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By H. Jung, J. Kim, Y. Lee, Y. Seo

"Shale gas has become an increasingly important source of natural gas supply in North America and around the world. Horizontal drilling and multi-stage hydraulic fracturing are the two key enabling technologies for the economic development of these shale gas reservoirs. It is believed that gas in shale reservoirs is mainly composed of free gas within fractures and pores and adsorbed gas in organic matter (kerogen). It is generally assumed in the literature that the monolayer Langmuir isotherm describes gas adsorption behavior in shale gas reservoirs. In this work, we have analyzed several experimental measurements of methane adsorption from the Horn River Shale core samples that obey the Langmuir isotherm. INTRODUCTION In nature, gas shales are characterized by extremely small grain size, extremely low permeability on the order of nano-Darcy (10-6 md), small porosity, and high total organic carbon (TOC). Shale can serve as both source and reservoir rock. The amount of gas in place in shale is strongly affected by the TOC, clays, and the adsorption ability of methane on the internal surface of solid (Martin et al., 2010). Since a considerable amount of gas in shale reservoirs is adsorbed, investigation of gas adsorption can provide critical insights into evaluation of well performance and reservoir characterization. Generally, natural gas in shale reservoirs is stored as free gas in both larger mineral pores and natural fractures, as well as adsorbed gas within organic matter (Leahy-Dios et al., 2011). EXPERIMENT METHOD & THEORY Adsorption Experiment Several experiments were carried out on 9 shale core samples obtained in a vertical well drilled within Horn River basin (Figure 1). The CH4 adsorption isotherms were measured for the different depth. In order to measure the amount of adsorbed gas, the high pressure Belsorp-HP equipment applying volumetric method was used. The temperature was kept at 298 K and pressure was increased up to 18 MPa. Approximately 5 g of crushed sample was used for each measurement."

Jan 1, 2016

By Bret N. Lingwall, Byron Foster

The problem of reliable extreme event modeling of large diameter piles under enormous structural or kinematic loads has gained more attention in recent years. In particular, the soil response around the foundation and impacts to buried adjacent infrastructure has gained interest. One of the principal shortcomings with analysis of large diameter pile foundations under extreme event lateral loading is the reliance on conventional beam on elastic foundation methods, which do not model the soil field response around the pile. These methods are limited for large displacement problems, and for large diameter piles. However, the fundamental interactions between steel and concrete, and structure to soil are difficult to constrain, especially in large strain problems where the structural elements become inelastic. The non-linear interaction of the structural materials and soil is desirable so that assessment of stress changes in the field and effects on adjacent facilities can be modeled. A numerical modeling methodology that addresses these shortcomings has been developed. This method utilizes the interaction of brittle concrete with discrete steel reinforcing and casing in a robust manner capturing inelastic non-linearity in both soil and structure. This paper presents a comparison study of the method, wherein three different validation studies were made to data from full scale laterally loaded pile testing. INTRODUCTION Extreme event lateral loading of deep foundations comes in many forms including earthquakes, landsliding, tsunamis, hurricanes, surface fault rupture, liquefaction induced lateral spreads and many more. These extreme events induce loads on foundations far greater than service or strength loads. Perhaps the most dangerous extreme event loads are those of large soil displacements such as landslides, lateral spreads, and surface fault rupture, wherein the soil surrounding the foundations can move laterally 100 mm to 3 m! In these extreme event loading scenarios, small diameter foundations are pushed past their limits and many engineers prefer large diameter deep foundations for these situations. These deep foundations of diameter 900 mm or greater may be auger cast in place piles, cast in drilled hole piles, cast in steel shell piles, cased or uncased drilled shafts, bored precast piles, etc. For convenience in this paper, large diameter deep foundations will be referred to as Large Diameter Shafts (LDS). In LDS, steel may or may not used as a shell around the perimeter of the concrete and/or as internal tensile reinforcement. The interaction between brittle concrete and ductile steel within and/or along the perimeter of the LDS is critical to understanding the non-linear inelastic behavior of LDS for problems of large lateral displacements from extreme events.

