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By W. D. Watson

"Early in mine development at Quintette Coal Limited major problems were encountered with the fleets of primary equipment which seriously hampered production. These major fleets (cable shovels, hydraulic shovels, hydraulic drills and electric trucks) have consequently been the focal point of maintenance efforts. Some were prototypes in the Canadian mining scene and brought with them new concerns to test their skills. The problems were studied and the category and areas which were having the greatest impact on the reliability of the equipment were determined. Once defined, priorities were established and a program was initiated which was designed to accomplish a resolution. Resulting from implementation of this systematic approach, over the past three and one-half years, the fleets are now giving good reliability and industry standard availabilities. Along with these significant achievements, cost per operating hour on some of the equipment fleets has decreased substantially and continue a downtrend through 1987. This paper identifies the problems and describes the resolutions. IntroductionIn the early years of the mine development, Quintette Coal Limited (QCL) experienced production shortfalls due to problems with the major excavator and haulage fleets. A large fleet of hydraulic excavators had been purchased, and QCL was among the first northern users of all hydraulic blasthole drills. They were also using some prototype equipment and encountered problems which were not common on other types of equipment or were unknown.Because of these unique problems and lack of experience from other mines to draw on, an analytical approach was taken to areas and associated causes of the delays affecting the availability and reliability of equipment. This was done by dividing the equipment downtime into seven classifications of delays, i.e. maintenance, electrical, hydraulic, mechanical, damage, service and preventative maintenance, and tires; and then each was expressed as a percentage of total downtime. Subsequently each of the delay classification was divided into categories e.g. electrical to six categories - wheel motors, main alternator, relays, cards, no propel, lighting and 24 V system. Then, the basis for further study had been established.From this preliminary analysis of historic records, it was possible to determine the areas which were causing the majority of the downtime. These areas were then analyzed to evaluate causes and to determine possible solutions to the problem s. This paper addresses the major fleets, their problems and eventual solutions. Plea se bear in mind that the over-all objectives were to increase physical availability and reliability."

Jan 1, 1988

By Laurence D. Burke

The electrocatalytic behaviour of gold in aqueous media is surprisingly complex and a novel view of gold electrode surfaces is proposed to explain the observed electrochemical responses. The metal surface is considered as a chemically (or redox) modified electrode, with equilibrated, low energy, surface gold atoms functioning as a relatively inert support and low coverage, high energy, protruding gold atoms (or minute clusters of same) functioning as electrocatalytic redox mediators. The protruding atoms are viewed as surface active sites and the complex electrocatalytic behaviour is attributed to the basic instability of the mediators, the diversity (and poor control) of same, and the acid/base (or hydrolysis) behaviour of the oxidized states of the mediators. It is assumed that major advances in the application of gold in the heterogeneous catalysis of gas phase reactions will be accompanied by similar advances in the use of gold in the electrocatalysis area; however, this will require considerable work of both a practical and theoretical nature.

Oct 1, 2003

By Webber. G. R.

Variation in content of some of the major and minor elements in the Lake Dufault granodiorite near Noranda, Quebec has been studied. The element variation and specific gravity data show a pattern consistent with the concept of a concentrically zoned intrusive on the western side of Lake Dufault with a potassium-rich core and a calcium-rich inner zone. The part of the intrusive on the eastern side of Lake Dufault is of more problematical origin, but the suggestion is made that it has resulted from assimilation of volcanic rock by the intrusive. THE purpose of this investigation was to test the application of x-ray fluorescence analysis to the study of variation in chemical com-position of the Lake Dufault granodiorite. The Lake Dufault granodiorite is an intrusive body approximately six miles long by three miles wide located four miles north of Noranda, Quebec. This intrusive is of particular interest because of its -

