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By M. Le Roux, Q. P. Campbell, N. Hughes

Water plays a significant role in minerals processing; this is especially true in coal preparation where water-based beneficiation is widely accepted and consistently delivering sharp separation efficiencies and high product yields. Although wet processing is favoured, the substantial process water requirement may prove this impractical and unsustainable in some parts of the world. Many coal-rich regions (including South Africa) have experienced severe water shortages. Coupled with the effects of drought, some countries experience freezing winters from which problems related to frozen process water and machinery may arise. Hence coal preparation practices will soon have to adapt, irrespective of the technical and economic feasibility offered by the currently employed water-based methods. As a result, extensive research into the development of dry methods for effectively beneficiating coal has progressed. This review paper intends to provide a collection of the relevant information pertaining to dry coal processing globally, and aid in understanding the applicability, performance, success or failure thereof. The methods available for dry materials preparation, with special regard to those applicable for coal beneficiation, are detailed in terms of principle, applicability, limitations and performance. Dry coal beneficiation has potential to aid the current wet-based methods with some considerations to possible limitations set forth by coal geology, application, product specification, particle size distribution, moisture, efficiency, capacity and cost. These methods may be established in future, especially in the arctic, arid and under-developed regions through new plant installations, expansions and small mines processing. Keywords: Dry coal processing, preparation, cleaning, beneficiation

Jan 1, 2020

By L. L. Godirilwe, and A. Shibayama, G. Danha, K. Haga, Y. Takasaki

Selective extraction through leaching of an amorphous slag obtained from a base metal smelter plant in Botswana is investigated in this paper, where the main objective is to optimise the experimental variables that would result in the maximum selective extraction of the three base metals (Ni, Cu and Co) from the slag waste. Mineralogical tests showed that the sample is composed mainly of fayalite (Fe2SiO4), with a total entrapped metal sulphides content of about 1.0 wt.% occurring as fine occlusions in the fayalite phase. In our experimental program, we compare the effectiveness of two common leaching techniques. In the first method, we use sulphuric acid to carry out atmospheric beaker leaching tests, and in the second method we use high pressure oxidative leaching. The effects of acid concentration, oxidant addition/oxygen partial pressure and pulp density on metal dissolution rate are examined. The optimal Ni, Cu, Co extractions of 80.5%, 81.9 and 98% respectively were obtained under high pressure oxidative leaching conditions (150 oC, 0.6 M H2SO4, 0.5 MPa O2), with substantially low dissolved Fe of 9.6%, the majority of which was removed as jarosite in the residue. Atmospheric beaker leaching yielded poor extractions of Ni below 40% when sulphuric acid combined with hydrogen peroxide (1.0 M and 0.6 M respectively, 65 oC) were used for leaching, while Fe, Cu and Co dissolutions were each about 80%. Therefore, using high pressure oxidative leaching provides a possibility to effectively extract Ni, Cu and Co while producing an environmentally benign residue, thus alleviating the current adverse environmental issues associated with the abandoned smelter slag. Keywords: Slag, amorphous, fayalite, atmospheric beaker leaching, high-pressure oxidative leaching, extraction

Jan 1, 2020

By B. Rezai, Z. Pourkarimi, M. Noaparast, S. Chehreh Chelgani

Nanobubbles (NBs) flotation separation can be an indicator for improving the efficiency of fine particles through the conventional process. Since flotation reagents such as frothers can reduce bubble size, they can potentially be used for the generation of NBs and develop a selective NB flotation separation. This study explored the flotation separation of fine phosphate particles from their associated minerals in the presence of NBs, which were generated by using a phosphate flotation reagent (Flo-YS: collector-frother). The results of flotation tests showed that in the presence of NBs, the flotation efficiency was significantly improved. However, in the presence of NBs, surface chemistry analyses (Fourier Transform Infrared Spectroscopy and High-Performance Liquid Chromatography) illustrated that the collector adsorption on the surface of phosphate particles decreased. A comparison between outcomes of various phosphate flotation conditions indicated that increasing the flotation efficiency in the presence of NBs may be due to the aggregation of fine particles by the generated NBs, and also selective adsorption of NBs (hydrophobisation) on the surface of particles. In other words, generating NBs by selective collectors may increase efficiency and decrease the collector consumption of a flotation process. Keywords: Phosphate, selective separation, fine particles, collector-frother, efficiency, mechanical flotation cell

