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By L. Drisdelle, S. Gendron

"Survival in today's business climate requires participation of all employees in a Total Quality Management Program encompassing everything - ""safety, quality of products, quality ofet1ch and every job done, and of course production "". We all know what needs to be accomplished, but struggle with how to do it, especially in an industry which has not always experienced management/union cooperation, and mistrust is still present.This paper describes a process to improve team work and employee involvement in Inco's nickel carbonyl refinery at Copper Cliff The process involves facilitatorship training for all employees, and a system for reinforcing and accomplishing the required behavioural change. The system is described in detail and a number of examples are presented. At the refinery, the staff is starting to understand as Max DePree recently wrote ""Without Quality Behaviour, you cannot have Quality Product"". IntroductionThe Copper Cliff Nickel Refinery (CCNR) is Inco's largest and most modern nickel refinery, which celebrated its twentieth year of successful operation in April 1993.The heart of the refinery is the Inco pressure carbonyl (IPq plant which produces high purity nickel pellets and specialty powders by refining an approximate 80% nickel granule feed. The carbonyl plant is a modem chemical plant with very special and demanding requirements for safety and environmental protection due to the toxic nature of the refining gas.Since 1987, there has been an emphasis at CCNR on a comprehensive Total Quality Improvement (TQI) Program which was designed based on recognizing customers' needs for improved systems for quality management. This program is customer oriented and comprises such elements as team organizational concepts, customer audits, process assessment and internal quality auditing.A detailed review of progress was made in early 1991 and it became apparent that the ""ownership"" of the TQI program was not broad based. In fact, the program was very much a staff driven effort and fell far short of total employee involvement and relentless continuous improvement that are now considered essential to remain competitive and stay in business.Inco staff has now come to regard that early phase of our TQI program as ""the technical aspects of total quality improvement"".The safety experience was also puzzling. Even though the safety statistics were good with an average lost time frequency of 1.6 for the last five years, the perfonnance improvement had plateaued and remained pretty much the same. Clearly a new approach was required if significant progress and continuous improvement was to be made."

Jan 1, 1994

By J. S. Kirkaldy, W. J. Slater, G. R. Mason

Activation analysis for copper and manganese in 10 mg samples machined from aluminum-base diffusion couples has been used in the study of ternary diffusion in the Al-Cu-Mn system. The accuracy, economy and convenience of the method are considered to be very competitive with other methods for analysis of such small samples. Neutron-activated aluminum-zinc alloys in the range from 10 per cent to 100 per cent zinc have been equilibrated with a known volume and the vapors subsequently condensed and collected. The vapor pressures relative to pure zinc (the thermodynamic activities) have been determined at 550°C' by recording the relative count of /'-rays from zn65 in the collected samples. The method is a sensitive one, although subject to serious obstacles to experimental accuracy.

Jan 1, 1961

By John J. Barakso

A summary of geochemical dispersion processes is presented. Secondary and tertiary dispersion of uranium was examined at several uranium prospects in British Columbia. The vertical migration of uranium from bedrock (primary dispersion) through overburden into the various soil horizons, and into snow and plants, was studied, and relationships were sought to explain the dispersion patterns in the secondary and tertiary environments. Soil developments were examined to obtain information on factors affecting the dispersion of uranium in soil profiles and tertiary substances; samples were analyzed for a number of elements. Biogeochemical data indicate that plant geochemistry is a possible exploration aid in areas of heavy overburden owing to the high selectivity of certain plants for specific elements. Some new data on the geochemistry of snow are discussed as a matter of research interest in the tertiary dispersion of uranium. Analytical techniques and problems are discussed, particularly extraction techniques, which must be carefully chosen to give reliable information on uranium dispersion.

