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By J. E. Tiffany

"The new permissible blasting device, Cardox, utilizes as a blasting agent liquid carbon dioxide which is discharged.as a gas from a steel container or shell. The loaded shell is placed in a borehole, stemmed, and tamped in a manner similar to that employed with explosives, and is fired by electricity.The Bureau of Mines' approval for use of the device in coal mines was granted as Approval No. 1 under date of October 3, 1928; as the result of tests made under the conditions and requirements of Schedule 20. There have been three subsequent extensions whereby minor modifications in the original design were granted.The permissibility of the device is subject to the following conditions; (1) It shall be in all respects similar to the sample submitted for tests; (2) certain thicknesses of disc and. weights of heater ingredient and of carbon dioxide, all of which are set forth in Table 2 under the provisions governing permissibility, must be used: (3) the rear cap must always be in place after the shell has been charged, to prevent accidental firing; and (4) firing must be done by means of a permissible-type blasting unit.The permissibility of Cardox was established by gallery tests similar to those used in testing explosives for permissibility. In these tests the shell was discharged into gallery 1 without causing any ignition of gas and air or of gas, dust, and air mixtures there. The conditions of charging the shell, such as weight of the ingredients of the heater element, the carbon dioxide charge, and thicknesses of the disc, were varied according to the conditions under which it would be likely to be used in blasting. The tests made in gallery 1 are here described in detail, as are also the tests which have been made for determining the propulsive strength of the device and the quantities of poisonous gases given off when a shell is discharged."

Mar 1, 1929

By M. Clair Smith

The Sweetwater, Castro, Trinidad, New London, and Hilltop chromite properties are situated within an area 8 miles long and 1 mile wide between San Luis Obispo city and Morro Creek, San Luis Obiso County, Calif. Development work at this group of mines was a part of a long-range project by the Bureau of Mines to develop strategic mineral reserves in the United States in accordance with the Strategic Minerals Act of 1939. The junior author of this report participated in the preliminary examinations made in 1941 of the chromite deposits that later in the same year were the subject of more intensive investigation under the immediate supervision of the senior author. The ore occurs in lenses and kidneys in masses of dunite contained in large poridetite areas. Production has boon in the form of lump ore and concentrates from disseminated ore. Work by the Bureau of Miner included surveying, mapping, trenching, sampling, and assaying. It is summarized separately in the text under the name of each mine investigated. The report gives a brief history of the district, describer the concentrating plant of the Castro Associates, and gives detailed results on sampling and assays at the various proportion.

Jan 1, 1951

By Floyd G. Anderson

The increasing trend toward use of continuous-type mining machines created a significant dust problem in coal mining, which resolved itself into three categories: Visibility at face, deposition on return airways, and the potential health hazard. The control measures applicable to these conditions and studied or developed from 1955 through 1957 are summarized and reviewed in this report. Other important problems brought into focus during the same period were radiation exposure in uranium mining and high temperature and humidity. Although temperature and atmospheric pressure alone may not be contributing factors in the incidence of silicosis, the few mining companies who operate under the extremes of these conditions are dust conscious and keep dust-control engineers on their operating staffs.

Jan 1, 1961

By W. H. Tomlinson

Although the thoughts and efforts of the great majority of people in many parts of the world are today directed toward killing each other, the purpose of this paper is to discuss means of conserving human life. In a world of turmoil and strife, we find time to discuss and make plans to achieve our objective -prevention of the "sacrifice" of life through avoidable accidents. The word" sacrifice" is used here advisedly, as one meaning of the word given in the 1942 edition of Funk and Wagnalls New Dictionary of the English Language is "the act of giving up some desired or valued object for the sake of *** future good." As everyone agrees that life is man's most priceless possession, one wonders if past sacrifices have been in vain. It appears that life is cheap in America; it is cheap because some of the industrialists are too much concerned with making a profit to devote much time and thought to conserving human life; it is cheap because some labor leaders apparently are interested solely in personal power and prestige; it is cheap because a great many workmen fail or refuse to cooperate energetically with the various organizations interested ill; their safety and welfare; it is of little value because, individually and collectively, we are indifferent to our responsibilities toward our fellow men.