Jan 1, 2020

By P. G. Toledo, R. I. Jeldres, G. R. Quezada

Chile is the main producer of copper in the world and lately the mining industry has suffered challenges due to the lack of water in the north of the country, along with the new policies of not using fresh water for the industry. This has prompted the use of seawater as an alternative source for mining. Several studies have been driven due to this new scenario, which have shown that seawater can be beneficial, if certain ions are removed from the process. This is the Mg that generates precipitates at high pH, that have been shown to make mining operations difficult. In particular, thickening operations are impaired by the presence of Mg ions, where aggregate formation and sedimentation decreases substantially. Our studies suggest the competence of the precipitates in adhering to the polyacrylamide (HPAM) flocculant and not towards the surface of the quartz minerals. This motivates the present work to use molecular dynamics to study the adsorption of a HPAM molecule on quartz surfaces and the surfaces formed by Mg precipitates. The surfaces are immersed in a saline solution or seawater that includes the HPAM molecule. Results are obtained by measure the adsorption frequency and duration. We obtained that the HPAM molecules are preferably absorbed on the surfaces of magnesium hydroxide. This gives us a good agreement with what is observed experimentally and strengthens the premise of the competition of hydroxide with the flocculant. Keywords: Molecular dynamics, adsorption, tailing flocculation, magnesium removal

Jan 1, 2020

By Xiaoxu Sun, Jianchao Yao, Qiheng Zhu, Dubo Wang, Jiancheng He, Shijie Lu

Tower mill is considered to have a better regrinding and fine grinding effect compared with ball mill, and its application is much broader. The spiral agitator of the tower mill is driven by the motor. Media inside the mill is under the combined actions of the spiral mechanism, the cylinder, and media nearby, and these parameters are key factors affecting the grinding effect. However, it is not possible to obtain detailed information of kinematic law of media based only on traditional laboratory experiments, let alone the relationship between parameters of kinematic law of media and grinding effect. Experimentation is the only way to develop industrial equipment. However, this is time-consuming and costly, which hampers the further research of the tower mill’s grinding mechanism. The paper selects two structural parameters (gap between the edge of the spiral agitator and the cylinder wall, ratio between the diameter of cylinder and that of the spiral shaft.) and three operating parameters (diameter of media, filling ratio, the speed at the edge of the spiral agitator) as variables to do an orthogonal designed experiment of five factors, four levels, and thereby obtaining change law of grinding indicators of different parameters. Experimental equipment may be simplified to enable an applicable simulation strategy. Simulation based on a discrete element method is conducted to obtain the change law of the speed of media, collision frequency, normal force, and radial force. The relational curve between parameters of kinematic law of media and energy consumption of grinding is clarified, and key factors affecting grinding efficiency are determined. Those factors will be used for optimising the design and operating process. The research result of this paper obtained from laboratory experiments and computer simulation provides data support and theoretical bases, and has directive meaning and applicable value for tower mill’s optimisation and large-sized design. Keywords: Tower mill, discrete element method, kinematic law of media, energy consumption of grinding

Jan 1, 2020

By K. Sasaki, S. Kuroiwa, H. Miki, Y. Aoki, T. Hirajima, Y. Orii, G. P. W. Suyantara

