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By Erica J. Wanless, Ghislain Bournival, Seher Ata, Jose Hamilton Tavares

In froth flotation valuable particles are captured by bubbles and transferred to a froth layer where bubbles are in close proximity. Bubble coalescence frequently occurs in flotation, especially in the froth layer. The coalescence of two bubbles causes a release of energy, which may expel particles from the bubble surface. A series of experiments were carried out to determine the effect of bubble interfacial properties on the detachment of particles upon the coalescence of capillary-held bubbles of 2 mm in size. The interfacial properties of the bubbles were changed by the addition of low molecular weight alcohols, namely 1-pentanol or methyl isobutyl carbinol (MIBC). Using esterified glass particles (? = 43 °) with a 10 % and 90 % cumulative passing diameter of 47.2 and 92.5 µm, respectively, as model particles, it was found a certain concentration of frother, different for each additive, is needed in order to observe a reduction in the detachment of particles. In the presence of frother, the detachment was evaluated at approximately 65 % which was a considerable reduction in the detachment compared with the value of approximately 85 % found in the absence of frother. Frother molecules changed the properties of the airwater interface. Upon the coalescence of two bubbles, the release of energy caused the merged bubble to oscillate; effectively resulting in the detachment of particles. The addition of frothing agents augmented the elasticity of the bubbles, which appeared to be related to the detachment of particles. Whereas frothing agents are generally used to prevent bubble coalescence and stabilise the froth phase, only transient stability is imparted. The results suggested that an additional role of frothers in flotation is to decrease the detachment of particles from bubble surfaces. The type and concentration of frother can be strategically selected to improve metallurgical recovery as an economic incentive.

Jan 1, 2016

By I. Osvath, I. Gombköto, G. Mucsi, Z. Molnár

"In the present research, a deposited brown coal fly ash was used as raw material for geopolymer. The reactivity of the fly ash was altered using mechanical activation, which is one of the promising methods to improve bulk and surface reactivity. The mechanical activation experiments were carried out in a high energy density mill using 5 m/s circumferential speed, and various residence times (1, 3, 5, 10, 15 and 60 min). The effect of mechanical activation on particle size distribution was measured by a laser particle size analyzer and structural changes using FT-IR. Geopolymer samples were prepared from mechanically activated fly ash with an alkali solution. The progress of geopolymerisation was monitored using an Isothermal Conduction Calorimeter. The heat flow curve obtained indicated that reactions were more prominent and started much earlier in the mechanically activated samples. This observation is further supported by the compressive strength results which also improved in geopolymers using mechanically activated fly ash. Based on the obtained results, it can be inferred that mechanical activation is a possible way to enhance the reactivity of fly ash and consequently properties of resulting geopolymers.INTRODUCTIONCoal fired power plants generate fly ash and slag in huge amount worldwide, about 780 million tons/year (Heidrich et al. 2013). Due to the relatively low utilization rate, enormous quantities of these wastes are landfilled in ponds. The fly ash is the finest grained particle fraction of the solid ash, which is transported with flue gas, and removed by electrostatic or bag filters. The fly ash has pozzolanic activity, it does not react with water, but in the presence of calcium hydroxide solution hardens and solidifies, producing a reaction product practically insoluble in water (Opoczky, 2001). The most important property of the fly ash regarding geopolymerization is its reactivity, which depends on the chemical and phase composition, the dispersity (specific surface area, particle size distribution), and the morphology of the fly ash particles, and determined by the physical properties and chemical composition of the fly ash. Geopolymers concerning their chemical structure are polysialates, where the sialate (silicon-oxoaluminate) network is built up from the bonds of Si-oxide and Al-oxide by sharing oxygen atoms (Davidovits, 1988)."

