Search Documents

By Joerg Hammerschmidt, Marcus Runkel, Steffen Haus

Given the limited number of new plant construction, focus is turning to the optimization of existing metallurgical roasting plants. To meet the goals of high process efficiency with limited capital expenditure, plant owners are looking for new strategies, including digitization and expert support. As a supplier for numerous roasting, gas cleaning and sulfuric acid plants, Outotec has intensified its effort in recent years to develop solutions to accommodate increasing customer need. This article presents a short review on how Outotec is applying advanced control tools for the fluidized bed industry. Focus will be given on how to transfer the existing technology (used in selected Zinc roasting plants for over a year now) to copper roasting. Outotec has developed the Pretium Roaster Optimizer, a system based on heat and mass-balanced simulation models. Direct experience with this technology will be shared and will highlight similarities to the Partial and Sulfate Copper roasting processes. Pretium detects equipment and plant bottlenecks and provides consistency in process development. The Pretium program combines 24/7 advanced online digitalization tools, along with expert personal support when required. INTRODUCTION Fluidized bed reactors have been used for commercial-scale zinc and copper roasting since the 1950s. While the principles of roasting remain unchanged, over time, the technology has advanced to improve process control of roasting plants. In the past, environmental and safety standards were the driving forces for improvement of equipment and plant design. Today, the emphasis is on plant efficiency and optimization. Another change has come in process control philosophy. While plant control and operation have traditionally been the responsibility of owner/operators, they have now shifted to include both integrated digital tools and specific know-how from engineering companies. This can be seen from the earliest design stages through commissioning and into production, as evidenced by zinc roasting plants in Mexico, Brazil and Turkey.

Jan 1, 2019

By Osvaldo A. Bascur

Industrial complexes rely on measurements of flow rates, qualities, and concentrations for monitoring and optimizing their operation. Corporations use the data from the various sensors and measurements to make business decisions, which affect the profitability of the operation. However, gross errors, due to a variety of reasons like faulty sensors, bad instrument calibration, or incorrect process models may corrupt the actionable information supplied to operations, quality managers, and maintenance personnel. The solution is to use the sophisticated new tools to model the process, sift through the available data to locate the gross errors, and use statistical data reconciliation to validate the sensors and instruments. In this way the data are unified to give the most accurate plant information for use by the monitoring and decision making processes. Most mining and metallurgical plants use predictive maintenance policies based on statistical analysis and special techniques, like vibration analysis, and oil and lube analysis for critical equipment. Process control strategies are installed in several metallurgical sites. All of these depend on reliable and accurate data. The data unification methods validate the individual measurements by using the concept of balances and statistical techniques where each instrument is no longer independent of the other measurements in the facility. This paper refers to the data unification and analysis methods required for profitable plant operations. Continuous improvement and monitoring of the measurement system at the plant and analysis of the reconciled data provide the best information for the decision-making process. On-line gross error detection and elimination methods are required to ensure efficient evaluation of process performance and process optimization. An open discussion of the new methods for gross error detection and data unification will be presented.

May 1, 2001

By P. C. Garg

"IntroductionThe Central Mine Planning and Design Institute (CMPDI) of India, started planning the extraction of thick seams highly susceptible to heating in 1977by the French method of sub-level caving and/or multi-slicing. Nitrogen flushing was proposed for inhibition of heating by the author in one such project - the Kotadih colliery.Inhibition of heating was unheard of in the Indian coal industry before 1977-78. The usual practice was to seal off a district or a part of the mine or the entire mine when spontaneous heating occurred. With very little equipment in a normal bord and pillar district and a low production rate, the financial loss in capital assets and in production did not warrant any serious thought for inhibition of spontaneous combustion. With the planned advent of longwall mining, particularly sub-level caving, with heavy capital investment as well as high production potential, the sealing of a longwall face due to spontaneous heating could not be considered an appropriate solution.Principle of Inhibition of SpontaneousCombustionFrench engineers have established that a fire will not break out when oxygen is 15% or lower in the general body of the air. However, once a fire starts, the percentage of oxygen has to be reduced to 2% - 4% to extinguish it. It is this principle which has been used at Blanzy Coalfield in France to inhibit heating and it is claimed that this has retrieved the integral sub level method of mining. Nitrogen infusion has been used in Frence since 1978 to keep the oxygen content below 14% in the goaf."