Selective flotation to separate copper minerals from, for example, Mo- and/or As-bearing minerals is a continuing problem because the selectivity of current systems is imperfect. Selective Cu-As flotation is currently difficult, and the most common Cu-Mo selective flotation method uses NaHS; this must be done in an enclosed system because, under acidic conditions, this method produces hydrogen sulfide. In this paper, some novel alternative flotation processes that use redox reactions are discussed; these methods have a much lower environmental impact. Oxidation and reduction reactions can be used to make copper minerals more hydrophilic and Mo-bearing minerals more hydrophobic. X-ray photoelectron spectroscopy (XPS) analyses indicated that the copper minerals became hydrophilic because hydrophilic iron precipitated and several hydroxides covered the copper minerals’ surfaces, whereas the molybdenum minerals remained hydrophobic because their sulfide surfaces were not covered. Flotation experiments on these minerals after redox treatments indicated that excellent separation of Cu-minerals from Mo-minerals can be achieved. Possible mechanisms for this separation were investigated using detailed surface analyses and thermodynamic calculations. The additives used to initiate the redox reactions are easy to handle and make these new flotation procedures better than current processes because the new methods do not emit effluent gas and because they are commercially viable. Keywords: Flotation; chalcopyrite; molybdenite; oxidation; reduction

Jan 1, 2020

By V. Sheikhzadeh, M. R. Sheikhzadeh, A. Haratian, M. Zare

High Pressure Grinding Roll (HPGR) as an efficient grinding technology plays a major role in mineral processing plants. Investigating the effects of this technology on different parts of mineral processing circuits reveals this technology’s capability. In this paper, HPGR grinding effects on an iron ore beneficiation circuit, in comparison with conventional crushing systems were studied. A representative feed sample was taken from an iron ore beneficiation plant, then crushed to minus 6 mm in a laboratory by two methods: HPGR and cone crusher, and finally a concentrate plant circuit was simulated. Plant simulation was performed by doing laboratory tests consisting of grinding, magnetic separation, flotation and filtration on HPGR and cone crusher products, respectively. According to comminution tests results, in particle sizes smaller than 6 mm, a cone crusher product is coarser than an HPGR product. Also, the Bond ball mill work index of the HPGR product was 10% less than the crusher product. Therefore, based on the Bond formula in applying HPGR, ball mill power consumption decreased by 12%. After ball milling to minus 100 microns, magnetic separation tests results showed that the recovery of the cone crusher circuit output was 90.8% and the product Fe grade was 66.4%. For the HPGR circuit these figures were 87.6% and 67.3%, respectively. Therefore, by using an HPGR, a higher Fe grade of the final concentrate was achieved. A flotation test was then performed on the magnetic separation concentrate, where the results showed that the crusher circuit recovery and the sulfur grade of the product were 96.5% and 0.192%, respectively; whereas the HPGR circuit recovery was 97.2% with a sulfur content of 0.185%. Findings revealed that flotation performance in the HPGR circuit was more efficient than the crusher circuit. Vacuum filtration tests on concentrate produced through the HPGR circuit resulted in a moisture content of 12% that was 2% higher than the crusher circuit’s concentrate in the same condition. Keywords: High pressure grinding roll, power consumption, magnetic separation, flotation, filtration

Jan 1, 2020

By K. Shame, H. H. Thiele

South Africa holds approximately 70% of the world’s total chrome reserves. Chromium is an important raw material for the production of stainless steel and ferrochrome alloys. Over the years, China’s ferrochrome market has been dependent on chrome ore imports from South Africa. In 2018, China imported about 75% of its chrome ore from South Africa. With the low platinum price and the rising demand for stainless steel, a growing demand to evaluate new beneficiation technologies for fine chromite was identified. Gravity separation of fine chromite (<75 μm) is inefficient, due to the limitations of the technology to upgrade fine particle size distributions. Potential for the recovery of chromite, specifically fines (<75μm), lost to UG2 PGM flotation tails, but also from MG and LG6 spiral circuit tailings exist. Flotation of podiform chromite ores from India and Kazhkhstan is successful in generating saleable product grade, following acid or alkaline flotation routes. Application to South African stratiform chromite is being evaluated, with the emphasis on evaluating reagent type, optimising dosages and the effect of pH in optimising flotation performance. Flotation can unlock additional value from chromite tailings material. The effect of ore characteristics such as gangue mineralogy, particle size distribution and headgrade are reported. The performance in terms of product quality and yield are evaluated and compared. The impact of this paper will not only prolong life of mine and increase revenue but will also alleviate environmental burdens associated with tailings dams. Keywords: Chromite, flotation, fine material, performance optimisation

