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By Misra VN

The carbon-carbon dioxide reaction is the rate determining step in industrial processes such as the rotary kiln direct reduction process for iron ores. The use of brown coal as a reductant in the rotary kiln process has been shown to result in higher throughputs and lower kiln temperatures. No experimental data has been reported on the effect of coal type or the use of brown coal chars. Methods of carbon-carbon dioxide reacti- vity measurement are discussed. None of the methods have been related to direct reduction practice. No standard test has been developed to assess the reactivity of brown coal chars to carbon dioxide. For routine comparative work the gas analysis method of Okstad and Hoy appears to be the most suitable although some modification to the experimental conditions is required. For detailed kinetic studies direct weighing techniques are to be preferred. The factors affecting the reactivity of brown coal char to carbon dioxide are reviewed. Numerous factors such as the origin of the coal, pretreatment and ,physical and chemical differences have been found to affect the reactivity of brown coal chars but no data has been reported on the effect of coal type on reactivity to carbon dioxide.

Jan 1, 1980

Christmas Island contains large deposits of phosphate minerals varying from high-grade calcium-phosphate (apatite) to lower grade iron and'aluminium phosphate (crandallite/millisite). The surface material is dominantly C-grade (Fe/Al) phosphate profiling into B-grade, a variable mixture of C- and A-grade ores, before reaching the high A-grade phosphate (apatite) which overlies a limestone Karrenfeld Base formation. A-grade ore is the basic phosphate used for the manufacture of superphosphate and phosphoric acid, whilst B-grade contains amounts of iron and aluminium which are unacceptable for these acidulation processes. Research into methods of separating the finer iron and aluminium phosphates from the coarser calcium phosphates has led to the development of wash-screen processes enabling recovery of 50 to 60%, as A-grade phosphate. Developmental stages included laboratory investigations, mineralogical studies, pilot tests leading the initial 20 tph prototype production unit and the current 100 tph production wash/screen plant, commissioned early in 1970 at Christmas Island.

Jan 1, 1971

By S Rice, A Midlin

Many of the stacking and reclaiming machines employed in the mining industry today are operating in ways that were never envisaged in the days before they were commissioned, with greater throughput, increased annualised operating hours and load cycles well in excess of their original specification requirements being the norm. In many cases these machines were supplied prior to the widespread use of finite element modelling or, in the era when such software became commercially available, those supplied designed using simplified and/or coarser meshes than would be employed today. With many of these machines being expected to operate for many years to come, it is important that their ongoing reliability be maintained and their operational limits understood. In this paper, a case study is used to outline the method required for estimating the fatigue life already consumed and the likely real life left in a machine. By reference to the machineÆs prior operating history, the use of strain gauges in the field and the development of finely meshed finite element analysis (FEA), a coherent picture of the machineÆs operational state can be generated and then investment/maintenance decisions made to ensure continuity of machine operation.

Jan 1, 2007

By Singh TN

Rampura-Agucha Zinc-Lead deposit is unique as it is reported for the first time in the gneissic terrain with a rich oregrade quality of early to middle Proterozoic of Bhilwara supracrustal belt in the Precambrian of Northwest India. These sulphide ores are mostly confined to the graphite bearing Quartzofelspathic gneisses with intermittent bands of Calc-Silicate granofels and amphibolite. The ore and country rock mineralogy and their textural features are indicative of highly metamorphosed deposit and further the presence of marmatite and monoclinic phyrrhotite revealed high temperature environment of deposition.The present paper deals with some of the ideas about the ore genesis and petrographics of the associated rocks for Rampura-Agucha Zinc-Lead deposits of Bhilwara District (Rajasthan).

Jan 1, 1990

By Jackson S

An investigation into different aspects of importance in the understanding of explosibility of hybrid mixtures of coal dust, air and gases potentially found within mine workings through a comprehensive laboratory program of explosibility tests was conducted. Plotting of test results revealed that conditions of potential explosibility could be described using two dimensional flammability limit surfaces- for coal dust/oxygen; methane/oxygen; and coal dust/methane mixtures. From these plots, the three dimensional flammability envelopes defining the explosibility of the coal dust/methane/oxygen mixtures can be defined and illustrated for a coal sample. The surfaces of the three dimensional envelope describe limits which separate inert mixtures of coal dust and methane at varying oxygen levels from those concentrations which are ignitable under defined conditions. It is considered appropriate to generalise that the geometric shapes of these limit regions are applicable to all type classifications of coal dust. There are practical applications of these results to the underground environment.The action of free radical initiators in the propagation of a methane gas explosion was examined for its applicability to the flammability of coal dust/gas/air mixtures. The oxides of nitrogen or NO x radicals have influence upon the lean limits of flammability of hybrid mixtures and this is illustrated by use of three dimensional coordinate geometry. Gases can be introduced to the underground environment through the exhaust gases of diesel equipment. It is concluded that radical species can substantially increase the flammability of gas and dust flames and as a consequence raise risk of mine atmosphere explosibility.

