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By F F. Pitard

The optimization of metallurgical processes requires knowledge of the heterogeneity carried by constituents of interest. The common scenario, almost an industry standard, is to rely on the engineering firm who in turn relies on favorite manufacturers of sampling equipment to provide the appropriate sampling systems in the plant to perform accurate metallurgical accounting. This sequence is flawed from the beginning to the end because everything should be based on a careful understanding of the Theory of Sampling (TOS) by the company project team and their expert who invariably would suggest various approaches and different sampling systems.The necessary progressive and iterative approach should be that the company’s project team (mining or other industries) would do its home work to have a good understanding of the geometallurgy, mineralogy and texture of the ore in each geological unit so consultants and engineers would have the best information to start with. Then a reputable sampling expert would recommend which sampling systems are needed, so the company would require engineering firms to follow pre-established, non-negotiable requirements, and finally select the sampling equipment existing on the market today that is most likely to lead to accurate and precise enough metallurgical accounting.It is the author’s experience that when this necessary progressive and iterative approach is bypassed, sampling systems installed in the plant are likely to transgress the most elementary rules of sampling correctness. Invariably the argument is that the company cannot afford correct sampling systems for metallurgical accounting as suggested in the Theory of Sampling. There is nothing that is farther from the truth when later problems will develop and inevitable reconciliation difficulties with miners and geologists become daily routine with impossible answers; as a last resource the sampling expert may be called to perform a post-mortem analysis.The progressive and iterative approach suggested in this paper should be a due diligence requirement for any bank providing a loan for an important new mining project; anything less is most likely to generate unpleasant financial losses; historical, well-known examples are referred to.CITATION:Pitard, F F, 2015. A progressive, iterative approach leading to reliable metallurgical accounting sampling systems, in Proceedings MetPlant 2015, pp 78–91 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 7, 2015

The Effect of Mineral Liberation on the Floatabilities of Pyrite, Arsenopyrite and Arsenian Pyrite for Carlin Trend Ores

Sep 13, 2010

By Andrew Wessman

Keywords: Recycling, Electrodeposition, Recovery, Dilute, Dissolved Metal Ions In order to facilitate the recovery of pure metals from solutions containing a mixture of dissolved metal ions, a pulsed electrodeposition method was developed. Using this method, it is possible to selectively remove metal ions from solution based upon the electrochemical potential of the particular ion desired. The use of pulsed electrodeposition rather than direct current electrodeposition creates an electrodeposited material with better morphology, increases electrical efficiency of the process, and avoids problems with short circuiting between electrodes. Using this method, it is possible to recover dissolved metal ions in a purified form in one simple step, and therefore maximizes recovery of the metal ions while obtaining them in a saleable form. This method is likely to be useful in improving the recycling process for numerous complex metal mixtures and alloys.

Jan 1, 2005

By Roberto C. G. Oliveira, Scott C. Brown, Brij M. Moudgil

"The wettability or surface energy of particle surfaces dictates a number of multiphase ensemble interactions that have a significant impact in mineral processing. Dispersion, bulk powder handling and flotation are just a few of the processes that are largely influenced by the degree of hydrophillicity or hydrophobicity on particulate surfaces. Because of the importance of surface wettability, a number of simple, precise and accurate techniques for accessing surface wettability or contact angle on macroscopic flat surfaces have been developed. However, these techniques cannot be directly applied to the particulate surfaces that are often in query. Though a number of techniques are available for accessing the wettability of particulate surfaces, these methods are either relative, application specific or prohibitively tedious. In the present study, key features of existing techniques are combined to formulate an improved method to delineate particle wettability that is simple, versatile and capable of providing reproducible measurements in an industrial environment.Through the use of an inert adhesive and an inert macroscopic surface as a support, it is illustrated that precise measurements of particle wettability are obtainable under suboptimal or ‘shop floor’ conditions. The measurement of the maximum external meniscus height formed between a test liquid and a particlecoated rod is employed to estimate phenomenological contact angles on particles ranging form a few nanometers to several hundred microns in size."

