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By L. W. Vollmer

Introduction During the past three years at least fifty strings of 9% nickel steel tubing have exhibited excellent resistance .to the variably severe corrosive conditions typical of many of the sweet condensate wells in Mississippi, Louisiana, and Texas. This experience, and the characteristically outstanding performance of other ?nickel alloy steels under hydrogen sulphide corrosive conditions, dictated the selection of 9% nickel steel tubing for the second well drilled in the sour condensate Pincher Creek field of southwestern Alberta. The damaging effects of the Pincher Creek reservoir fluids on well equipment had been manifested in the discovery well by the rapid and not yet fully understood failure of API Grade N-80 tubing, stainless steel wire lines, and alloy steel fishing tools. Two very unexpected failures in the 9% nickel steel tubing, after only six days of service in production tests, instigated an extensive and continuing investigation to ascertain the probable cause of failure. This discussion presents some of the results obtained thus far which cast a little light on the perplexing behaviour of steels in hydrogen sulphide environments in general, and in sour condensate wells in particular. History of Tubing Failures Walter Marr well No. 1, in which the 9% nickel steel tubing failures occurred, produces from the Madison lime at the depth interval approximately 12,200 to 12,750 feet. The gas-oil ratio is about 26,000 and the gas contains 10.2 per cent hydrogen sulphide and 6.3 per cent carbon dioxide by volume.

Jan 1, 1952

By C. M. Kleemann

The paper describes the present milling practice at Western Mining Corporation Limited's new nickel mine at Kambalda in Western Australia. It details the crushing, autogenous grinding, flotation and spray drying circuits for the production of a nickel concentrate. It also indicates some of the metallurgical problems which have been encountered in concentrating this ore.

Jan 1, 1973

By W. M. Williams

"Although manganese is a metal virtually unknown to the layman, it is hardly necessary to point out to the engineer the importance of manganese in modern metallurgy, an importance intimately linked with iron (and steel), the basic materials of engineering construction for hundreds of years and certain to remain so for long into the future. World steel production will approach and perhaps reach 1 billion tons/year in the 1980s; with a manganese content between 0.5% and 1 % in ordinary steels, and more in specialty steels, manganese use worldwide will soon approach 15 million tons annually. Manganese was discovered and isolated in Sweden in 1774 by Karl Wilhelm Scheele (who also discovered molybdenum), but the element was only of scientific interest for several decades. By the early part of the nineteenth century, however, manganese oxide had become commercially available and was in use for colouring glass and for the production of chlorine. Commercial application in metallurgy appears to have been limited to the manufacture of crucible (or ""cast"") steel, a highquality product made by carburizing wrought iron, and melting it in small batches to make ingots which could be rolled and used for special applications, e.g. for the manufacture of fine tools or for ""steeling"" the cutting edges of implements such as wrought iron axes and chisels.* However, it was not until Bessemer's epoch-making invention of cheap steel in 1856, and the dramatic expansion of the steel industry thereafter, that manganese assumed the importance that it holds in modern steelmaking."

Jan 1, 1999

By H. J. McQueen

Mineral and energy resource consumption were continuously reduced by process improvements as chemical understanding was developed and applied. During the past two centuries, technological improvements increased human productivity that was accompanied by social advances and labour saving products; however, these sometimes proliferated to endanger sustainability, e.g., automobiles. In the steel industry, precisely controlled rolling of HSLA steels required little extra mineral consumption but reduced weight and heat-treating energy. Continuous casting of slabs reduced scrap compared to ingots and energy for the homogenizing soaking pit. Al alloy extrusions were improved by retaining the strengthening in the near-surface substructure, of high strength textures and of press quenching that is suitable for direct age hardening. Continuous bar casting of Al-0.65Fe, coupled with rod rolling and followed by wire drawing with only a final recovery anneal, yielded electrical wiring for households to replace less plentiful Cu and later for light-weighting use in autos and aircraft Looking backwards, the 1970 decade saw the first oil crisis and inspired Ottawa to undertake a campaign to develop an energy strategy that would decrease dependence on imported fuels. One significant undertaking under Energy Mines and Resources was the organization of industrial energy conservation, managed by each industry association,that collected detailed current statistics and set the goals for a 2-year campaign. The metal producing industries, as compared by E.C.N. Perryman to about 7.2 exajoules (EJ) for the nation, consumed about 0.8 EJ, being about one third of all heavy industries. While manufacturing consumed 30.2% of total energy, it created 87.3% of total national dollar value. Within the industrial envelope, smelting and refining utilized 28% (0.67 EJ, mining beneficiation 6.7%, 0.16 EJ); there was a significant contribution to exports: 80% of iron ore and 70% of aluminium in 1973. A general concern was that decreases in ore grade would lead to a rise in energy expenditures countering benefits from processing efficiency.

