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By Mauri Kauppi, Pekka Niemelä

World HCFeCr production is 6.0 million tonnes. Correspondingly 1.1-1.6 t slag / t FeCr is produced depending on the raw material basis. Essentially all FeCr is produced in submerged arc furnaces, while the role of competitive technologies like DC is limited. In all furnaces fluxes are used to optimize the slag composition. Vital characteristics are smelting point, electric conductivity and viscosity. The main components of FeCr slag are SiO2, Al2O3 and MgO. Additionally it consists of Cr-, Fe-oxides and CaO. Granulated slag and/or classified slag products are produced depending on the production process. The slag products are mainly marketed in road and civil construction purposes but also in producing refractories. Normally crushed and screened slags are produced simultaneously when recovering alloy. The leachate of slag products is low and performance results are excellent. Slag products successfully replace natural sand and macadam. Generation of waste is essentially reduced. Producing and using slag products are described as BAT-technology and it is an essential environmental aspect. Outokumpu Tornio Works produces 320 000 t FeCr-slag/a. This paper deals with formation of slag in smelting process, its chemical composition, physical and structural characteristics, utilization and product specifications as well as environmental aspects. The slag products are standardized and CE marked. Additionally the role of slag in smelting and alloy recovery is reviewed in this paper.

Jan 1, 2007

By C. Machio

This paper reports the results of a study to determine the effect of process control agent (PCA) on the characteristics of Ti-Mg powders during milling. It has been shown that a 2% increase in PCA content leads to up to a 40% increase in yield of the milled powder but reduces the kinetics of the mechanical alloying process. The introduction of 4% PCA decreases the mean powder particle size by up to 30%, whereas 6% PCA increases the mean particle size by up to 230%. The characteristics of the milled powders will be discussed in relation to the role of PCA in the milling process. Keywords Titanium?magnesium, mechanical alloying, PCA.

Jan 1, 2011

By N. B. Devi

The extraction of copper(II) from sulphate solution was investigated using LIX®984N in kerosene. The parameters that could affect the extraction, such as equilibrium pH, extractant concentration, salt concentration, various diluents, and temperature, were separately investigated. On the basis of slope analysis, the complex formed in the organic phase is proposed to be CuR2, where R is the anionic part of LIX®984N. The extraction equilibrium constant and Gibbs free energy ( G) of the extraction process were determined. The positive value of H obtained from temperature variation studies showed that the extraction process is endothermic. The extraction of copper was lowest when chloroform was used as the diluent. Separation and recovery of copper from a synthetic copper-nickel solution containing 6.35 g/L Cu(II) and 0.58 g/L Ni(II) was carried out using 20%(v/v) LIX® 984N. The separation factor ( = DCu/DNi) was found to be pH-dependent. A two-stage batch countercurrent extraction was carried out at an O:A ratio of 3:4 at equilibrium pH 1.05 for extraction of copper from copper-nickel solution, followed by copper stripping from the loaded organic phase with 15% H2SO4 at an O:A ratio of 3:1.

Jan 1, 2014

By Juan Anes, Dominic Fragomeni, Tim Edwards, Dave Scott, Simon Yu

"The Montcalm concentrator operation was successfully commissioned in fall of 2004 at the Xstrata Copper’s Kidd Creek Metallurgical Site, Timmins. The start-up met or exceeded the Type 1 profile as defined by McNulty. Since the life-of-mine was estimated at seven years, concentrator optimisation endeavours had to be fast-tracked. These joint endeavours between the Kidd Creek Metallurgical Site staff and Xstrata Process Support were focussed on increasing ore treatment capacity and metallurgical performance. This paper reviews these endeavours. A flotation circuit survey, together with appropriate Process Mineralogy measurements, identified recovery opportunities in both locked and overground pentlandite in final tailings. The bypassing of first rougher concentrate directly to final concentrate was also recommended, given the composition of that stream. A subsequent grinding circuit survey identified a low circulating load due to poor classification performance. Modelling of these data suggested a change to the cyclone nest and pumping arrangements in the grinding circuit. Implementation of these recommendations has led to a 25% gain in milling circuit capacity as well as improved flotation circuit performance. These improvements amount to nickel and copper recovery gains of 2.57 and 1.83% respectively.INTRODUCTIONHistoryThe Montcalm Ni/Cu Ore is processed in a spare division of the Xstrata Copper’s Kidd Creek concentrator, located near Timmins in Northern Ontario. The flowsheet had been specified by earlier work, and the project fast-tracked so as to commission production operations into a time of rising nickel and copper prices. The Montcalm flow sheet starts with on-site ore crushing to - 19 mm. The crushed ore is trucked to the concentrator. This off-site crushing minimizes contamination with the Kidd Creek Cu/Zn ore. In the concentrator, rod and ball mill grinding to a target p80 of 39 µm produces the Rougher Flotation Feed. Flotation to Bulk Concentrate follows as Cu/Ni roughing and two stages of cleaning. Bulk concentrate is subjected to Cu/Ni separation using conventional column cells. Xanthate is the collector and MIBC is used as frother. Depramin C, a CMC (Carboxy Methyl Cellulose) is added to depress ferromagnesian silicates in the flotation process."

