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By C. Mattich, Å. Holmström, L. Hedström

"The fluidized bed at Division Ministro Hales (DMH) division of Codelco in Calama, Chile is currently the largest operating roaster for partial roasting of arsenic rich copper concentrates. The roaster converts the Mina Ministro Hales (MMH) enargite rich (Cu3AsS4) copper concentrates into calcine with a low arsenic content that is suitable for mixing with other copper concentrates feeding a flash furnace. The plant sets a new standard for the processing of arsenic rich concentrates, both from the quality of the calcine as well as the environmental performances. The process technology and expertise are based on the solid practical experience of treating arsenic rich concentrates from both the Boliden smelter and Outotec.The partial roasting process is located next to the mine and concentrator and includes a sulphuric acid plant with auxiliary equipment. The produced calcine has an arsenic content significantly below target and the residual sulphur meets the requirement of the flash furnace. The plant operates with high efficiency cyclones resulting in a low amount of calcine passing to the hot electrostatic precipitator (HESP). The small flow of HESP calcine dust can be combined with the low arsenic calcine and still meet the flash furnace feed arsenic requirements.SO2 formed during roasting is converted into sulphuric acid, while volatized arsenic is recovered in the wet gas cleaning section of the acid plant along with a large proportion of antimony present in the MMH concentrate. Arsenic is stabilized as calcium arsenate and sent to disposal at a specially prepared site.The present production rate (September/October 2015) is close to or higher than the original maximum design capacity of the plant.INTRODUCTIONMineralogyThe mineralogy of an ore and concentrate is important, since there is a direct link between roasting performance and concentrate mineralogy. The MMH concentrate has a good combination of minerals that makes the roasting process efficient and flexible. The main minerals are pyrite, enargite and chalcocite (Figure 1). The inert content is about 15% and consists mainly of silicate and alumina based minerals. The lead content is very low and this is desirable, since the presence of even a small amount of lead will cause a substantial increase of sintering during roasting."

Jan 1, 2016

By K. Barbetti, J. Avraamides

"The processing of gold ores with high silver contents can provide operational challenges, such as high cyanide consumption, retardation of gold leaching and competition during adsorption stages of carbon-in-pulp/leach/column (CIP/CIL/CIC) circuits. In particular, the silver, which is about 1.5% of the value of gold, competes with gold during carbon adsorption due to its higher concentration in many Ag-Au ores, potentially leading to gold solution losses. Fresh and partially fouled (barren and regenerated) activated carbons were evaluated at various Ag:Au ratios and total metal concentrations with regard to the adsorption kinetics and equilibrium loadings. Conventional Freundlich isotherms were found to be highly inaccurate for predicting equilibrium loadings in the competitive adsorption environment. An integrated model, which incorporates competitive adsorption kinetics with a modified competitive adsorption isotherm model has been developed and validated using plant and laboratory data. The model performance and some of its salient features will be discussed.INTRODUCTIONThe processing of gold ores with high silver contents can present a range of operational challenges, such as high cyanide consumption, retardation of gold leaching and competition in carbon adsorption circuits. Silver is often present at significantly higher concentrations than gold in many gold-silver ores and competes with gold in carbon adsorption circuits, limiting the gold loading rate and capacity, resulting in gold solution losses and reduced gold recovery.Curtin University’s Gold Technology Group has evaluated fresh and partially fouled (barren and regenerated) activated carbons at various Ag:Au ratios and total metal concentrations to determine the adsorption kinetics and equilibrium loadings for gold and silver. Conventional Freundlich isotherms were found to be highly inaccurate for predicting equilibrium loadings in the presence of both gold and silver.An integrated model, which incorporates competitive adsorption kinetics with a modified competitive adsorption isotherm model has been developed and validated using plant and laboratory data. This paper describes the model performance and some of its salient features."

Jan 1, 2016

By R. B. Roberts, A. L. Mular

A simple way to determine the IEP of oxide minerals is described. The method is shown to apply for fine powders of Fe203 and ZnO. The IEP lies at pH 6.95 for Fe203 and at pH 9.08 for ZnO.