Jan 1, 2020

By M. Saghaeian, R. Hejazi, L. Hosseini, M. V. Sheikhzadeh

HPGR equipment has been well proven to be energy-efficient in the first stage of grinding in iron ore beneficiation plants. Numerous advantages of utilising HPGR grinding prior to ball mill grinding, such as reducing the power consumption in a ball mill through generation of micro-cracks, has been thoroughly studied. Less attention has been paid to efficiency of the HPGR circuit rather than the downstream ball mill circuit. In this study the HPGR circuit has been optimised through feed size reduction by crushing, and feed iron content upgrading by dry cobbing. This optimisation leads to better operation of the HPGR, and a smaller product size which is expected to result in a lower wear rate of ball mill liners and balls. It is also expected that the top size of the ball mill balls be reduced. Additionally, by reducing the feed size of HPGR from 30 mm to 15 mm, it is possible to achieve similar K80 of HPGR product in lowered pressure, i.e. 2.5 N.mm-2 instead of 3.5 N.mm-2 which translates to ease of operation. Similarly in a given roll pressure, smaller feed sizes result in higher specific throughput of ~10% which means higher production capacities. The results also reveal that this optimisation increases the concentrate weight recovery by about 10%. It also results in slight increases in the Fe grade of the product iron concentrate. Keywords: HPGR, HPGR circuit optimisation, crushing prior to HPGR, dry cobbing prior to HPGR, ease of operation, concentrate grade optimisation, weight recovery optimisation

Jan 1, 2020

By T. G. Pedro, Q. Gonzalo, R. E. Roberto

Anionic surfactants, such as oleic acid and sodium oleate (OLE), and cationic surfactants, such as dodecyl amine-hydrochloride (DDA), are used as flotation collectors of spodumene. However, recovery is poor even if activating ions are used because gangue minerals are also activated. Some reports demonstrate that OLE/DDA mixtures act as a selective collector to enhance spodumene recovery. From mostly macroscopic tests, it has been argued that anionic OLE and cationic DDA form electroneutral complexes, which are adsorbed on the mineral surface through chemisorption; however, no molecular evidence has been presented. Therefore, the adsorption mechanisms of the collector mixtures remain mostly unknown. It seems necessary to first study the behaviour of these surfactants confined in salt solutions, to determine auto-associations when they are pure and cross-associations when mixed, the transition from monomers to micelles, and the structure of the micelles and the effects of pH, temperature and concentration. In this paper, ab initio calculations are first used to determine the surface charge distribution of OLE and DDA separately. Then molecular dynamics simulations are used to determine the conformation, aggregation, and diffusion of these pure and mixed surfactants in freshwater and saltwater with the ionic strength of seawater in a pH range. In particular, it is interesting to determine the various associations that result in mixtures of both surfactants and the impact of alkali and alkaline earth metal cations on the structures formedp. Cations influence the order of the structure and orientation of water dipoles, reducing the mobility of water, ions, and surfactant molecules. This knowledge is critical to improve the molecular understanding of the adsorption mechanisms on minerals. Keywords: Computer simulation, molecular dynamics, flotation, collectors, saltwater

Jan 1, 2020

By P. F. Dicks, N. J. Shackleton, E. H. W. Theron, V. Malysiak

Flotation is a complex physical chemical process in which flotation reagents play a vital role in valuable minerals recovery and concentrate grades. This study examines the performance of new generation AECI Mining Chemicals (previously named Senmin) collectors. They were developed to enhance the valuable minerals recovery and flotation selectivity by tailoring the collectors to target specific valuable mineral species present in an ore and thus create added value for concentrators treating PGM ores. The case study was conducted on a Platreef ore, where batch flotation tests were performed and the concentrates were mineralogically characterised for PGE and BMS using QEMSCAN. Further batch flotation testwork was conducted on Merensky and UG2 ores from various localities in South Africa to confirm the trends observed for Platreef ore. The results have shown that there is a strong correlation between PGE mineral type and AECI Mining Chemicals collector type - clearly demonstrating that one reagent type does not fit all flotation applications. Keywords: Batch flotation, QEMSCAN, collectors, PGE and BMS