Jan 1, 1962

By H. Y. Sun, Q. Y. Tan, X. P. Niu, L. Li, Y. Jia, R. M. Ruan

During bioleaching processes of sulfide minerals, the sulfide minerals act as the natural habitats for acidophiles, of which, most are autotrophic iron and sulfur oxidizing microbes. These microbes acquire energy by oxidation of sulfide minerals, and play crucial role in bioleaching processes. In the industrial bioleaching heaps, microbial community and their activity are highly related to engineering configurations, while the optimized industrial operation can help to fast dissolution of aim minerals and acid/iron balance under optimized microbial condition. Microbial community succession and activity formation, the function of microbes to mineral dissolution, the mechanisms to promotion and inhibition of sulfide minerals oxidation, and the industrial instances for microbial community regulation were reviewed. For these instances, promoted microbial activity helped to fast pyrite oxidation for sulfuric acid generation, which realized zero sulfur acid addition to the irrigation solution in the initiation of a bioleaching heaps. High microbial activity by optimized operation parameters improved Cu leaching efficiency during the heap bioleaching process. And also by inhibition of microbial activity, especially the iron oxidizing microbes, the excessive pyrite oxidation can be inhibited, which helped to the acid/iron balance during heap bioleaching. INTRODUCTION Around the world, high grade copper ore are exploited, while barely new high-grade deposits are succeeded, the copper grade of ore deposit is constantly decreasing. The increasing copper demands worldwide requests to process these low-grade ore deposits. Processing of low-grade ores are not economical by usual extraction processes. Heap leaching is a cheaper process for recovery of low-grade ores, and has been applied to extract valuable metals from sulfide minerals worldwide, such as copper, gold, uranium and nickel (Gericke et al., 2009). Heap leaching process has greatly decreased the economic grade and expanded the recoverable ore reserve worldwide (Brierley, 2008). It is usually carried out in the open environments, and could process huge amount of ore (usually in millions of tonnes in one reactor) in the heap reactor (Gericke et al., 2009). For copper sulfide, especially the secondary copper sulfides, heap (dump) bioleaching is successfully applied. Heap bioleaching process is cost saving, and sometimes can be achieved without adding chemical into heaps, by microbial fixing of the atmospheric N2 and CO2, and generating oxidant Fe3+ and sulfuric acid in heaps from oxidation of sulfide minerals. Also heap bioleaching is environment friendly by cycling use of the leaching solution, and without exhaust emission.

Jan 1, 2019

By N. Saeidi

"For a mine section comprising 100 different stoping activities, there are ~10158 different possible stoping sequences to explore in the mine schedule optimization search and this figure is indicative of the challenge posed in maximising profitability through mine schedule optimization. Any viable excavation timetable must satisfy all conditions that will constrain feasible sequences. In general, consideration of additional constraint will tend to reduce profitability. Geomechanical constraints on mine schedules, introduced with the aim of avoiding excavation instabilities, can be established for underground mine schedule optimization processes but, currently, this is done only rather crudely; precedence relations between excavation activities (stoping or development) are encoded to produce particular stope sequence patterns (e.g. ‘chevron’ or pyramidal sequences).The work reported aimed to investigate automated processes for formulation of such geomechanical constraints. The timetable optimization approach to the problem precipitated a fresh look at time dependent, and excavation sequence dependent, deformation. Abundant evidence emerged that supported the notion that any methodology developed that failed to account for such time and sequence dependencies was itself bound to failure. Yet, it was also recognised that any deviation at all from an assumption of linear elasticity for geomechanical numerical modeling, adopted to inform geomechanical constraint formulation, would rapidly lead to impractical levels of computational effort.Thus the approach presented here represents a compromise: the elastic stress fields induced by individual mining activities are computed for each activity, independently considered within a computational domain identical to that of all other activities. These are stored in a database. Instability risk for a specific sequence of mine activities can be assessed through superimposition of stress fields drawn from the pre-computed database. Time stamps allocated to events corresponding to the excavation processes permit the conversion of the sequence of elastic stress fields into a time table of stress fields. For specific locations within the computational domain, the aggregate effect of the sequence of mine activities leads to stress-time histories having a castellated appearance, a result of the near instantaneous response of an elastic medium to the excavation perturbations. Time dependent deformation responses are crudely allowed for through the re-profiling these castellated histories through graphical construction of curved responses, where the curve gradients are related to a viscous parameter. Such curves form the basis for a geomechanical constraint formulation to be adopted for mine schedule optimization."