Jan 1, 1966

By J. Lu, D. B. Dreisinger, G. Houlachi

"Zinc metal is primarily produced by electrowinning from sulfate solution. Zinc electrowinning is very sensitive to impurities such as Co and Ni. These impurities have to be removed to produce high-quality zinc and maintain a high zinc current efficiency. Zinc dusts are used to remove these impurities by cementation. However cobalt cementation is extremely slow and it is typically activated by the addition of Cu and Sb. Even with the use of Cu-Sb activation, cobalt is still difficult to remove. The zinc dust used for cobalt cementation is negligible compared to that consumed for hydrogen evolution. In some plants up to 6-7% of electrolytic zinc is used for cementation. This is a great waste of energy. Cu-Sb activation is not well understood. The objective of this study was to further understand the Cu-Sb activation and then find a way to reduce hydrogen evolution and promote cobalt cementation. The investigation reveals how hydrogen evolution (or zinc dissolution) and cobalt cementation and re-dissolution change with temperature, zinc dust dosage, the concentrations of copper and antimony and time. In the Cu-Sb activation, copper is deposited on a zinc particle to produce a porous shell. The zinc particle as an anode dissolves while the shell as a cathode provides a place where cobalt cementation and hydrogen evolution occur and they are catalyzed by antimony. A certain level of antimony (around 0.1 mg/L) is a key to maintain the catalytic effect of the shell. At a higher antimony concentration, cobalt cementation is accelerated slightly while hydrogen evolution is increased greatly. When a zinc particle dissolves to a certain degree, cobalt loses its cathodic protection and starts to re-dissolve. The change in cobalt concentration is determined by the rates of cobalt cementation and re-dissolution. The operation conditions can be optimized to maximize the cobalt removal and minimize the zinc dust dosage.INTRODUCTIONMost of the world’s zinc metal is produced by electrowinning from sulfate media. Many impurities such as iron, copper, cobalt and nickel are co-extracted into solution with zinc. Iron, mercury, indium, lead and tin are removed by co-precipitation as hydroxides. Copper, nickel, cobalt, aluminum, arsenic and germanium are partially co-precipitated with iron while cadmium, magnesium and chloride remain in solution. Cobalt, copper, cadmium, nickel and etc. are subsequently removed by cementation with zinc dust to achieve an acceptable current efficiency and high purity metal product for the economical production of zinc. Zinc provides a strong thermodynamic driving force for the cobalt cementation:"

Jan 1, 2016

By Sadan Kelebek, S. O. Fekete, Gerhard W. Heinrich, Peter F. Wells

"For many years, rejection of pyrrhotite at the milling stage has been a viable method for sulphur dioxide abatement. Pyrrhotite rejection options have included the use of selective pyrrhotite depressants in flotation; a depressant which has recently come into use is diethylenetriamine (DETA). This reagent has been the subject of recent research and development efforts in the processing of nickel-copper sulphide ores.In the present study, adsorption trends for DETA have been monitored under the dynamic conditions of flotation using a spectrophotometric method which has been adopted for this purpose at Falconbridge Limited. The results indicate that the adsorption of DETA is quite fast and in the majority of cases, accounts for the disappearance of 75-95 % of this reagent from pulp's liquid phase. The adsorption decreases linearly with an increase in the DET A dosage from 100 git to 600 git. The tailings produced in flotation tests were subjected to washing with deionized water at 60 °C to examine the desorption of DET A. These results indicate that the amount desorbed increases with increasing DETA dosage used during flotation but is less than 7 per cent of that adsorbed. It was found that adsorption of DETA alone, even at relatively high levels, does not always cause depression of pyrrhotite. A new combination of reagents identified in the metallurgical laboratories of Falconbridge Limited utilizes sulphur dioxide with DETA. These reagents together are capable of efficient depression of pyrrhotite on a consistent basis."