Jan 1, 2012

By D. W. Davis, P. Landais, L. J. Robb

Abstract -Nodules of carbonaceous matter have been observed in several Archaean peraluminous granites adjoining the gold- and uranium-bearing Witwatersrand Basin. These nodules, which resemble solid bitumen, usually replace uraninite or uranothorite and are paragenetically late. They show many similarities to kerogen seams and nodules associated with the conglomerate horizons in the Witwatersrand Basin, including composition, maturation, intimate association with uraninite, and a late paragenesis. U-Pb isotope ratios for granite-hosted and Witwatersrand kerogens define a single, albeit somewhat diffuse, Pb-loss discordia suggesting an upper intercept age of circa 2300 Ma. Carbon isotope analysis indicates lighter ?13C values for the granite-hosted nodules than for the sediment-hosted kerogen seams. Raman spectroscopy indicates that granite-hosted kerogen is more highly ordered than Witwatersrand seam kerogen. A model is presented which links the granitoid­ and sediment-hosted organic matter to an event of oil generation in the Witwatersrand Basin circa 2300 Ma ago. Light hydrocarbons migrated through the sediments and into underlying/adjacent granitic rocks, undergoing polymerization and accumulation in response to radiation accompanying the presence of high-uranium phases.

Jan 1, 1994

By Habib Zughbi, Paul Zulli

"A key step towards sustainability in iron and steelmaking is to optimise the use of raw materials and energy consumption, and consequently minimise CO2 emissions. Models based on a Process Integration (PI) approach play a key role in evaluating various scenarios and the impact of introducing changes in raw materials and operational conditions on the overall energy consumption and CO2 emissions. BlueScope uses a PI based comprehensive model for its Port Kembla Steelworks (PKSW), called the Integrated Steelworks Energy and Emissions Model (ISEEM). ISEEM is tightly coupled to the configuration of PKSW. It is based on mass and energy balances as well as thermodynamic relationships. ISEEM is a steady-state model and is used to predict overall and detailed unit-by-unit energy consumptions and CO2 emissions. It is also used for plant-based scenario modelling. This paper investigates the impact of major changes to PKSW configuration, including the shutting down of a blast furnace and cokemaking battery, on the energy consumption and CO2 emissions of the plant. It discusses some of the issues involved in updating the model and some identified opportunities."

Jan 1, 2015

By H. S. Wilson

"The property owned by the Lamaque Mining Company comprises a group of forty-four claims and fractions occupying an area of about 2,458 acres, in west-central Bourlamaque township, Abitibi county, Quebec. It is on ,the outskirts of the towns of Bourlamaque and Val d'Or, about 70 miles east of Noranda, near the eastern end of the belt of greenstones of Keewatin and Timiskaming age that extends eastward through Kirkland Lake into northwestern Quebec, terminating in Haig and Jurie townships 40 miles to the east.The claims on which the orebodies occur were first staked in 1923; No. 3 vein was discovered the following year. The original discovery was made by R. Clark in 1923. This was a small quartz vein containing a pocket of coarse gold on the north side of a hill near the northwestern corner of block 3. It is said that all the gold was removed in one shot in blasting into the vein; elsewhere it was barren. A picket line was then run west along the strike of the vein, which occupied a narrow shear zone, and about 2,000 feet west, in prospecting on either side of the picket line, a large boulder of quartz and tourmaline containing visible gold was found. This led to more intensive prospecting by trenching in the vicinity with the result that the No. 3, or 'float' vein, about 250 feet north of the boulder, was found. Due to low ground this vein was exposed in only one trench. The only other important vein found on the surface was the No. 1, or H, vein, which was exposed in several places by stripping and trenching, but it did not carry appreciable amounts of gold."