Jan 1, 1987

By M. Imamura

Sumitomo Metal Mining Co., Ltd. has developed a novel hydrometallurgical process for producing not only copper metal but also iron metal from copper concentrates. Because copper concentrates generally contains the same amount of iron as copper, cost-effective rejection of the iron is a key issue for the development of the process. Conventional hydrometallurgical processes produce a large volume of goethite or hematite for disposal and the residues are not environmentally friendly. In the novel Sumitomo hydrometallurgical process, copper is leached effectively from chalcopyrite concentrates using chlorine gas, followed by purification through solvent extraction and electrowinning for copper and iron recovery. This process has many advantages such as the minimization of the volume of solid waste by the recovery of metallic iron and the production of high purity copper. Iron metal with a purity of more than 98% can be recovered from the purified raffinate. This paper presents the results of the batch and continuous tests of the process flowsheet.

Jan 1, 2006

By T. Yameogo

Many ideas, tools, technologies, and methodologies are believed to have staked their claims on the future of mining. For example, automation is strongly positioned as the platform within which mining will be practiced. A subset of automation ? intelligent mining ? will add some smart interactions between machines, technologies, the rock, and the environment. The future also calls for an improved approach to sustainability and corporate social responsibility. Mines of the future are dreamed of to be more ethical and more balanced. They will boast optimized designs, integrated value and supply chains, produce less waste, recycle and reuse, and will require less energy to operate. Then, what about the people that will operate this optimized ecosystem? How is the education system teaching the operators of the mines of the future? What kind of a future should mining education foresee to prepare the workers appropriately? In recent years, the shortage of skilled labor for mines around the world has created a tough competition to attract, retain, and train the very people without whom mining will cease to exist. In Australia, Canada, and the United States in particular, the war for talent has resulted in higher-than-usual labour costs. Such costs have dented the unit costs of many mining businesses. Concomitantly, mining contractors? and consultants? prices have increased to reflect the escalation of labour costs across the value chain. From labourers to engineers, from juniors to seasoned professionals, the increase in compensation is unprecedented. Yet, the shortage is still hurting the industry, and the high calibre candidates continue to be rare gems. The industry has been implementing aggressive solutions that include the increased hiring of skilled immigrants, the training and recruitment of minorities, and the retaining of near-retirement experienced employees. Public relation campaigns about the benefits of embracing careers in mining are also common. The CIM has also devoted a ?M4S? section to its pan-Canada meetings to educate the public, especially the youth, about the importance of the mining industry for Canada. Moreover, mining associations and universities are enticing students? enrolment through scholarships and financial support. Still, the balance between quantity and quality of workers can be discussed. This paper intends to discuss the present state of mining education as an essential part of the future of mining. The authors brush the picture of the education of miners, technicians, and engineers, against the backdrop of the technology-advanced mines of the future.

Aug 1, 2013

By Ronald E. Pike

"PREFACEAt the CIM Annual General Meeting in Quebec City, R.E. Pike of The Toronto-Dominion Bank described how the Canadian banking industry worked with the minerals industry to assemble the large capital requirements for resource projects in Canada and overseas. He developed a profile of the mining industry and Canadian banking, both being important sectors of the Canadian economy and global in context. He also outlined the banking and financing partnership that existed in the past. In looking to the future and challenge that lies ahead f or each industry, Mr. Pike questioned whether the financing practices of the 1970s will be acceptable over the next decade. In that regard, he highlighted the risks that impact on each industry and illustrated how that financing partnership might evolve in response to those forces. The folio wing is a synopsis of his paper.IntroductionThe Canadian mining and metals industry is prominent in the domestic economy and respected internationally. Any measure of its performance illustrates that status-percentage of GNP, employment, exports, capital investment, size relative to other producing nations, etc.Energy, Mines and Resources Canada has forecast that the non-fuel minerals industry will grow in real terms by an average annual rate of 3.0% over the period 1981 to 1991. Using the GNP as reference, that growth in non-fuel mineral production will represent 7.7% of GNP. In translating that growth to capital expenditure, the EMR Canada estimates the aggregate amount at $43.8 billion ('79 dollars) or approximately 12% of total business investment in Canada during the 10-year period.About half of the $43.8 billion will be devoted to the ferrous sector-$8.4 billion in iron ore mining and $12.4 billion in the steel industry. Capital investment in nonferrous s projects is estimated at $13.3 billion, and it is projected at $6.7 billion for industrial minerals. The residual $3.0 .billion is exploration spending."