Jan 1, 2016

By H. Yasuhara, N. Kinoshita, S. Nakashima, K. Kishida

"In this study, flow-through experiments in fractured rocks have been conducted under different stress, temperature, and pH conditions so as to understand the evolution of permeability induced by these conditions. Throughout the experiments, the confining pressures and temperatures are well-controlled. Effluent concentrations are also measured for the ten elements of Si, Al, K, Fe, Ca, Na, Mg, Ti, S, and Cl that are included mainly in the targeted rocks. In the early stage of the experiments, the fracture permeability measured abruptly decreases with time, and subsequently reaches quasi-steady state within a relatively short period. In contrast, the permeability in the intact rocks monotonically increases with time. The permeability increase and decrease are attributed likely to the relative dominance of mineral dissolution in the pore spaces and to that of mineral dissolution/crushing at the propping asperities within the fracture and/or mineral precipitation onto the free surfaces, respectively. The evolving rates and magnitudes of the permeability are likely to be controlled by the stress exerted over the contacting asperities, temperatures, and pH of the permeant. Thus, this complicated behavior should be attributed to the coupled chemically- and mechanically-induced effects, which should be examined in more detail for longer period to contribute to the safe entombment of radioactive wastes. INTRODUCTIONUnderstanding of the flow and transport characteristics of porous/fractured rocks is required for the safe and long-term geological isolation of energy-related by-products (i.e., high level radioactive wastes and anthropogenic CO2). Notably, under relatively high temperature and stress conditions, mechanically- and chemically-mediated processes may alter the pore structures in rocks, resulting in an irreversible evolution of the flow and transport behavior. Augmentation in permeability may result from mechanical dilation due to shearing and mineral dissolution within the pore spaces, while reduction may result from reversible or irreversible mechanical compaction, mineral dissolution at the contacting areas, and clogging of pore spaces by precipitation of secondary minerals."

Jan 1, 2015

By B. L. Dorey

"Performance management is a systematic, practical approach to managing people. It is founded on some basic assumptions about people and is designed to focus on people in the work place. Organizing meaningful information and using it to involve people is a cornerstone of this system.Some common sense practices are developed to involve people in an organization's effort to improve performance. The successful implementation of this program requires solid commitment and total involvement from all levels of supervision and employees for maximum results and lasting impact. All levels of supervision participate in training sessions to tailor the systems for implementation in their areas. This style of management is data-oriented and the bottom line of success is to measurably improve performance. Basic Assumptions about PeopleMost people in an organization, regardless of level, take pride in their work and generally want to do a good job. When performance falls off, there is usually some explanation other than the employee not really caring. People like to know their exact responsibilities and clearly what is expected of them. People like to know where they stand with the boss and would like to be evaluated on what they do and accomplish, rather than on what others think or feel about them. Further, people like to be rewarded for their good results, indeed, to understand what motivates people, we must look at what happens as a result of their actions. Another belief is that supervisors often have a greater influence on the performance of their people than they fully realize. Simply letting people know how important their performance is can have an impact. The Key ElementsGiven these basic assumptions and beliefs about people, some common sense practices have been systematically developed to manage more effectively."