Jan 1, 2020

By K. C. Corin, M. S. Manono

The mining and mineral concentration of Cu-Ni-PGM sulfide ores in South Africa occurs in semiarid regions. The scarcity and availability of water resources in these regions has become one of the biggest challenges facing mineral concentrators.S Owing to this challenge, concentrators have to find ways through which they can manage and control their water usage. Recycling and re-use of process water in mineral concentrators has therefore become common practice. This practice is beneficial in that it reduces reliance on municipal water, harnesses compliance to stringent environmental regulations on water usage, and it also offers a better response to the Sustainable Development Goals. This could however be somewhat concerning to the operator as recirculated water often has higher concentrations of ions compared to fresh or potable water. The unintended change in the process water quality may potentially affect critical aspects of flotation such as the stability of the froth. This has led to the need to find those process water ions that have the greatest impact on froth stability. Thus, this paper investigates the effect of various ions common in process water of a typical Cu-Ni-PGM concentrator on froth stability. Bubble size, water recoveries, foam height, and dynamic froth stability in both twophase and three-phase flotation systems are used as proxies for froth stability. Findings of this study are deemed crucial towards the development of a process water management protocol in sulfidic Cu-Ni- PGM ore concentrators. Keywords: Bubble diameter, electrolytes, flotation, froth stability, water quality

Jan 1, 2020

By A. Y. Senchenkoa, Y. V. Kulikov

The relationships revealed between ore hardness and specific energy consumed by crushing and grinding are described in the paper. A comparison of key technical and economical parameters of SAG and HPGR circuits is made, based on testing of several ore types for greenfield projects. The comparison of results make it possible to estimate efficiency of the technologies application, depending on ore hardness and taking into account potential risks for a circuit under design. Keywords: Comminution circuits, SAG, HPGR, test results

Jan 1, 2020

By F. Qunfei, W. Laijun, X. Lyu, A. Cosmos, L Huijuan, Z. Jinggang, G. Yao

In this paper, four cyanide-utilising bacteria strains were isolated from a gold mine tailings pond, in the Hexi gold mine (Shandong), China. Based on the analysis of 16S rRNA gene sequence, four strains were identified as Aeromonas hydrophila strain C1, Bacillus mojavensis strain C3, Shewanella oneidensis strain C2, and Aeromonas media strain C4. Based on the cyanide detoxification efficiencies results of the four strains, Bacillus mojavensis C3 had the highest detoxification rate and was selected to assess its efficiency to detoxify cyanide in gold mine tailings at different pH (9.5, 10.5, and 11.6) using cyanide as the sole carbon and nitrogen sources. Strain C3 was capable of detoxifying 46.5mg/L of cyanide-containing gold mine tailings at all tested pH ranges at 30oC, 196 rpm after 15 d. The amounts of cyanide detoxified were 87.5%, 84.1%, and 73.5% at initial pH 9.5, 10.5, and 11.6, respectively. The highest cyanide detoxification was observed at pH 9.5. The viable cells growths in the samples were 5.7E+09CFU/mL, 4.9E+09CFU/mL, and 2.7E+09CFU/mL at pH 9.5, 10.5, and 11.6, respectively. Free ammonia concentrations were observed as a byproduct of the biodetoxification process. The residual ammonia concentration in the sample was observed at 0.35 mg/L, 0.33 mg/L, and 0.62 mg/L at pH 9.5, 10.5, and 11.6, respectively. The highest residual ammonia concentration was noticed at pH 11.6. The amount of cyanide removed by mixed culture strains C3 and C4 was 94.6% and showed a residual free ammonia concentration of 2.6mg/L, as biodetoxification byproduct after 120 h. The pure culture Bacillus mojavensis strain C3 and its mixed culture strains exhibited higher potential to detoxify cyanide-containing gold mine tailings at alkaline pH values and could be cultivated to detoxify gold mine effluents at large-scale. Keywords: Bacteria strain, cyanide, detoxification efficiency, gold mine tailings