Jan 1, 2018

By R. HAYDEN, H. B. HALLOWELL, H. O. Hofman

THE object of refining copper in the reverberatory furnace is to obtain a metal which will have the highest attainable degree of malleability, ductility and electric conductivity, and present at the same time a level surface when it solidifies in the mold after casting. These desirable physical properties are governed by the character of the impurities and the forms in which they are present, by the amount of cuprous oxide retained by the copper, by the quantity of gas held in solid solution, by the casting-temperature, and by the thickness of the casting. The effects of impurities, of cuprous oxide and of gases upon the mechanical properties of copper have been studied by Hampe in his classical paper "Contributions to the Metallurgy of Copper." The most recent research into the effect of metals upon the electrical conductivity of copper is that of Addicks.2 The influence of cuprous oxide upon the electrical conductivity has been investigated by Walker' and Addicks.4 The absorption of gases has received' attention by Hampe,5 Stahl 6 and Heyn.7 The effects of casting-temperature have been noted by Stahl.8

Mar 1, 1907

By M. G. Cheney

THE production record of the Sinclair-Moren pool, in southeast Young County, Texas, demonstrates that under efficient operating methods a single well may obtain normal oil recovery from an area of 100 acres or more. This record is the more surprising in view of relatively adverse reservoir conditions such as lack of water drive, moderate initial reservoir pressures and a consolidated sandstone reservoir with original permeability greatly reduced by processes of lithification. This case history is considered worthy of special study in view of the ever present problem of proper spacing of wells. Cupidity, abetted by the unrestrained law of capture, has in too many instances guided development and production methods without regard for sound economic and engineering principles. Largely as a result of ill advised spacing of wells, many oil fields have brought financial losses instead of deserved profit to those using capital, time and energy in this important business of adequately meeting the petroleum requirements of what is known as our modern civilization. In March 1923, the Sinclair Oil and Gas Co. obtained initial daily production of about 12,000,000 cu. ft. of gas and 1100 bbl. of oil in its first well near the center of a 372-acre lease on the L. P. Moren land, James Rose survey, Abstract 245. This exploratory test was drilled as a geological prospect of average promise, on a plunging anticline with possibly 10 ft. of closure as mapped on the outcropping limestone of upper Canyon (Pennsylvanian) age. In subsurface, the top of the producing res-ervoir is 16 ft. lower in this well than in the highest wells but probably 25 ft. above lowest closing contour. Wells No. 2 and 3 were drilled about 1/4 mile west and southwest near a normal fault with some 30 ft. of downthrow to the southwest. The producing sand was reached at a depth of 2512 ft. and drilled to 2529 ft. in the first well. This sandstone reservoir is of Millsap Lake (middle Strawn, upper Cherokee) age. It was absent in the second and third wells, which were abandoned at the depths of 3725 or more. In April 1925, a fourth well was drilled 600 ft. east and 24 ft. lower for top of sand than No. I. Production of about 100 bbl. daily was reported from 2521 to 2562 after an 80-quart shot. This well was drilled to 4560 ft., plugged back to 2575 and shot again; but was abandoned soon thereafter because of small production.

Jan 1, 1940

By R J. Longbottom

In this study the bonding within reduced titanomagnetite-coal compacts was investigated. The aim of the study was to better understand the binding mechanisms in the reduced compacts and, based on this understanding, to improve on their strength.Titanomagnetite ore was combined with sub-bituminous coal to form compacts. The compacts were then reduced by heating in a thermogravimetric furnace (TGA) to temperatures between 1000 - 1300°C under argon. The reaction progress was monitored by measuring the weight loss with time. The reduced compacts were found to have low strength in compression testing. The main form of bonding between the reduced titanomagnetite particles in the compact was by the formation of a slag-like material. Increasing the fi nal reduction temperature was found to have a profound effect on the strength of the compacts by promoting the formation of this slag-like material.Attempts to improve the strength of the compacts were made by changing two variables, the type of coal and the addition of rice husks. The addition of coking coal gave reacted samples that had little strength, while the addition of rice husks may have enhanced the strength of the reduced compacts.

Jul 11, 2011

By Gordon A. Irons, H. Y. Hwang

An impinging gas jet on a water surface was studied to understand momentum transfer in oxygen steelmaking. Depth, width and oscillation frequency of the jet cavity were measured and the splashes interpreted with Kelvin-Helmholtz instability and combined Rayleigh-Taylor and Kelvin-Helmholtz instability theory. A model to calculate separate gas and liquid velocities, applying the exact momentum boundary condition, is proposed.

