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By Jae-Chun Lee, Kang-In Rhee, D. B. Dreisinger, Hyo-Shin Yu, G. A. Kordosky

The development of a process for direct synthesis of very pure ZnO powders from zinc-bearing waste was investigated. The zinc waste which contains 55% zinc was leached with sulfuric acid. After iron removal by hydrolysis from this zinc solution, purification through solvent extraction by the use of D2EHPA as an extractant was carried out. Then, loaded zinc in the organic solution was stripped and precipitated simultaneously using oxalic acid as a precipitant. Synthesized ZnC2O4 precursors by precipitation stripping were calcined to obtain ZnO powders exceeding 99.9% purity. The effects of sulfuric acid concentration, leaching time, and pulp density on the extraction of zinc were studied and optimum conditions for the solvent extraction were obtained through purification of the zinc solution. The size, morphology, and size distribution of synthesized ZnC204 powders were studied in terms of oxalic acid concentration, temperature, surfactant added, precipitation time, etc.

Jan 1, 1993

By J. W. T. Ropkins, D. Allenby

The paper describes a technique by which large concrete boxes are unobtrusively inserted beneath existing highway and railway infrastructure to form new subways, culverts and under-bridges, thus avoiding the inconvenience and costs of disruption to traffic associated with traditional cut and cover techniques. A series of project examples, undertaken in the United Kingdom and United States, are used to illustrate the design and construction of the box structures, together with the technology required to control ground disturbance in the tunnel face and around the box, and the jacking systems necessary for box installation.

Jan 1, 2003

By Francesco Chiappalone, Marco Invernizzi, Franco Gasperin, Brad Yoder, Fabrizio Fara

The Ship Canal Water Quality Project includes a 2.7-mile, 18-ft and 10-in internal-diameter tunnel that extends from Ballard to Wallingford, two popular neighborhoods in the West of Seattle. During the TBM Main drive a 12' × 12' boulder with variable strength up to 47,000psi was encountered resulting on signicant damages to the Cutter ead. The rst part of this paper describes the design and construction of an underground recess in front of the TBM to create a safe working environment for the TBM repairs. The second part describes an injection campaign performed to seal an unforeseen water inow appeared during the excavation of the 11 Avenue Diversion Structure.

Jun 23, 2024

By J. G. Groppo

Froth flotation has been shown to be an effective method for reducing Loss-on-Ignition (LOI) of ponded or landfilled fly ash. Reduction of LOI is required for many fly ashes, particularly those produced from low-No, burners, in order to meet ASTM requirements for use as a mineral admixture in Portland cement concrete. An additional ASTM requirement, fineness, is critical in determining end use applicability, and in many cases, classification of fly ash is necessary to produce an acceptable product. Hydraulic classification has been shown to be a simple, cost-effective method for classification of a variety of minerals including silica, phosphate, mica, coal, etc. and has shown to be similarly effective on fly ash. The combination of froth flotation and hydraulic classification facilitate the production of a high quality pozzolan that meets or exceeds ASTM specifications. This combination has been rigorously evaluated and results of pilot-scale testing are presented. Pilot scale testing was conducted on fly ash from two active utility storage ponds and demonstrated that high quality, consistent pozzolan could be produced using APT's Fast Float? Technology. Along with the pozzolan, additional production of aggregate for masonry mortar and a low sulfur, medium Btu fuel were also demonstrated. The Fast Float? process incorporates several simple unit processes to ensure pozzolan consistency; classification controls particle size distribution which is critical to achieving early strength, flotation controls the grade with respect to L.O.I. (Loss on Ignition) while dewatering controls the moisture content.

Jan 1, 1998

By James D. Bliss

Evaluation of data for three engineering variables-absorption, bulk specific gravity, and freeze-thaw durability (350 cycles)-was made for quarries in carbon- ate rocks in Oklahoma that supply aggregate. It was found that lower Paleozoic carbonate rocks (Cambrian through Devonian) are likely to make a better quality aggregate than upper Paleozoic (Mississippian to Permian) carbonate rocks. In addition, freeze-thaw durability can be forecast from absorption and is exemplary for lower Paleozoic carbonate rocks.

Jan 1, 1999

By R. R. Rollins

Conventional methods of controlling abandoned mine fires include: loading out, inundation, fire barriers, flushing, and surface sealing. This paper describes a proposed fire-control technique utilizing a new explosive fragmentation method. An impervious barrier is created by using explosive energy and strategic emplacement in boreholes drilled from the surface. Blast round design, average fragment size, and impermeability of the fragmentation barrier are discussed. This barrier, created by the blasted floor rock, could also be used to fill in the open space in abandoned mines for subsidence prevention or control.