Jan 1, 1998

By R Bertuzzi

Permanent rock bolts in civil engineering are taken as having to serve their design purpose for at least 50 years. In many projects the design life is specified as greater than 100 years. A review of recent Australian tunnelling projects shows that substantial differences exist in the level of corrosion protection provided for permanent steel shafted rock bolts. This paper reviews the current state of practice and sets out what the authors consider to be appropriate requirements for corrosion protection.

Jan 1, 1999

Hindustan Zinc Limited has successfully installed an In-Stream Analysis and Process Control System in the flotation section of the Balaria Lead-Zinc concentrator at Zawar Mines. The system comprises In-Stream Analysis to continuously monitor lead and zinc levels in feed, concentrates and tailings streams, field instrumentation for reagent distribution and flotation cell level control linked to a central Distributed Control System for supervisory control functions. An intensive training scheme was conducted by the system supplier for concentrator metallurgical and instrumentation engineers. Since commissioning of the system in April 1989, Hindustan Zinc has enjoyed the benefits of improved lead, zinc and silver recoveries, improved concentrate grade control and reduced reagent costs.

Jan 1, 1991

This paper addresses the area of utilising automatic data capture systems in the metalliferous mining environment for the purpose of tracking personnel and vehicles, for both safety and productivity purposes.As automatic data capture systems in the form of barcodes have revolutionised the stock control procedures in retail establishments in recent years, so too will similar systems in the form of radio frequency identification products (an electronic version of the barcode) transform the way in which many aspects of mining operations will be managed.

Jan 1, 1992

An integrated computer system (the Short Term Mine Management System) has recently been developed by B.H.P. Steel Long Products Division in Whyalla, South Australia for use in their open pit iron ore mines.The system incorporates blast design, comprehensive blasthole data handling, grade coilrol, stockpile scheduling and management and reconciliation within a single, user friendly computer package. The blast design system allows the blasting engineer to design the layout of holes for a production blast using geological information projected from the bench above to aid in appropriate blasthole positioniog in particular rock types. The grade control system allows mining blocks to be designed and evaluated from blasthole information using interactive graphics processes. The handling, storage and reporting of blasthole survey, assay and geological logging data forms an integral part of this system. Stockpiles can be constructed from a number of mining blocks to reach a specified target grade using the stockpile management system. Although not yet integrated, the reconciliation system will reconcile stockpiles back to mining blocks and to the geological model.

Jan 1, 1990

By F Cappuccitti

A colourimetric technique, originally developed for methyl iso butyl carbinol (MIBC) based on the Komarowsky reaction, has been extended to a wide range of common mineral flotation frothers. The procedure, which is briefly described, is shown suited to on-site determinations in a campaign at Kennecott Utah Copper Copperton Concentrator (Rio Tinto). Some observations are described, including: frother (MIBC) concentration evolution down a bank, frother distribution between pulp and froth phases, and loss of frother over time due to adsorption on certain minerals. A possible interference with a fuel oil addition was overcome. MIBC in recycle water was also measured. The ability to monitor frother easily will help interpret gas dispersion behaviour and should permit further optimisation of flotation cell hydrodynamics and chemistry. The capability to directly measure should help optimise the type, amount and location of frother addition, and to assess frother recycled with reclaim process water.