Jan 1, 2004

By R. P. Charbonnier

"To understand the operation of jigs and other separating processes based on differences in gravity, it is desirable to analyse the motion of various particles in given media under specific conditions. A summary of the earlier theories shows that they lead to unsatisfactory or excessively complicated formulae in cases such as coal jigging. By adopting a simplified theory of the motion of particles in a fluid, the size and duration of the initial accelerated motion of a particle falling in hindered settling can be calculated. Based on this mathematical analysis, examples referring to actual coal jigging practice show that it is desirable to prolong and/or repeat, as frequently as possible, the optimum conditions corresponding to an effective acceleration of the particles. The separation is then obtained according to gravity rather than to particle dimensions, as would be the case if the velocity of the particles• were allowed to approach its terminal value. To achieve this gravity separation, it is suggested that the suction phase of the jigging cycle be artificially prolonged and the frequency of pulsations increased as much as possible for washing the coals of smaller sizes."

Jan 1, 1959

By Susan Jacob

The heat of fusion of silver was measured using high temperature differential scanning calorimetry (HTDSC). Heating rate, sample mass, calibration standard and cover gas flow rate were varied to determine their impact on instrument accuracy and reproducibility. Good reproducibility was achieved in most of the runs. Accuracy was not satisfactory in most of the runs, though three runs gave results within 1.7%, 3.3% and 3.5% of the literature value, within the acceptable limits. A larger mass and higher heating rate tend to generate more accurate results.

Jan 1, 2006

By D. Harker, M. J. Murphy

THE mechanism by which age-hardening takes place is still not completely understood. The principal theories range from the extreme of "precipitation-hardening" to that of "order-hardening," with many intermediate gradations. In the hope of obtaining new data on which to base a choice among the many theories, the authors have made electron micrographs of formvar replicas taken from metallic specimens at various stages of age-hardening. The results so obtained on an alloy of 2 per cent beryllium in copper and one of 20 per cent molybdenum in iron will be described in the following pages, as well as the technique used in preparing the replicas. PREPARATION OF FORMVAR REPLICAS OF METALLIC SPECIMENS This section is concerned with the techniques that have proved successful in preparing formvar replicas for studying the microstructure of metals with the electron microscope. Because of its simplicity and accuracy, the formvar replica1 method developed in the General Electric Research Laboratory has been used exclusively, since it is much simpler than the silica replica method of Heidenreich and Peck2 and produces as good results. The formvar method to be described requires a technique acquired only by practice, and no foolproof set of rules can be given. It is a rapid method and a replica can be obtained in less than five minutes under favorable conditions. This does not mean that perfect replicas can be produced every five minutes, but rather that one can well afford to take several strippings* in order to produce a replica of high quality. The metallographic technique required for replica work-very fine polishing and etching with very dilute solutions-is described here. It can be said, in general, that almost any surface that has been carefully prepared for a photomicrograph at 1000 or more diameters can be used to obtain a replica for the electron microscope. PREPARATION OF METALLOGRAPHIC SPECIMENS The preparation of the metallographic specimens is somewhat more exacting than that usually given to samples to be used for inspection under the light microscope. After much experimentation, it was concluded that the best method consists in polishing the metal through to the coarse cloth, then etching and repolishing on final cloth until the layer of distorted metal is removed. After this procedure has been completed, a dilute etch-to approximately the depth necessary for a micrograph at 1000 diameters-usually produces a sur-

Jan 1, 1945

In an area north of Mowit Ica chip sampling of limonitic outcrops on a regional scale led to the investigation of a number of areas considered to be geochemically anomalous for copper and zinc. These areas were closely gridded,end where geochemical results were favourable, they were subsequently drilled or ro¦titeaned Che results indicated that for copper Lne anomalies were mainly associated wiL_ ironstone formed in areas of faulting. is suggested that copper is able to move considerable distances by ground water movement and is likely to be fixed under conditions of low pH. The movement of zinc is more difficult to explain but it appears to have an affinity for iron and is only deposited in areas having a high pH (i.e. doioiirific scdimet=Cs).

Jan 1, 1973

By Wan Pu

Chrysotile asbestos samples from different mines have been studied by SEM and TEM, including high resolution electron microscopy, to find reasons for differences in physical properties of different types of asbestos fibres. The results show that the inner diameters of fibre tubes and the lattice images of fibres are different for soft and hard asbestos fibres. These differences are related to temperatures and geochemical conditions during the growth of chrysotile asbestos.