Jan 1, 1989

By A. D. Wunderlich

Providing a safe & secure environment for your employees and other company assets is absolutely necessary in our litigeous society. Security hardware is no different than computers or other technical equipment, in that new equipment is developed each year that makes older equipment obsolete. This presentation will help to explain how your existing security system and security procedures can be updated to meet industry standards without the expenditure of a great deal of money. If you are concerned about potential security problems and how to address these problems, this presentation is a must.

Jan 1, 1995

By Anthony Harding, Rodolfo D. Aradas, Juan M. Fernandez, Darío Tsingas

"The adoption of tunneled combined sewerage interceptors and outfalls leads to design linings which are often subject to internal pressures that are larger than the external pressures, resulting in significant tension loads. The need to meet stringent durability conditions for the normal design life of 100 years often drives client specifications to require a double pass solution with a cast in situ secondary concrete lining. However, improvements in concrete technology and the need to seek efficiency in terms of time and costs, have driven designers to consider single pass segmental linings. The Riachuelo Sanitation project in Buenos Aires is subject to these constraints both upstream and downstream of a sewage treatment plant. This paper describes how the challenges of up to 2 bar pressure differential have been addressed by careful analysis of soil structure interaction to ensure that the full benefit of external ground pressure is realized, resulting in a more optimal design for the constructor both in terms of cost and time. INTRODUCTION The construction of long sewerage interceptors and outfalls is becoming an increasingly common piece of infrastructure for modern urban cities facing a large water front and estuarine conditions, which are under a significant environmental burden imposed by decades of sustained growth. Such works intercept most of the distributed sewage discharges to then divert them to a central treatment point from which it will be finally diffused via an outfall into a water body capable to accept these discharges under acceptable environmental conditions. Depending on the magnitude of the sewage load to be handled, the configuration of the urban environment and the conditions of the receiving water body, both in terms of oceanography forces and seabed conditions, these schemes will vary in length, conveyance capacity and design and construction requirements. When conditions permit, the current trend is the execution of long outfalls using flexible solutions (such as the use of HDPE pipes) which usually require some form of concrete ballasted weights to resist off shore dynamic forces when directly laid over the sea bed. However, this concept faces limitations when the conveyance requirements indicate the need for large diameters (typically above 3000 m) and also when the outfall needs to avoid deep features off shore such as navigation channels. When this occurs, tunneling, particularly segmentally lined tunnel constructed by TBM emerges as the most feasible approach for large diameter, long deep outfalls. The operating conditions often result in internal pressures that are larger than the external pressures, resulting in significant tension loads in the lining. The need to meet stringent durability conditions for the normal design life of 100 years often drives client specifications to require a double pass solution with a cast in situ secondary concrete lining."

Jan 1, 2016

By Makoto Terada

The most important consideration in planning the plugging and sealing of a mine for mine water control is to predict the water flow from the mine. For this purpose, a method of numerical analysis on the water behavior in the ground at the concerned mine area was developed and the mine water flows were simulated. A hydrological survey at the surface of the mine determined the recharge rate of ground- water and the apparent permeability of ground.

Jan 1, 1982

By J. A. Cervantes

A statistical model for assessing the risk of ground subsidence in abandoned mine areas is presented. The model is based on the relationship that exists between .the frequency and the location-of subsidence events in a given area and the physical conditions of the ground. These conditions can be described by a series of geological, mining, and physical variables. The model suggests the existence of regions in the multidimensional space of variables which are associated .with increases or decreases in the frequency of subsidence events. Regions associated with an increase in the frequency of subsidence events correspond to regions of higher risks, and vice versa. Risk assessment is based on the ability to express the limits of these high and low risk regions in the, space of variables, and on the ability to express the degree of membership of blocks of land within any of these regions. The theoretical framework for the model is extracted, from discriminant analysis. Risk is quantified by the probabilities of membership of blocks of land into any of these regions. Risk maps are produced by displaying membership probabilities in. appropriate contouring levels. The model has been applied in two urban areas where subsidence of the ground has been active in the past. The two areas are Penn Hills, near Pittsburgh, and Scranton/Wilkes-Barre in northeastern Pennsylvania. In this paper, only the results for the Scranton/Wilkes-Barre area are presented. Those for the Penn Hills area have been presented elsewhere (Cervantes, et al, 1990). In the- Scranton/Wilkes-Barre area, geostatistical estimates of variables likely to affect the stability of the ground were made using samples from 53 drillholes. The estimates were made for 2000x2000 ft squared blocks of land covering the study area. Discriminant functions were computed from the estimated variables and used to establish regions for classifying blocks of land into one of these two populations: 1) blocks not likely to have a subsidence event, and ii) blocks likely to have one or more subsidence events. The same, discriminant functions were used to compute membership probabilities for blocks of land to tall within any of these two populations. These probabilities were contoured to produce a risk map. The risk map produced compares well with the location of the subsidence events which have occurred to date in the area.