Jan 1, 2009

By P G. Self, M D. Raven, R A. Eggleton

Investigation of an abandoned quarry near Rowland Flat in South Australia identified asbestiform antigorite as the fibrous serpentine mineral mined during the 1940s to 1978 for filler applications, not amphibole asbestos or chrysotile as reported in earlier investigations. Scanning and transmission electron microscopy (SEM and TEM) and selected area electron diffraction (SAED) of individual fibres were used to confirm the identification. Chrysotile is widely regarded as the only asbestos mineral in the serpentine group. Further work was done therefore, on the geology and mineralogy of the occurrence, and the health implications were reviewed. A zone of antigorite alteration, with associated talc, is traceable for 750 m along strike of recrystallised dolomitic siltstone within Woolshed Flat Shale of Neoproterozoic age. The antigorite formed, in part, by replacement of prismatic crystals of probable tremolitic amphibole. The deposit is proximal to the Williamstown Fault and the serpentine-talc alteration is possibly due to fluids expelled along the fault during late-stage deformation in the Early Palaeozoic Delamerian Orogeny. The antigorite comprises white to pale green bundles of lath-shaped fibres that occur either as randomly- arranged equant patches after amphibole or as cross-fibre veins, both intimately mixed with calcite. Highly fibrous product was mined from the weathered zone where calcite was leached during weathering. Gentle grinding releases fibres with a high aspect ratio (>10:1) that show a wide range of fibre thickness, including a significant proportion of fibres <0.25 ¦m width. Toxicological studies on fibrous antigorite from Poland and Italy indicate that the carcinogenic potential of this form of serpentine is similar to amphibole asbestos. X-ray diffraction (XRD) and fourier-transform infrared (FTIR) techniques readily distinguish antigorite from chrysotile. Determination of asbestiform habit and confirmation of antigorite mineralogy is most reliably done using electron microscopy, preferably with SAED capability.

Jan 1, 2008

The Acid Leaching Process for the Synthesis of Zeolitic Material from Paper Sludge Ash

Sep 13, 2010

By Fred C. Schmednecht

For years, the strategy was to contain waste and in many applications, is still the recommended method. Recently, it has become acceptable to create filters below ground for the in-situ treatment of waste. Consequently, in lieu of the waste being contained, it is desirable that the waste flow through a pervious treatment zone. For instance, subterranean pervious walls comprised of iron sand are particularly useful in treating chlorinated solvents in contaminated groundwater. The iron acts as a corrective filter to treat the contaminated groundwater. How are these impervious and pervious walls being constructed? One effective means of constructing an impervious barrier is the vibrated beam method. This method, in brief, involves the use of a fabricated steel beam, a vibrator, a pile driving crane, and a mixing plant. This method results in a 4-6" wide wall with depths up to and exceeding 100'. Over one hundred slurry walls have been installed using this method in the United States. The need for the vibrated beam method continues to escalate due to its reduced health and safety considerations, high level of quality control, lack of excavation, narrow working area, and ability to achieve depths greater than 100'. A recent project was in Marinette, Wisconsin at the ANSUL facility. The project consisted of a 28,000 square foot slurry wall and was completed in January of 1999. Another effective means of creating an impervious barrier, where structural support from the barrier is needed, is the Waterloo® Barrier System. This system involves the use of a pile driving crane, Waterloo® steel sheet piles which are patented steel sheet piles due to their groutable interlocks, and a grout plant. This system results in a water-tight barrier due to the grouted interlocks and provides structural support. A project was completed at Beta Steel in Portage, IN for a retention pond to protect Lake Michigan. Due to the new concept of "filtering", there are few accepted construction techniques available. One effective field proven construction technique is the patent pending mandrel emplacement technique. This technique involves the use of a fabricated hollow steel mandrel with a shoe, a vibrator, a heavy duty crane, and a material feeder. This technique results in a pervious wall which may be comprised of pure iron sand or any other flowable media. Using this technique, the pervious wall may be constructed in varying widths to depths in excess of 100'. A successful installation occurred in October 1997 at Cape Canaveral Air Station in Florida.

