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By Ronald D. Hill, Elmore C. Grim

Some of the terms defined here are not used in the text. However, the terms will be useful to those interested in this and other publications in the field of coal surface mining.

Jan 1, 1974

By William H. Pomroy

Fires in underground metal and nonmetal mines pose a threat to the safety of underground miners and to the productive capacity of this Nation's mines. Contaminated air (smoke, carbon monoxide, and other products of combustion) is the primary life safety hazard created by a mine fire. The most reliable defense against the hazard posed by the rapid spread of contaminated air underground is early warning fire detection and rapid evacuation. This Bureau of Mines report describes the design and operation of four prototype early warning fire detection systems, for underground noncoal mines, presently undergoing prolonged in-mine testing by the Bureau. The systems are described within the context of the underground mine environment.

Jan 1, 1985

By D. N. Nilsen

The Bureau of Mines is developing a method to recover Ni, Co, and Cu from laterites containing less than 1.2 pct Ni and 0.25 pct Co. The method consists of the following basic unit operations: (1) reduction roasting, (2) leaching, (3) solvent extraction, and (4) electrowinning. The method reflects three Bureau of Mines objectives: (1) recovery of critical minerals that are domestically in short supply from low-grade domestic laterites, (2) lower processing energy requirements, and (3) solution recycling. This report deals with the extraction of cobalt and the preparation of a suitable cobalt electrolyte by solvent extraction from liquor produced by this method. Nickel and copper are coextracted with LIX64N from an ammoniacal ammonium sulfate leach liquor containing about 1.00 g/l Ni, 0.30 g/l Co, 0.03 g/l Cu, and 0.02 g/l Zn. Cobalt (III) in the nickel-copper barren raffinate is reduced to cobalt (II) with cobalt metal. Reduction of cobalt (III) to cobalt (II) greatly aids subsequent extraction. Commercially available XI-51 extracts about 94 pct of the cobalt from the treated raffinate in one stage in a laboratory mixer-settler continuous circuit. Ammonia loaded on the solvent is removed in two washing steps. About 94 pct of the cobalt then is stripped from the XI-51 in one stage with spent cobalt electrolyte containing about 77 g/l Co and 18 g/l sulfuric acid (H2S04), Electrolytes containing less H2S04 also may be used. Preliminary data indicate that coextracted zinc may be removed from pregnant cobalt eletrolyte containing 3 g/l or less H2S04 with di-(2 ethylhexyl) phosphoric acid (D2EHPA).

Jan 1, 1980

By C. W. Dwiggins

The Bureau of Mines characterized the chemical and physical properties of metallo-organic materials in petroleum to determine their effect on petroleum production and refining. The structures and physical properties of porphyrins and materials that normally contain metalloporphyrins such as crude oils and asphaltenes were investigated using elemental analysis, NMR analysis, absorption spectrometry, and small-angle X-ray scattering. Petroleum fractions greatly enriched in metalloporphyrins were obtained using asphaltene precipitation, liquid extraction, and large-scale liquid-solid chromatography. Selected fractions containing porphyrins were further purified by chromatographic methods, crystallization, and demetalation followed by chromatography. Nonporphyrin metals could not be appreciably concentrated from the bulk of the asphaltene.

Jan 1, 1969

By R. V. Ramani

"Exposure to respirable contaminants in mine atmospheres has long posed a serious hazard to miners. The control of these hazards, some of which can have sudden and catastrophic effects and some others, slow and long enduring consequences, has been a major concern for labor, management and government alike. This concern has manifested itself in four primary mechanisms of control -- (1) regulatory control through minimum standard setting by the passage of mine health and safety laws, (2) engineering control through design and operation of 'mines according to the best recommended practices, (3) medical control through periodic physical examinations, wearing personal protection devices, etc., and (4) legal and social control through workmen's compensation laws for occupation related health deterioration:-The respirable contaminants in mine atmo¬spheres are toxic and explosive gases, toxic and explosive dusts, diesel exhaust particu¬lates, radon progeny, etc. Perhaps the most important of all these and the most widely occurring in mine atmospheres is respirable dust, an inevitable product of fragmentation, a unit operation fundamental to all mining operations. In fact; the-most serious health hazard for workers in the mining and minerals processing industries is still the exposure to respirable dust, and solutions to the problem of respirable dust disease remain to be found.The 1969 Coal Mine Health and Safety Act and its provisions for the respirable dust standards in underground coal mines are briefly reviewed. An overview of the research accomplishments in meeting the standards is presented. The current state of knowledge on the effectiveness of the standards and the new and emerging problems are discussed. A brief summary of the research programs of the Generic Technology Center on Respirable Dust is presented.In general, underground mines are becoming increasingly safe. The mine atmospheric environment is definitely improving * Professor and Head, Department of Mineral Engineering,-The Pennsylvania State University, University Park, PA for the better. Significant progress has been made in lowering the dust levels in mines. It is generally agreed that mines are less dusty today than they were a decade ago. However, as long as the risks of occupation-related diseases are not completely eliminated, vigilance can hardly be relaxed, and the search for engineering solutions must be intensified."

