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By Andrew E. Grosz

The United States is dependent on foreign imports for about 80 percent of its ilmenite, about 60 percent of its rutile, and virtually all of its monazite. Nearshore marine sand deposits and beach-complex sediments in the southeastern United States are important domestic sources of ilmenite, leucoxene, rutile, zircon, monazite, and a number of other less well known economic heavy-mineral (HM) species. Because global onshore reserves of placer titanium minerals may fall short of demand in as few as 20 years, offshore research in HM placers will become more important. The Atlantic Continental Shelf (ACS) defined by the shoreline and the 200-m isobath varies in width for the modern U.S. coastline from a fraction of a kilometer to about 150 km offshore of Cape Cod, Mass., and includes an area of about 3.91 x 105 km2. It probably contains 3-7 x 1011 m3 of sand and gravel which may locally contain commercially exploitable placer HM deposits.

Jan 1, 1986

By Willam R. Normark

During a series of dives with the submersible ALVIN in 1984, samples of massive sulfide were recovered from four vent sites. All sites occur within a linear, steep-walled cleft about 50 m wide and as much as 30 m deep. The cleft bisects the axial valley floor throughout the 15-km-long study area and appears to have been the source for the most recent volcanic eruptions in the valley. Three of the vent sites are defined by a set of discrete hydrothermal discharge zones; as many as eight have been identified over a distance of 500-800 m along the cleft floor. Sulfide deposits occur as individual and coalesced mounds, spires, and chimneys generally less than 3 m in height but a few might be as high as 10 m. The vents are also marked by extensive, yellow-to-amber ferruginous sediment and clots of bacterial matter. Some vents have extensive colonies of tube worms, gastropods, mollusks, and several predator species, such as crabs and squid. The fourth vent site has no visible discharge and consists mainly of "dead" spires and chimneys of massive sulfide. The massive sulfide samples collected with ALVIN are primarily sphalerite with minor marcasite, pyrite, pyrrhotite, isocubanite, chalcopyrite, wurtzite, and anhydrite. Bulk analyses of these chimney and spire samples show Zn contents approaching 60% by weight and significant enrichments in Ag and Cu. Vent fluids have the highest concentrations yet reported for Zn, Fe, and Mn. Thus, the Zn- and Ag-rich nature of massive sulfide from the southern Juan de Fuca Ridge study area

Jan 1, 1985

By Patrick J. C. Ryall

Remotely control led drills capable of being lowered to the sea-floor from ordinary research vessels have been developed over the past two decades. These drills are currently being used in geological survey programmes on the continental shelves (Canada, Japan, Norway, United Kingdom) and for studies of mid-ocean ridges. Generally the drills fall into two categories: 1) those which are powered from the surface and controlled by an operator, and 2) those which are battery powered and follow an automatic programme. Some drills have a television camera mounted on them sending a picture to the surface as an aid to site selection and geological interpretation. Typically the drills are capable of drilling a core 2.5 - 5 cm diameter up to 10 m long. While most of these drills are designed for <1000 m depth, some can drill in water depths of as much as 3500 m.

Jan 1, 1985

By Charles L. Morgan

The Minerals Management Service of the U.S. Department of the Interior and the State of Hawaii Department of Planning and Economic Development are investigating the cobalt-rich ferromanganese oxide crust deposits found within the Exclusive Economic Zones (EEZ) of the Hawaiian Islands and Johnston Atoll. The objective of this investigation is to complete a preliminary resource assessment and an Environmental Impact Statement for potential leasing of mineral rights to these crusts. The results of this effort will be summarized and published in a Draft Environmental Impact Statement in March 1986. Three oceanographic cruises to deposit sites in the Hawaiian Islands EEZ were conducted by the University of Hawaii in 1984. As a result, data and sample analysis yielded the following resource estimates (in thousand tonnes): (1) total crusts - 378,500; (2) cobalt - 2,500; (3) manganese - 76,200; (4) iron - 59,700; and (5) nickel - 1,400. These estimates do not include key factors such as deposit continuity, recoverability, and environmental sensitivity. A preliminary attempt to quantify some of these factors for one particular deposit is in progress and will consist of detailed field studies followed by laboratory analysis. Similar evaluations of the Johnston Island EEZ have also begun and are based upon field work conducted by West German researchers and the U.S. Geological Survey. The Johnston Island EEZ appears to have crust resources about as large as those contained in the entire Hawaiian EEZ.

