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By K. Ski

Three series of membranes were prepared by blending polyvinylidene difluoride (PVDF) or poly(vinylidene difluoride-co-hexafluoropropylene) [P(VDF/HFP)] with sulfonated poly(ether ether ketone) (S-PEEK), sulfonated polysulfone (SPU), or sulfonated polystyrene, in order to develop novel PEM membranes suitable for melt processing. By means of incorporating fluorine-containing block copolymer into the blended system, acceptable proton conductivity and low water containing PEM materials were prepared. The effect of sulfonated poly([vinylidene difluoride-co¬hexafluoropropylene]-b-styrene) block copolymers as compatiblizers was investigated: conductivity was enhanced for S-PEEK/fluoropolymer blends. Microstructures for the blends were examined by transmission electron microscope (TEM) and scanning electron microscope (SEM).

Jan 1, 2005

By C. G. Anderson

With demand and prices for copper and gold at near record high levels, coupled with a lack of readily treated orebodies, the emergence of environmentally sound hydrometallurgical treatment of enargite concentrates has become a priority. This paper will outline the application the industrially proven technologies of low pressure and temperature NSC (Nitrogen Species Catalyzed) pressure leaching and ASL (Alkaline Sulfide Leaching) for the recovery of copper and gold from enargite. Copper can be recovered as cathode metal or as a clean concentrate suitable for smelting. Gold is recovered by smelting, conventional cyanidation or alkaline sulfide hydrometallurgy. Coupled with this is the effective precipitation and stabilization of arsenic as scorodite and ferrihydrite.

Jan 1, 2007

By T. Yalcin

"This paper describes a process that can provide high rates of dewatering and that has the potential of bringing significant savings in tailing disposal costs. It involves a three-stage, closed-circuit operation employing a hydrocyclone, a settling cone and a thickener. The mill tailing, with adjusted pulp density, is first fed to the hydrocyclone. The underflow from the hydrocyclone goes to the settling cone for further dewatering. The overflows from the hydrocyclone and the settling cone are sent to a thickener which, with the addition of a flocculant, gives a clear liquid effluent and a dilute underflow which is recycled back to the hydrocyclone. The underflow of the settling cone is a material with as high as 78% pulp density and is suitable for direct disposal or for use as mine backfill.INTRODUCTIONDewatering is an essential process for the disposal of mill tailings and forms an additional cost item in milling operations. Cost-cutting measures are therefore desirable in this area as in any other stage of milling. One way of achieving this is through increased rate of dewatering which would require smaller dewatering units with correspondingly lower capital and operating costs."

Jan 1, 1987

By Bruce C. Smart

"Very little attention was given to the regulation of uranium mills by the Atomic Energy Control Board prior to 1974. The ore grade treated by Canadian mills in the past was in the order of 0.08 - 0.3% U and it was not difficult to keep the exposure of workers well below regulatory limits. Furthermore, uranium milling has also been substantially free of occupational illness because environmental control has been generally satisfactory (l).The discovery of higher grade ore bodies in Canada has resulted in higher radiation levels in one mill and this has partly contributed to a need for increased radiation monitoring in the mill. In addition, as greater insight is gained on the effects of radiation, the implementation of the ALARA principle is being stressed at all mills.The concept of ALARA was emphasized by the ICRP (International Committee for Radiological Protection) in 1977 and stands for '""as low as reasonably achievable'"". It is based on the premise that no proven threshold for potential effects of radiation exists and that the actual individual exposure should therefore be kept as far below the regulatory limit as possible, economic and social factors being taken into account."

Jan 1, 1982

By Tim Bekhuys

Equator Principles ? Applies to projects > $10 million ? Voluntary agreement between 58+ EPFIs ? Categorized projects based on environmental risk, consequences ? Requirements for EA, EMP, use of safeguard policies, consultation ? IFC Performance Standards on Social and Environmental Sustainability ? Apply if the project is in a low or lower-middle income country ? Low-middle income countries defined by the World Bank Development Indicators Database

May 1, 2008

By M. Moats

World copper refining tankhouse practices have been surveyed. This survey is a supplement to previous surveys that have been carried out in the 1987, 1991, 1995, 1999, 2001 and 2003. On a world basis, process technology trends include the further installation of automated electrode handling systems including permanent cathode systems, automatic anode preparation and cathode handling machines, section switches, fully automatic cranes and polymer concrete cells. General plant process control has increased with more automation of material handling in the copper refining tankhouse. The general trend for most greenfield copper refining projects remains in eastern Asia.