Jan 1, 2005

By G Chitombo, M Ruest

In surface mining, studies of the kinematics of blasted rocks using high speed film/video image analysis have allowed the estimation of the starting time, direction and magnitude of visible movement of fixed sections of the free face. Horizontal displacement versus time plots from discrete targets at the face generally report changes in slope over very small time intervals. These changes indicate step increases in velocity due to the action of explosive gases. In practice, the onset of rock mass movement, different to localised spalling, has been associated with a response time which exceeds the combined times of detonation, propagation and reflection of stress waves. This time is referred to as minimum response or burden movement time. As an engineering index, burden movement time has been used to provide guidelines for the selection of inter-hole and inter-row delay sequences in production blasting. With respect to improving breakage and fragmentation, it has been demonstrated that the delay interval between adjacent explosive charges should be less than the expected burden movement time. Similarly to reduce confinement between rows, delay intervals should exceed the expected burden movement time. The Hybrid Stress Blasting Model (HSBM) is a modelling framework that dynamically links an ideal and non-ideal explosives detonation code to a geomechanical rock model. This blast simulation tool is aimed at analysing the role played by different explosive formulations in fragmenting and/or damaging various rock types under different degrees of confinement. In the current framework, the rock behaviour under extremely high pressures and loading rates is calibrated from shock tests and the role of the explosive in fracture growth is accounted for and assumes a compressible fluid flowing through the explicit fracture network. The model is being developed as part of an international collaborative research project funded by a consortium of companies comprised of explosive and equipment suppliers and major mining houses. As part of the development and validation of the HSBM project, data from literature addressing the kinematics of the rock mass (ie burden displacement, face velocities and response times) has been collated and used to evaluate the current version of the code. A series of numerical experiments have been conducted with the view to: evaluate the response of the rock mass to changes in burden distance given by the impact of both stress waves and radial gas flow pressure;compare the modelling outcomes in terms of displacement, response time and face velocities to documented field observations; andcompare stress induced and stress/gas induced modes in terms of burden displacement outcomes. Results from these experiments have shown that in its current form the model is able to capture the trends observed and measured in practice. This is with respect to the simulation of burden displacement, response time and average face velocities for different geometries and charging conditions. The experiments have served as consistency checks which form part of an ongoing and comprehensive evaluation and validation of the HSBM code also aimed at addressing some of its current limitations.

Jan 1, 2007

By P Barrette

The manual gravimetric drying moisture determination methods currently employed by most mineral processing plants fail to provide timely and accurate information required for automatic control. The costs associated with transporting and handling concentrates represent a major portion of the overall treatment price. When considering the cash flow of a mining operation that is governed by both the smelter contract, with moisture penalties and the quantity and quality of the concentrates shipped, any tool that provides real-time feedback on the process is vital (Edwards, RP 1994). The introduction of an on-line moisture sensor would become a welcome addition to the process control field instrumentation package now applied. A novel on-line determination system for ore concentrate moisture content would replace the tedious manual procedure. Since the introduction of microelectronic-based control systems, operators have strived to reduce the treatment costs to the minimum. Therefore a representative and timely determination of on-line moisture content becomes vital for control set points and timely feedback. Reliable sensors have long been on the æwish listÆ of mineral processors since the problem has always been that you can only control what you can measure, (Konigsmann, 1990). Today, the task of moisture determination is still done by the classical technique of loss in weight utilising uncontrolled procedures. These same methods were introduced in the earliest base metal concentrators. Generally, it is acceptable to have ore concentrate moisture content vary within a range of seven to nine percent, but controlling the moisture content below eight percent is a difficult task with a manually controlled system. Many times, delays in manually achieving reliable feedback of the moisture content results in the moisture varying from five to twelve percent before corrective actions can be made. This paper first reviews the traditional and widely available methods for determining moisture content in granular materials by applying physical principals and properties to measure moisture content. All methods are in some form affected when employed on mineral ore concentrates. This paper introduces and describes a unique and promising novel on-line moisture sensor employed for mineral processing de-watering applications, which not only automates the tedious tasks but also results in reliable moisture feedback that can be used in the optimisation of the de-watering process equipment such as pressure or vacuum filters and fuel-fired driers. Finally, two measurement applications will be presented to indicate the usefulness and to summarise the measurement requirements for the proposed method of employing drag force and mechanical properties of the material itself to determine the moisture content. The commercial model of the equipment is described with the features and benefits to the users summarised.

Jan 1, 2003

The Japanese Government promulgated the æLaw Concerning Special Measures Against DioxinsÆ on 16 July 1999 and it was enforced on 15 January 2000. This is a unique law specialised to protect the environment by the control of dioxin emissions from waste incinerators and several industrial processes. In this law, a few metallurgical processes other than waste incinerators are designated as æspecified facilitiesÆ emitting certain dioxins. Thus, emission standards for dioxins to the air were set for electric arc furnaces (EAF) for steelmaking, iron ore sintering, zinc recovery from EAF dust and aluminum recycle processes. In this paper, the inventory of dioxin emissions for Japan and the recent research and development to reduce emissions from those processes are introduced. Further, some details on the formation mechanism of dioxins and future subjects for effective control of their emissions are discussed.