Jan 1, 1985

By Peter E. Halbach, Andreas Jahn

"Co-rich ferromanganese crust deposits exist on slopes, summits and platforms of seamounts and guyots throughout the global oceans, where deep-sea currents have kept the seafloor structures more or less free of sediment for millions of years. They form by direct precipitation from cold seawater under more or less oxic conditions and consist of thin layers (2 up to 25 cm thick) covering hard substrate rocks in water depths of 800 to 5000m (Halbach and Marbler, 2009; Hein et al., 2000). Besides Mn these crusts contain interesting concentrations of minor elements (Co, Ni, Ti and Cu) and trace elements (Mo, W, Te, Ga, Pt and REEs), thus they represent significant metal deposits and promise potentially valuable additions to the world’s metal resources.The prospects for mining of this marine type of metal deposits largely depend on the grades and the scale of the potential ore resources. However, only a few percent of existing seamounts and guyots have been mapped and sampled in detail, most of them in the Pacific Ocean. Therefore, a model to estimate the geological resources based on the global seamount catalogue of Wessel (2001; revised: Wessel et al., 2009) and the empirical parameters which control the metal composition and distribution was developed."

Jan 1, 2017

By C. R. Pearce, B. Murton, S. Howarth, P. Lusty

"With the expansion of “green” energy technologies, the demand for the critical raw materials required to sustain this growth is increasing. Many E-tech elements, including tellurium (Te) and rare earth elements (REEs), suffer from high supply shortage risk and the need for more diversified metal supply routes is driving research into alternative resources. Hydrogenetic ferromanganese crusts, seafloor deposits of Fe- and Mnoxyhydroxides that form from the direct precipitation from seawater, present a potentially important future source of E-tech elements. With growing interest in the potential wealth of these deposits and the issuing of permits for deep-sea mining and exploration, more work is underway to understand the nature of ferromanganese crust deposits, their elemental concentrations and distributions, and the potential impacts of mining activities.This research focusses on the formation of ferromanganese crust deposits and processes that control the extreme enrichment of elements such as Te, Co and REEs. The crusts were systematically sampled and mapped between ~ 1000 – 4000 m depths using ROV ISIS, from a range of environments, substrates and morphologies from Tropic Seamount (NE Atlantic) in order to determine the seamount-scale factors that control major and trace elemental concentration variations. These factors include depth, surface roughness and micro-bathymetry, location relative to long-term mean current direction and energy, influence of tidal energy dispersion across the seamount, sediment supply, substrate lithology, biological productivity and phosphatisation. The study analyses trace-element characteristics of 100 ferromanganese crust samples alongside standard reference materials NOD-A-1 and NOD-P-1 (US Geological Survey manganese nodules). At this initial stage, we report results from whole rock acid digestion and ICP-MS analyses."