Jan 1, 2007

"At the May 15, 2006 and the May 1, 2007 Canadian Securities Administrators (CSA) Canadian Institute of Mining, Metallurgy and Petroleum (CIM) meetings in Vancouver and Montreal, CSA requested CIM consider certain issues arising out of the CSA review of Technical Reports and public disclosure, in general, regarding the practice of estimation and reporting of Mineral Resources and Mineral Reserves. The following is a summary of the issues raised by the CSA and the responses of the CIM.Preamble: At the May 15, 2006 and the May 1, 2007 Canadian Securities Administrators (CSA)-Canadian Institute of Mining, Metallurgy and Petroleum (CIM) meetings in Vancouver and Montreal, CSA requested CIM consider certain issues arising out of the CSA review of Technical Reports and public disclosure, in general, regarding the practice of estimation and reporting of Mineral Resources and Mineral Reserves. The following is a summary of the issues raised by the CSA and the responses of the CIM Reserve Definition and the CIM Estimation Best Practices Committees (the Committees). This information is intended to provide the Qualified Person (QP) with further guidance when estimating Mineral Resources and Mineral Reserves and in preparing a technical report written under National Instrument 43-101 (NI 43-101). Several members of the CIM Reserve Definition Committee, the CIM Estimation Best Practices Committee and some members of the Committee for Mineral Resources International Reporting Standards have reviewed these issues and provide the following commentary.Issue 1. - CSA requested CIM review and comment on the selection of an appropriate commodity price to be used in Mineral Resources and Mineral Reserves estimates.Commodity prices are used in the estimation of Mineral Resources and Mineral Reserves and in the economic analysis of a property. In times of rapidly changing commodity prices, or when prices are at the extreme ends of a commodity price cycle, the QP has a difficult job in selecting an appropriate commodity price.• The selection of appropriate technical variables, including commodity price, is clearly the responsibility of the Qualified Person (QP). The QP must describe the reasons for selecting these variables, including price, in the technical report.• The definition of a ""Mineral Resource"" contains the wording ""reasonable prospects for economic extraction,"" therefore, a QP must select economic parameters, including commodity price, that will result in an estimate of Mineral Resources and Mineral Reserves that have ""reasonable prospects for economic extraction""."

Jan 1, 2003

By J. D. Templeton

A petroleum well that is not in use because it has ceased to produce oil/gas economically and dry holes are referred to as abandoned wells. Once a well is abandoned it is plugged with cement and can take anywhere from two days up to a week to cure depending on the number of plugs in the well. Since plugging a well costs capital, most wells are abandoned at the lowest possible cost and with the minimum obligations set by regulation agencies. These wells can present an enduring liability to petroleum companies. However, the depth and abundance of abandoned petroleum wells makes them an economically attractive source of geothermal energy. Geothermal energy harvested from an oil/gas well is a renewable energy source as long as it is extracted in a sustainable manner. The energy can be used to generate electricity, used directly for heating, incorporated into a water desalination process, or used by a heat pump for heating/cooling applications. In this paper we examine the possibility of extracting geothermal energy from abandoned oil/gas wells by studying the heat transfer in underground geothermal heat exchangers installed in these wells. The design configurations for the geothermal heat exchangers embedded inside a petroleum borehole can be a u-tube design or a shell and tube design (i.e. double pipe). Using in-situ gathered information from some representative petroleum boreholes, the effects of key parameters such as geothermal gradient, ground temperature values, and the flow inside of the tubes are evaluated. In order to provide a constant power production the inlet temperature can be adjusted to keep the difference between outlet and inlet temperatures equivalent. Higher differences between inflow and outflow temperatures will result in a less sustainable load put on the in-situ geothermal energy. Adding insulation to certain sections of the designs can minimize the transfer of thermal energy from the fluid to the surroundings. Insulation can also limit the thermal loss between the inflow and outflow tubes in the shell and tube design. Minimizing the energy loss of these designs leads to an increase in the outlet temperature, meaning a higher grade of heat. The sustainability of long term geothermal heat extraction is a balance between the rate at which geothermal energy is extracted and the rate at which the ground formation can replace this heat. Higher outlet temperatures can lead to a larger amount of power generation, and a higher coefficient of performance for heat pump applications.