Jan 1, 1999

By Dan A. Brown

Outline ? Basic Concept of ACIP Piles ? Factors Affecting ACIP Pile Performance ? Applications: - Favorable Conditions - Unfavorable Conditions ? Design for Axial Loading ? Lateral Loading Considerations ? Summary & Conclusions

Jan 1, 2004

By Madgwick J. C

The monosaccharides glucose, galactose and arabinose, and the polyols glycerol and mannitol (0.1 Ufo WIV) supported pure and mixed culture heterotrophic bacterial manganese leaching of solid pyrolusite (MnO2, 2% W/V) to yield 14-38 mg/litre manganous ion in 3 days from a simple mineral salts media at 30°C. Supplementation of pure bacterial isolates growing on glucose with soluble intracellular photosynthate from freshwater algae (0.07 g/l carbohydrate) and marine algae (0.11 g/l) led to an improvement in Mn++ yields of 24 and 100 per cent respectively. Extracellular products of the freshwater algae (0.3 g/l carbohydrate) boosted recoveries by 57 per cent.

Jan 1, 1982

By Warren L. J

The effectiveness of shear-flocculation as a method for upgrading simple mixtures of ultrafine (1-11 \lm) scheelite and garnet was evaluated. Statistical methods were used in the design and analysis of the main test program.The stirrer speed, stirring time, and initial weight ratio were all found to have significant effects on both the recovery and grade of the floes produced. The particle sizes also had an effect on the final grade. There were several important interactions between factors which also affected the results. Optimum conditions for shear-flocculation were established, and under these conditions about 80 per cent of the scheelite could be recovered at a grade which depended on the composition of the starting mixture. Starting with mixtures containing 10 and 50 per cent scheelite, the best final grades were between 20 and 50 per cent and between 70 and 90 per cent respectively, the actual value depending on the particular combination of particle sizes.

Jan 1, 1977

By Keith Heasley

This paper is a retrospective on the development, application, and enhancement of the LaModel program from a personal perspective. The narrative starts with an explanation of the objectives behind the original development of the program and then introduces some of the unique and very practical features of the program. Next, a demonstration of how LaModel was advantageously used to model stresses and displacements in a multiple-seam mining situation with highly variable topography is presented. This is followed by the details of a number of the major enhancements and expansions of the program over the years. A back-analysis of the Crandall Canyon Mine collapse is then briefly presented, along with the associated development of a recommended calibration procedure for the critical input parameters to LaModel. Finally, some of the present research areas are briefly described, and future enhancements are introduced.

Jan 1, 2011

By JOHN W. KOSTER, JAMES R. FLEMING

The following report is made through the Bureau of Mines as a result of the work under the cooperative agreement with the State geological survey and the engineering experiment station of the University of Illinois. It deals with the use of permissible explosives in the coal mines of Illinois, and is intended primarily to present to mining men the possibility of assuring safer conditions in mining through the use of these explosives. Twenty coal mines in Illinois were using these relatively safe explosives at the time this report was prepared. Of these, seventeen were in Franklin County, two were in Saline County, and one in Montgomery County. In these various fields experience had shown that although black blasting powder was a useful agent in breaking down the coal at the working face, yet it had given such conclusive evidence of its danger to life and property in causing explosions and mine fires that a substitute was sought and has been found in permissible explosives. Each coal mine in Illinois in which permissible explosives are used was visited and a study made of the problems involved. The report deals briefly with the dangers of black blasting powder now in such common use in coal mining. It discusses the development of permissible explosives and their introduction into Illinois coal mines and points out the characteristic differences between permissible explosives and black blasting powder. The present system of blasting and the most approved methods of using permissible explosives are described. Data are given to show that not only has safety and efficiency in these mines been greatly improved, but that the cost of explosives to the miner per ton of coal has been reduced, and that sizes of coal produced from permissible explosives compare favorably with those previously obtained at the same mines with black blasting powder. The successful use of permissible explosives in these Illinois mines as well as in many other mines throughout the country should aid in their introduction into a larger number of mines and bring about that degree of freedom from explosions and fires which should be attained in mining.