Jan 1, 2003

By Murali M. Gadde

Welded wire mesh is the most commonly used skin control technique in the United States underground coal mines. Currently, selection of the mesh is based on trial and error rather than any rigorous design methodology. Several factors affect a wire mesh?s performance including the amount of rock material to be supported and how the load is distributed, wire gauge, aperture size, grade of steel, weld strength, bolting pattern and sheet size. Although the best way to choose the mesh is to conduct full-scale physical load tests, because of the limitations on the number of variables that can be considered in such tests and the requirement of an elaborate test set-up, it may not always be possible to use this option. An alternative would be to use numerical modeling to study the load-deformation behavior of a wire mesh. In addition to providing a very detailed stress, strain distribution in the entire mesh, the advantage of this approach is the ease with which parametric studies can be conducted. In this paper it is shown that the load-deformation curves generated by nonlinear numerical models match closely with laboratory derived ones. Then, based on parametric studies, design guidelines are developed to choose the mesh appropriate for different loading conditions. The modeling studies also bring forth the limitations of the current lab studies. For example, under some conditions it was noticed that the small sheet size considered in lab tests would produce higher mesh deformations than a full-size one used in actual practice.

Jan 1, 2006

By Donald W. Baggs

This report describes economic mining feasibility studies conducted by the Bureau of Mines to estimate mining costs in the Porcupine mining area of the Juneau Mining District, southeastern Alaska. Investigations were conducted on the economics of three mineral deposit types: 1) massive sulfide deposits containing zinc, copper, and silver, 2) vein gold, and 3)disseminated gold. Cost estimates were developed using the Bureau of mines Cost Estimating S,-stem. Discounted cash flow rates of return were calculated using the Bureau of Mines MINSIM (mining simulation) computer program. Three sets of metal prices were used in the study based on recent historical price information. Underground longhole stope mining of a massive sulfide deposit containing 25 pct zinc. 1 pct copper, and 63.6 g/mt silver was found to be economic at high metal prices at a quantity of 13,200,000 mt ore. Cut-and-fill mining of a 26,400,000 mt massive sulfide deposit was found to be economic at medium metal prices. Open pit mining of a similar deposit was found to he economic at medium metal prices and 26,400,000 mt ore, or at high metal prices and 6,600,000 mt ore. Underground mining of a vein gold deposit was found to be economic at a grade of 17.1 g/mt medium metal prices and 1,320,000 mt ore. Open pit mining of a disseminated gold deposit was found to be economic at a grade of 1.71 g/mt medium metal prices and a quantity of 39,600,000 mt ore.

Jan 1, 1986

By Irwan S. Halim

For tunnels in horizontally bedded rock, geologic factors affect the selection and design of the initial supports, including the rock propensity toward parting along bedding and the resulting high potential for rock slabbing during excavation. To evaluate this ground behavior, numerical analyses and results with Mohr-Coulomb, Hoek-Brown, and Ubiquitous Joint constitutive models were used, using the Upper Rouge CSO tunnel in Detroit, Michigan as an example. The different rock models and other geologic considerations are shown to impact the selection of the tunnel initial support and design. This paper emphasizes the appropriate selection of an analytical model based on the site specific geology to achieve an optimum initial support design.

Jan 1, 2008

By Clyde L. Brown

The ignition source of fires and explosions in coal mines is sometimes difficult to explain because resulting widespread destruction often erases valuable evidence that might reveal the cause. However, through years of experience, investigators have been able to piece together enough evidence to establish the reasons and, thereby, have been equipped to recommend corrective or preventative measures. The pattern of hazards is not constant. It changes with the development of new practices and new equipment. Important among the new hazards to coal mining are those introduced by electricity. In addition to the dangers of electric shock, fires and explosions from heat and arcs, and premature blasts, certain others have developed as a result of stray electric currents from direct-current traction systems. The conventional direct-current power-distribution system in coal mines is conducive to electrolysis damage to mine tracks, metallic pipelines, grounded power conductors, and structures in a position to become conductors of stray currents. The voltage drop resulting from power demand on intentionally grounded power conductors and accidental grounds on insulated conductors are common sources of stray currents in coal mines. Uncontrolled electric cur-rents flowing through the earth and metallic structures can be a menace, and these contribute to the estimated $6,000,000,000 annual loss caused by corrosion. The purpose of this publication is to discuss some of the electrolysis hazards in the coal-mining industry and to outline corrective measures to alleviate them.