Jan 1, 1954

By J. P. Jylhä, A. Jokilaakso

The Outotec Flash Smelting process is widely used in primary copper production. A layer of slag on top of matte (copper–iron sulphide melt) creates a barrier through which matte droplets descend. Droplets of different sizes settle through the layer at different rates, which increases possibility of copper losses as smaller matte droplets may be removed with the slag. In this work CFD-DEM (computational fluid dynamics – discrete element method) coupling was used to simulate matte droplets settling through the slag during slag tapping. Discrete droplets and slag flow were simulated with DEM and CFD, respectively. This new approach enables tracking and solving movement and interactions of individual droplets. User-defined models were created to take coalescence and reaction kinetics into account. Coalescence created larger droplets, while the reactions decreased droplet size and increased its density. Drag caused funnelling effect, which pulled droplets towards the centre line of the descending cluster. This research is the only study known by the present authors in modelling liquid-liquid systems with the CFD-DEM coupling. Simulating coalescence and chemical reactions for discrete droplets enables more realistic simulations. However, CFD- DEM simulations are computationally resource intensive already without additional models, so a full scale industrial settler modelling still waits for further increase in computer performance. INTRODUCTION Flash smelting is a method used in copper and nickel production. In the flash smelting process, oxidation of sulphides in a concentrate is used to release energy needed to smelt the feed. In the process, copper matte is formed. Matte has copper content in the range of 55 – 70% (Sridhar, Toguri, & Simeonov, 1997), the rest is mainly sulphur and iron but has still many other impurities (Taskinen, Seppälä, Laulumaa, & Poijärvi, 2001). Oxidized iron forms iron-silicate slag while SO2 is collected for acid production (Davenport & Partelpoeg, 2015). The Outotec flash smelting furnace (FSF) can be divided in four major component: concentrate burner, reaction shaft, settler and uptake. Concentrate, flux and oxygen enriched air are injected into the reactor through the concentrate burner. The mixture then reacts in the reaction shaft forming matte and slag, which are collected in the settler, while off-gases flow out of the reactor through uptake for heat and dust recovery, and SO2 collection for H2SO4 production. The matte and slag form separate layers due to immiscibility and density difference. Raw material feed is continuous, but the matte and the slag are tapped periodically. A flash smelting furnace is depicted in Figure 1.

Jan 1, 2019

By J. A. C. Fortescue

"Reconnaissance geochemical mapping, based on the chemical analysis of waters, stream, and / or lake sediments had its origin in geochemical prospecting surveys carried out in New Brunswick during the 1950s. More recently, reconnaissance geochemical surveys carried out by government agencies for mineral resource appraisal purposes have been seen as a special case of regional geochemical mapping which is carried out with the aim of describing geochemical patterns f or elements which may he interpreted for mineral resource appraisal, environmental or geological purposes. The interpretation of pal/ ems on regional geochemical maps is based on the concepts of landscape geochemistry, in this paper, the regional approach 10 geochemical mapping is described with reference to an experimental regional geochemical survey which was completed in southwest Ontario during 1981-82. II is concluded, on the basis of data pal/ems for one element only (i.e. arsenic), that the new approach has much potential for solving modern problems in geoscience.""If things don 'I alter they will stay as they are... An old adage.IntroductionDuring the past hundred years topographic, geological, and geophysical maps have been made for all, or nearly all, of Ontario. During the past thirty years these maps have become related as components of what is now called geoscience. Geoscience maps at the regional (i .e. 1 :250,000) scale are often used together to solve general problems in earth science especially in relation to prospecting, or mineral re source appraisal."