Jan 1, 1995

By Tatyana Alexandrova

The problem of processing refractory (rebellious) gold ores is important for all the countries involved in recovering precious metals from ores. Technological aspects of processing precious metal ores are examined in two respects: enhancing gold recovery from double refractory ores; and using carbonaceous ores on a production scale. The dispersed carbonaceous matter (DCM) present in concentrates causes the adsorption of [Au(CN)2]- complex on their surface during cyanidation process. Depending on the degree of graphitization and the organic carbon content in DCM (including kerogens and bitumen), the technology used to recover precious metals varies considerably. The problem of processing refractory (rebellious) gold ores is important for all the countries involved in recovering precious metals from ores. Depending on the degree of graphitization and the organic carbon content in DCM (including kerogens and bitumen), the technology used to recover precious metals varies considerably. The possibility of rare metals recovery, including rhenium, from black-shale rocks, has been examined. Comparative assessment of analytical methods of rare metals detecting has been carried out. It has been proved that neutron activation analysis is a promising technique. It has been shown that colloid-salt fraction (nanofraction) with particle size less than 1000 nm makes up to 3 wt% of black shale samples and is extracted by water under special conditions. The use of water instead of chemically active reagents provides insolubility of the mineral matrix and fully reflects the colloid-salt element of the samples. To sum up, the justification of the choice of technology for processing of carbon-bearing ores is based on examining the type of carbonaceous matter and its adsorption behavior. When the content of carbon of high degree of metamorphism is considerable, it is possible to recover platinum group elements and rare elements from this type of ores. The obtained results predetermine the general guidelines for creating new methods and techniques of processing carbonaceous material for integral development of solid minerals in the mining and oilfield areas of Russia.

Jan 1, 2016

By K. Tsuchihashi, A. Kishimoto, T. Uda, Y. Kado, S. Maruyama

We recently proposed a continuous production process for titanium metal with some experimental results. In the process, titanium tetrachloride is reduced by Mg in the presences of Bi to form a Bi-Ti alloy at 900ºC. At this temperature, the obtained alloy is liquid and allows for the continuous removal of product and heat from the reaction vessel. The obtained Bi-Ti alloy was vacuum-distilled at 1000ºC for 24 hr, and 98 at % (92 wt %) titanium, which was easily crashed to powder, was obtained. Bi solvent was selected because of the highest titanium solubility at 900ºC and the moderate vapor pressure among the candidate metals (Bi, Sn, Pb, Zn, and Sb).

Jan 1, 2014

By J. Ipinza, J. P. Ibáñez, Casas J., S. Cortés

Copper powder generated during the treatment of electro-metallurgical bleeds by reactive electro- dialysis (RED) had totally reduced the content of ferric ions in acidic synthetic electrolytes (Cu (II)- Fe (III) – H2SO4). In batch and columnar experiments 100% of the ferric ions were reduced to ferrous ions with an extremely high kinetics. A preliminary conceptual design for reducing ferric ions based on an integrate RED- Column for treatment of electro-winning bleed system is discussed. This system is able to recover simultaneously sulfuric acid and copper powder, which will reduce ferric ions. INTRODUCTION It is well known the negative effect of ferric ions in the copper electro-winning process. The increase of ferric content in the electrolyte reduces the current efficiency, i.e., there is an increase in the energy consumption, and changes the surface morphology of the copper deposit (Das, Gopala & Krishna, 1996; Vargas & Parra, 2013). The increase of the specific energy consumption due to the loss of current efficiency occurs by the reduction reaction of ferric to ferrous ions in the cathode, at the anode the ferrous ions are slowly oxidized to ferric ions (Shaw, Dreisinger, Lancaster, Richmond & Tomlinson, 2004). To control the level of iron in the electrolyte, bleeds are needed; this bleed electrolyte containing copper, sulfuric acid, cobalt, iron and other impurities normally is waster, which increased the production cost of the plant (Milbourne, 2002; Mckevitt & Dreisinger, 2009). Then, permanent efforts oriented to treat those bleeds to avoid losses of valuables components are made; among them are use ion exchange resins (Shaw et al., 2004; Mackevitt et al., 2009), chemical precipitation (Izadi, Mohebbi, Amiri & Izadi, 2017) and electrodialysis (Cortés, Ipinza & Ibáñez, 2013). The last one allows to the simultaneous recovery of sulfuric acid and copper powder. If one of the valuables obtained by treating the bleed can be used to reduce ferric ion concentration in the electrolyte could be an important asset. This issue at laboratory scale is reported in this work, the use of copper powder, generated by reactive electro-dialysis when treating synthetic acidic electro-metallurgical bleeds, for reducing ferric ions in acidic electrolytes.