Jan 1, 1944

By Herbert H. Einstein

The thrust of research reported in Part I was to collect in-situ data from exploration programs and the published literature, and to empirically establish distributional patterns for these variables. Since discontinui¬ties in a rock mass govern to a large extent its engineering properties and thus the performance of any slope in the mass, work has been devoted to determining the appropriate distributional forms for attitude spacing and length of discontinuities and to distributional properties of resis¬tance and deformability parameters. The conclusion from these analyses is that trace lengths are logNormally distributed and that joint spacing is Exponentially distributed, regardless of orientation of the sampling line, and regardless of whether each joint set is considered separately or not. Joint orientation (attitude) data representing 22 individual joint sets from eight sites (a total or approximately 20,000 joints), do nor strongly support any of the commonly used distributions as broadly applicable in practice. The autocorrelation )f geometric joint properties is also examined. However, no significant spatial correlation could be found even after extensive data manipulation. The investigation of resistance and deformability parameters starts with a review of mechanisms and models that are used to represent them. Review and statistical evaluation of approxi¬mately 2,000 discontinuity shear tests has shown that good statistical estimates for use in reliability analyses can be obtained for friction angles.

Jan 1, 1979

By S. H. Ash

The paramount responsibility of Government is to protect the general welfare. One of the chief functions of the Bureau of Mines is to investigate and publicize methods of increasing safety and efficiency in mining operations. In an industrial civilization, energy resources constitute the foundation of a sound economic structure (14).4/ Coal is only one source of energy, but it provides more than half the energy consumed in the United States.

Jan 1, 1946

By Robert E. Wallhagen

The froth foam seal topping system is part of a system for remote sealing of mine passages using flyash transported pnuematically from the surface. Making the final 5 percent of the seal with a foamed-in-place fire retardant polyurethane reduces the required flyash volume by 50 percent and provides a more reliable seal. Foam components are held at the surface under proper conditions of temperature and pressure; then conveyed down the borehole through individual hoses and mixed at the bottom with a static mixer. The polyol component is pre-mixed with fluorocarbon-12 which, when released from system pressure in the mixer, boils and causes the foam to expand. Difficulties in handling this particular foam formulation are offset by a flame spread index well below the 25 level by ASTM E-162 normally required for under-ground applications. Isocyanate, polyol (TDI) and catalyst are conveyed to the downhole package by three separate lines. Five additional lines operate the valving and convey solvent so that the mixer and package lines can be flushed immediately after foaming. The eight-hose bundle is provided in segments of several lengths so that bore-hole depths can be matched. Cast-in-place plastic cylinders hold the bundle together and transfer the weight of the hose through a special quick-release clamp to the crane's wire rope. The downhole package and hose bundle are deployed using a specially designed winch and crane system capable of borehole deployment to 1500 feet.

Jan 1, 1977

By Deno M. Pappas

The purpose of this Bureau of Mines study of U.S. roof and rib (roof- rib) accident statistics and related accident costs is to define current accident trends (1980-84) associated with fatal and nonfatal roof-rib fall accidents. Data were retrieved from a data base containing all recorded U.S. mining accidents, then sorted and normalized utilizing a computer software program. The statistics indicate that roof-rib accidents have significantly declined in the 5-yr study period. Moreover, they indicate that there have been increases and/or patterns of roof-rib accidents associated with specific mine characteristics, such as seam height, mine size, geographic location, and seasonal variations. Also, roof-rib injury characteristics produced pattern changes involving worker activity, lost workdays, types of injury, and severity of injury. A conservative estimate indicates that there has been a 30% adjusted increase in the cost of a roof-rib accident over the 5-yr study period.