Jan 1, 2015

By Viraj Parekh, Kinnor Chattopadhyay, Sina Mostaghel, Xiao Zhang

Electric arc furnace steelmaking is a dominant approach in North America and controlling EAF emissions is a key issue today because of stringent permit limits imposed by various regulatory bodies. In the present study, an attempt has been made to mathematically model EAF emissions, and use the models as a predictive tool for fine tuning the process. CFD modelling has been used to model various fume release scenarios, and optimize the exhaust conditions for maximum capture. Thermodynamic calculations have been used to analyze various chemical reactions which lead to the emissions of hazardous air pollutants with special emphasis on Zinc, Lead and Manganese.

Jan 1, 2015

By P. A. Crane, N. Shirley, Aung Moe, H. M. Nicholson, D. Kan

Kazakhstan’s first commercial copper-leach solvent extraction-electrowinning plant, Central Asia Metals’ Kounrad project, was commissioned in April 2012. Exploiting low grade waste stockpiles produced during Soviet era open pit mining, a 10,000 tpa copper cathode plant was designed, constructed and commissioned within 18 months. Overcoming initial challenges with a workforce unfamiliar with the technology and with extensive periods of sub-zero conditions during winter the project has consistently met targets and produced high quality copper cathodes at cash costs of less than US$1/lb. Challenges encountered during the first two years of operation are described and future plans briefly discussed.

Jan 1, 2014

By Frank Otten, Jochen Greinacher

"In July 2017, Deilmann-Haniel signed a contract with IOO Slavkaliy to sink two 750 metre (m) deep freeze shafts for the Nezhinsky Potash mine in Belarus. This is the second shaft project where this technology is employed after two over 1,000 m deep shafts for a potash project in Saskatchewan, Canada, have been sunk by the application of the Herrenknecht Shaft Boring Roadheader (SBR) technology. Developed to sink shafts for green field projects in soft to medium hard rock, in frozen or unfrozen geology, the machine technology utilizes a roadheader-type cutterhead on a telescopic boom to mechanically excavate the rock, and a pneumatic mucking system to convey the muck from the face into the buckets. This leads to a manless face during the sinking cycle and thus a significant improvement in terms of workplace safety. For the Nezhinsky project, the SBR design was significantly modified in close cooperation between Deilmann-Haniel and Herrenknecht, based on the available experience and the special requirements of the project. Such modifications have been for example the adaptation of the Pneumatic Mucking System to cope with wet material as well as dry as originally planned or the shaft lining moving from shotcrete application to jump for and tubbing installation for which a step-change hands-off tubbing erector for the placement of segments was designed. Further modifications to optimize the machine technology for the requirements during shaft sinking were applied on the two machines for the Slavkaliy project as well as several revisions to match the special project requirements. The SBR is suitable for soft and medium hard rock up to 100 MPa UCS. The main design limits are maximum weight of the machine with 400 tonnes and length or height of 50 m due to the depth of the pre-sink. The Pneumatic Mucking System was changed in all components, sheaves and rope arrangement were redesigned and the concept of the hoist system was also re-engineered. The SBR in Belarus is configured for a daily sinking rate of three metres and all systems behind the cutting boom are not the bottle neck of the whole system. The works on site started in November 2017 including freeze hole drilling, construction works, site setup, installation of hoists winches, permanent headgears and other components required for sinking. The SBRs arrived on site in June/July 2018 and were preassembled on surface and then lowered into the 50 m pre-sink. SBR #1 started full face sinking in mid-December 2018, and SBR #2 in late January 2019. By the end of February 2019, the machines were at 150 m and 100 m depth respectively, and achieved up to 3.6 m/day concrete lined shaft. The SBR and the sinking system, the experiences, problems, technical solutions and performances of this challenging project will be presented in this paper."