Jan 1, 1986

By C. A. Jeffrey, K. Pearson

Abstract - The Croft diorite in central England belongs to a suite of Caledonian igneous rocks collectively known as the South Leicestershire diorite complex. Although the intrusions occupy separate outcrops, they are linked at depth to form a single pluton, buried beneath a cover of Triassic sediments (Le Bas, 1972; 1982, Allsop and Arthur, 1983). Both the Caledonian diorites and the overlying sub-Triassic unconformity have been affected by a complex history of alteration and mineralization which can be subdivided into four stages: (1) deuteric effects, caused by the release of volatiles during magmatic cooling; (2) albitization through sodic enrichment; (3) formation of lowtemperature laumontite, analcime and calcite veins with associated wall-rock alteration to prehnite and pumpellyite; and (4) sub-Triassic unconformity-hosted base metal, manganese and palygorskite mineralization. Zeolite mineralization occured some 200 Ma later than the intrusion itself, during post-Triassic times, as indicated by the presence of a single vein of laumontite and microcrystalline calcite which cross-cuts the sub-Triassic unconformity surface and enters the overlying Triassic sediments. Evidence from fluid inclusion work indicates that two fluids were involved in the deposition of the zeolite veins. One fluid was initially of relatively high temperature (~100°C to 320°C) and low salinity (~0.2 to 5.9 wt% NaCl equiv.), and was probably meteoric in origin, whereas the other was of relatively low temperature (~41°C to 165°C) and high salinity (~0.4 to 16.72 wt% NaCl equiv.), and is interpreted to represent a basinal brine. During Triassic rifting, thinning and fracturing of the crust, with the possible rise of associated magmas (Halliday and Mitchell, 1984), could have increased permeability and heat flow, initiating the circulation of hydrothermal fluids. Triassic unconformity-hosted base-metal mineralization in Central England is similar to other Triassic-Jurassic mineralization in Europe (Mitchell and Halliday, 1976).

Jan 1, 1997

By C. A. Jeffrey, K. Pearson

The Croft diorite in central England belongs to a suite of Caledonian igneous rocks collectively known as the South Leicestershire diorite complex. Although the intrusions occupy separate outcrops, they are linked at depth to form a single pluton, buried beneath a cover of Triassic sediments (Le Bas, 1972; 1982, Allsop and Arthur, 1983). Both the Caledonian diorites and the over-lying sub-Triassic unconformity have been affected by a complex history of alteration and mineralization which can be subdivided into four stages: (1) deuteric effects, caused by the release ofvolatiles during magmatic cooling; (2) albitization through sodic enrichment; (3) formation of low-temperature laumontite, analcime and calcite veins with associated wall-rock alteration to prehniteand pumpellyite; and (4) sub-Triassic unconformity-hosted base metal, manganese and palygorskite mineralization. Zeolite mineralization occured some 200 Ma later than the intrusion itself, duringpost-Triassic times, as indicated by the presence of a single vein of laumontite and microcrystallinecalcite which cross-cuts the sub-Triassic unconformity surface and enters the overlying Triassic sediments. Evidence from ?uid inclusion work indicates that two ?uids were involved in the deposition of the zeolite veins. One ?uid was initially of relatively high temperature (~100°C to 320°C) and lowsalinity (~0.2 to 5.9 wt% NaCl equiv.), and was probably meteoric in origin, whereas the other wasof relatively low temperature (~41°C to 165°C) and high salinity (~0.4 to 16.72 wt% NaCl equiv.),and is interpreted to represent a basinal brine. During Triassic rifting, thinning and fracturing of the crust, with the possible rise of associated magmas (Halliday and Mitchell, 1984), could have increased permeability and heat ?ow, initiating the circulation of hydrothermal ?uids. Triassic unconformity-hosted base-metal mineralization in Central England is similar to other Triassic-Juras-sic mineralization in Europe (Mitchell and Halliday, 1976).