Jan 1, 2019

By N. Kolev, M. Poibrenski, I. Nishkov

"The following paper examines the flotation of copper porphyry ores in Assarel concentrator with focus on the reasons for low molybdenum recovery in the final copper concentrate. The copper-porphyry ore of the Assarel deposit is characterized by its variable mineral composition and high clay content, which influence the process efficiency of their concentration. Particle size distribution, chemical and mineralogical analyses have been made on various flotation products showing the distribution of the main elements of interest - copper and molybdenum. It was found that molybdenum is not concentrated into the final copper concentrate as usual in the flotation of copper-molybdenum ores but into the tailings of the copper selective flotation (cleaner tailings). An attempt to explain these results has been made with proposals to improve molybdenum flotation. Low floatability of molybdenite is caused by the ultrafine clay minerals content in both the run-of-mine ore and copper flotation streams. In order to achieve selectivity of copper minerals against pyrite a significant amount of lime is used in the plant leading to higher pH conditions, which could be another possible explanation for the molybdenite depression. The results obtained after the laboratory experiments, showed that it is possible to restore molybdenite floatability using traditional reagents such as diesel, kerosene, etc., and introducing a new polymeric reagent as froth modifier.INTRODUCTIONOne of the main technical difficulties in the area of copper-molybdenum flotation is the selective recovery of both metals, especially the fine (<40 micron) mineral particles. The problem is even more serious when Cu-Mo ore treated contains a lot of natural fine particles, predominantly clays, micas and other gangue minerals. Peng and Zhao (2011) conclude that the mineral processing industry is well aware of the difficulty in treating ores in the presence of clay minerals. Tremolada et al (2010) found that clay minerals have been named as the main problem in ore beneficiation processes due to their small size, which cause a higher viscosity in grinding. In flotation, these clay minerals have natural hydrophobicity or float by entrainment.The impact of clay mineralogy on flotation performance has been reviewed in the literature and the various deleterious roles of clay minerals have been investigated (Bulatovic, Wyslouzil & Kant 1999; Jorjani et al, 2011; Farrokhpay, Bradshaw & Dunn, 2013). It is widely accepted that the actual flotation recovery problem appears to be caused by the properties of these fine particles: small mass (and/or momentum) – high interfacial free energy (Rubio et al., 2007; Farrokhpay, 2011). In most cases, the loss in recovery is found to be insignificant, but the detrimental effect on the concentrate grade is found to be more prominent. The main reasons for the flotation inefficiency are the low probability of bubble-particle collision and adhesion, formation of dense froths and as a result - low process kinetics. A great deal of fine valuable minerals is discarded as slime in flotation due to lack of effective recovery methods."

Jan 1, 2016

By K. K. Feng

"Spontaneous combustion has always been a problem in coal mines and is identified mainly with the mining of low-rank coals. The liability of coals to spontaneous heating is only one of the factors in determining whether spontaneous combustion will occur. However, knowledge of the relative oxidizability of the coal is a useful factor to take into consideration when selecting new coal seams and mining methods for future mine development.Four methods (static isothermal, ignitability, adiabatic and dynamic) have been used to compare the relative liability of Canadian coal to spontaneous combustion and to investigate the mechanism of spontaneous combustion of these coals. Among these f our methods, the static isothermal method is considered to be the best indicator of the susceptibility of various coals to spontaneous combustion. Western mountain coal adsorbs more oxygen and has a higher tendency to undergo spontaneous combustion than the Harbour seam coal of Nova Scotia. It has also been observed that a higher methane content in coal will indicate a lower liability to spontaneous heating."

Jan 1, 1985

By Suping Yao, Chuanyu Jiang

In the last decade, the copper industry in China has witnessed a significant change. The capacity and production of refined copper has grown remarkably from 1.5 million tons in 2002 up to 5.88 million tons in 2012. And now, China has become the biggest copper producer in the world, counting about 30% of the global refined copper production. This paper summarized modern copper smelting and converting technologies employed in China copper industry, such as OT flash technology, TSL (ISA/Ausmelt), SKS bottom blowing, Jinfeng side blowing, etc…This paper also presents some key development and improvement of these technologies up to date from their practical application in China, what will contribute as great value to any new / or renovation copper smelting projects down the road. As an engineering company in China, NERIN has been involved in many of these projects in the past decade, played an important role in the engineering works and accumulated intensive experiences. NERIN is one of the best choices for the world clients in the copper industry, providing quick engineering service, delivering cost effective projects.