Jan 1, 1982

By Ian S. Leslie

Seismic monitoring systems for mining operations are being utilized more than ever before in the characterization of rock mass response to underground and open pit mining. This paper provides a review of the use of microseismic monitoring for rock mechanics applications at mines throughout the world. Some practical considerations for the installation of these systems are presented along with techniques for optimizing seismic array coverage. Case studies and installation examples are also provided. Recent applications of advanced seismic analysis techniques are discussed including the determination of event mechanisms, mapping of maximum peak particle velocity (PPV) and seismic hazard fields, and the use of source parameter data for large event re-entry protocol.

Jun 1, 2012

By J. A. Haskin

The Engineering Department at Flin Flon has the following responsibilities: 1. Underground Surveying. 2. Open-Pit Surveying and Supervision of Blasting. 3. Mine Geology and Examination of Prospects. 4. Design of Plant Additions and Improvements. 5. Miscellaneous Field W ork, Reports, etc. The entire surface plant, as well as the underground workings, are located by co-ordinates based on a triangulation system covering an area approximately one mile long by one-half mile wide. The origin of this system and one end of the base-line is the southwest corner of Township 67, Range 29, west of the Principal Meridian. The bearing of the base-line was determined from the township boundary, which runs true north, so that all other bearings are almost astronomical. This is a great convenience when our surveys must be tied to mineral claims, rights-of-way, and land subdivisions. As the base-line extends across Flin Flon lake, its measurement across smooth ice was simple and accurate. The length, slightly over 1,600 feet, has been adjusted for the temperature and tension of the standard tapes used and checked sufficiently to ensure a maximum error of 1 : 15,000. Each angle was repeated ten times, but as no special refinements were used, errors of as much as four or five seconds are possible. The elevation of the origin of the triangulation system was approximately 1,050 feet above sea level. The use of this true elevation in our surveys would have resulted in negative elevations underground as soon as the mine reached a depth greater than 1,050 feet. To avoid this complication we therefore added 4,000 feet to this elevation. The collar of the Main shaft, for example, which is actually 1,072 feet above sea level, appears in our records as at elevation 5,072. Underground surveying, which follows standard practice, is done by two mine surveyors who share three helpers. The meridian is taken underground from two wires hung in either of the two vertical shafts.

Jan 1, 1935

By B. Schulz, T. Leißner, R. G. Merker

"Ores enriched in critical rare earth elements (CREE) keep on being of particular interest. The CREE are Nd, Eu, Tb, Dy, including Y. In conjunction with beneficiation tests on Y-mineral bearing flotation tailings of complicated mineralogy, the Mineral Liberation Analyses (MLA) was used to work out processing characteristics fraction-wise in terms of modal mineralogy, mineral recovery, locking and liberation, and particle size.Size fractions from mechanical sieving (“real fractions”) as well as fractions created virtually by using filters on the MLA-data of the unsieved head material (“virtual fractions”) were investigated comparatively thereby. The ""virtual-sizing-approach"" features a much simpler sample preparation procedure and considerably lower cost if a fraction-wise investigation of a head sample is needed. It can be conveniently applied to intimately locked ores needing a fine grinding to a particle size distribution (PSD) range below 25 microns for instance. However, its practical use is sometimes disputed in terms of the reliability of the results. Results are shown for the main Y-bearing mineral xenotime and selected main gangue minerals of a low grade REE-ore.The influence of sample representativeness, sample preparation and particle counting statistics turned out to be of crucial importance. Given that all preconditions for reliable results are met, locking characteristics, modal mineralogy, and even PSD trends can be read from virtual fractions.The authors encourage processing engineers to use the virtual approach. They propose practical measures to improve the reliability of the MLA results, identify and tackle conflicting results, and mitigate evaluation problems that may arise."

Jan 1, 2016

By S. Esmaeili

The yield strength model developed by Esmaeili, Lloyd and Poole [1] has been adapted to model isothermal aging in Cu-containing AA6xxx alloys, with (a) a moderate and (b) a very low Cu content in the solution-treated, as-quenched, condition, Isothermal calorimetry has been used to analyze the kinetics of precipitation in these alloys, While the kinetic parameters for the low Cu alloy has been derived from the present experiments, the previously determined kinetic parameters for the high Cu alloy AA6111 has been used to model the precipitation kinetics in the moderate Cu alloy. The age hardening responses of both alloys have been well predicted by the model.