Jan 1, 2017

By J. R. Hein

East Diamante is a submarine volcano in the southern Mariana arc that is a complex caldera about 10 km x 5 km (elongated ENE-WSW), and breached on its northern and southwestern sectors. A large field of barite-sulfide mounds was discovered in June 2009 and revisited in July 2010 aboard the R.V. Natsushima using the Hyper-dolphin ROV. The mound field occurs on the NE flank of a cluster of resurgent domes inside the caldera. The mound field extends for more than 100 m long and is about 30 m wide, and is aligned along a NE-SW rift valley. A sample of dacite yielded a 40Ar/39Ar age of 20,000±400 years. Individual mounds are typically 1-3 m tall and 0.5-2 m wide, with lengths from about 3 to more than 5 m. The mounds are composed of barite-dominant layers interbedded with Zn-sulfide-rich barite layers. Rare inactive spires and chimneys cap some mounds. Fe and Mn oxides are currently forming small (<1 m diameter, ~0.5 m tall) subsidiary mounds on the top of some of the sulfate/sulfide mounds and drape the flanks of others. Both diffuse- and focused-flow fluids emanate from the subsidiary oxide mounds. Ages of the basal sulfate/sulfide mounds cluster around 4,000 years old based on 226Ba/Ba, whereas the oxides are less than 5 years old based on 228Th/228Ra. Most mound and chimney samples are dominated by barite and amorphous silica; sulfides occur in variable amounts that in decreasing order of abundance include sphalerite, galena, pyrite, and chalcopyrite. Anglesite, cerrusite, and a Pb phosphate occur as late-stage interstitial phases. Some mound samples have fragmental textures; layered clasts composed of chalcopyrite and pyrite may have been derived from collapsed chimneys. Despite the abundance of barite, samples contain high concentrations of Zn (to 23 Wt.%), Pb (to 13 wt.%), Ag (to 500 ppm), and Au (to 15 ppm). Copper is enriched in a few mounds samples, up to 3 wt.%, but is typically <1 wt.%. Other significant metal enrichments include Sb (to 1320 ppm), Cd (to 1180 ppm), and Hg (to 55 ppm).

Jan 1, 2011

By Andrea Koschinsky, Luise Heinrich, Stefan Gößling-Reisemann

"Germany, like several other countries, has entered a contract with the International Seabed Authority (ISA) to explore the prospects of commercial manganese nodule mining in the Clarion-Clipperton Zone (CCZ). Ensuring a maximally sustainable deep-sea mining operation requires a thorough understanding of the environmental impacts associated with every step of the mining process from the extraction of the nodules at the seafloor to the refinery on land. Against this background, the project presented here applies a combination of scenario-building and life cycle assessment (LCA) to assess and evaluate the sustainability performance of the individual process steps as well as the entire mining operation.Life cycle assessment (LCA) is a comprehensive methodological framework that allows the identification and quantification of impacts occurring during a products life-cycle, as well as the analysis and evaluation of their contribution to pre-defined impact categories, such as climate change, acidification and toxicity (Rebitzer et al., 2004). Until now, LCAs with a focus on raw material extraction have almost exclusively been applied to terrestrial processes. Noteworthy exceptions are offshore drilling, offshore wind farms and ocean fishing. Hence, the first part of the project is to investigate in how far LCA can be applied to deep-sea settings and if and in what way it could be adapted to be used in a deep-sea mining context."

Jan 1, 2017

The chemical composition of the nodules varies with the type of manganese minerals and the size and characteristics of their nucleus, but those who have an economic interest have the following composition: Mn 29%, Fe 6% Si 5%, Al 3%, Ni 1.4%, Cu 1.3%, Co 0.25%, Na 1.5%, Ca 1.5%, Mg 0.5%, K 0.5%, Ti 0.2 0.2% and Ba 0.2% (Morgan, 2000; ISA, 2002). The Pacific Rim is an area of abundant occurrence of polymetallic nodules (Glasby et al., 1980; Morgan, 2000). According to these authors, the Pacific sea floor of the Clarion-Clipperton Zone (CCZ) is one of the most interesting areas in regard to the genesis of polymetallic nodules. Their abundance in the ocean floor is very variable, as there are places where they cover more than 70% of the ocean floor. The nodules can be found at any depth, but the highest concentrations are between 4000 and 6000m (Morgan et al., 1993). In studies conducted in the EEZ of the Mexican Pacific are those made within the project "Research on the origin, process and distribution of minerals in the Pacific ocean floor in the Exclusive Economic Zone of Mexico". Within this project Rosales (1989) conducted studies on the origin, process and distribution of polymetallic nodules, finding that a number of processes give origin to nodules, being diagenesis one of the main mechanisms of elements that contribute to the nodules. Besides hydrothermal processes that are carried near the East Pacific Rise at 21° N, inputs are contributing to the nodules metallic elements and sediments, especially in regions close to the dorsal, as a greater influence hydrogenetic processes occurs westward (Rosales and Carranza, 1990). In 1993, after cruise MIMAR II, Carranza and Rosales refer that metals such as Cu, Co, Ni, Sn, Fe, Mg, Pb, Zn and Ba may have a relationship with the East Pacific hydrothermal activity and sea currents carry these metals in solution to the Clarion-Clipperton fracture area, where there are hydrogenic metals sources (Al, Fe and Mn).