Jan 1, 1988

By J. H. Perry

The Bureau of Mines is conducting research to determine the effectiveness of long holes in degasifying an area of the Upper Split of the Lower Sunnyside coalbed at Kaiser Steel Co.'s Sunnyside No.1 mine. These holes were drilled from the two outside entries of a section that was closed to mining because of excessive methane emissions. Two holes drilled to 430 and 450 feet produced initial gas flows of 160,000 and 127,000 cfd, respectively. Sixteen days after the completion of the second hole, the total gas production declined to just over 144,000 cfd. In 9 months of degasification, over 35 MMcf of commercial-quality gas has been removed from the coalbed. The combined gas flows declined to 106,000 cfd in the 9-month period. The two holes have reduced face emissions by about 40 pet.

Jan 1, 1978

By David A. Benjamin

In 1989 and 1990, the Bureau of Mines conducted a mineral resource investigation of the 122,000-acre Trinities study area, located in the Trinity Mountains of south-central Idaho. No identified mineral resources were delineated during this study. There are 58 lode mining claims within the area. Five localities contained elevated metal concentrations which may indicate precious metal mineralization at four localities and molybdenum-precious metal mineralization at another. Four of the five localities appear to form a northwest trend through the center of the study area. Twenty-eight individual sites contain anomalous concentrations of gold, silver, bismuth, molybdenum, and beryllium.

Jan 1, 1991

By Ernest W. Loya

A method for preparing gravimetric primary standards of helium in the parts per trillion range has been developed by the Bureau of Mines. The standards are used to calibrate a specially modified mass spectrometer used in determining the abundance of helium-3 and helium-4 in geochemical samples and of helium-3 in isotopically purified helium-4. The desired gas standards are prepared in 5-kg metal cylinders filled to 1,800 psia. Relative errors of less than 1 pct have been attained in the parts per trillion range using a successive dilution technique.

Jan 1, 1982

By Ivan F. Avery

PRODUCTION of carbon black decreased 4 percent in 1961. Output in the major producing States of Texas and Louisiana decreased 1 percent and 8 percent, respectively. Production of channel black continued downward, declining 10 percent in 1961 compared with 9 percent in 1960. Furnace black production also decreased 3 percent from 1960. Total domestic sales, however, increased 2 percent, Sales to most major consumers increased, but sales to the ink industry decreased 10 percent. Producer's stocks decreased 5,083,000 pounds during the year. Exports decreased 4 percent. SCOPE OF REPORT Carbon black is a very pure grade of quasi-graphitic carbon; particle diameters range from 50 to 5,000 angstrom units. Annual reports were submitted to the Bureau of Mines by operators of all commercial plants in the United States.

Jan 1, 1962

Determine the site specific flow behavior of leachants and groundwater during development, production, and restoration phases of an in situ leaching operation. Approach A computer program has been developed which simulates the hydrologic activity associated with in situ mining. Various user options enable modeling of many of the site specific geologic conditions and well field specifications that affect the hydrology of solution mining. How It Works In situ hydrology is modeled, using a closed-form solution to the three-dimensional, partial differential equation that describes changes in hydraulic head as a result of pumping from leachant Injection and recovery wells. Model capabilities include arbitrary well patterns and pumping schedules, partially penetrating well screens, directionally anisotropic permeability and natural groundwater flow, in either