Jan 1, 1987

By H. W. St. Clair

This study was undertaken to provide a more adequate knowledge of the chemistry of the sulfide volatilization process for recovery of tin from low-grade Bolivian ores. The investigation was partly supported by the Department of State under its program for scientific cooperation with South American republics. The results of this investigation demonstrate the conditions under which cassiterite (Sn02) may be converted to stannous sulfide by reaction with pyrite or sulfur vapor, Quantitative data are given on the rate of sulfidization and on the vapor pressure of stannous sulfide.

Jan 1, 1954

By M. E. Tyrrell

This Bureau of Mines investigation was made to determine the possibilities of using Florida beach-sand concentrator wastes in ceramic products. Sands used in the investigation originated in the Trail Ridge area of Florida, where continued operation of processing plants for recovering titanium minerals promises a dependable source of raw materials. Three general classes of ceramic products were studied, namely: (1) Structural, (2) refractory, and (3) electric-furnace slags.

Jan 1, 1956

By H. C. Fowler

Hydrogen sulphide associated with the gasps and vapors from certain crude oils now produced in the United States has forced a serious health and safety problem upon the petroleum industry. Although the presence of hydrogen sulphide in or occurring with Mexican crudes has been known for some time, it was not until recently that crude oils which give off poisonous amounts of hydrogen sulphide have been produced to any extent in the United State. The injurious effects of this poisonous gas were first recognized by the refiners along; the Atlantic and Gulf Coasts upon receiving shipments of crude petroleum from Mexico. The problem of combating the hazards of the gases and vapors given off by this petroleum become more important as the use of Mexican crude increased. In 1925, the Bureau of Mines and Public Health Service under cooperative agreement with the American Petroleum Institute, studied the causes rend effects of hydrogen sulphide poisoning. Bureau of Mines Bulletin 2312 is report of this investigation, and although written with special reference to refineries, it nevertheless contains much information that is of value to the producer of petroleum.

Jan 1, 1927

By Frank D. Lamb, D. A. Woodard

"INTRODUCTION The iron-ore deposits near Cranberry, N. C., were worked as early as 1820, and records show that to date at least 1,500,000 tons of ore has been mined.. The early operators depended on selective mining and hand cobbing to yield a product containing 40 to 50 percent iron. Later, a magnetic concentrator was erected by the Cranberry Furnace Co. and was operated periodically until 1930. The magnetic cobbing method employed yielded satisfactory concentrates, but the plant was shut down because costs were too high. 4/Early in 1944, in connection with the sponge-iron program of the Bureau of Mines, North Carolina and Tennessee were surveyed for the purpose of finding a readily available source of high-grade iron ore for use in the experimental production of sponge iron at Salisbury, N. C., and samples from various sources were tested in the laboratory. The Cranberry ore proved to be best with respect to grade of magnetite concentrates produced, and it was decided that a pilot mill should be built on the Cranberry mine property and that the concentrate made there should be shipped to Salisbury for direct-reduction tests in a commercial brick kiln."

Dec 1, 1946

By Clarence Hall, CHARLES F. MUNROE

Of the common causes of the larger mine accidents, such as falls of roof and coal, gas and dust explosions, mine fires, and the misuse of explosives, all of which are often closely related, each must be studied and fought in a manner peculiar to itself. The last mentioned, the misuse of black powder and other explosives, is sometimes considered the least important of these causes of mine accidents; but its impor- tance is much greater than the statistics indicate, for the reason that the misuse of explosives is the true cause of many of the fatal mine fires, gas or dust explosions, and falls of roof that are credited to other causes. Both the quantity of explosives used and the number of purposes to which they are applied are increasing. They are now made at about 150 plants, in different parts of the United States, and the product of a single year is estimated at nearly 500,000,000 pounds. Nothing in all this material is a safe or "safety" explosive when in the hands of a careless or ignorant person; and this is true whether considered in connection with the shipment or the use of these explosives. In addition to the large losses of life and property resulting from an improper use of explosives in mining, the recent statistics of the railway bureau for the safe transportation of explo- sives have shown more than 400 persons killed or injured and over $3,000,000 worth of property destroyed by explosives in transit by rail. The fact that three years of cooperative effort under the wise supervision of this bureau has reduced these losses to almost nothing encourages the hope that similar cooperative effort may likewise greatly lessen losses of life and property from the use of explosives in mining. The additions to the large death roll of our mines make a recurring appeal to the public for fair treatment of the coal-mining industry, and to the miner and the manager that they join in every possible effort for greater safety. It may never be possible under conditions such as exist to-day to prevent mine accidents entirely. Little can be accomplished in that direction by either the operators or the miners working alone, but experience in all countries shows that