Jan 1, 2011

By I. Yu. Melekestseva, V. V. Zaykov

Paleooceanic structures of the Urals fold belt contain different volcanic-hosted massive sulfide deposits of the Urals, Kuroko and Cyprus types [Prokin, Buslaev, 1999]. Small Cobearing massive sulfide deposits, as Ishkinino, Ivanovka and Dergamysh, associated with ultramafites of the Main Urals fault, are less known. Interest to them had arisen after discoveries of the modern “black smokers” associated with ultramafic rocks of the Middle-Atlantic Ridge (MAR). Ores of the Urals deposits are enriched in Co (0.3 %) and Ni (0.6 %) that are concentrated in Co-Ni-Fe-sulfides, sulfarsenides, and arsenides. Ores also contain the increased gold contents – 3–6 ppm and up to 16 ppm in those saturated with As-bearing minerals. The aim of the paper is a comparison of precious metal mineralization in ores from the Paleozoic and modern ultramafic-hosted massive sulfides.

Aug 24, 2006

By Rolf B. Pedersen, Ingunn H. Thorseth, Håkon Dahle, Ingeborg E. Øklandm, Linn M. B. Olsen

Weathering of sulfides and the generation of acid mine drainage (AMD) is a well- known environmental issue in on-land mining. The process can release potentially toxic compounds and heavy metals to the environment and is highly influenced by microbial activity. However, the weathering of sulfides in deep-sea environments is not well studied. In 2014 we therefore deployed two titanium incubators filled with freshly ground pyrite grains into an inactive part of the hydrothermal sulfide mound of Loki´s Castle vent field, aiming to study the in-situ seafloor weathering of the freshly exposed sulfides. Each incubator had five chambers placed in a depth profile, where the upper chamber was exposed to the bottom seawater. After one year of exposure, one incubator was collected and analyzed for weathering features and microbial colonization and community composition. In addition, one sediment core (25 cm deep) was collected from the sulfide mound in close vicinity to the incubators, and another core (45 cm deep) was collected from the (hemi)pelagic sediment just outside the sulfide mound. The cores were analyzed for geochemical composition of the solid material and porewater, and the microbial community composition aiming to define the redox zoning and dominating geomicrobiological processes in the natural deposits, and to unravel how these processes influence the mobility of heavy metals during sulfide weathering. Scanning electron microscopy (SEM) revealed development of Fe-oxyhydroxide weathering rims on the pyrite grains in the incubator chambers. Spalling of the rims on the most weathered grains, exposing fresh pyrite surfaces to oxidation, was commonly observed. The SEM investigation also revealed a positive correlation between weathering degree and microbial community density. Preliminary results from the microbial community analysis show a high relative abundance of putative sulfide oxidizers, suggesting that the community is governing the degradation of pyrite.

Jan 1, 2018

By Ian Selby

Resource management is a key factor in the operation of a successful marine aggregates business; it is integral to the development of sustainability, satisfying increasing commercial, quality, and environmental performance standards. Resource management is based on the combination of; (i) a thorough evaluation and understanding of the resources on the sea bed and (ii) a dredging plan targeted to permit the effective and efficient extraction of the resources whilst mitigating impacts and leaving the sea bed ready for recolonisation.

Jan 1, 2004

By B. Prause

Ferromanganese crust samples collected from Central Pacific sea-mount areas became of special interest after surprisingly high nobel metal contents have been analyzed. Hydrogenetic crust growth is controlled by the conditions of the oceanic water column. Thicker encrustations show two crust generations of different age ranges. The mean values of the chemical composition state that the older generation is richer in P, Ca, Ni, Cu, Zn, and Pt and depleted in Fe, Ti, Co, Al, and Si. The differences apparently indicate a distinct change of the geochemical environment. The Pt concentrations vary up to 1800 ppb and do not clearly correlate to one of the other metals. This might indicate a bond of multiple nature. Several mechanisms have been proposed to explain the Pt concentrations in ferromanganese samples. Our models consider seawater and cosmic spherules as responsible Pt sources. In seawater the main species of dissolved Pt probably exist as the doubly negatively charged tetrachloro-complex. A precipitation of Pt in seawater may take place if the chloro-complex is decomposed by reduction of pt2+ to pt0. On the other hand, the Mn02 precipitation is caused by an oxidation of Mn2+ which is supplied from the oxygen-minimum zone. The large activation energy needed for the oxidation of divalent ~n" in solution has been recognised, and the resulting slowness in the formation of Mn(V1)-oxihydrate sug