Jan 1, 2020

By D. Das, B. K. Nandi

The present study focuses on utilising the electrocoagulation (EC) process for the treatment of process water generated in an iron ore beneficiation plant for safe discharge and reuse. Removal of heavy metals like Fe, Cr, Cu, Zn, Mn and Pb which was found in higher concentration along with some other impurities exceeding the permissible and discharge limit were attempted. The influence of different electrode material, current density, inter-electrode distance, and solution conductivity was explored for effective removal of the metal ions. Experimental results infer that almost 99.95% Fe, 97.77% Cr, 73.44% Cu, 99.34% Pb and 88.69% Mn was removed using aluminum electrodes at monopolar mode at a current density of 68.50 A/m2, inter-electrode distance of 1 cm and solution conductivity of 1.033mS after 60 min of EC. In addition, removal of other toxins like TDS, turbidity, salinity and conductivity etc. was also assessed during the process. Removal of such heavy metal ions by EC was found to follow 1st order kinetics with electric energy consumption of 3.93 kWh/m3, electrode consumption of 0.1191 kg/m3 and operating cost of 0.6115 US$/m3 respectively. Keywords: Fe removal, electrocoagulation, Al electrode, turbidity

Jan 1, 2020

By M. Buchmann, T. Mütze, F. Heinicke

Dry air classification is a well-known technique used for decades in the cement industry to separate material in the size range of 0.01-1.0 mm. Additionally, in corresponding dry grinding circuits with effective machines such as High Pressure Grinding Rolls (HPGR), the energy consumption can be reduced compared to wet applications. These dry systems are not state of the art in minerals processing plants, but first prototypes have been installed and an increasing number of projects are starting to evaluate this option. One challenge in this field is the mineral composition of ores, which have, by far, a higher variety in density and size than those of cement. High density particles such as iron- containing ones have higher settling rates than low density silica particles of the same size. The main question to answer in this paper is how to evaluate this effect, so a quantitative method using Mineral Liberation Analyses was developed to calculate two-dimensional partition curves. Additional statistical analyses allow for isolation and quantifying the interaction of density and size, enabling engineers to consider this effect for the sizing of process plants. The paper will present the method and selective results for a compounded ore of iron and silica. Keywords: HPGR, air classification, partition curve, MLA

Jan 1, 2020

By A. A. Rogozhin, S. I. Anufrieva, A. V. Kurkov

The results of development of technologies for flotation concentration of two types of complex beryllium ores are presented: beryllium-fluorite in apocarbonate metasomatites (Type I) and rare-earthberyllium in feldspar metasomatites (Type II). The researched samples of Type I ores contain a mineral complex that is difficult to separate by fatty acid flotation, including phenakite, bertrandite, fluorite, and carbonate minerals. The ores are characterised by an increased content of fluorite and carbonates. The sample of Type II ore contains such rare-earth minerals as bastnesite and orthite, and a beryllium mineral - cleiophane. The size of individualised grains of cleiophane does not exceed 0.04 mm, which significantly limits the possibility of extracting the mineral into the enrichment concentrates. For the Type I ores, a technological process for the extraction of fluorite using a phosphorus-containing reagent from the class of dialkylphenyl polyethylene glycol esters of phosphoric acid (DAPEGEPhA) has been developed. The use of DAPEGEPhA enables the production of a high-grade fluorite concentrate (95% CaF2). The production of commodity phenakite-bertrandite high-grade (10% BeO) flotation concentrate from the fluorite flotation tailings with using a fatty acid collector is based on binding calcium in the flotation pulp using soda, sodium hydroxide and sodium tripolyphosphate. The use of a combined collector based on fatty acids and DAPEGEPhA made it possible to produce a collective rare-earthberyllium- lithium concentrate with high REE extraction (88%) from the Type II ores. The concentrates obtained are suitable for production of commercial-grade hydrometallurgy products. Keywords: Beryllium ores, flotation, reagents, concentrates, hydrometallurgy products

