and gravel. Production of industrial minerals primarily used in infrastructure and residential construction — including, cement, construction sand and gravel, crushed stone and gypsum — increased in 2018. Overall, mining activity trended upward for the second consecutive year because of increases in oil and gas extraction and industrial mineral mining (Table 2).Mineral industry performanceDiscussion of mine production is commonly segmented according to the type of materials produced within the broad categories of metals and industrial minerals (also known as nonmetallic minerals). Industrial minerals can be further subdivided as natural aggregates and other industrial minerals. Metals tend to have higher unit values but very low production quantities compared with those of industrial minerals, such as crushed stone or construction sand and gravel, which have higher production quantities but are lower-valued materials. Therefore, for discussion and analysis of the performance of the nonfuel minerals industry, the value of production is used rather than the tonnage produced. Tonnages of natural aggregates are orders of magnitude larger than those for most other mineral commodities, thus making direct comparisons based on weight meaningless (Fig. 1)."

May 1, 2019

By G-L. Wu, S-W. Wu

"The hot deformation behaviour of Nb-Ti microalloyed high-strength steel was investigated. Hot compression tests were conducted in the temperature range 900 to 1100°C under strain rates of 0.1, 1, and 5 s-1. Dynamic recrystallization (DRX) occurs as the main flow softening mechanism at high temperature and low strain rate. The hot deformation activation energy was calculated to be about 404 699 J/mol. The constitutive equation was developed to describe the relationship between peak stress, strain rate, and deformation temperature. The characteristics of DRX at different deformation conditions were extracted from the stressstrain curves using the work hardening parameter. The Cingara-McQueen equation was developed to predict the flow curves up to the peak strain. The processing maps were obtained on the basis of a dynamic materials model. The results predict an instability region in the temperature range 1010 to 1100°C when the strain rate exceeds 0.78 s-1. IntroductionThe 700 MPa grade HSLA steel is widely used in engineering machinery, automotive beams, carriages, and axle tubes, etc. (Pan et al., 2017 ). Generally, such grades contain a moderately high amount of Mn (approx. 1.4% and above), and microalloying elements like Nb, Ti, V, and Mo to impart the desired strength and toughness through solid-solution strengthening, precipitation hardening, and grain refinement dislocation strengthening (Chen and Yu, 2012; Opiela, 2014). However, the production costs can be greatly reduced by replacing part of the Nb, V, or Mo with inexpensive Ti and adopting the compact strip production CSP process (Opiela, 2014; Chen et al., 2015). Furthermore, the microalloying technology coupled with new-generation thermomechanical control processing (NG-TMCP) has proved efficient for achieving the proper balance between strength, toughness, ductility, and formability by means of a suitable combination of chemical composition and thermomechanical treatment parameters (Shukla et al., 2012; Wu, Zhou, and Liu, 2017).In hot forming processes, the complex microstructural evolutions are often induced by multiplicative hot deformation mechanisms, such as work hardening (WH), dynamic recovery (DRV), and dynamic recrystallization (DRX) (Zhang et al., 2014; Liang et al., 2015). Dynamic softening behaviour during hot processing has generated considerable interest because component properties are influenced significantly by its corresponding microstructural evolution (Wu et al., 2010). During deformation in the DRX process, deformed grains are replaced with substructures and newly formed fine and uniformly distributed grains. This occurs only when a critical strain for the onset of DRX is reached, and at the same time, the minimum rate of energy dissipating is reached (Ferdowsi et al., 2014). DRV occurs at a high strain rate and low temperature, reducing the stored energy greatly and making DRX difficult (Liang et al., 2015). The microstructural changes during DRX are sensitive to the processing parameters, such as strain rate, deformation temperature, and strain (Zhang et al., 2014; Ferdowsi et al., 2014). Therefore, in order to optimize the hot processing parameters, it is important to understand the behaviour of hot deformation visà- vis control of microstructural evolution."