Jan 1, 1992

By R. Larry Davis

Over the past decade there has been a continual decrease in domestic oil reserves accompanied by a sharp increase in the demand for energy. Even with increased imports of foreign oil, the energy demand has not been met. This has forced many users to turn to substitute fuels. Of the many substitute fuels available most users are turning to and creating an increased demand for low sulfur coal. Because of the increased demand for low sulfur coal as well as the inherent problems in producing eastern coal, many producers have turned their attention to the large deposits of low sulfur coal in the western United States. Western coal mining is, however, not without its problems such as high moisture content, high ash content, highly variable sulfur content, multiple seams, and/or pitching seams. It is to aid in the solution of these problems that this chapter is directed.

Jan 1, 1979

By Pamela J. Nebgen

Surface mine planning and watershed management requires the manipulation of a massive volume of data. The processes of collecting, examining, selecting, and generalizing information for the production of maps and sediment structure designs are a major part of mine planning and evaluation. Computer aided design graphics systems are becoming increasingly more important to the surface mining industry. This paper illustrates the applications of a digitizer and plotter interfaced to an IBM PC-XT microcomputer, which form the hardware elements in the new University of Kentucky hydrology, sedimentology, and structure design package called SEDCAD.

Jan 1, 1986

By Ioannis Nicolaou

This paper demonstrates the method of approach for the optimization of such filters. This does not only incorporate the proven and simple recently developed equations for the calculation of the solids throughput, the residual moisture and gas throughput, but also introduces equations for the calculation of the specific product costs for both vacuum and hyperbaric filtration under consideration of the influences exerted by the filter compressor and a possible thermal drying. An easy-to-use method is offered which incorporates a special graphic representation concerning the plotting of the target parameters in dependence of the pressure difference with which the optimal process pressure difference can be established, independent of the specific cake permeability or product fineness. Finally, the optimization method is exemplarily demonstrated for a concrete application.

Jan 1, 1995

By E. William Rossi, Audrey F. Glowacki, Richard L. Unger

The U.S. Bureau of Mines has developed a graphics-based computer model to assess operator visibility for continuous miners, shuttle cars, and scoops. Using digitized drawings of the machine, the program can analyze visibility for both 5th percentile female and 95th percentile male operators. This model was used to predict 95th percentile male operator visibility for two shuttle car designs. These results were then compared to those obtained from a manual assessment of visibility using the actual shuttle cars. The methods showed good correlation except for several cases which were attributed to imprecise digitization of the machines.

Jan 1, 1992

By Hugh W. Rimmer

The design of comminution circuits and the evaluation of alternatives should be based on state-of-the-art equipment and appropriate design criteria - considerations that are often neglected by today's designers. This paper critically reviews common circuit designs, evaluates various alternatives for difficult-to-treat ores, and discusses the factors that should be considered when developing new plant designs or auditing existing plant performance. Data obtained from laboratory, pilot and plant-scale test work on a wide range of ores and circuits are used to justify the author's conclusions.

Jan 1, 1995

By Alice Blount, F. Patrick Carr

The quantitative evaluation,of quartz and other minerals in acid-insoluble residues from carbonate rocks and other industrial mineral products derived from sedimentary and low-grade metamorphic rocks is difficult. Commonly there are a dozen or more minerals present, and the suites vary from sample to sample. Because of these factors, either the absorption coefficient must be determined on a sample to sample basis or an internal standard must be used. Internal standards in general use are unsatisfactory. For example, [A1203] is often present in product samples because of ceramic grinding elements used in their production; CaF and LiF have peaks which overlap or nearly overlap mineral peaks in the samples. A careful evaluation has shown that magnesium aluminate (synthetic spinel) works particularly well as an internal standard for these types of samples. Not only does it have few, strong diffraction peaks which do not overlap, the peaks are in the same 28 region as the minerals, usually quartz and silicates, for which quantification is desired. Spinel also consists of equidimensional particles without prominent cleavages; this promotes a random orientation of the minerals in X-ray diffraction mounts. In addition, spinel can be used to correct for loss of diffracted-beam intensity due to thin sample preparations which are often unavoidable.