Jan 1, 2014

By Cesar A. Urbano Jr., Gretchen T. Lapidus

A series of experiments examined silver extraction from a high-grade sulfide concentrate employing thiourea solution. Thiourea was initially oxidized with hydrogen peroxide (H2O2) to form formamidine disulfide (FADS) and used to extract silver from the as-received concentrate and after various pretreatments. Very low recoveries (~30%) were obtained with the as-received concentrate due to competitive cementation reactions by metallic iron and easily oxidizable copper phases. Over 80% Ag recovery was obtained when the concentrate was pretreated to remove this iron and copper. The results suggest that an oxidative acid pretreatment of this concentrates significantly improves silver recovery upon leaching with thiourea.

Jan 1, 2014

By B. Loveday, G. W. Delaney, S. Cummins

"Applying DEM to prediction of tumbling mill performance is challenging because several different modes of breakage are active in the process. As our knowledge of breakage and computational capacity improve, it is worth revisiting previous simulation tasks which did not produce a satisfactorily realistic description of a measured process. At SAG 2006, we reported the simulated and measured outcomes of treating a well characterised ore in a 1.2 m diameter mill. This well instrumented, pilot scale mill at the University of KwaZulu-Natal has been combined with some new approaches to ore testing to allow different modes of breakage to be tested. The mill design allows the rate of generation of fine material to be measured in close to real time for autogenous and SAG mill charges. The updated simulation model estimates mass loss with particle evolution and embeds the cumulative damage and breakage.The simulated results are compared with the measured results. Issues such as relating modelling inputs to particle breakage characterisation data and the accuracy of the predictions of the models are discussed."

Jan 1, 2012

By D. R. Nagaraj, Napoleon Tercero, Raymond Farinato

"Several studies conducted recently have shown that molybdenite flotation from Cu-Mo ores is adversely impacted in sea water at pH >~ 10.0 irrespective of the pH modifier; under the same conditions Cu sulfide flotation is relatively unaffected. This has been attributed to the presence of Mg2+ ions and their hydrolysis products in the sea water which adsorb and precipitate on molybdenite surfaces as Mg(OH)2. However, why and how Mg(OH)2 impacts only molybdenite flotation in the complex flotation pulps containing a multitude of minerals is not understood. The work presented in this paper probes the interface and interphase regions near the edge and basal planes of natural molybdenite (MoS2) in aqueous solutions and flotation pulps, particularly in the presence of copper ore pulp and added Mg2+. Differences in interaction of metal ions and their hydrolysis products (Mg2+, Mg(OH)+) were measured on the two faces of this anisotropic mineral. How those differences relate to molybdenite floatability and the impact of aqueous solution chemistry are discussed.INTRODUCTIONWater resource management is an important sustainability challenge in mineral processing. In view of the shortage of fresh water in many parts of the world, mineral processing plants are evaluating alternative sources. Seawater flotation has received much attention recently and there have been several important studies reported in the literature, particularly for the processing of Cu-Mo ores (S. Castro, 2012; S. Castro, Rioseco & Laskowski, 2012; S. Castro et al., 2012; Laskowski & Castro, 2012; Ramos, Castro & Laskowski, 2013; S. Castro & Laskowski, 2013; Laskowski, Castro & Ramos, 2013; Nagaraj & Farinato, 2014; S. Castro, Uribe, & Laskowski, 2014; Veki, 2013). The main conclusions from these studies on Cu-Mo ores in seawater at elevated pH were: a) flotation recovery of Cu sulfides is either unaffected or only marginally reduced, b) molybdenite recovery is adversely affected in seawater at pH values necessary for rejecting pyrite (i.e. pH > 10 to 10.8 depending upon particular system), and c) the precipitation of Mg2+ in seawater as Mg(OH)2 is responsible for the adverse effect on Mo flotation. In order to further investigate the individual effects of Mg2+ and Ca2+ on molybdenite depression in Cu-Mo ore flotation, Nagaraj & Farinato (2014) conducted flotation tests wherein individual metal ions were spiked into tap water during grinding of Cu-Mo ores. They showed the strong adverse effect of Mg2+ addition on Mo recovery and, to a lesser extent, on Cu recovery when pH > 9.5. Under similar conditions, Ca2+ had virtually no effect on either Cu or Mo sulfide flotation. Figure 1 below shows the previous results for Cu- Mo ores in tap water and the effect of addition of Ca2+ and Mg2+ ions. Note that in seawater the adverse effect of Mg2+ on Cu recovery was much smaller than that in tap water (Nagaraj & Farinato, 2014; Figure 4a and 4b and Table 4 therein)."