May 1, 2019

By L. Makua, K. Langa, Ndlovu. S., C. Saguru

"Global demand for the three platinum group metals (PGMs) Pt, Pd, and Rh has been steadily growing due to their widespread use in emission control, industrial catalysis, and numerous other applications. The primary supply of PGMs is currently the mining industry. However, legislative, operational, and environmental challenges faced by many mining operations result in erratic supply patterns and deficits for these three metals. Naturally, recycling scrap material to recover Pt, Pd, and Rh has therefore aroused research interest in the scientific and engineering communities. Given that the majority of the global demand for these three metals is driven by emission control devices, autocatalytic converters are therefore a significant source of already processed and beneficiated PGMs for recycling.Although pyrometallurgical processes dominate the recycling industry, hydrometallurgical processes may offer certain advantages, chief among these being lower emissions and reduced energy consumption. In this investigation, scrap converter material was leached in acidic chloride media and the leach liquor subjected to solvent extraction and cloud point extraction (CPE) to recover the PGMs. The recoveries for Pt and Pd using Alamine 308® dissolved in kerosene with decanol as a modifier were 95% and 81%, respectively. The maximum recoveries using CPE after complexation with 2-mercaptobenzothiazole (2-MBT) in the presence of Triton X-100 and tin (II) chloride dihydrate as a reductant were 97% for Pd, 96% for Pt, and 91% for Rh. This demonstrates that CPE, although relatively new, may have some potential as a breakthrough PGM recovery technology. IntroductionPlatinum group metals (PGMs) have found a wide variety of applications in different industries due to their chemical, catalytic, and physical properties. PGMs are essential in automobile emission abatement, petroleum refining, and the pharmaceutical and electrical industries (Carabias-Martinez et al., 2000). However, the abundance of PGMs in the Earth’s crust is low and their primary sources are fast depleting (Crundwell et al., 2011).The high demand for PGMs, together with social, economic, environmental, and political aspects related to their production, has led to concerns about their future supply. This has resulted in renewed interest in recycling end-of-life material. PGM supply from recycling has doubled over the last decade, and currently contributes 22% to global supply (Johnson Matthey, 2016). This is in part due to the environmental, social, and operational challenges associated with mining of PGMs. For example, labour unrest, energy cuts, declining commodity prices, and declining ore grades have collectively made the mining landscape economically challenging (KPMG, 2015). On the other hand, the high content of PGMs in secondary sources makes their recovery from the increasing quantities of waste products important from a resource conservation viewpoint. Moreover, PGMs obtained through recycling have been demonstrated to have a 1% environmental cost from a life-cycle perspective, whereas PGMs obtained from mining contribute the remaining 99% of environmental cost (Bossi and Gediga, 2017). Sustainable resource recovery and the economic incentive of recycling have therefore been major drivers to justify investment in PGM recycling. The autocatalytic converter industry accounts for about 70% of the global consumption of these metals (Johnson Matthey, 2016) and therefore recycling spent converters has become a major source of Pt, Pd, and Rh (Figure 1)."

May 1, 2019

By J. G. M. Mukoya, B. Adebayo

"This work was carried out to determine the influence of rock properties and drilling machine parameters on the penetration rate at the SJ pit of Rössing Uranium Mine, Namibia. Rock properties (uniaxial compressive strength, tensile strength, and modulus of elasticity) of samples collected were determined in the laboratory. Drilling experiments were conducted in which feed pressure, air pressure, rotary speed, weight on the bit, and torque were varied to measure their effect on the penetration rate. The uniaxial compressive strength varied from 90–180 MPa for layered marble-quartzite and banded gneiss. Increases in feed pressure, weight on the bit, and rotary speed beyond the optimum level led to a decrease in penetration rate and caused the drill bit to ‘stall’. Results of the study revealed that penetration rate increases with an increase in the feed pressure and air pressure. After reaching a maximum value, the penetration rate begins to decrease despite increasing feed pressure. A very high torque causes the drill bit to stall, since the feed pressure is too high and the air pressure is not sufficient to remove the cuttings from blast-hole at maxium bailing velocities. The average penetration rate varied from 19 to 45 m/h for phase 2 of the pit, and from 17 to 68 m/h for phase 3. The optimum drilling machine parameters obtained in phase 2 and phase 3 were slightly lower than those currently being used at the mine. The trials of the optimum machine parameters will assist in reducing the cost of drilling, which varied from N$29.48 to N$36.31 per metre for the tricone bit. IntroductionDrilling and blasting contribute most to the operational cost in opencast mining and have the potential to influence the cost of downstream operations (Aipanda, 2011). The drillability of rocks depends not only on the rock properties, but also on the drilling tools and operational variables. In rotary drilling, rotational speed, thrust, and flushing are the operational variables, and are known as the controllable parameters. Rock properties and geological conditions are the uncontrollable parameters. Although, many attempts have been made to correlate drillability with rock properties, the rock characteristics affecting rotary drilling have not been entirely defined (Hartman, 1962; Kahraman, Bilgin, and Feridunoglu, 2003). The drill bit is forced into a rock surface from the rotary power head, hence creating stresses and cracks at the bit-rock interface. The performance of a particular bit in any formation i"