Jan 1, 1981

By J. J. Demeter

Anthracite from the four producing regions in Pennsylvania was both ashed in the laboratory and burned on a chain-grate stoker to determine the sulfur-retention properties of its ash. The retention of sulfur in laboratory-prepared anthracite ash was shown to be related to ashing temperature and to the amounts of sulfur and calcium present in the coal. At the usual laboratory ashing temperature of 750° C sulfur retention ranged from 0.8 to 13.2 percent of the total coal sulfur. Sulfur retention in the ash was negligible, o to 0.3 percent, at 1,200° C, which is the thermal decomposition temperature of calcium sulfate; thus calcium sulfate does not form and cannot serve as a sulfur-retaining agent. In several tests the anthracite was mixed with 6 or 10 percent dolomite prior to firing in the chain-grate stoker. The dolomite did not improve sulfur retention owing to the high temperature in the fuel bed. Sulfur retention was, however, related to the unburned carbon in the ash. The relationship of the percentage of original coal sulfur retained in the ash (Y) to the percentage of the original carbon in the coal remaining in the ash (X) is expressed by Y = -0.579 + 0.914X. The percentage of sulfur retained is almost directly proportionate to the percentage of original coal carbon in the ash.

Jan 1, 1968

This chapter describes the adverse health effects associated with exposure to respirable coal mine dust. Epidemiological studies of underground and surface coal miners in the United States and other countries are discussed. Also discussed are animal studies that add to our understanding of particle deposition and retention in the lungs and associated disease responses. This chapter emphasizes studies that (1) were performed since the passage of the Federal Coal Mine Health and Safety Act of 1969 [P.L. 91- 173], (2) used standardized methods of exposure monitoring and disease classification, and (3) investigated exposure-response relationships between respirable coal mine dust exposure and disease. Several published review articles contain further discussion of health effects studies of coal miners [Attfield and Wagner 1992b; Petsonk and Attfield 1994; Cotes and Steel 1987; Merchant et al. 1986; Morgan and Lapp 1976; Morgan 1975].

Jan 1, 1997

By Ann G. Kim, Thomas R. Justin, John F. Miller

The U.S. Bureau of Mines applied its mine fire diagnostic method to an abandoned anthracite mine fire site in Carbondale, Lackawanna County, PA. The technique to locate fires in abandoned coal mines and coal refuse piles includes the determination of hydrocarbon concentrations in mine gases, the imposition of an underground gas flow direction, and use of a surface mapping method, to define heated and cold zones in underground coal strata. The heated zones at Carbondale were characterized by elevated methane concentrations. The results of 25 communication tests were analyzed to define 2 large (approximately 100 by 250 ft) and 5 small, isolated heated zones. An approximate correlation existed between the location of the heated zones and areas of anomalous snow melt. The correlation between the results of the diagnostic test and subsurface temperatures was not significant.

Jan 1, 1992

By B. H. Eccleston

Experimental work is reported showing the effects of gasoline characteristics on auto emissions. Fuel volatility is shown to influence evaporative losses, with the higher losses associated with higher volatility. Fuel front-end olefin is shown to contribute significantly to reactivity of emissions. Large vehicle-to-vehicle differences were found. The study was conducted by the Bureau of Mines at its Bartlesville Energy Research Center in cooperation with the Coordinating Research Council Air Pollution Research Advisory Committee. The work was done using 15 1968-70 model autos and eight fuels were tested at ambients ranging from 20° to 95° F. Data on emissions from each vehicle-fuel-temperature combination are presented. Also included are calculated photochemical reactivity data and the distribution of hydrocarbon and nitrogen oxides during the test cycle.

Jan 1, 1972

By Fred D. Wright

A compressor and utility station, which is believed to be one of the largest mobile units of this type ever constructed, was placed in operation at the Bureau of Mines experimental oil-shale mine near Rifle, Colo., during. 1949. This mobile unit mounts two 770-cubic-feet-per-minute air compressors, a 2,500-gallon water tank, and a 200-cubic-foot air receiver. The mobile base of the unit is a 30-ton trailer 30-feet long and 12-feet wide. Prior to the construction of this unit, compressed air was supplied to underground workings through pipe lines connecting with a stationary compressor plant on the surface. The power consumed in supplying compressed air to underground drilling crews was 0.531 kw.-hr. per ton of shale broken. Use of the mobile unit has cut this figure to 0.421 kw.-hr. per ton of shale broken and, more important, has eliminated the cost of installing and maintaining underground air and water lines.