Jan 1, 1991

By S. K. Kawatra, S. Valluri

With increased CO2 emissions from steel and coal industry, there is great opportunity to capture CO2 and utilize the captured CO2 for economic advantage. The primary goal is to develop energy-efficient processes that reductively couple CO2, an abundant and renewable carbon source, for the production of value-added chemicals such as methanol, ethanol, and oxalic acid. These chemicals can be used elsewhere in the refining process or sold as valuable by-products. Geological sequestration, in comparison, has no economic return. Current CO2 utilization research at Michigan Technological University focuses on electrochemical reduction of CO2. Electrochemical reduction of CO2 to hydrocarbons and other chemicals is a complex multistep reaction with adsorbed intermediates. The exact reaction mechanisms leading to various products are not clear from the literature to date and will likely change over the range of conditions like pH, electrode potential, electrolyte medium, catalyst, etc. This paper will present different ideas and their viability to utilize CO2 as a feedstock to produce several value-added compounds. INTRODUCTION Carbon dioxide (CO2) emissions into the atmosphere will need to be drastically reduced to curb the various undesirable effects of climate change. The large contribution in total CO2 emission originates from coal or natural gas power plants, and a considerable amount from steel plants. Average CO2 emissions in the US from steel industry is 2.9t CO2/t steel (Global CCS Institute 2013). Capturing the available CO2 from the steel and coal industries for economic advantage is a win-win situation for the industry. This technology is not only important scientifically but is also vital for a sustainable future. The various ongoing investigations can be categorized as biochemical, thermochemical, photochemical, and electrochemical approaches. Among these, the electrochemical method shows the most promise as an efficient form of CO2 conversion technology, because of its many advantages like high reactivity under ambient conditions and good extensibility from small- to large-scale processes1 BACKGROUND Extensive research has been done on the chemistry of transforming carbon dioxide into more useful products. Methods are known to convert carbon dioxide into a wide variety of substances, including methanol, isobutanol, carbohydrates, methane, carbonates, urea, formic acid, oxalic acid, carbon monoxide, epoxides, formaldehyde, and so on. Several of these (carbohydrates, formaldehyde, isobutanol etc.) are primarily results from biological processes. The rest are results of strong reduction reactions or electrolytic reduction. In short, electrolytic reduction can be used to form methane, methanol, formic acid, oxalic acid, carbon monoxide from carbon dioxide2. CO2 reduces at the cathode in an electrolysis cell. These processes have the general form of generating the carbon dioxide anion radical (2⋅−) and allowing it to react with itself or the electrolyte3. Catalysts can be added to influence the formation of the anion radical or to suppress side reactions3. The electrolyte, catalyst, voltage, electrode material and CO2 content are all known to effect the reaction pathway. Table 1 shows the overall reactions and energy requirements for electrochemical conversion of CO2 to chemicals

Jan 1, 2019

By Jan M. Mutmansky

While production scheduling for both surface and underground mining operations is similar in nature, a rather large array of techniques is applied in solving such planning problems. The techniques consist of both rigid operations research (OR) methods and practical procedures which are not mathematically based. In the following sections, a short summary of some of the techniques that are applicable to production scheduling problems in mineral operations is presented. The techniques discussed are: linear programming, integer programming, dynamic programming, graph and network theory, simulation, and heuristic methods. For an in-depth comprehension of these techniques, the reader is referred to any of the available textbooks on these subjects. One or more references will be listed for each topic to provide a starting point.

Jan 1, 1979

By Pierre Mousset-Jones, Felipe Calizaya

The design of an auxiliary ventilation system for long underground openings (drifts, ramps and shafts), often requires the installation of multiple fans. The fans are installed in series and separated from each other by rigid ducts of fixed or variable length. However, problems relating to excessive leakage often occur, with each project representing a unique problem requiring an efficient solution. In this study, a method to determine the design parameters of an auxiliary ventilation system is presented. The method is based on the principle of partitioning a long ductwork into segments of finite length and solving the resulting networks separately. Specifically, the method is developed to solve two types of problems: constant fan spacing, and constant fan size. In the former, the fan spacing is fixed, and the problem is solved for fan sizes. In the latter, the problem is to solve for fan spacing. An example is used to illustrate the method.

Jan 1, 1993

By Jeong-Heum Kim, Jan M. Mutmansky

A number of solution methods for solving the nonlinear equations derived from mine ventilation networks use meshes selected from the network as the basis of the solution techniques. Mathematicians working in network theory have outlined several methods for speeding up the computations through mesh selection and ordering procedures. In the mine ventilation area, a fair amount of attention has been paid by ventilation specialists to procedures for choosing the meshes so that the computational effort is eased. However, little attention has been paid to mesh ordering methods. This paper outlines research into random mesh ordering procedures plus two non-random mesh ordering procedures and compares some results using these procedures within four solution algorithms.

Jan 1, 1993