Jan 1, 1917

By D Craw

The Old Man Range, south of Alexandra, in central Otago consists of a package of highly folded greenschist facies schist of the Wanaka lithologic association. The range is crosscut by several east to ENE-striking high angle gold-bearing quartz veins, (eg Whites Reef and Grays Reef), which were extensively worked in the late 1800s. The range is bounded on its east side by the Old Man Fault, which separates these rocks from generally flat lying and planar Caples Terrane schist. To the west of the Old Man Fault, about halfway up the range, a large subparallel, 100 m wide fault zone strikes NNW and appears to cut off the historic veins. The fault zone consists of highly sheared and folded rocks and numerous high angle cataclasites and centimetre-scale clay gouge zones. Hydrothermal alteration is not apparent and the individual faults and shears are clay altered, possibly due to weathering, without visible quartz veins. Gold, limonite pseudomorphs after pyrite and rutile are concentrated in some of the narrow cataclasites and gouge zones. These mineralised structures are texturally similar to the gold-bearing reefs and may be structurally related. It is postulated that the NNW-striking shear zone and ENE-striking veins may be a conjugate array formed during a period of Cretaceous normal faulting.

Jan 1, 2004

By Patrick J. Doig

In mid-1991, the design/build contractor set to work on the Pergau HEP in a remote corner of Malaysia, armed with only a slim volume of conceptual drawings. The next five years saw roads, power lines, buildings, dams, and over 30 kilometers of tunnel constructed, followed by two years of E&M installation and commissioning. Along the way, the project overcame geothermal groundwater, faults, land disputes, monsoon rains, marauding tigers, and those most fearsome of foes, politicians and the press. This paper is a testament to the ingenuity, commitment, and persistence of the construction industry professionals who brought this massive project to fruition.

Jan 1, 2001

By I. A. Mwamba

Plain and alloyed titanium aluminides of composition Ti-47.5 at.% Al were prepared by melting commercial-purity titanium and aluminium with additions of 1 at.% precious metal. The as-cast alloys were subjected to potentiodynamic scans in 5, 15, and 25 wt% HCl aqueous solutions at room temperature and compared for their abilities to spontaneously passivate. Addition of precious metals resulted in a general improvement of corrosion resistance by increasing the open circuit potential to more noble values. Addition of 1 at.% gold or silver to titanium aluminide did not significantly increase the corrosion potential (Ecorr) above that of the plain titanium aluminide alloy, indicating that gold and silver are not sufficient cathodic modifiers to improve the corrosion resistance of titanium aluminide in all the solutions tested. However, platinum, palladium, and iridium additions shifted the corrosion potentials to the position of the passive region of plain TiAl for all solution concentrations. This indicated that TiAl alloyed with these platinum group metals would passivate spontaneously by cathodic modification. TiAl alloyed with palladium performed the best in 5 wt% HCl solution with the most positive corrosion potential. In 15 wt% HCl solution, alloys with platinum exhibited the most positive corrosion potentials, while alloying with iridium or palladium revealed more negative corrosion potentials. Thus, palladium alloying led to the best cathodic modification of titanium aluminide in low-concentration HCl solution, whereas platinum and iridium alloying additions resulted in the best cathodic modification of titanium aluminide in high-concentration HCl solutions.

Jan 1, 2013

By Claude MacDonald, John H. Ashburn

"IntroductionIndustrial growth and technological change over recent years had been accompanied by two major sources of concern to management and employees: (a) increase in occupational injury and illness and the resultant costs involved; and (b) equipment damage and breakdowns in concentrated production lines causing more extensive loss potential.Due to economic factors, management attention has focussed more on production and quality than on safety, health and related loss potential sources. As a result , occupational safety and health activism has grown, government legislation of compensation and occupational safety and health standards have progressively developed and stronger liability attitudes have been taken by courts of law.To improve efficiency and allow development in more competitive markets, rising labour costs, equipment costs and safety related financial losses have dictated that attention be given to conservation of all resources. Conservation of resources, people, equipment, material and environment, can no longer be addressed in isolation but must be managed integrally with production and quality. To this end, systems have developed utilizing sound management principles applied with equal intensity to production, quality and loss potential"

Jan 1, 1987

By P M. Hancock, Associates

Lacustrine sediments, hydrothermal explosion breccias and spring precipitates deposited 5200 - 1800 years BP as a result of geothermal activity at Lake Rotokaua, contain New Zealand's largest known sulphur reserves. Current drill indicated reserves are 2 600 000 tonnes of elemental sulphur, assuming a ten per cent (dry basis) cut-off, contained in some 17 000 000 tonnes of ore with an average grade of 214.0 per cent (dry basis) sulphur. Additional inferred ore containing 500 000 - 900 000 tonnes of sulphur has yet to be prospected by drilling. Geological factors will be important in exploitation of the deposit, particularly the extent and disposition of the orebody, sulphur grades and distribution, physical characteristics of the ore, permeability and stability of the overburden and the nature and extent of geothermal activity in the area. Trials to date indicate that Frasch mining and possibly opencutting are unlikely to be successful mining methods. Further mining feasibility studies will be required to ascertain the most likely mining system for the deposit.