Jan 1, 1979

By M. B. Greyver

The results of laboratory tests on iron precipitation from non-decopperized nickel anolyte are discussed. The parameters (pH, oxygen consumption and stirring speed) for iron precipitation from the anolyte, using the oxygen in the air, were determined. In the experiments conducted under optimized conditions, the residual concentration of iron in the anolyte after precipitation was 0.7-2.7 mg/L, and the copper and nickel losses to the solid phase were 0.05-0.07% and 0.05-0.16%, respectively. The filtration ability of the iron slurry obtained was 2 to 5 times higher as compared to that after chlorine oxidation and oxyhydrolysis. The leaching of the non-ferrous metals from the iron cake made using the separate nickel anolyte purification process was possible by dissolution in sulphuric acid. It was established that after cobalt precipitation from the copper- and iron-depleted anolyte, the precipitates obtained had lower ratios of Fe:Co and Ni:Co.

Jan 1, 2006

By B. N. Nandi

This paper is a study of the application of the science of coal petrology to the use of coal in the iron and steel industry. The petrography of coal is given the most attention, with some mention of coal palynology. The history of the petrographical analysis of coal is first out-lined, with a description of the various coal entities, and then the apparatus and experimental techniques employed for coal evaluation are discussed. The coke stability factor and the relation of coke strength to petrographical data are also covered, and some space is given to the new science of coke microscopy, in particular its use in following the oxidation of coals.

Jan 1, 1966

By Sejong Kim, Younghoon Moon, Youngseon Lee, Eunyoo Yoon, Yonghyun Song

"Mg alloy has a high specific strength, however, their thickness reduction was limited on most parts because of their poor stiffness. Since the modulus of rigidity is an intrinsic property, improvement of modulus of rigidity to the enhancement of stiffness is impossible. Therefore, the modification of shape and structure is available method to enhance the stiffness of real part fabricated by Mg alloy sheet. There are many thin walled parts which are located in outer section of electromagnetic system.Poor stiffness is often shown on wide surface area part with steel sheet, which has also high modulus of rigidity. In these cases, various groove patterns are used to increase the stiffness of part. However, some different methods have to be used when general groove pattern can’t be used. So, we would like to propose some new method to high stiffness on thin walled precision forging of Al or Mg alloys.An effect of proposed method on stiffness enhancement can be confirmed by fabrication of prototypes as well as structure and forming analysis based on FEM."

Jan 1, 2015

By C. Rodgers, E. (Ted) Warren

"LocationThe Key Lake operation of Cameco Corporation is located at latitude 57°N in northern Saskatchewan, within the southem boundary of the Athabasca formation. The nearest city is LaRonge, located 240 km to the south. Access to the mine is by all-weather road and by private airstrip.Description of OperationThe mill was designed to produce twelve million pounds of uranium oxide (U3O8) a year from a feed grade of 2.4% U3O8. Current production is fourteen million pounds from 2.0% feed.Following grinding, the uranium is leached using sulphuric acid and oxygen in autoclaves. An eight thickener counter current decantation (CCD) circuit is used to separate the uranium-bearing solution from the solid waste residue. The uranium in solution is further purified in a solvent extraction circuit. The purified uranium is then precipitated using ammonia, calcined at 840°C, and packaged in drums for shipping to refineries. There is a crystallization circuit to recover excess ammonium sulphate produced in the process, and a waste treatment circuit.HistoryUranerz Exploration and Mining discovered the Gaertner and Deilmann orebodies in 1975 and 1976, respectively. Between 1975 and 1977, Uranerz conducted laboratory studies and delineated a process for the Key Lake ore known as the ""Bonn process."" In 1977, Sherritt Gordon Mines Ltd. was retained to conduct further studies in cooperation with U ranerz. The technical feasibility of the Bonn process was generally confirmed. Howeve1~ alternative processing methods also appeared feasible, and over the period 1978-1979, a detailed research and development program was conducted to finalize the processes to be used and to provide data for design of the plant."

Jan 1, 2000

By S. Dessureault

The relatively recent explosion of available data in all business sectors has induced a common expression of “drowning in data, starving for information.” The mining sector is affected by the information age through equipment-based sensors, process monitoring, and traditional enterprise data sources. Information technologists have developed techniques such as data mining that apply new and old statistical algorithms to large datasets. Mine planners and managers can apply these tools for improved planning and control, thereby increasing the use of the highly underutilized information system infrastructure in most modern mines. This paper describes the use of data mining and its enabling technology, data warehousing, in the development of an energy consumption model for large surface mines using real historical data.