Aug 1, 2013

By G. E. Agar, R. Stratton-Crawley

"The applicability of a hydrocyclone model to simulation of the cyclone banks in a multi-stage sandplant circuit producing mine back fill has been demonstrated. The model ha~; been used in conjunction with a modular computer program for circuit simulation in order to study the effect of changes in the operating conditions. It has been shown that weight recovery to sand fill increases as feed percent solids decreases, and, to a lesser extent as pressure drop across the banks increases. An increase in apex diameter also causes an increase in weight recovery. Increased weight recovery must, however, be balanced against sump an1l cyclone capacity and dilution of sand fill by fines. The predicted results from circuit simulation were in good agreement with plant data.The model has been found to be applicable to widely different ores."

Jan 1, 1979

By Carlos Antônio de Morais, Renata Dias Abreu

The present work describes a study of the separation of terbium and dysprosium from heavy RE concentrate through a solvent extraction circuit in a counter-current system. As the efficiency of the REE extraction by acid extractants rises with the increase of the atomic number of the element, the aim of this work is to extract the elements with higher atomic number maintaining Tb and Dy in the aqueous phase. Thus, terbium was separated first with subsequent separation of dysprosium. The experiments were carried out by using IONQUEST®801 as the extractant and a REE-hydrochloric liquor as feed solution. The optimum operational circuit in terbium separation was comprised of 37 stages: extraction, scrubbing, stripping, and solvent washing. For the dysprosium separation 39 stages were required. Terbium separation over 92% with over 95% purity and a Dy separation over 97% with over 95% purity were obtained.

Jan 1, 2014

By Cheryl L. Allen

Increasing energy costs associated with mining have become an issue that must be addressed by industry to ensure sustainable production. As underground mine ventilation systems account for 40% to 50% of a mine?s total energy requirement, initiatives to maximize their efficiency have been introduced worldwide. A control method known as Ventilation-On-Demand (VOD), which adjusts the ventilation system by responding to the activities of mine personnel and air quality, has been commissioned at Vale?s Coleman Mine. This initiative is an effort to reduce energy consumption, maximize efficiency of the ventilation system while ensuring air quality. There are five control strategies that can be executed with the VOD control system in place at Coleman Mine: Manual real time control Time-of-Day Scheduling Event-based control Environmental control Activity Based Control/Tagging This paper describes the system, control strategies and impact on energy consumption and flexibility of airflow distribution as applied at Vale?s Coleman Mine.

May 1, 2011

By K-A. Adamson

If fuel cells and hydrogen are to become a mass market reality a substantial amount of further research and development needs to be undertaken. Work in hydrogen storage, production, the economics of all aspects of fuel cells and hydrogen, materials balances, and product integration are just a few of the areas that are under focus. Setting R&D targets, and providing R&D funding are therefore areas that are central to the long term development of the market, and areas in which a number of governments worldwide are highly active. Some governments, such as Japan and Korea, have set a number of very ambitious, highly focused, long term targets and are backing this up with substantial funding, others such as the EU are working on a more integrated approach, wrapping some fairly fundamental R&D into large integrated projects which run in combination with a number of other market aspects, such as public acceptance and roadmapping. The US is slightly different, in that although is has a number of long term programmes and targets, FreedomCar and SuperGen being just two, the levels of funding are set annually with the passing of each years Fiscal Budget. This paper takes three high profile regions and analyses the R&D targets and funding levels for fuel cells and hydrogen. Criteria that will be looked at include: Time frame of target(s), level of ambition, funding issues, including: Funding windows, levels available, funding barriers, overall programme goals. The added value to this paper is that it will provide a clearer picture of where each region is heading, what are its strengths and weaknesses, in terms of R&D and where there may be areas for potential international collaboration.

Jan 1, 2005

By Yuwang Wang, Yanggeng Tan, Kezhang Qin, Zengqian Hou

Abstract- The large Derni Cu-Co (-Zn) deposit in Qinghai Province exhibits unusual geological features, and its genesis is controversial. Based on previous research and detailed field investigations, petrographic studies of the host volcanic rocks, isotope and trace element geochemistry of the sulfide ore, and comparison with typical ore deposits, this deposit is a VHMS (submarine volcanichosted massive sulfide deposit) type. This argues against previous interpretations of a magmatic or a hydrothermal replacement origin. Systematic rock, mineral and geochemical studies of the host serpentinites of the ore district indicate that the protoliths of several types of serpentinites that are widespread in the ore district are mainly ultramafic volcanic rocks. The mineralization formed within an ultramafic volcanic breccia, or between the breccia and its overlying Mg-rich carbonate rocks and volcanic sedimentary rocks. The ore-forming components were derived mainly from ultramafic rocks and partly from mafic rocks. The ultramafic rocks are MgO-rich, CaO-poor with a high MgO/FeO ratio, and the mafic rocks are rich in Na2O and poor in K2O. The chemical composition of the ultramafic rocks is similar to that of volcanic peridotite, or komatiite. The volcanic rocks that host the Derni deposit are among the most basic host rocks known for VHMS deposits, and the Derni deposit represents the most basic member in the VHMS deposit spectrum.