Jan 1, 1950

By D. L. Pool

To increase metal recoveries and to minimize pollution by improved extraction technology, the Bureau of Mines investigated a hydrometallurgical technique to recover copper, lead, nickel, and cobalt from lead smelter mattes. The metals were converted from insoluble sulfides to soluble chlorides using a HCI-CI2-02 leaching system. Parameters studied in a 50-gallon, glass-lined reactor were the ratio of hydrochloric acid to chlorine, chlorine consumption per pound of matte, oxygen reaction pressure, and temperature. The matte material used contained, in percent, 19.7 Cu, 52 Pb, 2.9 Ni, 1.5 Fe, 0.38 Co, 0.19 As, 0.41 Zn, and 0.12 Cd. Extraction of Cu, Pb, Ni, Co, and Cd ranged from 92 to 98 pct, with concomitant extractions of Fe and As of <0.1 pct. The Cu and Pb were recovered as electrowon metals, while the Ni, Co, and Cd were recovered as mixed hydroxides.

Jan 1, 1981

By D. R. Tesarik, R. W. McKibbin

Material properties affecting slope stability were measured in a large 50-year-old, partially consolidated rockdump located in an active open-pit mine. Field tests included single-ring infiltration and density. In addition, a nuclear depth-moisture gauge was used to measure water content in six stainless-steel-cased drill holes on the crest and an upper bench of the rock dump. Precipitation, evaporation, wind speed and direction, and temperature data were collected at a weather station installed on the dump’s crest. Laboratory tests included particle-size distribution, specific gravity, Atterberg limits, and water content. By measuring material properties of a rock dump presumed to be stable, the safety of miners working on or at the toe of old rock dumps constructed of similar material and located in a similar climate can be assessed.

Jan 1, 1999

By John Millhiser, Stephen J. Kravits

The U.S. Bureau of Mines preproduction Wireless Survey System (WSS) and its performance during an in-mine test are discussed in this report. The WSS was developed to reduce downhole surveying time in order to increase the efficiency of drilling long horizontal methane drainage boreholes in coal. Borehole survey data are electromagnetically transmitted from the WSS7s downhole guidance probe, via the drill rod, to the uph&apos;ole subsystem in less than 1 min per survey transmission, regardless of borehole depth. The WSS7s in-mine test consisted of providing borehole survey data during the directional drilling of a 2,538-ft horizontal methane drainage borehole in the Pittsburgh Coalbed. By considering available drilling time, which does not include hydraulic drill downtime and the time spent traveling portal to portal, 24 shifts were needed to complete the borehole. Of the available drilling time during the tcst, 50 pct of the time was spent drilling and 50 pct surveying and maintaining the WSS to keep it operational. Previous Bureau experience indicates drilling efficiency was increased 108 pct because of the WSS, in comparison with using a commercially available wire-run directional survey instrument at 10-ft intervals.

Jan 1, 1990

By D. S. Kingery

The practice of using doors to control main ventilating currents in bituminous-coal mines is common throughout the industry. When doors are erected in pairs to form air locks, they are usually accepted as satisfactory by both State and Federal coal-mine-inspection agencies. A review of the contributing factors in recent methane ignitions showed that interrupted ventilation (often caused by doors latched open, destroyed, or damaged) was the principal cause of methane accumulations that subsequently were ignited.

Jan 1, 1958

By J. H. East, D. Harrington

Fires in metal mines have resulted in some of the worst disasters in American mining history insofar as loss of life is concerned. One fire caused the death of 163 miners and individual less spectacular fires have cost the lives of scores of workers. Metal mines are often very deep, and the men working on numerous levels far removed from direct communication with the surface. In many instances they cannot be warned quickly of an emergency or a mine fire by telephone or other usual method of communication, or by messenger, flashing lights, gongs, sirens, or whistles. Telephones are not paricularly effective as a means of warning unless placed at all strategic points and with attendants always on duty; though telephones well placed have a definite value in any well-pla.mied emergency procedure in mines of all kinds. Messengers are slow and men working in remote parts of a mine would not receive a warning quickly enough. Most metal mines are not electrically lighted, except at or adjacent to shaft stations and in principal haulageways, and this limits the effectiveness of flashing lights. Electric gongs and sirens or whistles have been tried as warning signals, but the sound is quickly deadened and does not travel upward into the stopes, especially those of an extensive volume. Shutting off the compressed air is by no means satisfactory as a warning, as not infrequently it is stopped accidently, so that it loses its value as an alarm. The introduction of water into compressed air lines is undesirable as a fire warning and necessitates considerable care, especially in deep mines; pressure-reducing valves must be provided to reduce pressure that otherwise would break connections or split the pipe. A quick, effective method of warning miners underground of the existence of an emergency requiring them to leave the mine immediately, such as a fire on the surface or underground, is provided by the introduction of stenches in the compressed-air lines. This method of warning is by no means experimental, inasmuch as it has been used successfully for many years in

Jul 1, 1943