Jan 1, 1911

By Larry A. Haas

A major problem encountered in dump leaching operations is the plugging of both the dump and the piping by precipitated iron compounds. Bureau of Mines research to obtain basic data on agitation leaching and dump leaching methods has shown that the addition of organic chelating reagents can significantly enhance the lixiviant permeability through the ore and the concentration of the metal values in the liquor. For example, the addition of 5 giL citric acid (CA) to a conventional sulfuric acid lixiviant almost doubled the fluid flow rate through 5-cm-diameter laboratory columns containing copper ore. After 185 h of per-colation leaching, the metal concentrations with (and without, in parentheses) CA were 1.7 (1.5) giL Cu, 200 (70) ppm Mn, 160 (40) ppm AI, and 6 (3) ppm Co. The enhancement of metal concentrations with chelating reagents such as CA was confirmed by determining the solubil-ity of several metal ions as functions of pH and chelating reagent con-centration. When ferric ions became insoluble at pH values above 3, the concentrations of other ions also decreased. The addition of che-lating reagents kept iron, as well as the other dissolved metals, in solution even at pH values as high as 5. Citric acid was a more effective chelating reagent than gluconic acid, oxalic acid, or sodium lignin sulfonate.

Jan 1, 1985

By William S. Roberts

As part of the Bureau of Mines critical and strategic minerals program in Alaska, 34 high-purity chromian spinel samples were analyzed for trace and major element geochemistry and mineralogy. The samples were analyzed by X-ray diffraction, X-ray fluorescence, and chemical techniques. Systematic differences in chemistry are evident when samples collected from the Chugach Mountains and their related extension are compared with chromian spinel samples collected from interior Alaska. Compared with the Chugach samples, the interior Alaska samples have higher average amounts of A1203, Fe203, Ti02, and NiO, have lower average amounts of FeO and Cr203, and exhibit greater dispersion in values. Considerable mineralogical variability of chromian spinel exists between and within individual Alaskan chromite-bearing ultramafic complexes. Of 34 samples analyzed, 25 samples are magnesiochromite, 5 are chromite, 3 are spinel, and 1 is hercynite. As a group the interior Alaska samples have a smaller average unit cell dimension than the Chugach group of samples. The chemical and mineralogical differences between the two groups of samples can be attributed to different genetic histories and may have implications for locating chromian spinel deposits amenable to standard beneficiating techniques.

Jan 1, 1985

By Nicholas Kyriazi

The Bureau of Mines subjected three commercial compressed-oxygen self-contained self-rescuers to a series of laboratory treatments designed to simulate various environmental conditions in underground coal mines. The environmental treatments consisted of extremes of temperature and of shock and vibration. The tests were designed to predict the ability of the self-rescuers to withstand those environmental stresses without causing a decrease in wearer protection. A critical concern was internal damage to an apparatus that would cause it to malfunction or seriously degrade its performance without any obvious external signs. The Bureau has previously tested chemical oxygen self-contained self-rescuers in a similar research program. Although the three compressed-oxygen units are not as sturdy as the chemical oxygen self-rescuers tested previously, they performed reliably after treatments on treadmill tests with human subjects and on machine tests using a breathing and metabolic simulator. Serious damage was caused by both the heat treat-ment of 71° C (venting of the 02 bottle in most cases), and in the shock treatment (breaking open of the case and dislodging of the components). When physical damage is obvious, a complete refurbishing of the damaged self-rescuer is recommended.