Jan 1, 2005

By H. Staton, V. Suontaka, E. Sharifi

"Flotation circuits are typically controlled using on-line elemental assays obtained from the slurry lines. In base metal applications, X-ray fluorescence (XRF) analyzers are the most common instruments for elemental analysis of the slurries. Eagle Mine has been utilizing a Courier XRF Analyzer since 2014. Typically, in XRF analysis, the sampling rate is 10-25 minutes which is good enough for manual process control. In 2018, Eagle Mine upgraded the Courier XRF analyzer with the Rapid Measurement module that is based on reflectance spectroscopy. This option reduces the sampling rate to 10-15 seconds, while maintaining the superior accuracy of the XRF analyzer. This paper presents the results from implementation of Rapid Measurement at Eagle Mine.INTRODUCTION Eagle mine is an underground mine producing nickel and copper concentrates. Eagle Mine is owned by Lundin mining and located in the Upper Peninsula of Michigan, USA. The Humboldt Mill, previously an iron ore processing facility, was refurbished in 2014 and is used to process the ore and produce separate nickel and copper concentrates. Approximately 2,000 metric tonnes of ore is milled per day. Ore is processed using a conventional crushing followed by single stage ball mill and flotation. Nickel and copper concentrate are transported to facilities in North America via rail car. A bulk copper-nickel concentrate is produced by separating the copper and nickel minerals from gangue material by flotation. The copper-nickel bulk concentrate is reground, followed by one stage of cleaning to reject further gangue minerals. The bulk cleaner concentrate is then subjected to a final flotation stage where the copper and nickel minerals are separated from one another through the addition of lime. Final concentrate grades are 14% Ni and 2% Cu in the nickel concentrate and 31% Cu and 0.8% Ni in copper concentrate."

Jan 1, 2019

By A. Henk, C. M. Aruffo, K. Fischer

"Geomechanical reservoir modeling offers a valuable tool to predict tectonic stresses, in particular the local perturbations in orientation and/or magnitude which occur at lithological boundaries and faults. The paper presents a workflow for building and calibrating such geomechanical models. The numerical simulations are based on the Finite Element method and can range from field-scale models to smaller, highly detailed submodels of specific fault blocks. The approach considers the reservoir-specific characteristics with respect to subsurface geometry (lithostratigraphic boundaries, faults), mechanical properties and ambient stress field. During the subsequent calibration stage calculated stresses are compared to stress data actually observed in borehole data. Poorly constrained input parameters are iteratively modified within reasonable limits until a satisfactory fit between calculated and measured stresses is achieved. This validated model can then be used for stress predictions between wells and in undrilled parts of the reservoir, respectively. The workflow is applied to two case studies - a large gas field in Northern Germany and a CO2 sequestration project in Australia – to test and illustrate its practical value. INTRODUCTIONDetailed knowledge of the tectonic stress field is crucial for the optimal exploration and use not only of conventional and unconventional hydrocarbon reservoirs, but also for deep geothermal reservoirs, carbon capture and storage (CCS) projects as well as underground mining and nuclear waste repositories. Any reliable stress prediction is hindered by the observation that the magnitude and orientation of the stress field can vary significantly – not only in time, but also in space. Such spatial stress variations comprise all scales, i.e., from the scale of lithospheric plates down to the grain-scale. On the reservoir- and fault blockscale, the local stress field can be influenced by faults and different mechanical properties of lithologies (Sassi & Faure, 1997). The resulting variations in stress magnitude and/or stress orientation are commonly referred to as stress perturbations and give rise to a unique, reservoir-specific stress pattern (Yale, 2003). Thereby, local stress fields can deviate by up to 90° in orientation and several tenth of Megapascal (MPa) in magnitude from regional trends."