Jan 1, 2007

By E. Swartzman

"IntroductionGENERALLY, the necessity for mining coals of higher impurity content, the drive for lower costs by intensive mine mechanization, changing market requirements, and the increasing competition of oil and natural gas, have continued to result in an upward rise in coal preparation, and have necessitated a more intensive study of coal preparation problems.Increasing adoption of •continuous mining equipment, for example, is introducing new problems in coal preparation. Limited experimental work in the United States (1) shows that the effect of the continuous miner on size distribution varies with the characteristics of the seam. In some seams, the fines problem is lessened, in others it is greatly aggravated. Generally there is a decrease in the relative amount of the top sizes (plus 2 in.) and a substantial increase in the intermediate sizes (down to about 1/8 in.). Contrary to expected results•, where continuous miners with vertical-moving cutting heads are used, an increase in impurities in the slack sizes does not necessarily occur where draw-slate is taken. This is because the draw-slate tends to be kicked out in lump form. However, if a seam contains bands •and lenses of impurities they are bound to be in the mined product."

Jan 1, 1952

"Block caving is the preferred underground mining method to profitably extract massive, low-grade orebodies; however, lack of cave access inhibits understanding the rockmass response to mining, which is needed for safer, more productive operations. Combining large datasets from multiple sources with virtual reality scientific visualization (VRSV) is an alternative method for understanding complex cave behaviour, by providing virtual access to the cave. A customized VRSV module was developed at UNSW Australia to investigate rockmass response to undercut developments at a case-study block caving operation. Time/sequence effects are investigated in rockmass response to blasting, which is an important factor in hard-rock mines.RÉSUMÉ La méthode d’extraction souterraine par blocs foudroyés est la méthode préférentielle pour extraire rentablement des gisements massifs à faible teneur. Toutefois, le manque d’accès à la chambre restreint la compréhension de la réponse de la masse rocheuse à l’exploitation, ce qui est nécessaire pour obtenir des opérations plus sécuritaires et plus productives. La combinaison de grands ensembles de données de multiples sources avec la visualisation scientifique par réalité virtuelle (VRSV) constitue un autre moyen de comprendre le comportement complexe de la chambre en fournissant un accès virtuel à la chambre. Un module de VRSV sur mesure a été développé à l’Université de Nouvelles-Galles du Sud (UNSW) en Australie afin d’étudier, dans une étude de cas d’une exploitation par blocs foudroyés, la réponse de la masse rocheuse aux développements de galeries de sous-cavage. Les effets de temps/séquence sont étudiés dans la réponse de la masse rocheuse au sautage, ce qui est un facteur important dans les mines de roches dures."

Jan 1, 2016

By M. J. Merwin

Heat treated seamless tubular products are processed in a fashion that can be easily modified to produce dual phase microstructures, through the implementation of intercritical soaking prior to quenching. Dual phase steels are known to possess low yield strength compared to tensile strength. The steel line pipe market is interested in low yield-tensile ratio materials for application in reel barge pipe laying operations. In the current work compositions of commercially produced material already in use for the line pipe market were examined and dual phase microstructures were successfully developed. The microstructure and properties of the materials were found to be stable over the range of intercritical temperatures employed. Tempering temperature and, somewhat unexpectedly, small chemistry differences were found to have the largest influence on properties. Excellent toughness performance was observed in samples tempered at temperatures in excess of 550°C. Tempering in this temperature regime produced materials with strength suitable for application as API X60 line pipe. A difference in tensile strength between steels of similar chemistry was observed, and is not fully understood at this time. Welding performance was considered through simulation of three regions of the heat-affected zone. Neither intercritical temperature, nor tempering temperature, were found to have a significant influence on the heat-affected zone properties. The peak temperature achieved in the thermal cycle was the only significant factor. The hardness of the heat-affected zone was found to increase continuously with increasing peak temperature. While toughness was found to be low for both partially-transformed and coarse-grain heat-affected zones, the toughness of the fine-grained heat-affected zone was substantially better. Based on the results found in this laboratory study, a limited production trial is expected.