Jan 1, 1989

By K Byrne, W. Hawker

The average grade of copper concentrate is steadily declining, forcing the industry to turn to lower grade and metallurgically challenging orebodies. When faced with a low grade, challenging ore, mining companies are often forced to choose between high recovery at low grade or low recovery at high grade. Hydrometallurgical processing of copper concentrates using metathesis reactions, which replace iron with copper in copper-iron sulphide minerals and increase the copper to sulphur ratio in copper sulphide minerals, provide an opportunity to upgrade copper concentrates and potentially allow high copper recovery for a high grade concentrate. Factors such as concentrate mineralogy, reaction time and temperature, and the concentrations of copper, chloride and acid in solution are reported to affect the reaction extent and mineral phases formed by metathesis. In this paper, a copper concentrate has been studied over a wide range of conditions to investigate the influence of these key parameters on the extent of copper metathesis reactions and product phases formed. Solution and solid phases are assayed with the main mineral phases identified by Quantitative X-Ray Diffraction. INTRODUCTION The minerals present in copper deposits determine the prospective processing options either: pyrometallurgical or hydrometallurgical. For copper oxide ores, copper is typically present as oxides, carbonate, chlorides, silicates and sulphates. These minerals are readily solubilised in acid and are usually treated through hydrometallurgical processes. The typical process route for copper oxides is to leach copper into aqueous solution, purify and upgrade the solution phase through solvent extraction and then recover copper as metal by electrowinning (Davenport, King, Schlesinger, & Biswas, 2002). Copper sulphide deposits may contain a multitude of copper bearing minerals, including chalcopyrite, bornite, enargite, covellite, digenite and chalcocite. The copper ore grade and treatment options are affected by the mineral type and distribution. Sulphide ores are typically treated through comminution and mineral flotation to form concentrates, followed by pyrometallurgical smelting. Hydrometallurgy can also be used to process sulphides depending on the mineralogy and impurity levels (Davenport et al., 2002). The trend of decreasing copper grade with increasing impurity levels are common across the mining industry and pose future challenges to copper processing. This trend has prompted research into hydrometallurgical options for upgrading copper concentrates. One promising hydrometallurgical option is using metathesis reactions. Metathesis reactions, sometimes also called double replacement or displacement reactions, are chemical processes involving the exchange of bonds between two chemical compounds or species. In this case, the metathesis reactions involve copper in solution exchanging with cations in the solid sulphide concentrate. The driving force for copper sulphide metathesis is the relative affinity of the exchanging cation elements for sulphide. Based on sulphide precipitation diagrams, the expected order of affinity for sulphide should be Hg2+ > Ag+ > Cu+ > Cu2+ > Bi3+ > Cd2+ > Pb2+ > Sn2+ > Zn2+ > Co2+ > Ni2+ > Fe2+ > Mn2+ (Monhemius, 1977). Hence, copper metathesis reactions are capable of increasing copper content and removing impurities such as iron, nickel, zinc and lead from copper concentrates.

Jan 1, 2019

By W. S. (Steve) Vaughan

The Origins of Joint Ventures in Canada?s Mining Industry ? Among the most important financing structures used in our mineral industry today ? Virtually unheard of in the Canadian industry prior to the 1970s ? Borrowed from the U.S. oil and gas sector where it came into prominence in the late 1930s ? The Securities Acts of 1933 and 1934 in effect killed the sale of (equity) shares for financing oil and gas wells and start up mining companies

May 1, 2013

By J. Y. Kim, Kenneth Stowe, Stephen Chryssoulis

"A series of flotation tests was carried out on Brunswick Mining ore with various pH modifiers (soda ash, lime, KOH) and added ions (ferric, nitrate, sulphate) in the copper lead rougher circuit. The main objective was to identify downstream effects on sphalerite activation and subsequent zinc rougher flotation. Some significant differences in zinc flotation were obtained. Most notably, soda ash and nitrate ions had a positive impact and ferric ions a pronounced negative effect on selectivity.Selected products from the flotation tests were deslimed at 400 mesh, washed with methanol, air dried, placed in teflon vials purged with nitrogen and stored at -15 degrees C. Numerous liberated sphalerite and pyrite particles were selected under a stereoscope and placed in rows on indium foil. The surface compositions of the particles were analyzed with an innovative laser probe (LIMS). The very small analysis area of the LIMS enables the surfaces of individual grains to be characterized. In addition, the rapid analysis time allows a statistically significant number of grains to be analyzed quickly.Surface lead appears to play a major role in zinc activation/flotation. Possible mechanisms are proposed to explain the variations in metallurgical performance at the different test conditions.IntroductionAlthough the bulk composition of mineral grains is an important consideration for the mineral processor it is ultimately surface composition and topography (edges and dislocations preferred sites for reactions) that control reactivity in flotation and cyanidation (passivation, encapsulation and preg-robbing). Determination of the surface properties of particles from process streams poses a particular challenge for the surface chemist for a variety of reasons, including:"