Jan 1, 2000

By P. J. Deveaux, M. J. Kreczmer

The Tartan Lake deposit 12 km northeast of Flin Flon, Manitoba, was discovered in March of 1984 during the investigation of a VLF anomaly. The discovery hole intersected 16.83 metres averaging 21 gm Au/tonne. Since then, 99 holes, over 21,000 metres, have been drilled outlining 419,491 tonnes grading 11.79 gm Au/tonne in a di stinct group of mineralized lenses referred to as the Main Zone. Three other mineralized zones are known on the property but no reserves have been allowed for these, the South , East and Base Line zones. The Main Zone consists of seven parallel, east-west striking, quartz lenses. The lenses dip steeply to the north and plunge steeply west to northwest. Lens number l strikes for 160m and extends vertically to the 90m level. Within th is lens there is a 60m interval of low grade materi al. Lens number 2 is located about 5-l0m within the foo twall of Lens number I. Near surface this lens stri kes for 40m, at 200m level the strike length increases to 200 m. To date the deepest mineralization on Lens 2 has been intersected at a vert ical depth of 527m. Five smaller lenses are located in the foo twall of Lens 2 , containing gold va lues similar to the two main lenses but erratically distributed. The South Zone, located 100m south of the Main Zone, strikes east-west fo r l00m above the 100m level. The East Zone, found 230m east of the Main Zone, strikes fo r 80m and may possibly be an ex tension of the South Zone. The Base Line Zone is located 275m south of the Main Zone. Sporadic, but very significant gold intersections have been obta ined1n all three zones. Gold-bearing quartz-ca rbonate tourmaline veins are generally confined to a silicous crystal tu ff hori zon. The crystal tuff exhi bits fi ve distinct types of alteration: silicification, sericitization, ca rbonati zation, chlorit ization and pyritization. Silicification has resulted in a perasive addition of silica and the generation of multiple quartz veins. Sericiti zation is restricted to the crystal tuff. All rock units are pervasively carbonatized . Ankerite is abundant in the quartz veins and within the shear zones, particul arly those located along the chilled margin of a nearby gabbro-diorite intrusion. Chloritization is widely spread th roughout the rock units, while pyritization fo rms a broad alteration halo associated with the orebody. Sulphide accesso ry minerals associated with the gold , whi ch fo r the most part appears to be free, are chalcopyrite and pyrite. Generally, the higher grade gold values are related to an increased content of sulphides in the qua rtz veins. The average sulphide content in the deposit is less than 5 %.

Jan 1, 1986

By Arne Renström

A fleet management system such as Minestar with CAES and Aquila could basically be defined as a tool for production control and distribution of drill and load maps, but should also be considered as continuous improvements and a never ending production study. The objective of production studies is to establish facts to be used for production improvements. In a mine operation there are many issues to improve and they spread from achieving productions plans, drilling precision, improved spotting while loading to equipment utilisation. This gives that there is not one single key value to present; we need to manage information presented on maps, as trends, graphs, tables and pre-calculated data for ?free-use? normally in spread-sheets to be able to turn data into useful information.

May 1, 2003

By Michael J. Beare

Requirements of both local permitting and international fundraising are forcing increasing numbers of projects in Russia and CIS to carry out dual technical studies. The principal focus of Russian mining project design is to satisfy local regulatory requirements. However, the technical documents are not generally accepted by international banks for project finance outside Russia. Similarly, international study documents are not accepted for permitting in Russia. The purpose of this paper is to compare and contrast Russian and international approaches to mine technical studies and draw conclusions from this. The Russian design and permitting system is centered around two key statutory technical documents termed the TEO Konditsy and the TEO Project. These documents are subject to regulatory approval and are broadly equivalent to the international prefeasibility study and the feasibility study respectively. A comparison of study criteria suggests similar approaches are used for the main technical disciplines in project design by the time projects are at the point of construction, but there is divergence on environmental matters where the OVOS (Russian ESIA equivalent) differs from an ESIA in some significant areas. The key differences relate to project footprint, level of technical detailed required for baseline studies, level of public consultation, consideration and disclosure of information, labour, coverage of community and social issues and the preparation of a Social and Environmental Management System (SEMS). It has been noted that the Russian Design Institutes often leave the detailed economic analysis until after the TEO Konditsy. A common problem is design teams tend to look for ?technological solutions? without due concern for project economics. The end result of this can be mines that are overcapitalized and hence sub-optimal. It can be concluded that Design Institutes have the monopoly on Russian permitting reports and this is likely to continue. Similarly, Russian institutes generally do not prepare feasibility studies to international standards and this is likely to continue to be the case. Therefore to achieve the requirement of dual technical studies, the international consultants and Russian Design Institutes will need to cooperate on a joint work program. Key issues will be to ensure the most appropriate option studies are carried out at the right stages, that project economics are considered throughout the study, and that the environmental work program covers the additional studies necessary for the ESIA.