Jan 1, 2019

By W. N. Wallinger

The mine and concentrator of Cyprus Anvil Mining Corporation are situated in south-central Yukon, some 120 miles north of Whitehorse. The large lead-zinc concentrator employs conventional crushing and grinding , followed by differential flotation, to produce selective lead and zinc concentrates, as well as a mixed lead-zinc (bulk) concentrate. Since the commencement of operations in 1969, the concentrator has undergone expansions and modifications which have increased the capacity to 10,000 tons per day, and afforded some metallurgical improvements.

Jan 1, 1978

By J. E. Nesset, E. R. Bobicki, K. L. Bilaniuk

The introduction of froth flotation technology in Canada, and in particular, in British Columbia, began not long after it was successfully applied in the Broken Hill mining area of Australia which began around 1905. It proved to be a revolutionary and transformative technology that resulted in marginal operations in copper, lead and zinc becoming profitable in spectacular fashion. The paper presents the technology of both oil flotation and froth flotation in the context of the challenges of the time and its early application in British Columbia at the Le Roi No.2 mine (1903), the Britannia Copper mine (1912), and at the Allenby concentrator of the Copper Mountain mine (1918-19). New-found archival documents indicate the Britannia application to be the first production application of froth flotation for copper ore outside Australia, a claim that is currently made by the Braden mine (now El Teniente) in Chile. Flotation was initially an add-on process following gravity methods but was rapidly shown to be far superior method for the bulk and selective recovery of metal sulphides. Flotation proved particularly successful for the recovery of zinc sulphide (the so-called ‘zinc problem’) which was considered a contaminant at the time. The ‘copper problem’ related to the poor recovery of fine copper sulphide particles that were not amenable to gravity methods. The success of flotation led to changes in both the scale and methods of mining, concentration and smelting in a manner that allowed integrated mining companies to flourish. Many are still with us today. INTRODUCTION The advent of froth flotation in the early 20th century was truly a revolutionary technological development, not only for the mining and metallurgical industries, but arguably more so for business and society overall. The Canadian technology historian Jeremy Mouat stated (1996) “The development of flotation was the greatest single metallurgical improvement of the modern era...it is not overstating the case to claim that flotation was of central importance to the smooth functioning of the global economy”. It should, therefore, be a story of interest to us all. The aim of this paper is not to retell the full story, that has been well covered by others (Hoover, 1912; Rickard, 1916a; Hines & Vincent, 1961; Lynch et al., 2010) but rather to add some Canadian perspective and the key role played by companies and individuals in those early days, focusing on events in British Columbia’s copper industry. EARLY DEVELOPMENTS During the later half of the 19th century, a number of flotation-related patents were issued. These include the 1860 patent (Britain) granted to William Haynes for a process to separate sulphides from ground ore by mixing it with oil (1-10% wt) followed by a separation process in a water-filled vessel; the 1877 patent granted to Georg and Adolph Bessel (Germany) for a process involving the mixing of oil and graphite ore followed by boiling in water to produce a high grade graphite froth (>90% carbon); and the 1885 patent granted to Rebecca ‘Carrie’ Everson for the separation of sulphides by mixing sulphide ore with small quantities of oil, and adding water followed by sulphuric acid. These processes are more properly referred to as bulk oil flotation due to the relatively large quantity of hydrocarbon used.