Jan 1, 1983

By Alfred Bellows

The objective of this contract is to design, build and demonstrate a support system to improve roof control in the entries of longwall mines. The objective of this phase has been the detailed design of such a system and the selection of a test site in which to perform the pilot demonstration. The result is a complete set of detail drawings or specifications which define the three major components of the system. The Gate Support is a variation of a face chock which has an extended canopy and additional hydraulic legs to protect the region of the face-entry intersection. The Entry Support is a steel beam and hydraulic prop set which is reusable and serves to support the first 100 or more feet of entry inby the longwall face. The Transporter is a bolter-like vehicle with a crane used for installing and retreating the beam sets. The test site selected is CF&I's Allen Mine in Colorado. They presently use simi¬lar steel beams and expect the FMA support system to be more effective as well as recoverable. It is recommended that the completed drawings be used to build a prototype system and test it first in a remote section of the mine and then in the active longwall tail entry.

Jan 1, 1978

By Andrew Allan

[Research conducted by the Bureau of Mines hrinq the last 5 years on the uce of machines for 7!naer:rolmrl ?.eve loym~nt in pi.t,c hlng anthracite beds l~a~ provide? data ?howin? that ?:;panrt of thc roof an9 str?eg of thes? oTen - jnqs requires almst half of' the PRS? workin? time. The possibilitie~ of i!rinz a mvable,. te1.ee*co@. c tpr? 3f ?tee1 ~h-!.oltl at the face in~tetcrl of conventional wood a*ti~yorts w?r? si:~q~eteil by engineers engaqad on the~ work If ~uch a shi~l8 COLI.~,~. be ~sve~.~yad, it tnillil man that face workera w~uld be provi8ed with mulrnu.m prot?ct+on from falls of' roof and ribs mi! the en- tire ehift could he I~W? Lo ~lro,J.~:ce cocl. Fermanent tim3er coald be p'l.acnA behind the shielR independently of the 'face work as the face advanced.]

Jan 1, 1953

By R. L. Loofbourow

The adjacent towns of Rouyn and Noranda, centers of the Rouyn mining district of western Quebec, are 360 miles by air line almost duo north of Toronto. Rouyn is reached from the main lines of the Canadian National Railways and the Canadian Pacific Railway at North Bay, Ontario, by the Temiskaming & Northern Ontario Railway and its subsidiary, the Nipissing Central Railway. Noranda is the southwestern terminus of a branch from the Canadian National Railway between Winnipeg and Quebec. The Rouyn mining district is a part of a mineralized zone that has been traced for a distance of 140 miles from Kirkland Lake in Ontario eastward into the Province of Quebec to the Pascalis district. From Rouyn the mine is 5 miler almost duo south over a gravel rend built by the company with assistance from the Province of Quebec.

Jan 1, 1933

By William J. Campbell

The purpose of this investigation was to develop a rapid, accurate method of analysis for small amounts of calcium in wolframite concentrates. This analysis is necessary to determine if the wolframite concentrates meet United States National Stockpile Specification P-57R2, which limits the calcium content to 0.2 percent. Because of the small depth of the sample analyzed in fluorescent X-ray spectrography, the calcium Kaline intensity was a function of the chemical composition of the calcium-bearing particle as well as the total matrix composition. This particle-composition effect was particularly important in this analysis, as the calcium may be present as a carbonate, tungstate, phosphate, etc. Three methods of preparing the sample eliminated the variation of calcium Ka intensity with mineralogical occurrence: (1) Reduction in particle size by extensive grinding, (2) chemical fusion with sodium carbonate, and (3) solution of the calcium by an acid attack.

Jan 1, 1958