Jan 1, 1989

By Peter M. Bartlett

The Republic of South Africa ranks among the world leaders in both reserves and production of numerous land-based mineral commodities. Over the last three decades, however, South Africa has also identified several commodities that may exist in commercial quantities in the marine environment. The major targets include 1) placer diamonds; 2) titanium- and zirconium-rich beach sands; 3) sedimentary and concretionary phosphorite and glauconite deposits; 4) manganese nodules; and 5) hydrocarbons. South Africa ranks second in world reserves of diamonds and has potentially enormous sea resources. Diamonds are currently recovered on the Atlantic side from ancient beach gravels in the Northwest Cape Province and from the seabed south of the Orange River to Lamberts Bay. Approximately 100,000 carats (or just 1% of South Africa&apos;s total annual production) are produced each year from offshore operations. DeBeers is investing approximately $5 million per year on sea prospecting activities and currently operates three vessels in offshore recovery operations. Diamonds recovered at sea will remain a small percentage of total production because of huge land-based reserves that are mined at a fraction of the cost of seabed operations.

Jan 1, 1986

By H. Shimoda, K. Tamaki, K. Iizasa, M. Watanabe, K. Okamura

Modern Kuroko-type deposits occur in submarine calderas of island-arc fronts and back-arc rifts in Japan. They occur primarily on or adjacent to caldera boundary faults. Hydrothermal sulfides in the Myojinsho submarine caldera are one of Kuroko-type deposits, but their occurrence is different from other deposits found within the area 200 km2 around the Quaternary volcanic front of Izu-Ogasawara arc.

Aug 24, 2006

By Johnson R. Cann

Ocean floor sulfide deposits are now known from many parts of the world mid-ocean ridge system and from some seamounts. Clearly they can be expected to occur commonly on the ocean floor. However, only two or three of the known deposits appear to approach the million-ton size, and in none of the deposits has the grade been well-defined. Can knowledge of the processes that happen within the hydrothermal plumbing below deposits help define the conditions under which large, high-grade deposits form? Here I review present knowledge of ocean-floor hydrothermal processes to attempt a first answer to this question. There are three sources of information about these processes. The solutions emerging from active systems must be compatible with patterns of alteration that underlie the volcanogenic sulfide deposits of ophiolite complexes, which are slices of ocean crust thrust onto land. Both of these types of evidence can be linked by computer modelling of the exchange of heat and metals between rocks and flowing water.

Jan 1, 1988

By Peter Halbach

Hydrothermal activity is well known from many locations on most mid-ocean ridges, however no hydrothermally mineralized area had yet been found at the ultraslow spreading southwest Indian Ridge up to October 98 when the Japanese RV Yokosuka with the submersible Shinkai 6500 investigated this area. A massive sulfide field was discovered near 27º51S / 63º56 E in the 11th segment west of the Rodriguez Triple Junction. The Free University of Berlin had joined this cruise and taken over the responsibility for the study of the respective sulfide mineralizations. Hydrothermal minerals were sampled during two dives at water depth of about 2940 m close to the summit of an axial volcanic ridge called Mount Jourdanne. There massive sulfides occur on the seafloor as small smooth mounds with an average area of about 5 m2. Their surfaces are weathered and have a reddish to brownish colour. In addition to these mound-like structures, small tube-like chimneys were observed. These chimneys rise approximately 30 to 40 cm above the floor and are less than 10 cm in diameter. No indications of hydrothermal fauna could be detected. All the hydrothermal features are spatially related to faults and smaller fissures controlled by an E-W trending graben system crossing the summit region of the submarine volcano. Such tectonized areas are generally considered to be ideal for hydrothermal activity because they may have both a magmatic heat source in the deeper underground and pathways for fluid circulation, respectively.