Jan 1, 2002

China has abundant bauxite resources, but these resources are mostly of a diaspore, which has a feature of low Al2O3 to SiO2 mass ratio, typically ranging from four to six. Compared to other materials, this kind of raw materials consumes more alkaline and energy in the process of metallurgy, and incurred a high alumina production cost. To solve this problem, researchers in China have done a lot of work on removing of the silicon from bauxite. Under the impetus of these works, in 2003, the first flotation plant of diasporic bauxite in the world was constructed in Zhongzhou, Henan, China. Seven years of operating experience shows that this technology can signifi cantly reduce the costs of following-metallurgy processing. These efforts are an important reference for the processing of similar resource. In general, for Western scholars it is diffi cult to fully understand these works because most of them are published in Chinese. In this paper, a detail introduction for the research progress on China bauxite de-silica flotation was presented, these works involved crystal chemistry, wettability of bauxite minerals, collector and modifi er in bauxite fl otation and flotation practice, etc.

Sep 13, 2010

THERE are few industrial and metallurgieal processes which do not require the application of heat energy, and the modern demand for increased working efficiency has resulted in attention being paid to temperature control as a means of ensuring fuel economy and more efficient plant operation. In general, mill accuracy required is not very contant in laboratory work, and few industrial operations are controlled to within less than 5° while in many cases greater limits are allowable. Almost every thermal property of matter has been suggested as a basis for the construction of pyrometers, but the thermo-electric type finds by far the widest application, and hence this paper will deal only with the principles, construction, and uses of this type of instrument. THERMOELECTRIC PYROMETRY.In the year 1821 Seebeek discovered that if the ends of two dissimilar metal wires were joined and one junction heated, a current flowed in the circuit, and the KMF (electro-motion force) set up could be measured by inserting a galvanometer at the cold junction. The phenomenon was not thoroughly investigated for many years, but, as the demand for high-temperature thermometers increased, several investigators, of whom Le Chatelier was one of the pioneers, successfully endeavoured to utilize the principle in pnometric construction. The couples which gave the most satisfactory results were discovered, improvements were made in material and design and the present-day type of instrument gradually evolved. The apparatus consists of three main parts, viz. (1) The thermo-couple itself of two dissimilar metal or alloy wires together at one end. (2) The leads which connect the terminal of the thermo-couple with the measuring instrument.

Jan 1, 1923

By L M. Lobato, J C. S Seoane, F J. Baars

The Carajßs Province presents several volcano-sedimentary sequences that comprise the Itacai·nas Supergroup. The rocks represent bimodal volcanism, and clastic and chemical sedimentation in relatively unstable basins subject to recurrent structural events with subsidence and volcanism. The Grpo Parß Group represents one of these sequences with mafic volcanic rocks that enclose discontinuous jaspilite lenses, with development of large high-grade orebodies (Fe >65 per cent). This unit is named the Carajßs Formation and presents peculiar characteristics compared to other iron districts in the world, thereby departing from the classic Lake Superior or Algoma iron formation types. Owing to the dense vegetation, lack of outcrops and harsh landscape, the structural analysis of the district can only be accomplished by combination of regional field work, detailed structural work on the open pits, and remotely sensed image interpretation, in this case Landsat ETM7, JERS-1 images and the SRTM digital terrane model. The regional trend of the several sequences of the area is approximately N-S and the structure is dominated by a flattened flexural fold system with axes moderately dipping WNW, intersected by several strike-slip faults subparallel to their axial plane. The Serra dos Carajßs represents an s-shaped synform-antiform pair, herein named the Carajßs Fold. This regional structure is partially disrupted by the Carajßs Shear Zone that divides it in the northern (Serra Norte) and the southern (Serra Sul) Ranges and also probably prepared the terrane with the development of pathways for mineralising hydrothermal fluids forming large high-grade massive iron bodies. Syntectonic granitic bodies played an important role in the structural evolution of the area as well. They caused localised ductile flattening deformation and thermal contact metamorphism in surrounding terranes. The Estrela pluton, for instance, was responsible for the discontinuity of the regional trend between the Serras do Rabo and Leste. The Carajßs Province is regionally the upper crustal product of a very shallowly eroded dome-and-keel geometry of Neo-Archaean volcano- sedimentary units intruded by syntectonic calc-alkaline intrusives and overlying pre-existing infracrustal rocks. The lithostructural data suggest continental-margin back-arc basin development and closure in an oblique collision belt, with N-S shallow crustal shortening, parallel to the inferred pre-existing strike of the stratigraphy.