Jan 1, 1984

Water Balancing in Mineral Processing - Issues and Opportunities

Sep 13, 2010

In preparing this paper, the writer hopes to achieve two main objects. Firstly, an indication of the desirable features of coke from the viewpoint of a blast furnace operator should be of assistance and value to those connected with coal and coke research, coal mining, the manufacture of coke and the production of iron. Secondly, it is hoped that the conclusions and opinions expressed herein, which are known to be of a controversial nature, will promote some discussion and thought. In this way, other workers may see fit to contribute and enlarge our general knowledge of Australian coke and its behaviour in blast furnaces.Those properties of coke that are considered to be of importance to blast furnace operation will be examined. Although broadly speaking, the composition and characteristics of coke are inherent in the coals used, any special features of coal preparation and carbonization that affect the resultant coke will be discussed. An attempt will also be made to indicate the effect on blast furnace operation of significant irregularities in these properties.THE FUNCTION OF COKE IN A BLAST FURNACECoke has four important functions in a blast furnace:1. To reduce the oxides of iron and other elements to metal and to provide the carbon absorbed by the iron.2. To supply the necessary heat for the process.3. To provide an open supporting structure in which the descending ore and limestone lie exposed to the action of the ascending gas.4. To provide voidage in the bottom of the furnace, so that iron and slag can accumulate in the hearth.

Jan 1, 1957

By Lane White

The 1989 Annual Meeting and Exhibit of SME in Las Vegas, NV, February 27 - March 2, 1989, was the largest ever, drawing more than 4000 regis¬trants and 240 exhibit booths. Technical sessions included presentation of nearly 500 papers, including symposia on Biotechnology in Minerals and Metals Processing, Surplus Capacity in the International Metals Industry, and APCOM `89 - the 21st International Symposium on Application of Computers and Operations Research in the Mineral Industry. Technical sessions covered the gamut of minerals industry interests; however, the proximity of the meeting to recently surging gold development in Nevada drew special attention to gold operating practices. Several of the papers on gold processing are reviewed below. To keep pace with the strong world- wide interest in gold development, SME has scheduled three additional upcoming programs that will focus specifically on gold: World Gold '89 - Gold Forum on Technology and Practices will be held November 5 - 8, 1989 in Reno, NV, as a joint meeting and exhibit between SME and the Australasian Institute of Mining and Metallurgy. Technical sessions will encompass a full program of papers covering geology and exploration, mining, and mineral and metallurgical processing. Cooperating sponsors for this meeting include the Canadian Mineral Processors Division of CIM, The Institute of Metals, The Institution of Mining and Metallurgy, The Mining, Geological & Metallurgical Institute of India, and The South African Institute of Mining and Metallurgy. Gold '90 - Salt Lake City, UT, February 26 - March 1, 1990, will be a symposium held in conjunction with the 1990 SME Annual Meeting. Current research on the processing of refractory gold ores will generate innovative papers on process mineralogy at this symposium, with special emphasis on gold with pyrite and gold with carbon. Other sessions are planned for gold exploration and mining, gold metallurgy, gold plant design and practice, and gold in scams. Advances in Gold and Silver Processing Conference, October 1 - 3, 1990 will be held in Reno, NV. Preliminary planning calls for technical sessions on heap leaching practice, refractory ore processing, non-traditional lixiviants, bioleaching, metal recovery from solution, and the environmental aspects of processing operations. PLANT DESIGN, OPERATION Technical sessions organized by the Minerals and Metallurgical Processing Division of SME at this year's meeting in Las Vegas covered a wide range of gold operating practices. Eight papers relating to gold plant design, operation, and equipment are summarized here. Preprints of these papers are available by writing to Publications Sales, PO Box 625002, Littleton, CO 80162-5002 ($2.50 per paper for AIME members, $4 for nonmembers). Continuous elution process A. M. Stone, of Bechtel Australia Pty. Ltd., described the "Development of the Continuous Elution Process for Extraction of Gold from Carbon" (pre-print 89-75). Developed by Bechtel Pacific Corp. for Ok Tedi Mining Ltd., the Continuous Elution Process uses the same reagents as batch processes for elution of gold from carbon, while yielding significant savings in stripping vessel size and energy consumed in comparison with equivalent batch processes. The process is also simpler to operate than batch processes. Other advantages include reduced maintenance costs, higher average eluate grade, and near steady final eluate grade. Pilot testing for the Continuous Elution Process was conducted at Western Mining's Kambalda gold plant beginning in December 1982. The Continuous Elution Process is a continuous countercurrent system operating in a pressure vessel at elevated

Jan 1, 1989