Jan 1, 1997

By J. G. Kelly, C. P. Brown

"In June 1983 a new borehole hoisting system was commissioned at Sherritt Gordon's Fox Mine. Twelve hundred tons-per-day of ore from the 2600 and 2800 levels are being hoisted to the 2000 level through an 8-jt diameter bored winze. This new method replaces the diesel truck haulage system which had been in operation at the mine since 1975.A study was initiated in 1980to determine the most effective method of achieving the required production. The study examined several hoisting alternatives including: expanding the existing trucking system; converting to electrically -powered truck haulage; and deepening the skip compartments of the existing main shaft. The alternative selected as the hoisting method most suited to the requirements was borehole hoisting.Development of the new system commenced in April 1982. Underground excavations included 700 feet of 8-ft diameter borehole, a hoistroom and headframe, storage bins, and a grizzly and rockbreaker station. Equipment installations included: a 5-ft diameter double-drum Nordberg hoist; a counterweighted Kimberley-type skip; two rockbreakers; and the steel sets in the winze. These installations were completed in June 1983. Some problems were encountered after the initial commissioning but these were solved, and since August 1983, the system has proven that the designed capacity is achievable within expected costs."

Jan 1, 1985

By G. E. Agar, W. B. Kipkie, R. A. Tenbergen

"This paper describes the successful pilot plant testing of a flowsheet, developed at Inca Ltd.&apos;s J. Roy Gordon Research Laboratory (JRGRL), for improved separation of the constituent minerals in a bulk copper-nickel concentrate.The flowsheet utilized the fact that xanthate concentration on the mineral surfaces is the most important variable affecting the high lime separation and that reduction of the xanthate concentration could be affected by an oxidative conditioning stage.When the adsorbed xanthate was reduced to a suitably low level, chalcopyrite and pyrrhotite could be floated to leave a high-grade nickel concentrate as the residue. Sodium cyanide was added to the froth product 10 depress pyrrhotite and any remaining pentlandite. The temporary depression of chalcopyrite by the sodium cyanide was overcome by introducing a conditioning step following cyanide addition . The advantages of the flowsheet; improved copper-nickel separation, operation without heating of the pulp, production of both high-grade nickel concentrate (29.5% Ni, .26% Cu) and copper concentrate (<0.5% Ni, 30% Cu) were all realized.IntroductionLaboratory test work undertaken at Inco and described previously(1) has demonstrated the importance of low xanthate concentrations on the mineral surfaces in the copper-nickel separation at the Copper Cliff mill.It was determined that oxidation of the separator feed (a cleaned bulk concentrate, grading about 11% Cu and 11% Ni) to lower the xanthate concentration on the mineral surfaces prior to separation significantly improved the quality of the separation (CI 4)*, particularly when no cyanide is used, but also when cyanide is added. As well, it was found that the oxidation permitted a pentlandite-pyrrhotite separation - the oxidation step brought about a decrease in the flotation-rate of pentlandite leaving pyrrhotite and chalcopyrite largely unaffected. Consequently, it was possible to produce a highgrade pentlandite product (30% Ni, 0.3% Cu) at ~83% Ni recovery , as well as a high-grade copper concentrate (0.5% Ni, 30% Cu at -96% Cu recovery)."

Jan 1, 1985

By Mansoor Barati, Xue Yin, Yanhui Sun, Alex McLean, Yindong Yang

The formation and evolution of inclusions in Ti-Stabilized, 17Cr Austenitic Stainless Steel produced by the ingot casting process were investigated through systematic sampling of liquid steel and rolled products. Analysis methods included total oxygen and nitrogen contents, optical microscopy, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). The results indicate that the composition of inclusions was strongly dependent on the types of added alloying agents. During the AOD refining process, after the addition of ferrosilicon alloy and electrolytic manganese, followed by aluminum, the composition of inclusions changed from manganese silicate-rich inclusions to Al2O3-rich inclusions. After tapping and titanium wire feeding, pure TiN particles and complex inclusions with Al2O3-MgO-TiOx cores coated with TiN were found to be the dominant inclusions when [%Ti] was 0.307 in the molten steel. These findings were confirmed by thermodynamic calculations which indicated that TiN inclusions could be formed in the liquid phase due to the high contents of [Ti] and [N] in the molten steel. From the start of casting to the rolled bar, there was no obvious change in the composition of inclusions compared to the titanium addition stage. Stringer-shaped TiN inclusions elongated along the rolling direction with lengths varying from 17 to 84µm were observed in the rolled bar, which could detrimentally impact the mechanical properties of the stainless steels.