Jan 1, 2005

By K. El-Ouassiti, M. Zouadi, C. Bazin, D. Hodouin

Data reconciliation techniques are used to attenuate the effect of measurement errors and estimate unmeasured variables. This paper illustrates the application of data reconciliation to hydrometallurgy processes using measurements from leaching and solvent extraction obtained from laboratory experiments. The application of data reconciliation provides an efficient way to detect gross and systematic errors and produces reliable performance indices for process evaluation.

Jan 1, 2005

By B. K. Bhattacharyya, Morley. L. W.

"The primary purpose of conducting aeromagnetic surveys in mineral areas, and interpreting the data thus obtained, is to aid in the extrapolation of the geology from known to unknown areas-both in a horizontal and vertical direction. This paper describes one of the steps in the process of interpretation which has, in the past, been neglected-that of mathematically or quantitatively treating the data in two-dimensional map form. For this, several techniques are available.These techniques determine the downward and up-ward continuation fields, the second vertical derivatives and the fields reduced to the pole from the total magnetic field data. Second vertical derivatives and downward continuation fields increase the resolution and sharpness in the observed magnetic anomalies and tend to outline the surface traces of causative bodies with a reasonable amount of success in most cases. The 'reduction to the pole' is a mathematical process of calculating the field at the north pole from the observed field so that the un-desirable effects of the dip and declination of the earth's field and of rock magnetization are eliminated.New and accurate means of carrying out these calculations have been developed by the Geological Survey of Canada. In this paper are also presented the results of a method for obtaining the symbol and numerical map of the processed data with the help of the printer associated with the computer. The tedious work of digitizing magnetic field values in a map can be speeded up by the use of a semi-automatic coordinatograph, with the aid of which field values can be accurately transferred to punched cards."

Jan 1, 1966

By K. Lillkung, J. Kourunen, M. Latva-Kokko

"Carbon-in-leach (CIL) and carbon-in-pulp (CIP) processes utilize activated carbon to adsorb solubilized gold for recovery. Due to carbon attrition and non-ideal carbon management, however, some of the gold is lost in carbon fines and to the solution. The carbon attrition mechanism inside CIL/CIP reactors is mainly abrasion-related. This is critical to gold loss since gold loading takes place predominantly in the outer shell of the carbon particles. Thus fine carbon dust has a relatively high gold content and such a small particle size that it cannot be captured with safety screens. The attrition rate depends on ore and carbon characteristics, but it is always proportional to the mixing power intensity. This rate can be minimized by continuous suspension level measurement and control of agitation speed. In addition, a novel tank bottom structure can significantly reduce the required mixing power input compared to a flat bottom tank. A major challenge in carbon management is infrequent and inaccurate measurement of carbon concentration in the reactors. In order to reduce soluble gold losses by means of improved carbon management, Outotec has been developing a continuous in-situ measurement for carbon concentration that is tolerant to changes in slurry density.INTRODUCTION Cyanide leaching has been utilized since the late 19th century as a standard technology for hydrometallurgical gold production. Since then, gold and silver recovery rates have increased due to technological development, but very similar recovery methods are still being used. The original recovery method was to use zinc precipitation – similar to the Merrill-Crowe process, which is still common for feed materials with low throughput and high silver content. However, in most cases, activated carbon recovery is preferred due to its improved efficiency. The carbon-in-pulp process (CIP) and its modification, carbon-in-leach (CIL), have a lower residual soluble gold level and are not similarly affected by soluble base metals. The main alternative for the use of carbon is ion exchange resins. The principle of resin processes is similar to the CIL/CIP processes, with a different type of adsorbent material. Carbon processes are usually preferred over resin processes due to the significantly higher cost of resin material and the possibility to use simpler, well-established technology with carbon processes."