Jan 1, 2005

By P Hollings, J Holliday

Porphyry copper, gold and molybdenum deposits form in subduction-related settings in association with calc-alkalic or alkalic magmatism. Hydrothermal alteration assemblages are zoned, with potassic cores and propylitic haloes overlain by extensive domains of clay alteration and silicification (lithocaps). Copper sulfides, gold and molybdenite typically occur in veins or hydrothermal breccias, and less significantly as wall rock replacements. Epithermal deposits may form above or to the side of porphyry systems, and may be juxtaposed into the core of a porphyry deposit if rapid uplift and exhumation occur through the life of the magmatic-hydrothermal system. Volcanichydrothermal breccia pipes (ædiatremesÆ) commonly form late in the life of a porphyry system. They may contain clasts of porphyry-style mineralisation, and can host significant epithermal gold resources. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

This paper presents the water management plan of the Mae Moh Project in the North of Thailand, which includes a large lignite opencast mine and thermal power plants. Lignite production will increase from the present 5.5 million tons per annum to approximately 20 million tons per annum by 1995 when the pit area will be about 20 sq.km. and the depth at over 300 meters. Seven power plants are proposed of which two are under construction. The total capacity to be installed is 2,925 MW. The principles considered for water management are firstly flood protection, including drainage of the mining pit and diversion of the Mae Moh stream away from proposed future mining areas; and secondly, a plan to meet the water requirement of the thermal power plants, while maintaining downstream supplies for irrigation and other purposes. The limited annual run-off of Mae Moh and Mae Chang watershed basins are inadequate for the proposed power plants. A study has been prepared to compare two approaches, namely conveying water from remote watersheds to meet the water requirement of the power plants up to total installed capacity; or by limiting future total generation, at the existing site, to only 2025 MV.

Jan 1, 1988

By E Whiteman, L Reyneke, H Horsch

Heavy mineral sand deposits are a source for the economically important element titanium, which is contained in minerals such as ilmenite and rutile. In heavy mineral deposits ilmenite displays various degrees of alteration. Natural weathering of ilmenite involves the removal of Fe and thus results in an increase in the Ti-content. Minerals such as pseudorutile, ferropseudobrookite, anatase and the ill-defined mineral aggregate leucoxene, which consists mainly of various amounts of remnant ilmenite, pseudorutile, ferropseudobrookite and anatase, are typical replacement products of ilmenite. Ferropseudobrookite occurs as a recrystallised, optically and chemically distinct mineral phase. Textural relationships suggest a diversity of physicochemical conditions including weathering and metamorphism that led to the formation of complex mineral assemblages and textures. In the heavy minerals industry the alteration products of ilmenite are generally referred to as æaltered ilmeniteÆ and/or leucoxene. The distinction between æaltered ilmeniteÆ and leucoxene is not consequently defined and is very much dependent on economic factors and specific mining operations (ie determined by deposit specific mineral assemblages). Generally the term leucoxene is used in the heavy minerals industry as a collective description for ilmenite alteration products with TiO2-components ranging from 65 - 95 per cent. A detailed comparative mineralogical investigation including microscopic, SEM and QEMSCAN« techniques show that it is possible to identify and quantify the replacement products of ilmenite on a micron scale. QEMSCAN« generated particle maps were graphically compared with photomicrographs taken by applying reflective light microscopy. The resulting information can be integrated over the entire sample with respect to composition, absolute and relative mineral abundances, grain sizes, volumes, densities, textural relationships and liberation potentials. This provides a powerful tool for a first appraisal of the physicochemical behaviour of bulk samples and individual particles during metallurgical processing.

Jan 1, 2008

By Skaviniak M

Some better perspectives applying to the exploitation and dressing of polymetallic ores in the Banskfa. gtiavnica-Hod- rusea Ore District are supposed to be achieved after a suc- cessful investigation and proving there the existence of deep-seated mineralization as well as due to increasing de- mand for non-ferrous metals and consequently to higher mar- ket prices of those recently noticed. With respect to the present situation in mining and to the further technical development as well, a several times higher exploitation may be in this region expected, especially in the deeper .eated parts of the deposit. When solving the tasks of a complex economic exploitation over the whole region, consi- derable attention is paid to regional relations and impact studies (due to expected exploitation and ore dressing but also to very difficult problems of dewatering (drainage pro- blems-). It will be first of all necessary to find there an equilibrium between the consequences resulting from the re- naissance of mining industry and environmental requests un- dispensable for the city of Banska 9tiavnica and the other neighbouring towns in the vicinity of mining plants.

Jan 1, 1988