Jan 1, 1994

By L. S. Brooks

TIMBER HANDLING presents a problem for any mine where appreciable amounts are used. This problem is accentuated where the shaft compartments are too small to allow a loaded timber truck to be lowered in the mine cage. When Normetal Mining Corporation, Limited, found it necessary to resort to square-set mining it faced this problem of getting large quantities of timber down a shaft that was also required for hoisting ore. A 'timber car' that could be suspended under the cage was developed to overcome this difficulty. Production started at the Normetal mine in 1937, at the rate of 250 tons per day. In 1938 a winze, known as No. 3 shaft, was sunk from the 800-foot level ?to the 1,385-foot level. This was later raised to surface and then deepened to 3,275 feet in three stages and became the main production shaft. The portion of the mine below the 3,070-foot level is serviced by a winze, locally referred to as No. 4 shaft, which has been developed for stoping down to the 3,990-foot level and which has been deepened to the 5,365-foot level. No. 3 shaft has two hoisting compartments, each 4 ft. 6 in. by 5 ft. 0 in. inside the timbers, through which the ?ore must be hoisted and timber and supplies lowered.

Jan 1, 1956

By H. C. Cooke

"The Eustis mine, which was discovered in 1865, lies about 6 miles southwest of the city of Sherbrooke, Quebec, in lots 2, 3, and 4, range 9, Ascot tp. The mine was operated almost continuously from 1865 to 1937, under vanous owners.The ore was pyrite with varying amounts of chalcopyrite, a small amount of zinc blende and galena, and a low content in gold and silver. Parts of it ran quite high in copper, but the mine average would probably have been between 3 and 4 per cent. The high percentage of pyrite made it profitable to separate the ore into a copper concentrate and a pyrite concentrate. The latter was shipped away for manufacturing sulphuric acid, or was treated in a plant erected in 1887 at Capelton by the Nichols Chemical Company.The ore is a replacement of mica schist, which in turn was formed by the shearing of rhyolite flows. Ore also replaces the 'green rock', a term locally applied to carbonatized mica schists. The ore contained numerous 'horses' and smaller fragments of country rock, in all stages of replacement, ranging from those whose character was quite distinct to those whose ancestry could only be detected by an indefinite banding preserved in the sulphides."

Jan 1, 1954

By José Cáceres

Mine To Mill? ? Carlisle(1954) ?The economic of a fund resource with particular reference to mining?. ? Steine(1978) ?Coarser grind may mean lower metal recovery but higher profit?. ? Metalica (1999) ?Mine Plant Integrated Planning?. ? JK (2002) Mine to Mill Strategic Planning ? Camus, Kelebek (2002) ?Management of Mineral Resources: Creating Value in the Mining Business?. ? Caceres (2003) ?Integrating Milling Parameters in the Mining Planning?

May 1, 2006

By Sarah Bélair, Denis Beltrami, Deka Moussa Ragueh, Valérie Weigel

"Scandium is a highly valuable element belonging to the rare earth elements (REE) but it has different chemical and physical properties from those of lanthanides. This metal is generally used in aluminum-scandium alloys and in fuel cells but the development of its market is slowed down by its high price (more than 1000 US$/kg for a 99.0% grade product). Indeed, the low scandium content in the continental crust (an average of 22 ppm) and the difficulties to extract it selectively from solutions containing high impurity concentrations increase the cost of the recovery processes. Nowadays, scandium is primarily recovered as a byproduct.ERAMET is developing a hydrometallurgical process in Gabon (Mabounié) in which the scandium content in the deposit reaches 10 to 100 ppm. The Maboumine project consists in the extraction and purification of uranium, niobium, tantalum and REE from Mabounié ore. In the frame of this hydrometallurgical project, ERAMET had also studied the feasibility to recover scandium as a byproduct. During the ore leaching, uranium and rare earth elements including scandium are solubilized into the pregnant leach solution (PLS). Among the various methods investigated to recover scandium from the PLS, liquid-liquid extraction using Primene JM-T as extractant was chosen and tested first at laboratory scale and then at pilot scale. Selective stripping of the loaded organic was carried out by using phosphoric acid solution, allowing the selective recovery of scandium from thorium and zirconium partially extracted from the PLS by Primene JM-T under the process conditions."