Jan 1, 2015

By P. Cheung, J. Gulyas, R. Clary

Over the past 50 years, the use of autoclaves in the metallurgical industry has evolved from final metal recovery (hydrogen reduction) and purification (sulphide precipitate oxidation) to treating whole ores and concentrates. Recent process developments, such as the use of autoclaves for laterite leaching, have necessitated higher temperature and pressure operations, which in turn have seen marked advancements in technology and manufacturing capabilities to keep in step with process demands. This paper will discuss the advances in technology in terms of design, materials and construction of autoclaves and liners, typical dip tube design and geometric layout. This paper will also address specific auxiliary equipment, such as acid and steam injection systems, and components, such as agitator seal systems.

Jan 1, 2004

By A. G. B. Hayes, C. L. Renzoni

"AbstractThis paper provides a rough outline of economic expectations for the near future and then goes on to discuss their effect on the expected demand for metals, using zinc, copper, nickel and aluminum as detailed examples.IntroductionMINING, as you are all painfully aware, is a cyclical business. We believe that it will remain so as long as there are economic cycles.The fortunes of the industry are tied to those sectors of the economy where decisions can be postponed until more favourable times: automobiles, housing, appliances, inventory building and capital spending. Over the past two years, while U.S. GNP fell by 3.8%, automobile production declined by 31 %, from 9.7 million units in 1973 to 6.7 million in 1975. Housing starts plummeted some 43% from 2.1 million units in 1973 to 1.2 million in 1975. Little wonder that U.S. copper consumption fell by 37% and zinc consumption by 38% over the same period.With the rest of the world's economies moving in unison with that of the United States, it is also not surprising that times have been tough for mining.Arthur Burns, chairman of the U.S. Federal Reserve, contends that each recession sows the seeds of its own recovery. The worse the recession, the better the subsequent recovery. If this is true, then the lot of the mining industry should improve significantly over the next two to three years."

Jan 1, 1977

By K. Liu

"In the present work, two-step heat treatments with preheating treatments at different temperatures (175, 250 and 330°C) as the first step followed by the peak precipitation treatment (375°C/48h) as the second step have been performed in Al-Mn-Mg 3004 alloys to study their effects on the formation of dispersoids and evolution of elevated-temperature strength and creep resistance. During the two-step heat treatments, the microhardness is gradually increasing with increasing time until to a plateau after 24 hours when first-treated at 250°C and 330°C while there is a minor decrease with time at 175°C. Results show that both the yield strength and creep resistance at 300°C reach the peak values after the two-step treatment of 250°C/24h+375°C/48h. The formation of dispersoids is greatly related to the type and size of pre-existing Mg2Si precipitated during the preheating treatments, in which that coarsened rod-like ß’-Mg2Si strongly promotes the nucleation of dispersoids while finer needle-like ß’’-Mg2Si has less influence. Under optimized two-step heat treatments and modified alloying elements, the yield strength at 300°C can reach as high as 97 MPa with the minimum creep rate of 2.2×10-9 s-1 at 300°C in Al-Mn-Mg 3004 alloys, enabling them as one promising candidate in lightweight aluminum alloys for elevated-temperature applications.INTRODUCTION Due to the rapid demand from weight-sensitive automotive and aerospace industrials for the light alloys, such as aluminum alloy on the elevated-temperature applications, Al-Mn 3xxx alloys has been developed to obtain the good properties at both room temperature (RT) and elevated temperature, in which the dispersoid-strengthening mechanism plays a significant role (Li & Arnberg, 2003; Li, Muggerud, Olsen & Furu, 2012; Liu & Chen, 2015, 2015). In our previous works (Liu & Chen, 2015, 2015; Liu, Ma & Chen, 2017), the yield strength and creep resistance at 300°C of Al-Mn-Mg 3004 alloy were further improved by modifying the alloying elements, such as Fe and Mo, to optimize the characters of dispersoids, including the size, distribution and the dispersoids free zone (DFZ). For instance, Mo was introduced in aluminum alloy to further improve the volume fraction of dispersoids and reduce the area of DFZ, leading to increasing on both the strength and creep resistance at 300°C (Liu, Ma & Chen, 2017). On the other hand, the mechanical properties became worse at higher Fe content due to its consumption more Mn to form Al6(MnFe) intermetallics, resulting in less available soluted Mn for the precipitation of dispersoids (Liu & Chen, 2015). Therefore, optimizing the characters of dispersoids is always the key to improve the elevated-temperature properties of dispersoid-strengthened aluminum alloys for elevated-temperature applications."