May 1, 2009

By W. Grell

"In this paper, two methods of standardizing mill language are proposed; one is based on metric units and the other on English units. Tentative procedures for chemical and screen analysis based on published methods are proposed.Standard procedures for determining work index, and for leaching, flotation, and classification tests are outlined.Objects of Standardization:(1) to improve communication -(a) among gold metallurgists(b) with other branches of mineral dressing(c) with mineral dressing in other countries(d) with general scientific procedure(2) to improve mill control by -(a) standard methods of analysis (i)(ii)(iii)(b) standard methods of calcula tiort(c) standard accounting proceduresin the plantin the mill laboratoryin the assay office(3) to improve mill test work and investigationAreas of Standardization(1) Nomenclature or terminology(2) Measuring techniques(3) Test procedures(4) Accounting procedures"

Jan 1, 1966

By Daniel B. Leznoff

The cyanoaurate anions [Au(CN)2]- and [Au(CN)4]- are shown to be useful building blocks for synthesizing supramolecular coordination polymers. For the gold(I) unit, aurophilic interactions often increase the structural dimensionality of the system and can impart increased thermal stability to the metal-polymers produced. A series of polymers of the form M[Au(CN)2]2(Ligand)x have also been prepared and show large colour changes upon changing the ligand, thus illustrating a sensor-type application. Both building blocks can mediate significant antiferromagnetic and ferromagnetic interactions between transition-metal centres in the polymers. For the gold(III) unit, no metal-metal interactions are observed, although weak Au-N(cyano) interactions control the intermolecular packing. Several structural examples of cyanoaurate-based coordination polymers are presented, including 2-D and 3-D arrays and a supramolecular square.

Oct 1, 2003

By Leibniz University, D. Zapf

"The demand for gas storage operations with high withdrawal rates and operation modes different to a seasonal storage regime requires a more detailed rock mechanical consideration of thermal induced stresses in the vicinity of the caverns. This means that the change of gas temperatures during operation and the consequences of these temperature changes on the stressing of the salt rock mass must be taken into account in the rock mechanical dimensioning. Within the rock mechanical calculations a loading history, i.e. a pressure versus time dependency, has to be defined. As rock salt has a time dependent material behavior stress redistributions in the rock salt mass take place even under constant internal pressure conditions. Therefore not only withdrawal and filling periods but also the duration of phases with nearly constant internal pressure is significant for the resulting state variables. Within the paper the differences and consequences for the rock mechanical recommendations are discussed. As a result it can be concluded that recommendations with respect to minimum operation pressure as well as for maximum withdrawal rates can be answered only in connection with the respective time intervals."

Jan 1, 2015

By N. Hiroyoshi

In the leaching of chalcopyrite with sulfuric acid solutions, the copper extraction rate reaches a maximum at a given redox potential. This article reviews our studies on the determination of the optimum redox potential for chalcopyrite leaching. Shaking flask and column leaching experiments for a chalcopyrite concentrate were performed under various conditions, and the results were analyzed using a normalized redox potential defined from a reaction model assuming the formation of an intermediate CU2S from chalcopyrite. Factors, such as metal ion concentrations, solid/liquid ratio, and presence of iron-oxidizing bacteria, caused significant variations in the copper extraction versus time plots. However the copper extraction rate versus normalized redox potential plots were independent of the above factors and the copper extraction rate reached a maximum at the normalized redox potentials around 0.43. Converting the normalized redox potential to the solution redox potential gives the optimum redox potential for chalcopyrite leaching as a function of cupric and ferrous ion concentrations. This semi-empirical equation can be used to predict the optimum redox potential during leaching operation, and is useful to design the redox-controlled heap leaching for chalcopyrite.

Jan 1, 2007