Jan 1, 2016

By H. Dundar

The first application of High Pressure Grinding Rolls was in 1985 at a cement plant, for the purpose of capacity improvement. Then various circuit configurations were derived to achieve a reduction in overall specific energy consumption, by transferring more of the grinding required to the HPGR. In most circuit configurations, the recycle of fines is required for effective breakage between the rollers. By increasing the fines amount in the feed material to a specific level within the recycling load, a uniform material bed is created and a higher pressure gradient along the roller width is obtained, resulting in compact flakes, including more fines. The fines recycle results in enhancement of the interparticle breakage. This paper will discuss the effect of the feed size distribution on HPGR performance.

Jan 1, 2012

By P. Fleming, W. Pascheto

"Rod mills processing nickel and copper ore experienced recurring failures of liner bolts. In some cases failures became very frequent, requiring constant mill intervention and consequently impacting process stability and operating costs. Investigation related to the causes of bolt failures involved a multidisciplinary approach with the participation of engineering, maintenance and operation. It included the determination of bolt failure mechanisms as well as the assessment of mechanical properties, fabrication quality and handling and installation procedures. In addition, other parameters affecting bolt performance such as mill and liner design, operating parameters and maintenance practices were studied. This paper reports the failure investigation results and proposed solutions for failure prevention. INTRODUCTIONOccasional liner bolt failures are common in rod mills. However, chronic bolt failures developed in rod mills processing nickel and copper ore caused frequent shutdowns for bolt replacement to an extent that affected process stability. At first, it was thought that the cause of recurring failures was related to bolt quality. The operation then submitted several failed bolts to failure analysis. However, it became apparent that bolt quality was unlikely to be the main cause of failures. The determination of root cause (s) then became more complex, requiring a multi-disciplinary approach to failure investigation, requiring the assessment of bolt installation methods, mill design, operating conditions and maintenance practices. The results of the metallurgical failure analysis and investigation of other possible causes of failures are reported here."

Jan 1, 2016

By R. Bruce Graham

"For the purpose of this paper, the Chibougamau area is taken as lying between lats. 49°20’ and 50°10’ N;-longs. 73°45’ and 75°30’ W. It comprises an area of some 4,000 square miles and is centred 300 miles north of Montreal.The first recorded report of metal deposits in Chibougamau was that of James Richardson in 1870-71 (I). In 1903 discoveries of asbestos, copper, iron, and gold made by Peter McKenzie stimulated considerable activity in the district. By 1909 interest had become so marked that considerable pressure was brought to bear on the Quebec Government to build a rail-way into the region. It was finally decided to have an authoritative opinion on its economic possibilities, and the Chibougamau Commission was appointed for this purpose (2). They examined the district in 1910 and concluded that at that time a railway was not warranted. Nevertheless, the district continued to be prospected and from time to· time gold and copper discoveries were made. Thus the Merrill Island deposit was discovered in 1920, the Campbell Chibougamau Cedar Bay deposit in 1922, Obalski in 1928, Opemiska Copper in 1929, and Norbeau in 1930.Difficulty of transportation was a severe detriment to the development of the region. Consequently the Quebec Department of Mines completed a road into Chibougamau in 1949. Further activity was encouraged. The Chibougamau Explorers, Quebec Chibougamau Goldfields, and Kayrand deposits were found in 1950. ** The copper-siderite zones on Copper Cliff ground were found in 1952 and 1953. Opemiska Copper, Campbell Chibougamau Mines, and Chibougamau Explorers were encouraged to prepare for production following favourable exploration results."