May 1, 2019

By H. Cevizci

"Numerical simulation of the plaster stemming method (PSM) was performed and compared with the conventional drill cuttings stemming method (DCSM). Many earlier in situ tests have proved that PSM can use the blast energy more efficiently than DCSM. Despite PSM generating more blast vibrations, it has advantages over DCSM such as better fragmentation and lower cost per unit volume of rock blasted. In this study, numerical simulation with Autodyn software using a 2D tool was employed to prove the efficiency of plaster stemming by comparing parameters such as pressure, Y-velocity, Y-force, internal energy, acceleration-Y, and compression. For example, the maximum pressure attained at the top of explosive column was 7 395 MPa for DCSM whereas it was as high as 11 945 MPa for PSM. Most of the computed parameters were significantly higher in PSM than those obtained for DCSM. This paper is the first study elucidating the efficiency of PSM by numerical simulation. It is concluded that PSM can save substantial amounts of money and effort. IntroductionThe stemming of blast-hole collars in surface mines with an inert material redirects blasting energy to the rock more efficiently, thus the blast-induced energy is utilized more effectively in breaking rock. With proper stemming, the gases should not escape due to loose stemming material. More efficient stemming with better confinement therefore increases the blast fragmentation. In addition, the distance of scatter is increased, giving rise to a looser rock pile that can be more easily loaded and transported. In order to improve the performance of a blast, stemming is used to help maintain the gas pressure over time (Konya and Konya, 2018). Proper stemming has been shown to increase the explosive efficiency by over 41% (Snelling and Hall, 1912).The most common stemming material in open pits and quarries is drill cuttings because of their ready availability at blast sites and the drill cuttings stemming method (DCSM) is a low-cost method. However, it has a major disadvantage in that dry drill cuttings eject very easily from blast-holes during an explosion, thus a great percentage of the blast energy is wasted and lost to the atmosphere. Cevizci (2012, 2014, 2013, 2017) studied blasting parameters in open pits and obtained better results with the plaster stemming method (PSM) in many limestone, basalt, and clay quarries. Moulding plaster is preferred for stemming because of the fast hardening time of 25–30 minutes."

May 1, 2019

By X. Xiang, W. Xia, J. Yin

"TiCl4 slurry containing valuable metals is an unavoidable by-product of the titanium ore chlorination process. The recovery of these valuable metals, which include titanium, niobium, tantalum, and aluminum, is an urgent issue to tackle in the titanium industry. The results of this investigation show that the valuable metallic elements can be recovered from the slurry by evaporation in a sealed container and leaching with dilute hydrochloric acid. After evaporation at 200°C for 60 minutes, nearly 99% of the titanium was recovered in the form of TiCl4, which was formed by the reaction of the TiO2 in the slurry with AlCl3. After evaporation, metals like niobium, aluminum, and tantalum remained in the residue. By leaching with 2.1 mol/L HCl at a L/S ratio of 6:1 mL/g at 80°C for 60 minutes, the soluble metals, such as aluminum, iron, and copper were all removed from the residue, and the niobium and tantalum were further enriched in the leach residue. A concentrate containing 53.40 wt% Nb and 5.57 wt% Ta was obtained by washing the leach residue with dilute aqueous ammonia under stirring. A potential waste water purifying agent containing 263.75 g/L AlCl3 was produced by purifying the leaching solution with Al(OH)3 and modified polyacrylamide. IntrodutionTitanium tetrachloride (TiCl4) is an important intermediate in titanium metallurgy that is widely used in the production of titania and titanium sponge (Akhtar, Xiong, and Pratsinis, 1991). In conventional titanium metallurgical processes, high-titanium materials such as synthetic rutile and high-titanium slag are reacted with chlorine to produce TiCl4 in a fluidized-bed furnace. Accompanying elements, such as Al, Nb, and Fe also react with chlorine to form chlorides, which are mixed with gaseous TiCl4 (Anderson, 1917). In the condensation process, gaseous TiCl4 is refrigerated and high-boiling-point chlorides are precipitated in the liquid TiCl4 to form a slurry containing 50~60 wt% TiCl4 (Wang, Xiang, and Wang, 2012).Various methods have been proposed to recover TiCl4 from the slurry, including microwave heating and spray drying (Wang, Xiang, and Wang, 2012, Wang et al., 2010a). To date, the only way to recover the TiCl4 is to return the slurry to the fluidized-bed furnace. However, this causes fluctuations in the temperature in the furnace, resulting in incomplete reaction between titanium-rich materials and chlorine. Therefore, the slurry is often rinsed with water and neutralized by adding lime, which caused serious environmental pollution and wastes a valuable resource (Roy, Bhatt, and Rajagopal, 2003)."

May 1, 2019