Jan 1, 2016

By Y. Mercadier, M. Ait-Ali, M. Dostie

"This paper presents the results of an analytical study to assist in the design of blast furnace tuyeres, including a prediction of the heat transfer process.IntroductionA blast furnace tuyere must be made of a material which must con serve its geometric and structural integrity in the environment of the fire-ball of the furnace. It must be cooled by a fluid forced through its internal cavities in such way as to keep its maximum temperature below the allowable limit. The prediction of the convective heat transfer coefficient inside the tuyere is of great importance in the design of new tuyeres with increased service life. We have developed a computer program which can predict the convective heat transfer coefficient for two-phase flow. This paper shows how the program work s and how it can be used for the numerical simulation of tuyeres.To simulate the h eat transfer conditions in water-cooled tuyeres, one has to predict:a) The heat flux (radiation and convection) generated by the combustion gases. This was evaluated using the single-zone gas-furnace model. This model yields results which are of the right order of magnitude. A more fundamental study of radiation heat transfer based on combustion and gas concentration s will be reported in a future publication.b) The local convective heat transfer coefficient at all points with in the tuyere.Prediction of the Convective Heat Transfer CoefficientTo calculate the convective heat transfer coefficient for refrigerant stream, semi-empirical correlations developed by the nuclear industry were adopted. These correlations permit us to analyze the entire range of the convective boiling range, as shown in Table 1. Our first attempt, with a single-phase flow correlation, has shown the need to take nucleate boiling into account."

Jan 1, 1982

By L. S. Trenholme

"Belleterre Quebec Mines, Limited, is a subsidiary of Mcintyre Porcupine Mines, Limited. The property is in Guillet township, Quebec, 45 miles due east of Haileybury, Ontario. It is accessible by 72 miles of gravelled road from New Liskeard, Ontario (Fig. 1).Gold production at the property commenced in 1936 and to March 31st, 1945, had exceeded $9,000,000. For the past 3 years the milling rate has averaged 325 tons a day and the gold recovery about $14 a ton.GENERAL GEOLOGYThe rocks of the district consist of Keewatin-like volcanics conformably overlain by Timiskaming-like sediments. Together they form the remnant of an easterly plunging anticline engulfed by granite (Fig. 2). The pregranite intrusives consist of diorite, gabbro, and ultrabasic rocks, occurring as dykes, sills, and irregular stocks. Dykes of porphyry and lamprophyre presumably related to the batholithic intrusive are common in this area. The veins of quartz are also probably derived from the batholithic intrusives. A few dykes of Keweenawan-type diabase have been observed."

Jan 1, 1954

By P. Au, P. Patnaik, H. Saari, D. Y. Seo, S. Bulmer

Ti-48Al-2Cr-2Nb-xW (where x = 0, 0.5, and 1 at. %) powders were consolidated by hot isostatic pressing (HIP). The consolidated samples were solution heat treated above the a-transus followed by stepped cooling to room temperature. Selected samples were subsequently aged at 950 °C for up to 72 hours. The post-heat treatment microstructure was examined by optical and electron microscopy. It was found that increasing holding time above the a-transus generated a more homogenous microstructure. Utilizing the stepped cooling sequence, especially with a transition temperature of 1270 °C, massively transformed gamma (Ym) was diminished. Aging caused coarsening of the fully lamellar microstructure in the 0%W and 0.5%W samples while almost no coarsening occurred in the 1 % W sample. Precipitates began to form during aging in samples containing W. The precipitates at the lamellar interfaces are fine and have a needle like shape, while precipitates at the lamellar grain boundaries are coarse and circular in shape. The size and number of the precipitates depend on aging time and the level ofW content.