Jan 1, 1949

By F. Shi

The JKRBT (JK Rotary Breakage Tester) is a newly developed impact breakage testing device for rapid ore breakage characterisation, and has recently been commercialised after a three year comprehensive validation study, involving five major mining companies and six industrialised JKRBT units deployed worldwide. Comparisons of breakage mechanisms and characterisation data between the JKRBT and the Drop Weight Tester (DWT) indicate that, despite the differences in the breakage modes, the JKRBT can provide statistically similar A*b parameters, by using a data reduction procedure which takes into account the difference in the number of contact points, strain rate and potential for secondary breakage. Feedback from the validation sponsors has indicated higher productivity and better repeatability of the JKRBT compared with the DWT. This better precision, combined with the JKRBT’s wider particle size capability and wider specific energy range, provide a more powerful tool, ideally suited to rapid mapping of ore hardness in geometallurgical and comminution applications.

Jan 1, 2012

By G. W. Brooks

This short article is quite different to the general run of papers that are presented to the Institute, but no apology is offered because I consider that first-aid and mine-rescue work are of equal importance to many other subjects that are dealt with in our Transactions. Members of the Institute should be as much interested in the safety of persons engaged in the mining industry as they are in the practical methods of modern mining. We must not only do our best to conserve life and property by adopting every known device to that end, but we must also prepare ourselves so that we may take prompt and effective action when life is in danger, or when property is subject to loss. The need for such preparation in Alberta is perhaps greater than in most places where mining is carried on, and we must spare no effort to assemble at every mine men who are well trained in first-aid and mine-rescue work. The large area over which the mines are distributed renders central training stations out of the question, hence the need for local rescue-teams. Hospitals with skilled staffs, close enough to the mines to be convenient, also seem to be out of the question; therefore the greater need of a high standard of first-aid training for the people in our mining camps. The Government mine-rescue cars are supplied with the equipment necessary for training persons in this essential work and also for dealing with disasters should they occur. The question then arises: are there a sufficient number of men who are trained ? If so we can rest assured that what is possible to be done will be done. But if a sufficient number of trained men are not available much loss of life and damage to property is likely to result.

Jan 1, 1925

By Curtis Rempel, John Bartlett, Alex Holtzapple

METSIM is a powerful program capable of modelling and simulating every known metallurgical and inorganic chemical process. METSIM is used by companies throughout the world to design, simulate and control operations from mine to tailings and everything in between. At its absolute simplest, METSIM can be used to create a process flowsheet. METSIM modules and built-in unit operations cover mass and energy balances for either steady-state or dynamic simulations of mine, stockpile, heap leach, material handling, comminution, beneficiation, hydrometallurgy, pyrometallurgy, gas and steam handling, and tailings management processes. Data for the material being processed can include mineralogy, particle size analysis, grade by size or multicomponent size analysis, washability data, mechanical, physical and thermodynamic properties. METSIM is written in APL (A Programming Language). Unlike C++, APL is simple and easy to learn, allowing the user to program whatever they can imagine, without first obtaining a degree in computer science. METSIM can also interface with EXCEL and other software through dynamic data exchange (DDE), allowing data to be imported and exported for viewing, analyzing and controlling. METSIM can answer simple or complex metallurgical and process questions allowing the user to predict and engineer without the issues of clumsy and tortuous spreadsheets.

Jan 1, 2014

By P. Woo, N. Brodusch, R. Gauvin, H. Demers

The scanning electron microscope (SEM) was primary developed for imaging applications. With the introduction of the Si(Li) energy dispersive spectrometer (EDS), simultaneous imaging and x-ray microanalysis became possible. However, long working distance and high current were needed because the position and small solid angle of the EDS detector. The high spatial resolution is generally obtained at short working distance with a SEM. Unfortunately x-ray microanalysis is never performed in the best imaging conditions. The annular silicon drift detector system is inserted below the objective lens which gives a higher solid angle (up to 1.3 sr). In consequence, a lower working distance and probe current can be used. An improved spatial resolution becomes possible during x-ray microanalysis. With this x-ray detector installed on a cold-field emission scanning electron microscope, quantitative x-ray microanalysis with high spatial resolution at low beam energy and low current becomes possible with the possibility of using the various different type of imaging at the same time. Also, since the count rate can be as high as 1,500 kcps, which lowers significantly the detection limit of elements as well as the minimum feature sizes of different phases that can be distinguished.