Jan 1, 1962

By S Kasaneva

TheSan Cristobal gold district is located 110 km east of the port of Antofagasta, Chile. It contains the San Cristobal gold mine, where Niugini Mining Ltd. commenced a heap leach operation, with initial reserves of 10.1 million tonnes grading 1.34 g/t Au, in December, 1990. The San Cristobal district occurs within an upper Cretaceous-lower Tertiary magmatic arc. The main mineralisation occurs within a northwest trending subvertical zone, 1km long and 70 - 100 m wide, which contains rhyolite porphyry and minor breccia, and is locally termed the 'subvolcanic complex'. At the San Cristobal mine, most gold mineralisation occurs in subvertical quartz-pyrite veins which were emplaced in dilational sections of an imbricate fault system. The bulk gold resource comprises four ore shoots which formed where the vein system intersects the subvolcanic complex. Gold-bearing quartz-pyrite veins also occur at separate prospects, the Three Sisters and Sol prospects, west and south of the San Cristobal mine.   Hydrothermal alteration consists of potassic and propylitic assemblages related to intrusion of the subvolcanic complex. This alteration is overprinted by a phyllic stage which is associated with the emplacement of the quartz-pyrite veins. The oxide zone is 180 m thick, and contains native gold, electrum, limonite, and manganocarbonates. The underlying hypogene zone contains pyrite with minor chalcopyrite, sphalerite, galena, covellite, bornite, chalcocite, and arsenopyrite. Fluid inclusion studies indicate that the deposit formed at approximately 270¦C, and the mean salinity of the fluid was 4% NaCl equivalent. These observations enable the San Cristobal deposit to be classed as a porphyry- related, mesothermal quartz-vein system of the low sulphidation type.

Jan 1, 1995

By Alfred V. C. Meyer

A Blastcorder4 was calibrated on the Bureau of Mines shaking table in the frequency range of 12 to 40 c.p.s. and in the amplitude range' of 0.25 to 1.0 g. The results of this calibration study show that in the frequency range of 12 to 30 c.p.s. the average accuracy of the Blastcorder is approximately ± 0.1 g.

Jan 1, 1962

By David Shatwell

Recent epithermal gold discoveries in Chile and Bolivia provide increasing evidence of a belt of intermittent, epithermal, precious metal mineralization east of the main Andean porphyry copper belt. This relationship may be the result of an easterly decrease in the age of magmatism and erosional levels, in¬crease in depth above the underlying Benioff zone and consequent changes in magma chemistry, or some other unrecognized factor. Examples are: • The Choquelimpie gold-silver mine in Chile and numerous other epithermal prospects (such as La Riviera, Bolivia) in late Tertiary volcanics along the Chile-Bolivia border. These lie east of the belt that contains the Toquepala, Quellaveco and Cuajone porphyries in southern Peru and the Cerro Colorado, Copaquire and Quebrada Blanca porphyries in northern rhila

Jan 1, 1990

By A. J. Partos

One Liberty Place, at 315 m is the tallest building in Philadelphia, PA USA. It is supported on drilled piers socketed in heterogeneous rock. 3832 kN/m2 end bearing and 383 to 766 kN/m2 shaft resistances were selected. Design load distribution was 40% on the base and 60% by shaft resistance. The maximum compression on the corner core columns is supported by clusters of 3 drilled piers. In order to confirm load distributions along shaft and at the base, Drilled Pier G-10 supporting T13-A type outrigger column was instrumented. This column supports 53,849 kN compressive load which includes 13,440 kN windload. This paper reveals details about the process to select the final design for One Liberty Place together with pertinent Information about site geology, foundation construction, quality control, and methods of steel erection. It also presents detailed Information on the type of Instruments, their calibrations, field fabrication, and installation in the shaft of Pier G-10. Readings of concrete temperatures, computed loads, and load distributions are presented for a period from October 1985 through May 1988. The building was completed in 1987.

Jan 1, 1989

By Ronald T. Mayerle

A mineral survey of portions of two contiguous WSAs (Wilderness Study Areas) along the South Fork Owyhee River in southwestern Idaho and north-central Nevada was done by the U.S. Bureau of dines in 1984. The portions of the WSAs, known as study areas, have a combined area of 47,610 acres. The Idaho study area consists of 42,430 acres of the 42,510-acre South Fork Owyhee River WSA (ID-16-53). The Nevada study area consists of 5,180 acres of the 7,840-acre South Fork Owyhee River WSA (NV-010-103A). The Idaho study area is within the Boise District of the Bureau of Land Management, and the Nevada study area is within the Elko District. In the Nevada study area, no claims or hard rock mineral occurrences are known.