Jan 1, 2006

By A. Jafarnia

Aluminum alloys are frequently grain refined during solidification in order to promote the formation of an equiaxed grain structure in the casting. The application of Ti-based grain refiners and/or Ti containing master alloys for improving mechanical properties may result in formation of Al-Ti based intermetallics. Although the grain refinement produces many desirable qualities in aluminum castings such as improved castability and mechanical properties, the addition of Ti to Al-Si foundry alloys may lead to the formation of some undesirable intermetallic particles such as AlTiSi and cause a number of operational problems such as nozzle blockage due to segregation and agglomeration of aluminide particles within the nozzle. There are several questions to be clarified when minor amount of Ti is added to Al-Si alloys. They include nucleation and growth of AlTiSi particles, their morphologies and orientation relationships with aluminum matrix and the dissolution of these intermetallics during the course of solidification and/or post solidification treatments. The current study was initiated to study the process and possible mechanism of aluminide dissolution and the related phenomena such as segregation and agglomeration. It reports the results found during reheating of laboratory prepared Ti-added A356 alloy at three temperature ranges of below solidus, mushy zone and above liquidus.

Jan 1, 2004

By S. E. Malouf, W. Thorpe

"The Chibougamau Explorers property comprises 35 claims or 1,726 acres in La Dauversiere and Rohault Townships along the west shore of Norhart Lake. The property is serviced by a twelve-mile all-weather high-way leaving the main St. Felicien-Chibougamau highway at mileage 121. This road junction will be a railway siding on the C.N.R. St. Felicien-Chibougamau branch line in early 1957. The property lies 30 miles due south from the town of Chibougamau. The mine-sponsored Chibougamau Explorers town has a population of 250 with 28 residences and a well equipped recreation centre.The original showing was found by Rider Storn, a prospector financed by Val d'Or interests during the 1950 field season. This showing did not stand up to detailed prospecting but it did lead to the discovery of the main zone by A. Oakley during the following winter.The company was incorporated in I 950 under the presidency of E. Ayrhart. Financing following the initial drilling involved an increase of capitalization from 3 to 5 million shares and the advent of financing and management control by Anacon Lead Mines Limited.Exploration and development to Jan. I, 1956, has included 42,331 feet of surface diamond drilling; 31,363 feet of underground drilling; a 3-compartment shaft to 1,245 feet, with 8 levels at 150-foot intervals; and I 1,054 feet of drifts, crosscuts, and raises. Ore reserves to the 900-foot level, proven and partly developed, total 546,725 tons averaging 0·30 ounces gold and 0·93 per cent copper. A mill with capacity of 500 to 750 tons will be installed by January 1956.GeologyThe Chibougamau Explorers property lies along the belt of Keewatin volcanics striking through Bachelor Lake, Opawica Lake, Doda Lake, Coapatina, Norhart Lake, and Rohault Lake, where it is in close proximity to the paragneisses of the Grenville series. The boundary of the paragneisses, a gradational contact, lies within a mile of the Chibougamau Explorers shaft collar."

Jan 1, 1949

By Rodney S. Read

This paper outlines a reasoned argument why no large-scale fracturing or faulting will be induced in the host rock by a deep geological repository (DGR) for nuclear fuel waste. Four DGR designs in three possible host rocks, including crystalline and sedimentary rock types, are considered. The reasoned argument draws from results of previously conducted thermal- mechanical analyses and new scoping calculations, along with evidence from experiments conducted in Canada and elsewhere. It is concluded that large-scale fracturing in the far-field is implausible given the expected in situ stress conditions in relation to rock strength. Near-field damage development and fracturing are expected in DGR scenarios in the different rock types, but these near-field effects are not expected to lead to large-scale fracturing that could compromise the integrity of the DGR and surrounding rock mass. Additional analysis and characterization activities are recommended to further validate the reasoned argument. Thermo-poroelastic loading of the rock mass is identified as one possible driving mechanism that should be studied further.

May 1, 2009