Jan 1, 2014

By W. M. Lupton

"Internal grinding mill entries are routinely done by mill personnel during scheduled maintenance periods. Reasons for entry include mill liner life profiles, liner inspcections and replacement and grinding media investigations. These entries require employees to adhere to safety regulations and policies including special permitting, testing, procedure-following practices and the wearing of proper personal protective equipment.A realized semi-autogenous mill entry safety hazard is the unpredicted breakage and occasional shattering of large diameter grinding media while personnel are inside. This was a concern to both media user and supflier. American Barrick's Holt McDermott Mine has improved mi l operational procedures and the media manufacturer has assisted by their developments to essentially eliminate this problem.This paper presents the improvements instituted; and the author's wish to communicate this potential hazard to other large diameter SAG ball users or potential users.INTRODUCTIONAmerican Barrick' s Holt McDermott mine is situated on Highway 101, some 70 kilometers northeast of Kirkland Lake, Ontario, 120 km east of Timmins and 90 km northwest of Rouyn Noranda, Quebec. The mine draws 160 employees from these surrounding areas to extract and process the underground ore, and recover near 60,000 ounces of gold per year. The mill department is completing it's fifth year of operation this spring.The company and the employees are proud of the safety improvements realized over the short history of the mine. Post accident/incident reviews and pro-active safety awareness programs have substantially reduced the mine's accident frequency and severity to date.One of the mill department's objectives is to provide a safe working environment for mill personnel, which includes the interior of the grinding mills."

Jan 1, 1993

By Dale A. Sketchley

"Abstract - Large differences in gold content between rock fragments or small volumes of unbroken rock, commonly referred to as the nugget effect, are related to sample and subsample weights, crushing and pulverizing sizes, and density, shape and size distribution of gold grains. Gy’s sampling theory, which relates gold grain characteristics to sample weight, fragment size, and error, provides a method of estimating a sampling constant that quantifies deposit characteristics that contribute to the nugget effect.Sampling control tests provide methods for determining the sampling constant. Sampling control charts, comprising nomographs that relate sample weight, error and particle size, use the sampling constant to optimize sample weights and comminution sizes, and to minimize the variability introduced by incorrect or inadequate sampling and sub-sampling procedures. The sampling constant is useful in classifying ores into arbitrary categories according to expected sampling difficulties. Spatial variations in the sampling constant can be used to aid in defining ore types for modeling geological domains, which should have unique sampling protocols. Examples that illustrate the relationship between the sampling constant and expected sampling problems, and the spatial variation of the sampling constant, are given for various deposits. Case histories of sampling programs are presented.Quality control procedures consist of monitoring sample contamination amd accuracy and precision of analytical results. Accuracy, precision and contamination are monitored by including standards, duplicates and blanks into batches of samples being analyzed. Analytical results of standards and blanks are plotted on a batch-and-time basis with control lines at plus or minus two/three standard deviations as confidence limits of the accepted round-robin value. Examples are given that illustrate a laboratory system in statistical control and the various types of problems encountered when interpreting quality control data. These include sample transcription errors, degradation, contamination, sampling errors, detection limit problems, instrumental drift, lack of statistical control, laboratory bias, procedural problems and data tampering.Where bias is negligible, precision, as a function of concentration, can be obtained from duplicates using the Thompson-Howarth precision algorithm, which also allows calculation of the practical detection limit. Examples are given that illustrate variations in precision, with grain size, for different types of duplicates, as well as mineralogical changes and sampling errors."

Jan 1, 1998