Jan 1, 1986

By M. Kahn

This paper traces the rise of South Africa's mining industry in the context of the different state forms that oversaw its development. It commences with the mining-led industrial revolution through four periods of conflict, each of which contributed to a deepening of the industrial base, with constant battles between domestic and foreign capital and labour, and the rise of both Afrikaner and African nationalism. The role of state-owned enterprises has been crucial in shaping this dynamic so that at its peak the public sector and leading mining houses constituted two massive centres of power. This was followed by a thirty-year period of neo-liberal experimentation. The current debate on the 'developmental state' is an attempt to reconstruct the state as a counterweight to capital. It is argued that while the country has moved toward inclusive political and economic institutions, these are both limited by deep 'extractive' characteristics. This transformation failure provides a fertile ground for populism that presents one of the biggest threats to inclusive growth. Cited examples point to the many ways that states have sought to deal with the bonanza that conversion of mineral non-resources into resources brings. Such greenfield resources on state land, or in areas where the state holds monopoly rights, do not present ownership issues. It is suggested that this is the route that South Africa should follow, as the alternative will be conflictual.

Jan 1, 2013

By M D. Hannington

On the southern flank ofLihir Island, a group of three volcanic cones were discovered at water depths from 1000 - 1500 m. The volcanoes are located in a narrow zone of recent seismic activity and elevated heat flow (up to 100 mW/m2). The recovered rocks consist of fresh alkali-olivine basalts, clinopyroxene-rich basalts, and porphyritic phlogopite basalts. One of the volcanoes has a recently erupted ejecta blanket (recovery of warm ash!), containing a suite of abundant mafic to ultramafic xenoliths. These xenoliths appear to represent a unique cross-section of subduction-modified mantle material sampled by volatile-rich primary fore-arc magma during its ascent to the seafloor. The most spectacular finding was the discovery of an active hydrothermal system with associated vent fauna and mineralization at Edison Seamount, and the recovery of unusually gold-rich (up to 43 ppm Au) hydrothermal precipitates in 1050 m water depth at the top of Conical Seamount, only 25 km south of the world-class epithermal Ladolam gold deposit on Lihir. The discovery of submarine hydrothermal vents associated with highly alkaline, quartz-undersaturated fore-arc volcanics represents a significant departure from similar hydrothermal systems on the mid-ocean ridges and in back-arc basins. The high gold grades in hydrothermal precipitates at Conical Seamount may indicate the first documented example of a shallow-marine epithermal system analogous to those known on land, and has important implications' for the gold potential of submarine arc environments.

Jan 1, 1995

By H. Saridikmen, C. S. Kucukkaragoz

In the present study, the measurement of sulphur distribution ratios between the slag and metal phases encountered in the ferromanganese smelting has been carried out at 0.83 atm of partial pressure of CO at 1773 K by using classical gas-slag-metal equilibrium quenching technique as a function of composition. The distribution results were employed in calculating the sulphide capacities of SiO2-Al2O3-CaO-MgO-MnO slags in equilibrium with the Mn-Fe-Si-Csatd.-S metal phase. It is shown that the sulphur transfer from metal to slag phase increases with increasing the basicity of the slag. As expected, the sulphur distribution ratio decreases by increasing the silica content of the slag system. The effect of metal composition on the sulphide capacities of the slag as well as on the sulphur distribution ratios between the slag and metal phases have been discussed. Emprical relationships were developed to express the sulphur distribution ratios and sulphide capacities of the above slag system.

Jan 1, 2007

By B. S. Terry, C. L. Harris

After measuring the kinetics of Ni reduction from a SiO2-saturated fayalite slag into a Cu-based metallic phase on a laboratory scale, a general model was developed that is capable of simulating mass transfer to and from metal-slag, slag-gas and metal-gas interfaces for multiple species. The model was used to simulate the reactions that occur when Cu and Ni are reduced from fayalite-based slags into a Cu-based metallic phase. Good agreement was achieved between model predictions and experimental data

Aug 1, 1995

Ground conditions at the Kencana mine, Indonesia, are generally poor and an underhand cut and fill mining method is used for extraction. Due to these poor ground conditions, all vertical development has been conducted using blind, top-down, sink and line excavation methods. Due to time constraints, raiseboring was considered the only viable excavation method for the installation of a return ventilation system for the K2 (Kencana extension) project. In order to achieve successful raiseboring in the poor ground conditions a number of strategies were used including: a detailed geotechnical study for optimal position of the shaft/s, splitting shaft excavation vertically, raiseboring of multiple smaller diameter shafts, extensive pregrouting, installation of drainage holes, and rapid installation of support following excavation.