Jan 1, 2019

By I. Cotman

Dimensional stone processing has become an important part of the world extractive industry, and today?s total stone block yearly production is estimated to be around 134.000.000 tons and is still growing by an average yearly rate of approximately 20%. In future, the same production will become an important part of the mining industry and presently, in some countries it represents even the main mining output. New environmental regulations, together with landscape and nature conservation requirements, create a number of difficulties in setting up new open pit dimensional stone quarries. As a result, many dimensional stone producers have recently started to apply underground techniques in order to produce the ornamental stone blocks intended for further processing. Underground production of stone blocks requires special mining methods and so far it has not been a cost-effective excavation method for all types of rocks. Presently, this type of stone excavation is generally applied in sedimentary and marble deposits because the rock has small to no mineral quartz content. When starting a new underground dimensional stone mine, it is necessary to analyse the impact of all primary factors which are crucial to set up a technically and cost effective advanced underground dimensional stone mine. The role of physical and mechanical properties of the rock, geological conditions, mineralogical composition, micro-tectonic state of the site, rock mechanic conditions on the site, durability and saw ability of the stone are decisive factors in foreseeing the future methods of extraction. The laboratory research work as well as the field work, is very important in decision-making aimed to choose the future excavation method. Also of equal importance is the serious market research, because it renders the indication of selling price potential. Having obtained the results from both types of research, mining engineers can design the mining methods which optimize financial return to the mine. The practice approved by 15 years of testing in the underground limestone quarry of Kanfanar gives future producers very useful advice and general data to facilitate the process of exploration intended to establish new similar underground quarries.

Aug 1, 2013

By G. F. Doggett

In describing accounting methods at Lake Shore Mines, it is the intention of the writer to limit the discussion to the principal features of the system used in securing cost figures and other statistics. The subject can be conveniently treated under the following divisions: (1) Time-keeping and Labour Distribution (2) Supplies: Handling and Distribution (3) Method of Assembling Data for Cost Purposes (4) Details of Operating Costs Time-Keeping and Labour Distribution After a new employee has gone through the routine of being 'hired on', he is assigned an employment number corresponding with the group applying to his occupation. This is for identification purposes in the plant and time office. He is also given an individual serial number, the use of which will be refer-red to later. On entering and leaving the plant, each employee passes through the clock room adjoining the time office, where he registers the time in and out on time recorders, on the clock card (Figure 1) bearing his name and number. It is the duty each morning of the time clerk to extend the hours worked by each employee, as indicated by the clock for the previous day, and at the end of the half-month period the total hours are multiplied by the rate and entered in the space provided for total wages at the bottom of the card.

Jan 1, 1935

By K. Harris, J. B. Wahl

Ni-base superalloy cast materials provide an outstanding balance of high temperature strength, fatigue resistance, oxidation resistance and coating performance and can be produced to very tight tolerances in extremely complex configurations, such as axial and centrifugal integral cast turbine wheels. As a result, cast superalloys are used in the most demanding applications of aero and industrial gas turbine engines. Use of these materials is expanding to smaller microturbine, turbojet, turbocharger and missile engine applications due to this unique combination of desirable properties. This paper will present an overview of the application of investment cast Ni-base superalloys and process capability to small turbine and missile engines.

Jan 1, 2010

By P. Mengé

The covering of a hydraulically filled goethite pond is discussed from a geotechnical point of view. The characteristics of the goethite were defined in order to allow a detailed study of the procedure for the construction of the cover on top of the soft material and a verification of the stability of the cover and side slopes after construction. These characteristics and the main results of the studies are given, as well as the experiences and observations made during the execution of the work. Finally, the monitoring plan, during and after construction, is also discussed and some results are given. The 'Design and Construct' contract form was used to allow the contractor to choose the optimum and most economical method to realize the closing of the pond, based on his experience with similar projects. The works were carried out between mid 2003 and the end of 2004. The paper will, amongst others, discuss the special method of working that had to be developed to allow the covering of the whole pond in a relatively short time period, without soil improvement methods such as vertical drains or stabilization by in situ treatment. Fill material was used to establish a platform on top of the soft material so that the cover liner and finishing layer could be installed on top of the fill layer. The 'floating roof' principle was used; subsidences were allowed to occur during the installation of the impermeable top liner and soil cover.