Jan 1, 1989

By Thomas J. Kennedy, Michael D. Bennett

The study of geotechnical history is well-established. Most geotechnical practitioners, teachers, and graduate students have some grasp of the origins of the field. However, this understanding often consists of a jumble of names and anecdotes. This paper discusses how a deeper comprehension of geotechnical history can benefit academia and practice alike and describes how the authors have begun a wide-ranging study of the subject. The paper reviews the dual-track methodology the authors have generated for the study, which consists of written articles about different works in geotechnical history and a database tracking how often pieces have been cited in geotechnical literature. The first technique has shed light on aspects of geotechnical history such as the connection of the Darwin family to the origins of geotechnical engineering, the St. Francis Dam failure of 1928, and the rivalry between theoreticians and practitioners in the early days of the field. The second has helped quantify subjects such as the outstanding contributions of Karl Terzaghi, the disagreements between Terzaghi and Donald Taylor, and the specialization of the field over time. The paper concludes by discussing the authors’ planned future work on geotechnical history.

Oct 1, 2022

By M. T. Ityokumbul

The liquid phase mixing in Western Research Centre (WRC) pilot plant flotation column with diameter of 0.76 m has been characterized using a salt tracer. The process variables studied were gas and liquid flow rates. The response of the column to a tracer pulse input was monitored at three axial and two radial locations. For all the experimental conditions investigated in the present study, radial and axial concentration gradients were not observed. It is thus concluded that the 2 tph flotation column is behaving as a well mixed tank. This finding is consistent with the observed poor recoveries of coarse fractions in the column flotation circuit. Based on the findings of this report, it is recommended that several schemes of reducing the backmixing be implemented and evaluated for their effectiveness in improving the column recoveries.

Jan 1, 1994

By A. M. Taweel, M. T. Ityokumbul, A. I. A. Salama, M. W. Mikhail

The liquid-phase mixing within CANMET's Western Research Centre's (WRC) 0.76-m-diem pilot-plant flotation column was characterized using a salt tracer. The process variables studied were frother addition and, gas and liquid flow rates. The response of the column to a tracer pulse was monitored at three axial and two radial locations. The results showed that the 2-tph flotation column was well mixed. Discussed are the implications of this observation to column design and scale-up.

Jan 1, 1996

By D. F. Malan, D. Ile

This study explores the use of backfill in hard rock bord-and-pillar mines to increase the pillar strength and extraction ratio at depth. The use of backfill will also minimize the requirement for tailings storage on surface and the risk of environmental damage. A literature survey indicated that backfill is extensively used in coal mines, but rarely in hard rock bord-and-pillar mines. To simulate the effect of backfill confinement on pillar strength, an extension of the limit equilibrium model is proposed. Numerical modelling of an actual platinum mine layout is used to illustrate the beneficial effect of backfill on pillar stability at greater depths. The magnitude of confinement exerted by the backfill on the pillar sidewalls is unknown, however, and this needs to be quantified using experimental backfill mining sections equipped with suitable instrumentation.

May 3, 2023

By F. Boudreault, C. Hendricks, M. Scobie

Drilling accuracy represents an important quality control factor in minimizing dilution. Apart from geology, the factors governing drilling accuracy are largely within the control of the mine. Setup location and alignment, as well as actual drilling accuracy, can all be monitored toward their improved control. Trajectory deviation during drilling, although usually beyond the control of even the most experienced and conscientious driller, can be accounted for (if not full controlled) by down-hole surveying of blastholes prior to explosives loading. This paper reviews the available instrumentation for improved drill setup and recent field experience with several commercial systems designed for monitoring borehole deviation. It reports on a recent survey of 50 Canadian mines which use blasthole stoping and addresses the reasons for the apparent lack of interest in instrumentation: i.e. does this reflect a lack of awareness of the technology, perceived inadequacies in its performance or a predominant reliance on productivity (drilling and mucking) as a measure of operational efficiency? The survey findings supported the latter viewpoint and showed that very few Canadian mines operate drilling incentive programs that are related to drilling accuracy.