Jan 1, 2001

By Ning Yang, Sup Hong

INTRODUCTION Metal components contained in deep-seabed mineral resources are being highlighted as “energy metals”, which are widely utilized in the entire fields of energy: harvesting and generation, storage and transportation, and saving. Those are mostly trace and rare metals, and rare earth elements as well: manganese, nickel, cobalt, copper, molybdenum, tellurium, selenium, platinum, etc. Toward low carbon society, for global sustainability, the role of metals and minerals is growing up in industries of energy and transportation [1]. In this context, the production and supply of energy metals from deep seafloor have to be approached also based on sustainable development. In deep-seabed mining activity, the sustainability is focused on potential impacts on ecosystems in benthic area and water column. The environmental impacts in deep-seabed mining are caused basically by intervention in benthic zones and transportation of materials. Those are, in particular, removal of benthic habitats, generation and dispersion of sediment plumes, surface transportation of seawater and sediment, tailing from mining vessel, sound and light noises, and chemical leakage, etc. This paper is aiming at fundamental guidance towards sustainable mining of polymetallic nodules.

Jan 1, 2018

By M. Ye. Melnikov

The report is about oceanic ferromanganese crusts ? covers of iron and manganese hydroxides developed over an opened rock of seamounts and rises. Ore bed parameters of crusts are understandable as their thickness and content of main economic components ? manganese, cobalt and nickel. All known results of research activity on ferromanganese manganese crusts point to that crust are characterized by notable variability of thicknesses and composition. It is possible to separate few levels of variability. The most evident is the first level of parameters variability, which is manifested in various regions of the Ocean, and connected first of all, with an age of submarine mountains, a host objects for a crusts. It was proved by many authors, that most powerful crusts are connected with submarine mountains of Cretaceous age. [1]. Crust thickness at the Magellan Seamounts reaches, for example 12-15 cm, sometimes exceeds 20-22 cm. Thicknesses of Hawaii Archipelago or Tuamotu crusts in 3-4 times less. Biostratigraphy studies of crustal sections at the Magellan Seamounts already show, that its main part started to form in the Late Paleocene. Four layers with well expressed features in structure and composition of a layer are separated in the section. From foot to top: Late Paleocene ? Early Eocene layer I-1, Middle-Late-Eocene layer I-2, Miocene layer II and Pliocene ? Quaternary layer III. Relics of more ancient Campanian ? Maastrichtian ore layer [2, 4] were discovered. It is evident for example, that Oligocene mountains could not be a host for two lower layers in the crust section.

Jan 1, 2010

By M. Ye. Melnikov

The report is about oceanic ferromanganese crusts ? covers of iron and manganese hydroxides developed over an opened rock of seamounts and rises. Ore bed parameters of crusts are understandable as their thickness and content of main economic components ? manganese, cobalt and nickel. All known results of research activity on ferromanganese manganese crusts point to that crust are characterized by notable variability of thicknesses and composition. It is possible to separate few levels of variability. The most evident is the first level of parameters variability, which is manifested in various regions of the Ocean, and connected first of all, with an age of submarine mountains, a host objects for a crusts. It was proved by many authors, that most powerful crusts are connected with submarine mountains of Cretaceous age. [1]. Crust thickness at the Magellan Seamounts reaches, for example 12-15 cm, sometimes exceeds 20-22 cm. Thicknesses of Hawaii Archipelago or Tuamotu crusts in 3-4 times less. Biostratigraphy studies of crustal sections at the Magellan Seamounts already show, that its main part started to form in the Late Paleocene. Four layers with well expressed features in structure and composition of a layer are separated in the section. From foot to top: Late Paleocene ? Early Eocene layer I-1, Middle-Late-Eocene layer I-2, Miocene layer II and Pliocene ? Quaternary layer III. Relics of more ancient Campanian ? Maastrichtian ore layer [2, 4] were discovered. It is evident for example, that Oligocene mountains could not be a host for two lower layers in the crust section.

Jan 1, 2010