Jan 1, 2020

By G. Akdogan, I. J. Geldenhuys, Q. G. Reynolds

Efficient recovery of titanium from titaniferous magnetite ores continues to be a promising, yet unrealised opportunity, despite significant occurrences of titaniferous magnetite deposits worldwide and the existence of established industrial-scale practices. Current smelting processes only recover iron and vanadium, while the titanium is discarded in the waste slag. These slags are stockpiled and present massive environmental challenges, while still containing value as residual iron, vanadium and titanium. The complex mineralisation of these deposits does not allow for a significant opportunity to separate the titanium and magnetite minerals through normal physical upgrading processes. An upgrading process is therefore required to derive economic value. An efficient process technology could create an opportunity to unlock all three valuable commodities. South Africa’s Bushveld Complex, the largest known deposit of its kind in the world, is known for the high vanadium content but is also associated with relatively high concentrations of titaniferous magnetite. The quality of the Bushveld Complex was one of the drivers for the establishment of the Highveld Steel and Vanadium Company in the mid-1960s. The unfortunate demise of Highveld Steel and Vanadium created an opportunity to review current practices and evaluate the best available process for this complex ore in the context of the three elements of interest. Past and current processes, the nature of these deposits and the potential to recover titanium are assessed to highlight the potential of fluxless smelting of titaniferous magnetite to produce a titania-rich slag as feedstock to the pigment, titanium metal industry in conjunction with recovery of iron and vanadium. Ilmenite smelting practices are proposed as a suitable alternative to achieve the goal, namely sustainable processing. Keywords: Titaniferous magnetite, titanomagnetite, smelting, titania slags, comprehensive processing

Jan 1, 2020

By S. Zhang, Z. Hua, D. Feng, X. Tong, X. Xie

The separation and beneficiation of low grade collophanite has long been a technical challenge in phosphorous production. It requires the joint efforts of process design, reagents optimisation and operational control. In this study, the statistical response surface method was applied for determining the optimum reagent dosing in the flocculate flotation of a low grade (18.59%) collophanite ore. The dosage of three reagents, including a pH regulator (Na2CO3), depressant (Na2SiO3) and flocculant (modified starch), were input parameters of the modelling design. Two quadratic mathematical models were derived for prediction of grade and recovery based on the statistical design. Statistical analysis of the experimental results validates the reliability of the models. Through further calculation, the optimum dosage of the three reagents were found to be 3,020g/t Na2CO3, 1,990g/t Na2SiO3 and 880g/t modified starch, with which a maximum recovery of 75.81% and P2O5 grade of 30.08% was obtained from flocculate flotation test. Keywords: Process optimisation, modelling, froth flotation, collophanite ore, response surface methodology

Jan 1, 2020

By L. S. Bicalho, W. J. Rodrigues, P. M. A. Rollo, P. R. G. Brandão, W. C. da Silva

Quadrilátero Ferrífero is an important mineral province located in Minas Gerais state, responsible for a substantial amount of iron production in Brazil. Among the concentration methods for iron ore practised by the mining companies in this region, the most important is the reverse cationic flotation. Dolomite iron formations, with the presence of hematite, quartz and dolomite, occur in several areas of mining and, with the deepening of the deposits, this type of ore, with low iron content and more complex mineralogy occurs frequently. Carbonaceous minerals, mainly dolomite, present a technological challenge for the concentration of iron ore by flotation. In the present study, the concentration of iron ore with 6% of dolomite content was evaluated. Bench flotation trials indicated that conventional iron ore flotation is not selective to float dolomite, thus compromising the iron content in the final concentrate. Alternative flotation routes were evaluated, and a selective condition was reached to float both quartz and dolomite using the combination of the cationic collector Flotigam 16424 with an anionic collector Flotinor 16551. It was demonstrated that the flotation of dolomite was improved with the combined use of both collectors in the cleaner stage, and by a previous quartz flotation in the rougher stage. Zeta potential analysis indicated specific adsorption as the adsorption mechanism between Flotinor 16551 and dolomite, confirming the high selectivity observed in the bench flotation tests. Keywords: Flotation, iron ore, dolomite

Jan 1, 2020