Jan 1, 2017

By Y. Q. Li, X. H. Long

In this work, structural and electronic properties of smithsonite (ZnCO3) and cerussite (PbCO3) as the typical lead-zinc oxide minerals is simulated by means of DFT. The calculated results could be concluded as: (1) The density of states (DOS) of Zn atom in ZnCO3 is nearer to the Fermi level than that of Pb atom in PbCO3, suggesting that the Zn atom of ZnCO3 is more active and easier to interact with water molecules and hydroxyl ions. Smithsonite, therefore, could be more readily depressed in the flotation process. (2) The bond population value of Zn-O (0.23) and C-O (0.92) in ZnCO3 is obviously larger than that of Pb-O (-0.01) and C-O (0.85) in PbCO3, indicating that the covalent characteristic of ZnCO3 is stronger than that of PbCO3. (3) It is shown that the charge of Pb (+1.32e) in PbCO3 is more positive than that of Zn (+1.22e) in ZnCO3, suggesting that cerussite is easier to interacting with HS- compared with smithsonite in the flotation process. In summary, the structural and electronic property of smithsonite is completely different with cerussite, leading to the difference of their flotation behaviour.

Jan 1, 2015

By W. A. Roliff

The renewed interest of the past few years in the Appalachian and Michigan oil provinces has not, as yet, created any marked increase in activity in Southwestern Ontario. During 1960 development drilling in-creased somewhat over 1959, but exploratory drilling decreased slightly. More attention was devoted to the deeper horizons, but lake drilling de-creased considerably. Oil production reached a new peak and gas production increased slightly. During 1960 an interesting oil and gas discovery was made in the Cambrian and gas discoveries six miles off-shore in the eastern part of Lake Erie were made in the Clinton-Cataract zone of the Silurian. This paper reviews activities during 1960, summarizes the discoveries made to-date and the pertinent exploration data relating to the prospects of the region and discusses some of the economic aspects of exploration and development. D URING the last few years there has •been a marked renewal of interest in the old petroleum

Jan 1, 1961

By Fathi Habashi

The year 1987 marked the centennial of the beginning of modern hydrometallurgy. On October 19, 1887 British Patent No. 14174 entitled Process of Obtaining Gold and Silver from Ores was issued*. The discovery was made by John Steward MacArthur (Fig. 1), a chemist-metallurgist, supported and assisted by Robert and William Forrest, two brothers practicing medicine in Glasgow. The discovery was made in the basement of their clinic. The process, which became known as the cyanidation process in reference to the alkali cyanide reagent used, immediately received industrial success in New Zealand in 1889 and in South Africa in 1890t. It displaced the chlorination method which had been in use. In 1903 MacArthur was awarded the first Medal of the Institution of Mining and Metallurgy in London1131 - The cyanidation process was responsible for the doubling of gold production in the world in the two decades which followed its first application (Fig. 2). To the modern metallurgist, it may be surprising to think of MacArthur coming across an obscure reagent such as an alkali cyanide as a leaching agent for gold ores. It is the purpose of this paper to discuss the background and the factors that led to this invention, the development of the understanding of the process, and the application of modern technology.

Jan 1, 1999