Jan 1, 2006

By Edgar Stanfield

Since April, 1923, the Scientific & Industrial Research Council of Alberta has had an analyst, Mr. W. P. Campbell, steadily employed analyzing coal samples taken by the provincial Mine Inspectors. Mr. Campbell has also analyzed a number of coal samples taken by one of the Council's Geological Survey parties. We have thus, at the time of writing, over four hundred analyses of Alberta coal, made by the same analyst, and strictly comparable. These samples come from widely distributed points, some 88 townships being represented. The stream of samples is still flowing in, and it is hoped by the end of this year that the number of townships represented will be increased at least fifty percent. The time has arrived to publish some of the data collected; but it must be clearly understood that this is merely a progress report, subject to revision as further information is obtained. Three hundred and fifty-three coal mines in the province were operated during 1923. The production per mine varied from 5 up to 500,000 tons. With this number of mines to examine (and fresh mines are being opened every year) it is a large task to make even a proximate analysis of representative samples from every mine. Any chemist will appreciate the fact that to make ultimate analyses representative of even the larger mines will be a long and tedious task. It has seemed better to make a comprehensive survey by proximate analysis and determination of calorific value before beginning the more thorough survey by ultimate analysis. This paper, therefore, deals only with proximate analyses and calorific values; and, owing to limitations of time and space, does not deal with other chemical and physical characteristics of coal, such as storage quality and fusibility of ash, important though these are.

Jan 1, 1925

By I. C. Edwards, E. O. Lilge, H. H. Mccreedy

"Introductory and GeneralTHE DRIESSEN CONE bas been used fairly extensively commercially as a classifier. Its use as a concentrator in the upgrading of ores at a fairly high ratio of concentration with concomitant recoveries has been almost negligible. Certain known features about the cone, however, such as its high throughput capacity, cheapness of construction and operation, and simplicity of design have attracted the attention of mill men. An inadequate knowledge of the operating characteristics of the cone when used as a concentrator seems to have been the main reason for its lack of use. It was for this reason that the present investigations§ were undertaken to determine the operating characteristics of the cone and its application to the concentration of uranium ores, with particular emphasis being placed on the concentration of low-grade uranium ores.The investigations were started in December, 1951, and have continued uninterrupted to the present. The initial work was confined chiefly to investigating the operating characteristics of the cone in order to establish the trends that certain variables would exert on the general metallurgy of uranium concentration. Optimum metallurgy was therefore not the prime initial objective."

Jan 1, 1955

By M. Fiset, D. Belley

"To better understand the wear process of various materials that may be used as blades on snow removal equipment, the first step is to evaluate the influence of the load applied and the moving speed on road wear rates of one type of steel and three types of polymers. While the behavior of steel conforms to Archard's law, wear rates of polymers increase to a power of ex of the load applied according to a model implying that the wear of these materials is due to fatigue. The wear rate of some of the polymers varies considerably in terms of speed, unlike the steel. The wear resistance of some of these polymers outclasses the steel tested as long as the speed is not too great. They, therefore, present interesting alternatives for snow removal on more fragile surfaces such as sidewalks and zone made of inter-block slabs.IntroductionSince the dawn of the Industrial Revolution, the massive use of machines has brought with it a number of different problems regarding wear. Snowplowing roads, parking lots and sidewalks is an activity that generates enormous expense in a country such as Canada. To better understand these wear processes and in the hope of stimulating new approaches designed to reduce the costs related to this sector of activity, this paper presents the behaviour of several materials (steel, polymer and rubber) as they wear on an asphalt-fines matrix surface lubricated with water. Also discussed is the effect of various parameters such as the load applied and speed."

Jan 1, 1990

The Red Lake greenstone belt is an irregular mass of lavas sedimentary rocks and intrusives which is approxiately 35 miles long 18 miles wide and 7 miles deep. Basaltic volcamcs are the oldest rocks w1thm the belt. They are believed to have been laid down on an ancient crust which is at least 3 billion (3 x 109) years old and was composed partly of sediments. The basaltic rocks are overlain by acid volcanics and sedimentary rocks which have been complexly folded and are preserved as a down-folded remnant of younger rocks within the older crust. The volcanics and sedimentary rocks of the greenstone belt have been cut by intrusives with a wide range of composition. The emplacement of the intrusives and the accompanying regional metamorph-ism which terminated the orogenic activity in this area are believed to have occurred approximately 2.4 billion years ago. The basalts and many of the basic and ultrabasic intrusives undoubtedly had their source in the sub-crust or mantle. At least some of the granitic intrusives are believed to have had