Jan 1, 2017

By H. Bannach

"This paper focusses on what seem to be the leading indicators of prosperity in the minerals industry during this decade: the geographical distribution of deposits, environmental impact, capital allocation and acid consumption. There is a potential for meeting environmental criteria at a reasonable profit margin, but those with limited acid demand within economic range will face hard times to meet growing environmental concerns, resulting in additional mine closures. At the other end, those with old waste dumps who are thinking about smelting capacity additions will need capital influx at a much larger rate than ever before. All things considered, a change should be made in the way the world's copper reserves are computed, because there is a growing need to internalize these effects back to the ore blocks before a meaningful estimate of reserves becomes available.IntroductionThe copper industry has undergone several changes during the past decade, many of which were expected to take place because they rel1ect the economics of ageing mines. However, many others took place that shocked the industry because they were not completely under control. The focus of this paper is to rel1ect on those changes, and on market expectations for this decade that somehow depend on their impact.To review the prospects for new mine developments and expansions from an industry perspective to a full extent, it would be necessary to consider not only the deposits themselves, but also geographical constraints, environmental constraints, labour composition, technology development and use, the availability of capital, ownership issues, and integration within the industry. This paper, however, will concentrate on only some of the key elements that are believed to playa major role in shaping the market in the decade that has just begun. These elements, all interconnected, are:"

Jan 1, 1992

By Kari Niiranen, Andreas Boehm

LKAB (Luossavaara-Kiirunavaara AB) is operating underground iron ore mine, with three beneficiation and pelletizing plants in Kiruna, Northern Sweden. The wet low intensity magnetic separation (WLIMS) is regarded as the crucial part of silicate mineral separation from the ore. The Kiirunavaara iron ore deposit shows a rather low content of silica (ca. 2.3 to 3.3 % SiO2) but the silica grade is expected to increase in the deeper parts of the deposit. This can be problematic in the case of DR pellet quality with an average silica grade under 0.75 % SiO2. A laboratory scale methodology was developed for the systematic characterization of the ore for mineral processing with the focus on silicates at the Institute of Mineral Processing, University of Leoben. This methodology is combining mineralogical, geochemical and process mineralogical characteristics. Automated mineralogy (QEMSCAN) was used to study the modal mineralogy, the distribution of silicate minerals in different particle size classes after comminution, the deportment of silicon (Si) between various silicates and degree of liberation and intergrowth of magnetite and silicates. Based on the mineralogical investigations, actinolite, phlogopite and even quartz and albite are the predominating SiO2 bearing minerals in the ore. The important result of the investigations was the discovery of two separate subtypes within the high silica ore type B2 based on their mineralogy and mineral processing characteristics. The crucial part of the investigations of intergrowths and liberation of magnetite results was the magnetic separation tests carried out with the Davis magnetic tube. The binary intergrowths of magnetite and the silicate minerals (mostly actinolite) are the most common type of mineral association discovered. The significant characteristics in the intergrowths of magnetite and actinolite are the fine-grained magnetite inclusions in actinolite which may end up increasing the SiO2 grade in the magnetite concentrate despite magnetic separation.