Jan 1, 2015

By J. E. Carrasco, J. D. Stinnette, R. A. Alvarez

"Chuquicamata Underground Mine is one of the main projects for the Chilean government copper company (CODELCO). Underground mine project has been under construction since 2013 and presents a solution for the lower production levels of the open pit and prolongs the life of the mine for the next 40 years. Currently, around 2000 workers operate in the mine daily. Dozens of trucks and heavy machines drives through all main routes and access in the mine. As a mine under construction not all the infrastructure necessary to operate safely in the mine has been completed. Risk of a truck or fixed facility fire is always a challenge to keep under control. One important part of fire simulation relays on what we can do prevent a fire and what can be done with the existing infrastructure to control a declared fire and start evacuation plans. This study has been made as a feasible emergency plan to implement, in this case, of a mine under construction, were limited resources are available. Several fire scenarios have been made to support all the emergency plan strategy and a detailed step by step procedure indicates what the elements of a fire emergency plan and risk analysis are.INTRODUCTIONThe main objective of this study is to describe the importance of fire risk analyses (FRAs) and different methods to be used before commencing fire simulation and methodology steps utilized for a fire emergency plan strategy (EPS) at the Chuquicamata underground mine. It also describes how to classify zones which are going to be affected by fumes and gases propagation derived from the exact location of a fire event. Fire simulation study is helpful to determine the impact on a ventilation system with the main purpose of providing relevant information to complement emergency plans and stablished control techniques in ventilation design and its operation. Most fire simulation studies only concentrates in simulation techniques on itself. But what is the next following step in developing an emergency plan? How can we evaluate, classify and treat risky areas? This study is focused mainly in the phases before and after a fire simulation process. Phases corresponds to a good FRA and how output data can be used for an EPS."

Jan 1, 2019

By A. C. Hatton

Doped SrCoO3.8 was found to be a promising material for use as a cathode component in intermediate temperature SOFCs. In this work, strontium cobaltite ceramics doped with 10 mol% to 90 mol% samarium were synthesized using the glycine nitrate process in order to study the electrical conductivity and thermal expansion at temperatures of up to 800°C. As-synthesized powders were deagglomerated, pressed and sintered at temperatures ranging from 1100-1250°C. The effect of temperature and composition on electrical conductivity and thermal expansion are presented and discussed.

Jan 1, 2005

By D. J. Lucifora

Monitoring-While-Drilling (MWD) is a proven technique that records instantaneous on-drill parameters which can be used to supply contextual information for in-situ, down hole conditions, such as: changes in geology, the presence of pre-existing fractures and dynamic alterations, down hole conditions including bit bailing, bit blockages and bit wear, and improper drill operation. This technique has been widely used in the oil and gas industry and, eventually, it was transferred to the mining industry. A challenge when analyzing and interpreting MWD data is in utilizing proper filtering which enables one to properly eliminate any ?noise? from the signals of interest. Overall the importance of MWD data is that, through the collection of operational field-based data, a dataset can be acquired which allows experimentation and analysis to be carried out. Such a dataset is often impossible to replicate in a laboratory setting. If successful, and through iterative refinement, any promising method can eventually be implemented on-machine and using real-time monitoring techniques. This paper will provide a state of the art review of presently used MWD techniques and applications in industry. The paper?s primary focus will be on shallow, mining-style, blast hole drilling but will also take into account techniques and applications utilized in oil and gas drilling which have not been adopted in the mining industry. In the cases where MWD techniques and applications exist solely in oil and gas drilling the paper will examine and comment on the potential utility of technology transfer to mining applications.

Aug 1, 2013

The mining industry has generally been slow to apply ion exchange processes to hydrometallurgical applications even if ion exchange offers an ideal solution for a particular problem. Two notable exceptions are in gold and uranium recovery. The largest application of ion exchange in the metals processing industry has been the use of resin-in-pulp (RIP) for gold recovery as an alternative to activated carbon. Iron is a ubiquitous impurity in hydrometallurgical solutions. In many cases, bulk removal of iron from the process solutions is accomplished by precipitation. However, precipitation for iron control is often accompanied by losses of base metals by co-precipitation. Increasingly, the option of ion exchange for removal of smaller amounts of iron from process solutions has been favoured. A number of applications have been developed and proven at the commercial scale for the removal/control of iron from a range of metal processing solutions. This paper provides an overview of the application of ion exchange for iron removal from a range of metal processing operations, including Cu, Ni and Co solutions. A number of case studies are provided which review operational and resin regeneration strategies and the impact upon the commercial operation of metal processing with improved iron control.