Jan 1, 1965

By M. Pearson, W. Bristowe, A. Hanson

"There's no such thing as quality assurance; only quality control ... by inspection. "(1) A common misunderstanding in the procurement and construction of custom designed, fabricated pressure vessels and piping systems is that quality assurance can be achieved by simply referencing codes, standards, ISO 9002, QMS or other such programs in the contract documents. In the authors' experience, nothing could be further from the truth, not detrimental to the performance of the equipment than the exclusion of inspection activities and reliance upon warranties and "fit-for-purpose" clauses. Likewise, the expectation that fabricators, suppliers, or third party inspectors can provide such assurances is also unrealistic where they have limited knowledge of the process, material selection criteria, or limited technical resources. The development and successful execution of a quality assurance program is a collaborative effort by engineers, designers, material suppliers, equipment fabricators, and field inspectors with the full understanding and support of the end user.This paper presents an outline of the quality control activities undertaken by the authors for several recently completed and on-going hydrometallurgical projects. The activities include: prequalification of fabricators and sub-vendors, shop audits, material validation testing, material source control and verification, positive material identification of weld metal overlay, specialised welding inspection, contamination control for titanium and titanium-clad fabrication, eddy current and mass spectrometer (helium) leak testing of shell-and-tube heat exchangers, hot cycle testing of titanium clad equipment, tolerance verification for refractory lined equipment, final inspection and cleaning.

Jan 1, 2004

By J. Cui, Z. Meng, W. Zhao

"The decomposition of rare earth concentrates containing bastnasite and monazite by alkali solutions has been investigated. A slurry of the rare earth concentrate and the alkali solutions was calcined at different temperatures. The impacts of calcination temperature on the decomposition of rare earth minerals, the oxidation of cerium, the deportment of fluorine and phosphorous, and the adaptability of the method to the different grades of rare earth concentrate were all studied. A possible technique for comprehensive recovery is proposed in which the chemical elements such as rare earth, fluorine, phosphorus, calcium, iron and thorium could be recycled or recovered. INTRODUCTIONThe liquid alkali decomposition method is an important technique for the decomposition of mixed rare earth concentrates. The technique is relatively clean compared with the sulfuric acid roasting method. However, its operation is intermittent rather than continuous. The two-step solid-liquid reaction and the subsequent water washing make it not very suitable for mass production and application. An important reason for the disadvantage is that an additional process of ""calcium removal by acid leaching"" is needed for the technique. The content of calcium in Baotou rare earth concentrates is usually 6-12%. The requirement of the current technique is that the content of calcium should be reduced to about 0.2% after the calcium removal process. Otherwise, the decomposition and leaching of rare earth will be affected. Therefore, calcium removal by acid leaching is a necessity before the alkali decomposition process is carried out. Research on different alkali decomposition techniques has been conducted with prior calcium removal by acid leaching (Xu, 1995; Yu, 1993; Han, Li, Chang, Liu & Xu, 1985). There have been some investigations of direct decomposition of the bastnasite (Feng, Pan & Li, 1998; Zhao, Zhang, Yang & Liu, 2002)and monazite (Sun, Li, Li, Su, Zhao & Liu, 1998; Zhou, 2005) by alkali-liquid, however, all studies were carried out in solid-liquid reaction system, and continuous calcination studies have not been reported.This paper investigates the process of direct decomposition of Baotou rare earth concentrates by continuous calcination with concentrated alkali. Using the rotary tubular electric furnace, the mixture of rare earth concentrate and concentrated alkali solution were decomposed continuously. Satisfactory decomposition results were achieved. A method for clean processing and comprehensive resource recovery from Baotou rare earth concentrates is proposed."

Jan 1, 2012