Jan 1, 1994

By Kathleen M. Kowalski, Audrey Podlesny

The Maslach Burnout Inventory (MBI) was administered and scored for 154 Mine Safety and Health Administration (MSHA) employees kom the US Department of Labor. These employees serve as accident investigators for serious accidents and fatalities as part of their job duties. During a workshop on stress designed for them, subjects volunteered anonymous written anecdotes, confirming and illustrating the findings. The subjects represented locations across the USA and all mining commodities: coal, metal, non-metal, stone, and sand and gravel. The Maslach Burnout Inventory assesses three aspects of experienced burnout: emotional exhaustion, depersonalisation, and reduced personal accomplishments. The average results of the scores for each of the three subscales for the study group of MSHA accident investigators fell in the moderate range. These scores show that the subject population was at some risk for emotional exhaustion and depersonalisation, tending toward burnout. The group evidenced a lower sense of personal accomplishment in their jobs, indicating a higher risk for burnout. From this outcome accident investigators may be at moderate (note: this does not mean average) risk for burnout. The authors recommend follow-up with this population - specifically in training to work with grieving families; and greater organisational support for the accident investigators in this area would be appropriate. Keywords: Burnout; accident investigators; occupational safety and health; job stress.

By M McGeough

Following the success of calcrete sampling at Challenger, calcrete sampling has been widely adopted as the primary exploration technique for gold exploration, in the Gawler Craton. Calcrete is uniformly distributed over large areas and produces discrete gold anomalies. This allows drilling to focus on specific gold anomalous targets. However, despite widespread use of calcrete sampling, very little is known of the origin of calcrete in the Gawler Craton, and the link between calcrete gold anomalies and primary mineralisation. In an attempt to understand this association Lisa Gibbons recently completed an honours project at the Old Well Prospect approximately 45 km SSE of Tarcoola. Her work is part of a collaboration between CRCLEME, MESA and MIM Exploration. At Old Well, a calcrete anomaly (>10 ppb Au)covers an area approximately 7 km x 2 km with a peak value of 97 ppb Au. The study looked at the regolith as a whole, processes of its formation and nature of mineralisation within it. She was able to combine previous calcrete and drilling results with her own observations. The results from this study highlighted problems in relating surface calcrete anomalies to in situ gold mineralisation.

Jan 1, 1998

By Chen Wen, Li Zhao-jia, Zhao Qiang, Ning Shun-ming, Tang Sanchuan, Wang Hong-qiang

"The carbon-burdened and cold-bonded pelletizing-electrosmelting process is used to dispose low-grade manganese, and the qualified rich-manganese slag is obtained. On the condition that reduction roasting temperature was 1000?, reduction time was 45min, particle-size was -1mm, reductant dosage was 1.6%, basicity was 0.3, smelting temperature was 1410?, smelting time was 60min, it had a good effect on the melting between slag and metallographic phase, the manganese content was 32.58%, manganese recovery was 92.16% in the slag; while the iron content was 94.40%, iron recovery was 95.32% in the metallographic phase. It was proved by the demonstration tests.IntroductionManganese is an important raw material for steelmaking, which is extensively utilized in modern industry, the consumption of manganese for iron and steel industry accounts for 90% to 95%. After mining over 30 years, the high-grade manganese resources drop markedly, especially with the hypergrowth of steel industry, the domestic manganese is far from the requirement, as a result, we have to buy significant quantities of manganese overseas. Besides, the property of imported manganese is more and more complex, and the high-grade and lump manganese decrease year by year, while the fines and high-crystal water manganese are on the increase. Therefore, how to make effective use of domestic low-grade manganese and intensify the manganese’s smelting is an effective approach to reduce the cost of manganese series ferroalloy and improves market competitiveness[1-4]. It has important practical meaning."

Jan 1, 2012

By P. Somasundaran, Yee-Ho Wang

Carrier flotation of anatase impurities from clay using oleate is compared in this study with conventional flotation. The role of relevant parameters such as carrier size, carrier amount, dissolved calcium and carbonate, conditioning speed, pH, time and temperature and collector concentration is investigated in order to elucidate the mechanisms involved in carrier flotation. Addition of coarse calcite particles is found to contribute towards the enhanced separation of anatase from clay mainly due to aggregation of anatase fines with calcite and the subsequent flotation of the aggregates.

Jan 1, 1980