Jan 1, 2006

By Mohammad. M. Khajeh

Rock mechanical properties are important parameters in geomechanical simulation. Considering stochastic heterogeneous models rather than conventional homogeneous layer cake models leads to more realistic simulation results and uncertainty assessment. These heterogeneous models are usually fine scale models generated by geostatistical techniques. Although considering high resolution property models is desirable, geomechanical simulation with a fine scale model is not computationally feasible for full?field, coupled geomechanical-flow simulation. Upscaling of property models is necessary to move from fine scale/high resolution property models to coarser scale/low resolution models appropriate for simulation. Local numerical upscaling was proposed by Khajeh et al. (2012) to describe the macroscopic elastic behavior of complex heterogeneous media and is expanded upon in this work. This numerical technique is not restricted to specific geologies as typical analytical techniques are. Moreover, transversely isotropic deformation is considered rather than the usual assumption of isotropic deformation. To compare the accuracy of the upscaling methodology, in this study shear strain is considered as the geomechanical response of a synthetic facies model and the response of the coarse scale model is compared to other conventional analytical averaging techniques. It is found that the numerical upscaling technique better approximates the geomechanical response of the fine scale model.

Jun 1, 2012

By Yasser Mohamed

Daily field management of earthmoving operations requires quick and regular decisions for allocating available equipment to different jobs on a project. A general foreman?s day starts with matching several activities with a suitable set of available equipment to achieve the highest productivity and lowest unit cost. Usually, this decision-making process needs to be quick, and depends to a great extent on the foreman?s experience, which varies from one individual to another. Many analytical solutions with various degrees of sophistication and optimization exist to address such decisions. However, adopting any of these solutions is contingent on how accessible and easy-to-use the solution is. This paper discusses the development process of a webaccessible solution for evaluating earthmoving fleet composition and allocation scenarios. The solution relies on discrete event simulation and an optimization backend engine, but introduces the user with a simplified and easy-to-use interface that is accessible from any mobile device, and is customized to specific user?s needs. The developed system gathers most equipment and site-related input data from a company?s information systems to minimize user input. The user mainly needs to formulate equipment and job combinations and allocation scenarios (e.g. soil type, quantity, and hauling distance), according to equipment availability each day. Then the system will evaluate the productivity and unit cost estimates for each scenario, allowing the user to choose the most suitable one. It may also be used to automatically recommend the optimum solution given an available list of equipment. The paper presents the process followed in prototyping the proposed system in collaboration with a major Canadian earthmoving contractor, and customizing it to the user needs within the company. It also describes the overall structure of the developed system and its core simulation model.

Aug 1, 2013

By C. J. Clayton, A. J. Haynes, D. A. Hickson, B. Thiele

The Meadowbank Gold Project, formerly owned by Cumberland Resources Ltd. and currently owned by Agnico Mines Ltd., is currently being developed approximately 70 km north of Baker Lake, Nunavut, in the eastern Canadian Arctic region. The Meadowbank Gold Project currently consists of a series of gold-bearing deposits within relatively close proximity to one another, which are planned to be mined primarily as a truck-and-shovel open pit operation using conventional gold milling and extraction. The mining plan indicates that approximately 20 million tonnes of ore will be mined over a mine life of eight to ten years. The operation will generate approximately 160 million tonnes of mine waste rock and about 20 million tonnes of tailings. The site is located in an area of continuous permafrost with mean annual average air temperature of -11°C and average annual precipitation in the range of 100 to 200 mm. Lakes cover a large portion of the site, including some of the ore deposits. The location of the site and the physical environment pose challenges to development. This paper presents some of the designs considered to effectively manage and utilize the waste products of mining at the project. Note that volumes, tonnages, construction concepts, and data presented in this paper are accurate for the time of writing and are subject to change and modification as the project progresses, additional modelling is carried out, and additional data are obtained.

Jan 1, 2007

By J. A. Hurd

Towards the goal of a better understanding of the structure-proton conductivity relationship in PEM materials, this project concerns the design of ordered polymeric solids containing well-defined sulfonate aggregates. The approach employed involves the templation of sulfonated monomers using core principles of crystal engineering. In addition to sulfonate groups, the monomeric units contain crosslinkable functionalities to enable formation of a covalently linked network. The templation strongly directs the construction of well-defined sulfonate clusters and aggregates. Structural, sorption and conductivity data for the networks will be shown.

Jan 1, 2005