Jan 1, 2016

By F. Mohamm

"Recent changes in regulations and scientific advances concerning selenium bioaccumulation have placed greater importance on non-biological treatment systems for selenium control. Mining wastewater contains hexavalent selenium (selenate) as the predominant aqueous species and possibly small amounts of tetravalent selenium (selenite). Non-biological removal of selenite is accomplished readily and cost effectively by ferric co-precipitation and adsorption using ferric oxyhydroxides sourced from ferric salts or iron anodes in electrocoagulation cells. Selenate on the other hand is difficult to remove. It is often incorrectly assumed that electrocoagulation is suitable for removing both selenite and selenate. Selenate removal efficiency by electrocoagulation is low and the amount of waste residue produced high. In contrast, BioteQ’s Selen-IX™ process removes selenate very efficiently and produces a much smaller amount of stable residue. The process combines selective ion exchange with electro-reduction of selenate in electrocells that physically resemble electrocoagulation cells but are designed and operated differently. This paper summarizes four years of pilot scale demonstration on a wide range of mine waters and discusses the key benefits and limitations of Selen-IX™. The pros and cons of combining ion exchange with electro-reduction in comparison to direct electro-reduction of selenate are also reviewed.INTRODUCTION Selenium in Mining and Mineral Processing Effluents Similar to sulphate and metals, selenium presence in mining and mineral processing wastewater originates from minerals contained in the mined deposits. Therefore, no organoselenium species are typically present in these kinds of waters and inorganic species including selenite (SeO32-), selenate (SeO42) and elemental selenium account for the majority, if not all, selenium present in these streams. Elemental selenium is not always present in mine water but is often contained in smelter wastewater. To comply with new environmental regulations, a successful water treatment plant must remove selenium from all these forms effectively and economically without generating by-products that are difficult to dispose of or manage. Elemental selenium can be dealt with using filtration or gravity separation in clarifiers often assisted by flocculants and/or coagulants. Mine impacted waters typically contain other forms of suspended solids which are removed from water in this way. Once the solids are removed, the selenium species that remain untreated are the dissolved forms. In mining waters this is mostly selenate with small fraction of selenite. In smelter wastewater, the majority could be selenite. It is well established that tetravalent selenium is readily removed from water by using ferric iron co-precipitation at pH > 4 (NAMC SWG, 2010). Ferric hydroxide/ferrihydrite solids act as the adsorbent for tetravalent selenium when it is in one of the ionic forms of biselenite or selenite. This treatment for tetravalent selenium is highly efficient. Therefore, tetravalent selenium removal is generally not an issue and is often easily incorporated into lime neutralization or unit operations such as electrocoagulation used for removing other metals present in mine impacted waters. Another option of dealing with tetravalent selenium is sulphide precipitation in acidic pH which produces SeS2 and can separate selenite from other metals and/or sludge produced at neutral to alkali pH."

Jan 1, 2017

By B. R. List, E. R. F. Lord

The Syncrude open pit mine, located near Fort McMurray in northeastern Alberta, produces approximately 410 000 tonnes of oil sand feed daily, which, after undergoing a bitumen extraction phase, generates approximately 315000 tonnes of tailings solids daily. The tailings are used to hydraulically construct containment dykes and supporting beaches of the storage facilities. Tailings deposition commenced in May 1978 with the commissioning of the Mildred Lake Settling Basin which is currently composed of approximately 600M m3of solid sand approximately 300M m3of contained fluids with fine tailings in suspension for consolidation. Two other storage facilities, commissioned over the past six years, have been developed to store sand and consolidated fine tailings referred to as mature fine tailings. Fine tailings reduction initiatives being developed will be successful in reducing future production of fine tailings volume by 20%. These initiatives include spiking (addition of fine tailings to coarse tailings lines for deposition), composite tailings (addition of gypsum to promote consolidation) and freeze/thaw dewatering, also to promote consolidation. The mandate of research efforts is to enhance tailings disposal and to develop economical and technically feasible reclamation initiatives. Final tailings landscapes will be geotechnically stable and ecologically productive to minimize or eliminate long-term liability. This technical paper will review the design philosophies of the current facilities and provide an overview of the areas of continuous improvement in the field of tailings management practices through the concerted research efforts and their implementation.