Nov 25, 2010

By H. B. Charmbury, D. R. Mitchell

Everyone in the coal industry from top management to the preparation engineer is vitally interterested in recovering as much salable coal as possible from the run-of-mine product. Coal losses from a preparation plant occur in the solid refuse material being discharged from the plant and in the bleed-off slurry from the water circuit. The refuse is generally hauled from the plant in solid form by trucks, conveyors, or aerial trams to the refuse or culm banks or it may be crushed and transported by hydraulic methods to refuse ponds or dams. The loss of coal in refuse material and the extent of this problem has been covered in another paver.' The loss of salable coal in the plant bleed-off slurry is one of the water circuit problems in coal preparation plants. Slurries originate at various places in the processing circuits and are usually disposed of by transportation to waste ponds known as slurry ponds. Even though the combustible material discharged as slurry and refuse from the plant is labeled a loss, the loss must only be considered temporary. There is a tendency at the present time to examine refuse and slurry losses and to reprocess these materials to recover valuable coal. Slurries from eight bituminous coal preparation plants in central and western Pennsylvania have been sampled and examined to determine the amount of recoverable coal in each. Examinations of the samples were made to determine the tons per hour of solids and the gallons per minute of water in the slurry; the size, ash, and sulfur analyses of the solids; and the sink-float characteristics of the larger solids. The extreme fines (—325 mesh material) from one of the samples has been examined further to determine the micron size fractions as well as the ash and sulfur content of the micron sizes. Collection of the Samples: Field trips were made to each of the plants where samples were obtained and discussions held with the preparation engineer prior to sampling. The flowsheet of the plant operation was studied and a time-period selected to obtain a representative sample. At least 20 1-gal samples of total plant bleed-off suspensions were collected at each plant in increments over designated periods belived to be typical of the plant flow Three of the samples were obtained from plants in the Pittsburgh area. Each plant supplied information on the capacity, operating time, type of cleaning equipment used, water and material balances, and auxiliary equipment. From the time required to collect given amounts of slurry and from the amount of solids in the slurry, total solids discharges from the plant were calculated and compared with the plant flow. Ash and sulfur analyses of the total solids were also checked, at some plants, with company figures. In all cases where checks could be made there was reasonable agreement between company figures and those reported here. Analysis of the Slurries: Representative fractions of properly agitated samples were examined in the laboratory to determine the specific gravities of the slurries. The solids and water were separated by filtration to check the weight of each so that the percent of solids in the pulp could be determined. From the resulting data, presented in Table I, it may be seen that the percent solids in the slurries ranges from 2.8 to 39.0 and the amount of solids from 2.61 to 45.61 tph. Size Analysis of Solids: Representative fractions of the slurries were permitted to settle and the clear water was removed by siphoning. The solids were then wet-screened at 28, 35, 48, 65, 100, 150, 200 and 325 mesh. Results of the size analyses are presented in Table 11. These results indicate the extreme variation of sizes and in most cases the degree of fineness of the solids. The amount of —325 mesh ranges from 22.5 to 84.5 pct and the amount of+200 mesh from 8.3 to 69.1 pct.

Jan 1, 1961

The molecular structures of isobutyl xanthate (IBX), diisobutyl dithiophosphate (DIBDTP), O-isobutyl-N-ethyl thionocarbamate (IBETC), O-isobutyl-N-ethylcarbonyl thionocarbamate (IBECTC) and O-isobutyl-N-ethylcarbonyl thiourea (IBECTU) were fully optimized using density functional theory (DFT) at the B3LYP/6-31+G(d,p) level with the integral equation formalism for the polarizable continuum model (IEF-PCM) in the aqueous phases. The effects of the polar groups in these thiol molecules on their collecting performances were determined by the energies and compositions of frontier molecular orbitals and the atomic charge values. Our results indicate that the sulfur atom(s) in IBX, DIBDTP, IBETC, IBECTC, or IBECTU molecule is the centre of reactivity. And the collecting abilities of these reagents for copper sulfide minerals follow the order as: IBX > IBECTU ? DIBDTP ? IBECTC > IBETC, and the order of their selectivities against pyrite is suggested as: IBX < DIBDTP < IBETC < IBECTU < IBECTC. The theoretical analysis provides an insight into the collecting powers of these collectors, and offers an atomic scale approach to understand the experimental data available in the literature. Keywords:xanthate; dithiophosphinate; thionocarbamate; thiourea; density functional theory; structure-activity relationship; copper sulfide mineral

Feb 27, 2013