Jan 1, 1997

By X. Zhou

"Hydrogen induced failure and degradation in structural metals, namely hydrogen embrittlement, has been a long-standing industrial problem for more than one century and remains unsolved. Despite the proposal of numerous models, no consensus has been reached, and considerable discrepancies in experimental observations and theoretical calculations exist. One aspect that is central to the understanding of hydrogen embrittlement is the interaction between hydrogen and grain boundaries. In this study, we investigated the influence of several solute elements (i.e., Cr, Mo and Nb) on hydrogen segregation at the representative 9 grain boundary using first-principles calculations. Our results showed that the presence of Mo and Nb can reduce the tendency of hydrogen segregation at grain boundaries, while meanwhile enhance the grain boundary strength. This indicates that Mo and Nb are salutary elements that can be used to increase the material’s resistance to hydrogen embrittlement, providing new insights in designing hydrogen embrittlement resistant Ni alloys. INTRODUCTION Hydrogen embrittlement (HE), a phenomenon of hydrogen triggering premature failures in structural metals, has been a headache for industries ever since its first discovery one century ago (Johnson, 1874; Zhou, Marchand, McDowell, Zhu, & Song, 2016; Zhou, Ouyang, Curtin, & Song, 2016). It is well accepted that the segregation of hydrogen at microstructures such as grain boundaries (GBs) plays a key role in determining the occurrence and severity of HE. GBs are two-dimensional defects where significant local lattice distortion exist, which leads to large free volume and thus locations for hydrogen trapping and segregation. Numerous works have clarified GBs as the energetically preferable places for hydrogen segregation. For instance, Geng et al. demonstrated the preferential segregation of hydrogen at the S5(120) GB in several metals, and suggested a decohesion-type of HE in light of Rice-Wang thermodynamic theory (Geng, Freeman, & Olson, 2001). Birnbaum et al. illustrated that complete intergranular crack of Ni GBs can be induced by hydrogen segregation when the hydrogen concentration is sufficiently high, evidencing the significant role of hydrogen accumulation on GB weakening (Lassila & Birnbaum, 1987). Yamaguchi et al. demonstrated strong segregation hydrogen also occurs at S3 GBs in alpha-iron, showing that local hydrogen clustering (i.e., multiple hydrogen atoms, up to six, per unit cell) can be trapped at the S3 GB (Yamaguchi, Kameda, Ebihara, Itakura, & Kaburaki, 2012)."

Jan 1, 2017

By J. Olson

"A model was developed to use near-infrared (NIR) analysis of pulverized ore samples to estimate the recoverable gold content for ores from the Barrick Cortez Hills underground mine. Current routing practices use a ratio of the cyanide soluble gold content and fire assayed gold (CN/FA) to classify ores as oxide or refractory. Prediction accuracy of the NIR model was equivalent to the CN/FA ratio. Prediction accuracy was improved by combining the CN/FA ratio and the NIR spectra. Bootstrap validation estimates the root-mean-square error to be 9.92% with an estimated r-squared value of 0.893. This model will allow more accurate estimates of the variability in recoverable gold content throughout this mine. These data will aid in building an improved geo-metallurgical model or in making better informed routing decisions during the production cycle.INTRODUCTION The contained gold of an ore available for cyanidation is often related to subtle variations in the mineralogy. It is difficult and expensive to collect enough mineralogical information in order to predict how the variable mineralogy will impact the metallurgical results and project economics throughout the life of the mine or mill. Near-infrared spectroscopy may be an effective tool to rapidly and inexpensively collect discrete, quantitative mineralogical data for minerals that contain transition metal oxides, metal sulfides with semi-conduction properties, rare earth metals, and some chemical groups having di-pole covalent bonds such as carbonates, sulfates, and various types of clays (Hunt, 1977). Near-infrared spectroscopy can be a powerful tool for geo-metallurgical characterization of deposits where the presence of these minerals has direct or indirect relationships to metallurgical results such as grindability, regent consumption, or recovery. Near infrared spectroscopy is a rapid analysis that measures the intensity of reflected light in the near-infrared spectrum. The ranges for the ASD-Panalytical units used in this study extend through the visible spectrum and into part of the UV spectrum, reporting reflection by wavelength from between 350 nm to 2500 nm. Absorption peaks visible in this range are a result of interactions with outer valence elections or chemical bonds. The location and intensity of the peaks vary depending on the chemical composition and crystal structure of a solid indicating the presence and abundance certain minerals (Hunt, 1977; Clark, 1984)."

Jan 1, 2017